EA201170909A1 - Новые металлоценовые соединения, катализаторы, включающие такие соединения, способ получения олефинового полимера с использованием таких катализаторов и олефиновые гомо- и сополимеры - Google Patents

Новые металлоценовые соединения, катализаторы, включающие такие соединения, способ получения олефинового полимера с использованием таких катализаторов и олефиновые гомо- и сополимеры

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Publication number
EA201170909A1
EA201170909A1 EA201170909A EA201170909A EA201170909A1 EA 201170909 A1 EA201170909 A1 EA 201170909A1 EA 201170909 A EA201170909 A EA 201170909A EA 201170909 A EA201170909 A EA 201170909A EA 201170909 A1 EA201170909 A1 EA 201170909A1
Authority
EA
Eurasian Patent Office
Prior art keywords
catalysts
copolymers
substituent
branched
molecular weight
Prior art date
Application number
EA201170909A
Other languages
English (en)
Russian (ru)
Inventor
Торстен Зелль
Андреас Винтер
Мэттью Грант Торн
Анита Димеска
Франц Лангхаузер
Original Assignee
Люммус Новолен Текнолоджи Гмбх
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Люммус Новолен Текнолоджи Гмбх filed Critical Люммус Новолен Текнолоджи Гмбх
Publication of EA201170909A1 publication Critical patent/EA201170909A1/ru

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/642—Component covered by group C08F4/64 with an organo-aluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
EA201170909A 2008-12-31 2008-12-31 Новые металлоценовые соединения, катализаторы, включающие такие соединения, способ получения олефинового полимера с использованием таких катализаторов и олефиновые гомо- и сополимеры EA201170909A1 (ru)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/US2008/014144 WO2010077230A1 (fr) 2008-12-31 2008-12-31 Nouveaux composés de métallocène, catalyseurs comprenant ceux-ci, procédé pour produire un polymère d'oléfine par utilisation des catalyseurs, et homo- et copolymères d'oléfine

Publications (1)

Publication Number Publication Date
EA201170909A1 true EA201170909A1 (ru) 2012-01-30

Family

ID=40936621

Family Applications (1)

Application Number Title Priority Date Filing Date
EA201170909A EA201170909A1 (ru) 2008-12-31 2008-12-31 Новые металлоценовые соединения, катализаторы, включающие такие соединения, способ получения олефинового полимера с использованием таких катализаторов и олефиновые гомо- и сополимеры

Country Status (10)

Country Link
EP (1) EP2384343A1 (fr)
JP (1) JP2012513463A (fr)
KR (1) KR101351103B1 (fr)
CN (1) CN102257020B (fr)
BR (1) BRPI0823407A2 (fr)
EA (1) EA201170909A1 (fr)
MX (1) MX2011006667A (fr)
SG (1) SG172454A1 (fr)
WO (1) WO2010077230A1 (fr)
ZA (1) ZA201105497B (fr)

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2402354B1 (fr) 2010-07-01 2016-03-02 Borealis AG Procédé de polymérisation d'oléfines utilisant des métallocènes des métaux de groupe 4 comme catalyseurs
EP2402353B1 (fr) 2010-07-01 2018-04-25 Borealis AG Métallocènes des métaux de groupe 4 comme catalyseurs pour la polymérisation d'oléfines
EP2573091A1 (fr) 2011-09-23 2013-03-27 Lummus Novolen Technology Gmbh Procédé de recyclage de ligand libre provenant de leurs complexes de métallocènes correspondants
EP2722346A1 (fr) 2012-10-18 2014-04-23 Borealis AG Procédé de polymérisation et catalyseur
EP2722345B1 (fr) 2012-10-18 2018-12-05 Borealis AG Catalyseur pour la polymérisation d'oléfines
EP2722344B1 (fr) 2012-10-18 2017-03-22 Borealis AG Procédé de polymérisation
JP6176015B2 (ja) 2012-11-01 2017-08-09 日本ポリプロ株式会社 メタロセン錯体およびオレフィンの重合方法
JP5710035B2 (ja) 2013-02-27 2015-04-30 日本ポリエチレン株式会社 メタロセン化合物およびオレフィン重合体の製造方法
JP5695687B2 (ja) 2013-03-05 2015-04-08 日本ポリエチレン株式会社 エチレン／α−オレフィン共重合体の製造方法
US9464145B2 (en) 2013-07-17 2016-10-11 Exxonmobil Chemical Patents Inc. Metallocenes and catalyst compositions derived therefrom
US9938364B2 (en) 2013-07-17 2018-04-10 Exxonmobil Chemical Patents Inc. Substituted metallocene catalysts
EP3848401A1 (fr) 2013-07-17 2021-07-14 ExxonMobil Chemical Patents Inc. Polymères de propylène isotactique
CN105358589B (zh) 2013-07-17 2018-07-03 埃克森美孚化学专利公司 金属茂和由其衍生的催化剂组合物
SG10201802959WA (en) 2013-07-17 2018-05-30 Exxonmobil Chemical Patents Inc Cyclopropyl substituted metallocene catalysts
ES2612627T3 (es) 2013-07-24 2017-05-17 Borealis Ag Proceso
KR102405286B1 (ko) * 2017-12-06 2022-06-02 주식회사 엘지화학 메탈로센 담지 촉매의 제조방법, 상기 제조방법으로 제조된 메탈로센 담지 촉매, 및 이를 제조하여 제조한 폴리프로필렌

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003522550A (ja) * 1998-02-10 2003-07-29 アーテミス・メディカル・インコーポレイテッド 咬合、固定、テンショニング、及び流向装置とその使用方法
CA2395552C (fr) * 1999-12-23 2010-02-16 Basell Polyolefine Gmbh Composition de metal de transition, systeme de ligand, systeme de catalyseur et son utilisation pour la polymerisation et la copolymerisation d'olefines
EP1632506A1 (fr) * 2000-06-30 2006-03-08 ExxonMobil Chemical Patents Inc. Polymère à base de propylène
US7232869B2 (en) * 2005-05-17 2007-06-19 Novolen Technology Holdings, C.V. Catalyst composition for olefin polymerization
JP5598856B2 (ja) * 2007-10-25 2014-10-01 ルムス・ノボレン・テクノロジー・ゲゼルシャフト・ミット・ベシュレンクテル・ハフツング メタロセン化合物、それを含む触媒、その触媒を使用するオレフィンポリマーの製造プロセス、ならびにオレフィンホモポリマーおよびコポリマー
ATE547439T1 (de) * 2007-10-25 2012-03-15 Lummus Novolen Technology Gmbh Racemoselektive synthese von ansa-metallocen- verbindungen, ansa-metallocen-verbindungen, diese enthaltende katalysatoren, verfahren zur herstellung eines olefinpolymers durch verwendung der katalysatoren und olefinhomopolymere und - copolymere

Also Published As

Publication number Publication date
KR20110094349A (ko) 2011-08-23
JP2012513463A (ja) 2012-06-14
EP2384343A1 (fr) 2011-11-09
ZA201105497B (en) 2012-04-25
WO2010077230A1 (fr) 2010-07-08
CN102257020B (zh) 2014-04-02
KR101351103B1 (ko) 2014-01-14
MX2011006667A (es) 2011-07-20
CN102257020A (zh) 2011-11-23
BRPI0823407A2 (pt) 2015-06-16
SG172454A1 (en) 2011-08-29

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