EA201170909A1 - Новые металлоценовые соединения, катализаторы, включающие такие соединения, способ получения олефинового полимера с использованием таких катализаторов и олефиновые гомо- и сополимеры - Google Patents
Новые металлоценовые соединения, катализаторы, включающие такие соединения, способ получения олефинового полимера с использованием таких катализаторов и олефиновые гомо- и сополимерыInfo
- Publication number
- EA201170909A1 EA201170909A1 EA201170909A EA201170909A EA201170909A1 EA 201170909 A1 EA201170909 A1 EA 201170909A1 EA 201170909 A EA201170909 A EA 201170909A EA 201170909 A EA201170909 A EA 201170909A EA 201170909 A1 EA201170909 A1 EA 201170909A1
- Authority
- EA
- Eurasian Patent Office
- Prior art keywords
- catalysts
- copolymers
- substituent
- branched
- molecular weight
- Prior art date
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/04—Monomers containing three or four carbon atoms
- C08F10/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/642—Component covered by group C08F4/64 with an organo-aluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/04—Monomers containing three or four carbon atoms
- C08F210/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Crystallography & Structural Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Abstract
Представлены некоторые металлоценовые соединения, которые при использовании в качестве компонента в катализаторе на носителе для полимеризации в промышленно релевантных условиях полимеризации обеспечивают возможность получения высокой молекулярной массы гомополимеров или сополимеров, таких как полипропилен или пропилен/этиленовые сополимеры, без необходимости в каком-либо α-разветвленном заместителе в каком-либо из двух доступных 2-положений инденильных лигандов. Заместитель во 2-положении одного инденильного лиганда может представлять собой любой радикал, включающий водород, метил или любой другой С-Суглеводород, который не является разветвленным в α-положении, и заместитель во 2-положении другого инденильного лиганда может представлять собой любой C-Суглеводородный радикал, при условии, что этот углеводородный радикал является разветвленным в β-положении, и что β-атом углерода является четвертичным атомом углерода и частью моноциклической углеводородной системы. Данная металлоценовая топология позволяет получить высокую температуру плавления, очень высокую молекулярную массу гомополипропилена и очень высокую молекулярную массу сополимеров на основе пропилена. Кроме того, уровни активности/производительности катализаторов, включающих металлоцены по настоящему изобретению, являются исключительно высокими.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PCT/US2008/014144 WO2010077230A1 (en) | 2008-12-31 | 2008-12-31 | New metallocene compounds, catalysts comprising them, process for producing an olefin polymer by use of the catalysts, and olefin homo- and copolymers |
Publications (1)
Publication Number | Publication Date |
---|---|
EA201170909A1 true EA201170909A1 (ru) | 2012-01-30 |
Family
ID=40936621
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EA201170909A EA201170909A1 (ru) | 2008-12-31 | 2008-12-31 | Новые металлоценовые соединения, катализаторы, включающие такие соединения, способ получения олефинового полимера с использованием таких катализаторов и олефиновые гомо- и сополимеры |
Country Status (10)
Country | Link |
---|---|
EP (1) | EP2384343A1 (ru) |
JP (1) | JP2012513463A (ru) |
KR (1) | KR101351103B1 (ru) |
CN (1) | CN102257020B (ru) |
BR (1) | BRPI0823407A2 (ru) |
EA (1) | EA201170909A1 (ru) |
MX (1) | MX2011006667A (ru) |
SG (1) | SG172454A1 (ru) |
WO (1) | WO2010077230A1 (ru) |
ZA (1) | ZA201105497B (ru) |
Families Citing this family (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2402353B1 (en) | 2010-07-01 | 2018-04-25 | Borealis AG | Group 4 metallocenes useful as catalysts for the polymerization of olefins |
