CA2797177A1 - Thin separation membrane comprising electrode layers and catalyst - Google Patents
Thin separation membrane comprising electrode layers and catalyst Download PDFInfo
- Publication number
- CA2797177A1 CA2797177A1 CA2797177A CA2797177A CA2797177A1 CA 2797177 A1 CA2797177 A1 CA 2797177A1 CA 2797177 A CA2797177 A CA 2797177A CA 2797177 A CA2797177 A CA 2797177A CA 2797177 A1 CA2797177 A1 CA 2797177A1
- Authority
- CA
- Canada
- Prior art keywords
- layer
- cell
- electrolyte
- electrode
- thin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 239000012528 membrane Substances 0.000 title claims abstract description 65
- 239000003054 catalyst Substances 0.000 title claims abstract description 37
- 238000000926 separation method Methods 0.000 title claims abstract description 35
- 238000004519 manufacturing process Methods 0.000 claims abstract description 37
- 239000000463 material Substances 0.000 claims abstract description 37
- 229910052751 metal Inorganic materials 0.000 claims abstract description 31
- 239000002184 metal Substances 0.000 claims abstract description 31
- 239000004020 conductor Substances 0.000 claims abstract description 16
- 239000002243 precursor Substances 0.000 claims description 33
- 238000005245 sintering Methods 0.000 claims description 24
- 229910000422 cerium(IV) oxide Inorganic materials 0.000 claims description 22
- CETPSERCERDGAM-UHFFFAOYSA-N ceric oxide Chemical compound O=[Ce]=O CETPSERCERDGAM-UHFFFAOYSA-N 0.000 claims description 21
- 239000003792 electrolyte Substances 0.000 abstract description 77
- 239000007787 solid Substances 0.000 abstract description 48
- 239000002001 electrolyte material Substances 0.000 abstract description 22
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 abstract description 12
- 230000002441 reversible effect Effects 0.000 abstract description 12
- 239000010410 layer Substances 0.000 description 362
- 239000000725 suspension Substances 0.000 description 59
- 210000004379 membrane Anatomy 0.000 description 52
- 238000010438 heat treatment Methods 0.000 description 34
- 230000008595 infiltration Effects 0.000 description 31
- 238000001764 infiltration Methods 0.000 description 31
- 239000000843 powder Substances 0.000 description 29
- 239000000203 mixture Substances 0.000 description 25
- 238000010345 tape casting Methods 0.000 description 25
- 239000000543 intermediate Substances 0.000 description 23
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 22
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 description 22
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 22
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 22
- 239000011888 foil Substances 0.000 description 21
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 21
- 239000000446 fuel Substances 0.000 description 20
- 238000005470 impregnation Methods 0.000 description 20
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 19
- 239000002245 particle Substances 0.000 description 18
- 229910002651 NO3 Inorganic materials 0.000 description 15
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 15
- 238000000354 decomposition reaction Methods 0.000 description 15
- 229910052759 nickel Inorganic materials 0.000 description 15
- 150000002823 nitrates Chemical group 0.000 description 15
- 239000000654 additive Substances 0.000 description 14
- 238000003475 lamination Methods 0.000 description 14
- 238000002791 soaking Methods 0.000 description 14
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 13
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 13
- 239000001301 oxygen Substances 0.000 description 13
- 229910052760 oxygen Inorganic materials 0.000 description 13
- 238000000498 ball milling Methods 0.000 description 11
- 238000001816 cooling Methods 0.000 description 11
- 239000007789 gas Substances 0.000 description 10
- 238000000034 method Methods 0.000 description 10
- 238000004080 punching Methods 0.000 description 10
- 229910052712 strontium Inorganic materials 0.000 description 10
- 229910052688 Gadolinium Inorganic materials 0.000 description 9
- 238000005266 casting Methods 0.000 description 9
- 239000000919 ceramic Substances 0.000 description 8
- 229910052746 lanthanum Inorganic materials 0.000 description 8
- 229910000604 Ferrochrome Inorganic materials 0.000 description 7
- 238000001035 drying Methods 0.000 description 7
- 229910052742 iron Inorganic materials 0.000 description 7
- 230000009467 reduction Effects 0.000 description 7
- 239000001257 hydrogen Substances 0.000 description 6
