JP2012513463A - 新たなメタロセン化合物、それを含む触媒、その触媒を使用するオレフィンポリマーの製造プロセス、ならびにオレフィンホモポリマーおよびコポリマー - Google Patents
新たなメタロセン化合物、それを含む触媒、その触媒を使用するオレフィンポリマーの製造プロセス、ならびにオレフィンホモポリマーおよびコポリマー Download PDFInfo
- Publication number
- JP2012513463A JP2012513463A JP2011543489A JP2011543489A JP2012513463A JP 2012513463 A JP2012513463 A JP 2012513463A JP 2011543489 A JP2011543489 A JP 2011543489A JP 2011543489 A JP2011543489 A JP 2011543489A JP 2012513463 A JP2012513463 A JP 2012513463A
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- Prior art keywords
- group
- methyl
- carbon atoms
- indenyl
- dimethylsilanediylbis
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
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- 0 C*C1C(C)(C2)C2C2C(*)=C(*)C(*)=C(*)C2C1* Chemical compound C*C1C(C)(C2)C2C2C(*)=C(*)C(*)=C(*)C2C1* 0.000 description 5
- XDTMQSROBMDMFD-UHFFFAOYSA-N C1CCCCC1 Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 2
- NFJPEKRRHIYYES-UHFFFAOYSA-N C=C1CCCC1 Chemical compound C=C1CCCC1 NFJPEKRRHIYYES-UHFFFAOYSA-N 0.000 description 1
- YISLOVJGEWFVAQ-UHFFFAOYSA-N CCC1(CC(C2S)=Cc3c2cccc3-c2ccc(C(C)(C)C)cc2)CCCCC1 Chemical compound CCC1(CC(C2S)=Cc3c2cccc3-c2ccc(C(C)(C)C)cc2)CCCCC1 YISLOVJGEWFVAQ-UHFFFAOYSA-N 0.000 description 1
- GTTUKNWHBBEELY-UHFFFAOYSA-N CCOC(C(Cc(cccc1)c1Br)C(OCC)=O)=O Chemical compound CCOC(C(Cc(cccc1)c1Br)C(OCC)=O)=O GTTUKNWHBBEELY-UHFFFAOYSA-N 0.000 description 1
- WGVYCXYGPNNUQA-UHFFFAOYSA-N Cc1c(CBr)cccc1 Chemical compound Cc1c(CBr)cccc1 WGVYCXYGPNNUQA-UHFFFAOYSA-N 0.000 description 1
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/04—Monomers containing three or four carbon atoms
- C08F10/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/642—Component covered by group C08F4/64 with an organo-aluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/04—Monomers containing three or four carbon atoms
- C08F210/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Crystallography & Structural Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PCT/US2008/014144 WO2010077230A1 (fr) | 2008-12-31 | 2008-12-31 | Nouveaux composés de métallocène, catalyseurs comprenant ceux-ci, procédé pour produire un polymère d'oléfine par utilisation des catalyseurs, et homo- et copolymères d'oléfine |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2014117787A Division JP2014196319A (ja) | 2014-06-06 | 2014-06-06 | 新たなメタロセン化合物、それを含む触媒、その触媒を使用するオレフィンポリマーの製造プロセス、ならびにオレフィンホモポリマーおよびコポリマー |
Publications (1)
Publication Number | Publication Date |
---|---|
JP2012513463A true JP2012513463A (ja) | 2012-06-14 |
Family
ID=40936621
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2011543489A Ceased JP2012513463A (ja) | 2008-12-31 | 2008-12-31 | 新たなメタロセン化合物、それを含む触媒、その触媒を使用するオレフィンポリマーの製造プロセス、ならびにオレフィンホモポリマーおよびコポリマー |
Country Status (10)
Country | Link |
---|---|
EP (1) | EP2384343A1 (fr) |
JP (1) | JP2012513463A (fr) |
KR (1) | KR101351103B1 (fr) |
CN (1) | CN102257020B (fr) |
BR (1) | BRPI0823407A2 (fr) |
EA (1) | EA201170909A1 (fr) |
MX (1) | MX2011006667A (fr) |