ES2565438T3 (es) | 2010-07-01 | 2016-04-04 | Borealis Ag | Proceso para la polimerización de olefinas usando metalocenos del grupo 4 como catalizadores |
EP2573091A1 (en) | 2011-09-23 | 2013-03-27 | Lummus Novolen Technology Gmbh | Process for recycling of free ligand from their corresponding metallocene complexes |
EP2722345B1 (en) | 2012-10-18 | 2018-12-05 | Borealis AG | Catalyst for the polymerisation of olefins |
EP2722344B1 (en) | 2012-10-18 | 2017-03-22 | Borealis AG | Polymerisation process |
EP2722346A1 (en) | 2012-10-18 | 2014-04-23 | Borealis AG | Polymerisation process and catalyst |
JP6176015B2 (ja) | 2012-11-01 | 2017-08-09 | 日本ポリプロ株式会社 | メタロセン錯体およびオレフィンの重合方法 |
JP5710035B2 (ja) | 2013-02-27 | 2015-04-30 | 日本ポリエチレン株式会社 | メタロセン化合物およびオレフィン重合体の製造方法 |
JP5695687B2 (ja) | 2013-03-05 | 2015-04-08 | 日本ポリエチレン株式会社 | エチレン/α−オレフィン共重合体の製造方法 |
US9938364B2 (en) | 2013-07-17 | 2018-04-10 | Exxonmobil Chemical Patents Inc. | Substituted metallocene catalysts |
CN105358589B (zh) | 2013-07-17 | 2018-07-03 | 埃克森美孚化学专利公司 | 金属茂和由其衍生的催化剂组合物 |
US9464145B2 (en) | 2013-07-17 | 2016-10-11 | Exxonmobil Chemical Patents Inc. | Metallocenes and catalyst compositions derived therefrom |
US9458260B2 (en) | 2013-07-17 | 2016-10-04 | Exxonmobil Chemical Patents Inc. | Process using substituted metallocene catalysts and products therefrom |
WO2015009473A1 (en) | 2013-07-17 | 2015-01-22 | Exxonmobil Chemical Patents Inc. | Cyclopropyl substituted metallocene catalysts |
ES2612627T3 (es) | 2013-07-24 | 2017-05-17 | Borealis Ag | Proceso |
KR102405286B1 (ko) * | 2017-12-06 | 2022-06-02 | 주식회사 엘지화학 | 메탈로센 담지 촉매의 제조방법, 상기 제조방법으로 제조된 메탈로센 담지 촉매, 및 이를 제조하여 제조한 폴리프로필렌 |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE69941894D1 (de) * | 1998-02-10 | 2010-02-25 | Artemis Medical Inc | Okklusions-, verankerungs-, span- oder stromsteuergerät |
CA2395552C (en) * | 1999-12-23 | 2010-02-16 | Basell Polyolefine Gmbh | Transition metal compound, ligand system, catalyst system and the use of the latter for the polymerisation and copolymerisation of olefins |
CN1274701C (zh) * | 2000-06-30 | 2006-09-13 | 埃克森美孚化学专利公司 | 用于烯烃聚合的含有桥接4-苯基-茚基配体的金属茂 |
US7232869B2 (en) * | 2005-05-17 | 2007-06-19 | Novolen Technology Holdings, C.V. | Catalyst composition for olefin polymerization |
JP5598856B2 (ja) * | 2007-10-25 | 2014-10-01 | ルムス・ノボレン・テクノロジー・ゲゼルシャフト・ミット・ベシュレンクテル・ハフツング | メタロセン化合物、それを含む触媒、その触媒を使用するオレフィンポリマーの製造プロセス、ならびにオレフィンホモポリマーおよびコポリマー |
ATE547439T1 (de) * | 2007-10-25 | 2012-03-15 | Lummus Novolen Technology Gmbh | Racemoselektive synthese von ansa-metallocen- verbindungen, ansa-metallocen-verbindungen, diese enthaltende katalysatoren, verfahren zur herstellung eines olefinpolymers durch verwendung der katalysatoren und olefinhomopolymere und - copolymere |
-
2008
- 2008-12-31 EP EP08876396A patent/EP2384343A1/en not_active Withdrawn
- 2008-12-31 JP JP2011543489A patent/JP2012513463A/ja not_active Ceased
- 2008-12-31 MX MX2011006667A patent/MX2011006667A/es not_active Application Discontinuation
- 2008-12-31 CN CN200880132439.2A patent/CN102257020B/zh not_active Expired - Fee Related
- 2008-12-31 KR KR1020117016447A patent/KR101351103B1/ko not_active IP Right Cessation
- 2008-12-31 SG SG2011048345A patent/SG172454A1/en unknown
- 2008-12-31 BR BRPI0823407-8A patent/BRPI0823407A2/pt not_active IP Right Cessation
- 2008-12-31 EA EA201170909A patent/EA201170909A1/ru unknown
- 2008-12-31 WO PCT/US2008/014144 patent/WO2010077230A1/en active Application Filing
-
2011
- 2011-07-26 ZA ZA2011/05497A patent/ZA201105497B/en unknown
Also Published As
Publication number | Publication date |
---|---|
BRPI0823407A2 (pt) | 2015-06-16 |
EP2384343A1 (en) | 2011-11-09 |
KR101351103B1 (ko) | 2014-01-14 |
JP2012513463A (ja) | 2012-06-14 |
ZA201105497B (en) | 2012-04-25 |
CN102257020B (zh) | 2014-04-02 |
SG172454A1 (en) | 2011-08-29 |
WO2010077230A1 (en) | 2010-07-08 |
CN102257020A (zh) | 2011-11-23 |
MX2011006667A (es) | 2011-07-20 |
KR20110094349A (ko) | 2011-08-23 |
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