- 229910052739 hydrogen Inorganic materials 0.000 description 6
- 229910045601 alloy Inorganic materials 0.000 description 5
- 239000000956 alloy Substances 0.000 description 5
- 239000003610 charcoal Substances 0.000 description 5
- 239000011148 porous material Substances 0.000 description 5
- 239000000758 substrate Substances 0.000 description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- 230000006835 compression Effects 0.000 description 4
- 238000007906 compression Methods 0.000 description 4
- 229910052802 copper Inorganic materials 0.000 description 4
- 239000007772 electrode material Substances 0.000 description 4
- 229910002804 graphite Inorganic materials 0.000 description 4
- 239000010439 graphite Substances 0.000 description 4
- 150000002431 hydrogen Chemical class 0.000 description 4
- 229910052748 manganese Inorganic materials 0.000 description 4
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 4
- 238000003786 synthesis reaction Methods 0.000 description 4
- 239000000306 component Substances 0.000 description 3
- 239000010419 fine particle Substances 0.000 description 3
- 229910052750 molybdenum Inorganic materials 0.000 description 3
- 229910052763 palladium Inorganic materials 0.000 description 3
- 229910052721 tungsten Inorganic materials 0.000 description 3
- 229910052684 Cerium Inorganic materials 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- 229910052776 Thorium Inorganic materials 0.000 description 2
- 229910052770 Uranium Inorganic materials 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 229910017052 cobalt Inorganic materials 0.000 description 2
- 239000010941 cobalt Substances 0.000 description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 238000005868 electrolysis reaction Methods 0.000 description 2
- 239000010416 ion conductor Substances 0.000 description 2
- 238000010030 laminating Methods 0.000 description 2
- 229910052747 lanthanoid Inorganic materials 0.000 description 2
- 230000000873 masking effect Effects 0.000 description 2
- 239000002923 metal particle Substances 0.000 description 2
- 229910052758 niobium Inorganic materials 0.000 description 2
- 229910052697 platinum Inorganic materials 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 239000012078 proton-conducting electrolyte Substances 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 229910052720 vanadium Inorganic materials 0.000 description 2
- 229910000859 α-Fe Inorganic materials 0.000 description 2
- 229910001316 Ag alloy Inorganic materials 0.000 description 1
- 206010013786 Dry skin Diseases 0.000 description 1
- 229910003271 Ni-Fe Inorganic materials 0.000 description 1
- 229910052772 Samarium Inorganic materials 0.000 description 1
- -1 ScYSZ Inorganic materials 0.000 description 1
- 241000968352 Scandia <hydrozoan> Species 0.000 description 1
- 238000007792 addition Methods 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 239000011195 cermet Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 238000004320 controlled atmosphere Methods 0.000 description 1
- 235000019628 coolness Nutrition 0.000 description 1
- 230000001351 cycling effect Effects 0.000 description 1
- 239000002019 doping agent Substances 0.000 description 1
- 239000002737 fuel gas Substances 0.000 description 1
- 150000002602 lanthanoids Chemical class 0.000 description 1
- 229910000473 manganese(VI) oxide Inorganic materials 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- HJGMWXTVGKLUAQ-UHFFFAOYSA-N oxygen(2-);scandium(3+) Chemical compound [O-2].[O-2].[O-2].[Sc+3].[Sc+3] HJGMWXTVGKLUAQ-UHFFFAOYSA-N 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 229910002076 stabilized zirconia Inorganic materials 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- IGPAMRAHTMKVDN-UHFFFAOYSA-N strontium dioxido(dioxo)manganese lanthanum(3+) Chemical compound [Sr+2].[La+3].[O-][Mn]([O-])(=O)=O IGPAMRAHTMKVDN-UHFFFAOYSA-N 0.000 description 1
- 229910052715 tantalum Inorganic materials 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 229910052727 yttrium Inorganic materials 0.000 description 1
- RUDFQVOCFDJEEF-UHFFFAOYSA-N yttrium(III) oxide Inorganic materials [O-2].[O-2].[O-2].[Y+3].[Y+3] RUDFQVOCFDJEEF-UHFFFAOYSA-N 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/12—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte
- H01M8/1213—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte characterised by the electrode/electrolyte combination or the supporting material
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/12—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