SG (1) | SG172454A1 (fr) |
WO (1) | WO2010077230A1 (fr) |
ZA (1) | ZA201105497B (fr) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2014133001A1 (fr) | 2013-02-27 | 2014-09-04 | 日本ポリエチレン株式会社 | Composé métallocène, catalyseur destiné à un polymère d'oléfines, procédé permettant de produire un polymère d'oléfines et polymère d'oléfines |
WO2014136778A1 (fr) | 2013-03-05 | 2014-09-12 | 日本ポリエチレン株式会社 | PROCÉDÉ DE PRODUCTION D'UN COPOLYMÈRE D'ÉTHYLÈNE/α-OLÉFINE |
US9902749B2 (en) | 2012-11-01 | 2018-02-27 | Japan Polypropylene Corporation | Metallocene complex and olefin polymerization method |
Families Citing this family (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2402353B1 (fr) | 2010-07-01 | 2018-04-25 | Borealis AG | Métallocènes des métaux de groupe 4 comme catalyseurs pour la polymérisation d'oléfines |
ES2565438T3 (es) | 2010-07-01 | 2016-04-04 | Borealis Ag | Proceso para la polimerización de olefinas usando metalocenos del grupo 4 como catalizadores |
EP2573091A1 (fr) | 2011-09-23 | 2013-03-27 | Lummus Novolen Technology Gmbh | Procédé de recyclage de ligand libre provenant de leurs complexes de métallocènes correspondants |
EP2722345B1 (fr) | 2012-10-18 | 2018-12-05 | Borealis AG | Catalyseur pour la polymérisation d'oléfines |
ES2622627T3 (es) | 2012-10-18 | 2017-07-06 | Borealis Ag | Procedimiento de polimerización |
EP2722346A1 (fr) | 2012-10-18 | 2014-04-23 | Borealis AG | Procédé de polymérisation et catalyseur |
US9458260B2 (en) | 2013-07-17 | 2016-10-04 | Exxonmobil Chemical Patents Inc. | Process using substituted metallocene catalysts and products therefrom |
CN105358589B (zh) | 2013-07-17 | 2018-07-03 | 埃克森美孚化学专利公司 | 金属茂和由其衍生的催化剂组合物 |
US9938364B2 (en) | 2013-07-17 | 2018-04-10 | Exxonmobil Chemical Patents Inc. | Substituted metallocene catalysts |
US9464145B2 (en) | 2013-07-17 | 2016-10-11 | Exxonmobil Chemical Patents Inc. | Metallocenes and catalyst compositions derived therefrom |
CN105358586A (zh) | 2013-07-17 | 2016-02-24 | 埃克森美孚化学专利公司 | 环丙基取代的茂金属催化剂 |
ES2612627T3 (es) | 2013-07-24 | 2017-05-17 | Borealis Ag | Proceso |
KR102405286B1 (ko) * | 2017-12-06 | 2022-06-02 | 주식회사 엘지화학 | 메탈로센 담지 촉매의 제조방법, 상기 제조방법으로 제조된 메탈로센 담지 촉매, 및 이를 제조하여 제조한 폴리프로필렌 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2003522550A (ja) * | 1998-02-10 | 2003-07-29 | アーテミス・メディカル・インコーポレイテッド | 咬合、固定、テンショニング、及び流向装置とその使用方法 |
JP2004502699A (ja) * | 2000-06-30 | 2004-01-29 | エクソンモービル・ケミカル・パテンツ・インク | 架橋ビス(インデニル)メタロセン化合物 |
JP2011500800A (ja) * | 2007-10-25 | 2011-01-06 | ルムス・ノボレン・テクノロジー・ゲゼルシャフト・ミット・ベシュレンクテル・ハフツング | メタロセン化合物、それを含む触媒、その触媒を使用するオレフィンポリマーの製造プロセス、ならびにオレフィンホモポリマーおよびコポリマー |
JP2011502192A (ja) * | 2007-10-25 | 2011-01-20 | ルムス・ノボレン・テクノロジー・ゲゼルシャフト・ミット・ベシュレンクテル・ハフツング | アンサ−メタロセン化合物のラセモ選択的合成、アンサ−メタロセン化合物、それを含む触媒、触媒の使用によってオレフィンポリマーを製造するプロセス、ならびにホモポリマーおよびコポリマー |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR100789201B1 (ko) * | 1999-12-23 | 2007-12-31 | 바젤 폴리올레핀 게엠베하 | 전이 금속 화합물, 리간드계, 촉매계와 올레핀의 중합 및공중합에 사용되는 이의 용도 |
