KR101172362B1 - 얇은 고체 산화물 전지 - Google Patents

얇은 고체 산화물 전지 Download PDF

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Publication number
KR101172362B1
KR101172362B1 KR1020097012019A KR20097012019A KR101172362B1 KR 101172362 B1 KR101172362 B1 KR 101172362B1 KR 1020097012019 A KR1020097012019 A KR 1020097012019A KR 20097012019 A KR20097012019 A KR 20097012019A KR 101172362 B1 KR101172362 B1 KR 101172362B1
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layer
electrolyte
cell
solid oxide
electrode
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KR20090094273A (ko
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피터 할보어 라슨
소렌 린데로스
피터 뱅 헨드릭슨
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테크니칼 유니버시티 오브 덴마크
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/10Fuel cells with solid electrolytes
    • H01M8/12Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte
    • H01M8/1213Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte characterised by the electrode/electrolyte combination or the supporting material
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/10Fuel cells with solid electrolytes
    • H01M8/12Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D67/00Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0039Inorganic membrane manufacture
    • B01D67/0041Inorganic membrane manufacture by agglomeration of particles in the dry state
    • B01D67/00411Inorganic membrane manufacture by agglomeration of particles in the dry state by sintering
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D67/00Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0039Inorganic membrane manufacture
    • B01D67/0046Inorganic membrane manufacture by slurry techniques, e.g. die or slip-casting
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D69/00Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/12Composite membranes; Ultra-thin membranes
    • B01D69/1216Three or more layers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D71/00Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/02Inorganic material
    • B01D71/024Oxides
    • B01D71/0271Perovskites
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/86Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/8605Porous electrodes
    • H01M4/8621Porous electrodes containing only metallic or ceramic material, e.g. made by sintering or sputtering
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/86Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/88Processes of manufacture
    • H01M4/8878Treatment steps after deposition of the catalytic active composition or after shaping of the electrode being free-standing body
    • H01M4/8882Heat treatment, e.g. drying, baking
    • H01M4/8885Sintering or firing
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/86Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/90Selection of catalytic material
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/86Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/90Selection of catalytic material
    • H01M4/9016Oxides, hydroxides or oxygenated metallic salts
    • H01M4/9025Oxides specially used in fuel cell operating at high temperature, e.g. SOFC
    • H01M4/9033Complex oxides, optionally doped, of the type M1MeO3, M1 being an alkaline earth metal or a rare earth, Me being a metal, e.g. perovskites
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/86Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/90Selection of catalytic material
    • H01M4/9041Metals or alloys
    • H01M4/905Metals or alloys specially used in fuel cell operating at high temperature, e.g. SOFC
    • H01M4/9066Metals or alloys specially used in fuel cell operating at high temperature, e.g. SOFC of metal-ceramic composites or mixtures, e.g. cermets
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/02Details
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/10Fuel cells with solid electrolytes
    • H01M8/12Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte
    • H01M8/1213Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte characterised by the electrode/electrolyte combination or the supporting material
    • H01M8/122Corrugated, curved or wave-shaped MEA
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2323/00Details relating to membrane preparation
    • B01D2323/46Impregnation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2325/00Details relating to properties of membranes
    • B01D2325/08Patterned membranes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2325/00Details relating to properties of membranes
    • B01D2325/10Catalysts being present on the surface of the membrane or in the pores
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00Electrolytes
    • H01M2300/0088Composites
    • H01M2300/0094Composites in the form of layered products, e.g. coatings
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/86Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/8647Inert electrodes with catalytic activity, e.g. for fuel cells consisting of more than one material, e.g. consisting of composites
    • H01M4/8652Inert electrodes with catalytic activity, e.g. for fuel cells consisting of more than one material, e.g. consisting of composites as mixture
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/86Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/90Selection of catalytic material
    • H01M4/9016Oxides, hydroxides or oxygenated metallic salts
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Electrochemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Sustainable Energy (AREA)
  • Sustainable Development (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Ceramic Engineering (AREA)
  • Composite Materials (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Inert Electrodes (AREA)
  • Fuel Cell (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)
KR1020097012019A 2006-11-23 2007-11-23 얇은 고체 산화물 전지 Expired - Fee Related KR101172362B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP06024338A EP1928049A1 (en) 2006-11-23 2006-11-23 Thin solid oxide cell
EP06024338.3 2006-11-23
PCT/EP2007/010194 WO2008061782A2 (en) 2006-11-23 2007-11-23 Thin solid oxide cell

Publications (2)

Publication Number Publication Date
KR20090094273A KR20090094273A (ko) 2009-09-04
KR101172362B1 true KR101172362B1 (ko) 2012-08-08

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KR1020097012019A Expired - Fee Related KR101172362B1 (ko) 2006-11-23 2007-11-23 얇은 고체 산화물 전지

Country Status (10)