- B01D67/0039—Inorganic membrane manufacture
- B01D67/0041—Inorganic membrane manufacture by agglomeration of particles in the dry state
- B01D67/00411—Inorganic membrane manufacture by agglomeration of particles in the dry state by sintering
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
- B01D67/0039—Inorganic membrane manufacture
- B01D67/0046—Inorganic membrane manufacture by slurry techniques, e.g. die or slip-casting
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
- B01D69/12—Composite membranes; Ultra-thin membranes
- B01D69/1216—Three or more layers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/02—Inorganic material
- B01D71/024—Oxides
- B01D71/0271—Perovskites
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/8605—Porous electrodes
- H01M4/8621—Porous electrodes containing only metallic or ceramic material, e.g. made by sintering or sputtering
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/88—Processes of manufacture
- H01M4/8878—Treatment steps after deposition of the catalytic active composition or after shaping of the electrode being free-standing body
- H01M4/8882—Heat treatment, e.g. drying, baking
- H01M4/8885—Sintering or firing
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/90—Selection of catalytic material
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/90—Selection of catalytic material
- H01M4/9016—Oxides, hydroxides or oxygenated metallic salts
- H01M4/9025—Oxides specially used in fuel cell operating at high temperature, e.g. SOFC
- H01M4/9033—Complex oxides, optionally doped, of the type M1MeO3, M1 being an alkaline earth metal or a rare earth, Me being a metal, e.g. perovskites
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/90—Selection of catalytic material
- H01M4/9041—Metals or alloys
- H01M4/905—Metals or alloys specially used in fuel cell operating at high temperature, e.g. SOFC
- H01M4/9066—Metals or alloys specially used in fuel cell operating at high temperature, e.g. SOFC of metal-ceramic composites or mixtures, e.g. cermets
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/02—Details
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/12—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte
- H01M8/1213—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte characterised by the electrode/electrolyte combination or the supporting material
- H01M8/122—Corrugated, curved or wave-shaped MEA
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2323/00—Details relating to membrane preparation
- B01D2323/46—Impregnation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2325/00—Details relating to properties of membranes
- B01D2325/08—Patterned membranes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2325/00—Details relating to properties of membranes
- B01D2325/10—Catalysts being present on the surface of the membrane or in the pores
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2300/00—Electrolytes
- H01M2300/0088—Composites
- H01M2300/0094—Composites in the form of layered products, e.g. coatings
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/8647—Inert electrodes with catalytic activity, e.g. for fuel cells consisting of more than one material, e.g. consisting of composites
- H01M4/8652—Inert electrodes with catalytic activity, e.g. for fuel cells consisting of more than one material, e.g. consisting of composites as mixture
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/90—Selection of catalytic material
- H01M4/9016—Oxides, hydroxides or oxygenated metallic salts
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Electrochemistry (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Sustainable Energy (AREA)
- Sustainable Development (AREA)
- Life Sciences & Earth Sciences (AREA)
- Ceramic Engineering (AREA)
- Composite Materials (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Inert Electrodes (AREA)
- Fuel Cell (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP06024338A EP1928049A1 (en) | 2006-11-23 | 2006-11-23 | Thin solid oxide cell |
| EP06024338.3 | 2006-11-23 | ||
| CA002669811A CA2669811A1 (en) | 2006-11-23 | 2007-11-23 | Thin solid oxide cell |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002669811A Division CA2669811A1 (en) | 2006-11-23 | 2007-11-23 | Thin solid oxide cell |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA2797177A1 true CA2797177A1 (en) | 2008-05-29 |
Family
ID=37714681
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA2797177A Abandoned CA2797177A1 (en) | 2006-11-23 | 2007-11-23 | Thin separation membrane comprising electrode layers and catalyst |