US7232869B2 (en) * | 2005-05-17 | 2007-06-19 | Novolen Technology Holdings, C.V. | Catalyst composition for olefin polymerization |
-
2008
- 2008-12-31 SG SG2011048345A patent/SG172454A1/en unknown
- 2008-12-31 EA EA201170909A patent/EA201170909A1/ru unknown
- 2008-12-31 BR BRPI0823407-8A patent/BRPI0823407A2/pt not_active IP Right Cessation
- 2008-12-31 MX MX2011006667A patent/MX2011006667A/es not_active Application Discontinuation
- 2008-12-31 CN CN200880132439.2A patent/CN102257020B/zh not_active Expired - Fee Related
- 2008-12-31 EP EP08876396A patent/EP2384343A1/fr not_active Withdrawn
- 2008-12-31 JP JP2011543489A patent/JP2012513463A/ja not_active Ceased
- 2008-12-31 KR KR1020117016447A patent/KR101351103B1/ko not_active IP Right Cessation
- 2008-12-31 WO PCT/US2008/014144 patent/WO2010077230A1/fr active Application Filing
-
2011
- 2011-07-26 ZA ZA2011/05497A patent/ZA201105497B/en unknown
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2003522550A (ja) * | 1998-02-10 | 2003-07-29 | アーテミス・メディカル・インコーポレイテッド | 咬合、固定、テンショニング、及び流向装置とその使用方法 |
JP2004502699A (ja) * | 2000-06-30 | 2004-01-29 | エクソンモービル・ケミカル・パテンツ・インク | 架橋ビス(インデニル)メタロセン化合物 |
JP2011500800A (ja) * | 2007-10-25 | 2011-01-06 | ルムス・ノボレン・テクノロジー・ゲゼルシャフト・ミット・ベシュレンクテル・ハフツング | メタロセン化合物、それを含む触媒、その触媒を使用するオレフィンポリマーの製造プロセス、ならびにオレフィンホモポリマーおよびコポリマー |
JP2011502192A (ja) * | 2007-10-25 | 2011-01-20 | ルムス・ノボレン・テクノロジー・ゲゼルシャフト・ミット・ベシュレンクテル・ハフツング | アンサ−メタロセン化合物のラセモ選択的合成、アンサ−メタロセン化合物、それを含む触媒、触媒の使用によってオレフィンポリマーを製造するプロセス、ならびにホモポリマーおよびコポリマー |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US9902749B2 (en) | 2012-11-01 | 2018-02-27 | Japan Polypropylene Corporation | Metallocene complex and olefin polymerization method |
WO2014133001A1 (fr) | 2013-02-27 | 2014-09-04 | 日本ポリエチレン株式会社 | Composé métallocène, catalyseur destiné à un polymère d'oléfines, procédé permettant de produire un polymère d'oléfines et polymère d'oléfines |
EP3078670A1 (fr) | 2013-02-27 | 2016-10-12 | Japan Polyethylene Corporation | Composé métallocène, catalyseur de polymère d'oléfine, procédé de production de polymère d'oléfine et polymère d'oléfine |
US9783625B2 (en) | 2013-02-27 | 2017-10-10 | Japan Polyethylene Corporation | Metallocene compound, catalyst for olefin polymer, method for producing olefin polymer, and olefin polymer |
US10005864B2 (en) | 2013-02-27 | 2018-06-26 | Japan Polyethylene Corporation | Metallocene compound, catalyst for olefin polymer, method for producing olefin polymer, and olefin polymer |
WO2014136778A1 (fr) | 2013-03-05 | 2014-09-12 | 日本ポリエチレン株式会社 | PROCÉDÉ DE PRODUCTION D'UN COPOLYMÈRE D'ÉTHYLÈNE/α-OLÉFINE |
Also Published As
Publication number | Publication date |
---|---|
CN102257020A (zh) | 2011-11-23 |
WO2010077230A1 (fr) | 2010-07-08 |
KR20110094349A (ko) | 2011-08-23 |
KR101351103B1 (ko) | 2014-01-14 |
CN102257020B (zh) | 2014-04-02 |
MX2011006667A (es) | 2011-07-20 |
SG172454A1 (en) | 2011-08-29 |
EA201170909A1 (ru) | 2012-01-30 |
ZA201105497B (en) | 2012-04-25 |
EP2384343A1 (fr) | 2011-11-09 |
BRPI0823407A2 (pt) | 2015-06-16 |
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