Country Link
US (1) US9496576B2 (enExample)
EP (3) EP1928049A1 (enExample)
JP (1) JP5219298B2 (enExample)
KR (1) KR101172362B1 (enExample)
CN (2) CN101563805B (enExample)
AU (1) AU2007323291B2 (enExample)
CA (2) CA2797177A1 (enExample)
NO (1) NO20091876L (enExample)
RU (1) RU2427945C2 (enExample)
WO (1) WO2008061782A2 (enExample)

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EP1928049A1 (en) 2006-11-23 2008-06-04 Technical University of Denmark Thin solid oxide cell
EP2103582A1 (en) * 2008-03-18 2009-09-23 Technical University of Denmark A method for producing a multilayer structure
EP2104165A1 (en) * 2008-03-18 2009-09-23 The Technical University of Denmark An all ceramics solid oxide fuel cell
CA2740293C (en) * 2008-10-14 2017-10-03 University Of Florida Research Foundation, Inc. Advanced materials and design for low temperature sofcs
DK2194597T3 (da) 2008-12-03 2014-06-16 Univ Denmark Tech Dtu Fastoxidcelle og fastoxidcellestak
JP5383232B2 (ja) * 2009-01-30 2014-01-08 三菱重工業株式会社 固体電解質型燃料電池の発電膜及びこれを備える固体電解質型燃料電池
KR101177621B1 (ko) * 2010-06-25 2012-08-27 한국생산기술연구원 고체산화물 연료전지 단위셀의 제조방법
KR20130106862A (ko) * 2010-11-16 2013-09-30 생-고뱅 세라믹스 앤드 플라스틱스, 인코포레이티드 고체 산화물 연료전지 스택용 실질적 평면형 단일 전지
US9642192B2 (en) * 2011-08-04 2017-05-02 Fuelcell Energy, Inc. Method and manufacturing assembly for sintering fuel cell electrodes and impregnating porous electrodes with electrolyte powders by induction heating for mass production
JP5790772B2 (ja) * 2011-10-12 2015-10-07 トヨタ自動車株式会社 非水電解質二次電池
CN102347495B (zh) * 2011-10-19 2014-01-08 华北电力大学 固体氧化物燃料电池结构及其制备方法
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CN106654362B (zh) * 2016-12-07 2019-07-19 珠海光宇电池有限公司 复合固态电解质膜、制备方法及锂离子电池
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JP7746158B2 (ja) * 2019-01-11 2025-09-30 ユティリティ グローバル,インコーポレイテッド 水素を生成する方法
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CN110098434B (zh) * 2019-04-09 2021-04-27 中国科学院合肥物质科学研究院 全固态锂电池中电极-电解质双层平整块材及其制备方法
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CN110828669A (zh) * 2019-11-15 2020-02-21 中南大学 一种低温介孔碳基钙钛矿太阳能电池及其制备方法
CN111416138A (zh) * 2020-03-12 2020-07-14 西安交通大学 一种质子陶瓷膜燃料电池及其制备方法
RU2735327C1 (ru) * 2020-05-12 2020-10-30 Федеральное государственное бюджетное учреждение науки Институт физики твердого тела Российской академии наук (ИФТТ РАН) Способ изготовления двухслойной анодной подложки с тонкопленочным электролитом для твердооксидного топливного элемента
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CN113564625A (zh) * 2021-09-14 2021-10-29 北京思伟特新能源科技有限公司 质子传导型固体氧化物电解池及其制备方法
CN113667998A (zh) * 2021-09-15 2021-11-19 北京思伟特新能源科技有限公司 一种可逆型固体氧化物电解池及其制备方法
CN113937318B (zh) * 2021-10-14 2024-04-19 东莞华创教育科技有限公司 一种电解质支撑型固体氧化物燃料单元电池的制程方法
CN114182288B (zh) * 2021-12-15 2023-09-12 中国科学院大连化学物理研究所 一种固体氧化物电解池氧电极及其制备方法
JPWO2023148903A1 (enExample) * 2022-02-03 2023-08-10
CN114597462B (zh) * 2022-03-08 2023-05-16 中国科学技术大学先进技术研究院 对称型固体氧化物电池
CN114634164B (zh) * 2022-03-31 2024-04-30 合肥氢成科技有限公司 陶瓷氧泵及氢氧燃料电池的氧气提纯装置
CN114583226B (zh) * 2022-03-31 2024-07-12 电堆科技(合肥)有限公司 一种金属支撑质子导体固体氧化物电池及其制备方法
CN114622231B (zh) * 2022-03-31 2024-12-31 电堆科技(合肥)有限公司 陶瓷氢泵及氢氧燃料电池的氢气提纯装置
CN115483422A (zh) * 2022-08-26 2022-12-16 中国科学技术大学 高性能超薄正极-电解质-负极固体氧化物电池及其制备方法
CN119542479B (zh) * 2024-11-07 2025-07-22 华北电力大学 一种含有梯度层的固体氧化物电池及制备方法

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