| CA002669811A Abandoned CA2669811A1 (en) | 2006-11-23 | 2007-11-23 | Thin solid oxide cell |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002669811A Abandoned CA2669811A1 (en) | 2006-11-23 | 2007-11-23 | Thin solid oxide cell |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US9496576B2 (enExample) |
| EP (3) | EP1928049A1 (enExample) |
| JP (1) | JP5219298B2 (enExample) |
| KR (1) | KR101172362B1 (enExample) |
| CN (2) | CN101563805B (enExample) |
| AU (1) | AU2007323291B2 (enExample) |
| CA (2) | CA2797177A1 (enExample) |
| NO (1) | NO20091876L (enExample) |
| RU (1) | RU2427945C2 (enExample) |
| WO (1) | WO2008061782A2 (enExample) |
Families Citing this family (55)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1928049A1 (en) | 2006-11-23 | 2008-06-04 | Technical University of Denmark | Thin solid oxide cell |
| EP2104165A1 (en) | 2008-03-18 | 2009-09-23 | The Technical University of Denmark | An all ceramics solid oxide fuel cell |
| EP2103582A1 (en) * | 2008-03-18 | 2009-09-23 | Technical University of Denmark | A method for producing a multilayer structure |
| US9343746B2 (en) | 2008-10-14 | 2016-05-17 | University Of Florida Research Foundation, Inc. | Advanced materials and design for low temperature SOFCs |
| DK2194597T3 (da) * | 2008-12-03 | 2014-06-16 | Univ Denmark Tech Dtu | Fastoxidcelle og fastoxidcellestak |
| JP5383232B2 (ja) * | 2009-01-30 | 2014-01-08 | 三菱重工業株式会社 | 固体電解質型燃料電池の発電膜及びこれを備える固体電解質型燃料電池 |
| KR101177621B1 (ko) * | 2010-06-25 | 2012-08-27 | 한국생산기술연구원 | 고체산화물 연료전지 단위셀의 제조방법 |
| US8968968B2 (en) * | 2010-11-16 | 2015-03-03 | Saint-Gobain Ceramics & Plastics, Inc. | Substantially flat single cells for SOFC stacks |
| US9642192B2 (en) * | 2011-08-04 | 2017-05-02 | Fuelcell Energy, Inc. | Method and manufacturing assembly for sintering fuel cell electrodes and impregnating porous electrodes with electrolyte powders by induction heating for mass production |
| US20140255736A1 (en) * | 2011-10-12 | 2014-09-11 | Toyota Jidosha Kabushiki Kaisha | Non-aqueous electrolyte secondary battery |
| CN102347495B (zh) * | 2011-10-19 | 2014-01-08 | 华北电力大学 | 固体氧化物燃料电池结构及其制备方法 |
| US20130316264A1 (en) * | 2012-05-24 | 2013-11-28 | Phillips 66 Company | Functionally layered electrolyte for solid oxide fuel cells |
| CN103872366B (zh) * | 2012-12-12 | 2016-12-07 | 中国科学院上海硅酸盐研究所 | 一种金属支撑固体氧化物燃料电池及其制备方法 |
| RU2522188C1 (ru) * | 2013-03-26 | 2014-07-10 | Федеральное государственное бюджетное учреждение науки Институт высокотемпературной электрохимии Уральского отделения Российской Академии наук | Способ получения двухслойного несущего катода для твердооксидных топливных элементов |
| US9660273B2 (en) | 2013-10-08 | 2017-05-23 | Phillips 66 Company | Liquid phase modification of solid oxide fuel cells |
| US10418657B2 (en) | 2013-10-08 | 2019-09-17 | Phillips 66 Company | Formation of solid oxide fuel cells by spraying |
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- 2007-11-23 KR KR1020097012019A patent/KR101172362B1/ko not_active Expired - Fee Related
- 2007-11-23 US US12/515,816 patent/US9496576B2/en not_active Expired - Fee Related
- 2007-11-23 EP EP07846794A patent/EP2084772A2/en not_active Withdrawn
- 2007-11-23 RU RU2009119261/07A patent/RU2427945C2/ru not_active IP Right Cessation
- 2007-11-23 CN CN200780043660.6A patent/CN101563805B/zh not_active Expired - Fee Related
- 2007-11-23 AU AU2007323291A patent/AU2007323291B2/en not_active Ceased
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- 2007-11-23 JP JP2009537554A patent/JP5219298B2/ja not_active Expired - Fee Related
- 2007-11-23 CA CA002669811A patent/CA2669811A1/en not_active Abandoned
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| RU2427945C2 (ru) | 2011-08-27 |
| JP2010510635A (ja) | 2010-04-02 |
| CA2669811A1 (en) | 2008-05-29 |
| EP2701227A1 (en) | 2014-02-26 |
| EP1928049A1 (en) | 2008-06-04 |
| EP2084772A2 (en) | 2009-08-05 |
| CN101563805B (zh) | 2015-09-02 |
| RU2009119261A (ru) | 2010-12-27 |
| CN103861470A (zh) | 2014-06-18 |
| KR20090094273A (ko) | 2009-09-04 |
| US20100062312A1 (en) | 2010-03-11 |
| CN101563805A (zh) | 2009-10-21 |
| NO20091876L (no) | 2009-07-28 |
| AU2007323291B2 (en) | 2011-07-07 |
| KR101172362B1 (ko) | 2012-08-08 |
| WO2008061782A3 (en) | 2008-12-24 |
| AU2007323291A1 (en) | 2008-05-29 |
| JP5219298B2 (ja) | 2013-06-26 |
| WO2008061782A2 (en) | 2008-05-29 |
| US9496576B2 (en) | 2016-11-15 |
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