KR101121315B1 - 개질기 - Google Patents

개질기 Download PDF

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Publication number
KR101121315B1
KR101121315B1 KR1020067015335A KR20067015335A KR101121315B1 KR 101121315 B1 KR101121315 B1 KR 101121315B1 KR 1020067015335 A KR1020067015335 A KR 1020067015335A KR 20067015335 A KR20067015335 A KR 20067015335A KR 101121315 B1 KR101121315 B1 KR 101121315B1
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KR
South Korea
Prior art keywords
reforming
exhaust gas
reformer
flow path
cylindrical body
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
KR1020067015335A
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English (en)
Korean (ko)
Other versions
KR20060132884A (ko
Inventor
가즈유키 히가시노
Original Assignee
이데미쓰 고산 가부시키가이샤
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Publication of KR20060132884A publication Critical patent/KR20060132884A/ko
Application granted granted Critical
Publication of KR101121315B1 publication Critical patent/KR101121315B1/ko
Anticipated expiration legal-status Critical
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/06—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds in tube reactors; the solid particles being arranged in tubes
    • B01J8/067—Heating or cooling the reactor
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/0242—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid flow within the bed being predominantly vertical
    • B01J8/0257—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid flow within the bed being predominantly vertical in a cylindrical annular shaped bed
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/0285—Heating or cooling the reactor
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/22—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds
    • C01B3/24—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds of hydrocarbons
    • C01B3/26—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds of hydrocarbons using catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/384—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts the catalyst being continuously externally heated
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
    • H01M8/0606—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants
    • H01M8/0612—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants from carbon-containing material
    • H01M8/0625—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants from carbon-containing material in a modular combined reactor/fuel cell structure
    • H01M8/0631—Reactor construction specially adapted for combination reactor/fuel cell
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/00106—Controlling the temperature by indirect heat exchange
    • B01J2208/00168—Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles
    • B01J2208/00212—Plates; Jackets; Cylinders
    • B01J2208/00221—Plates; Jackets; Cylinders comprising baffles for guiding the flow of the heat exchange medium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/00504—Controlling the temperature by means of a burner
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/0053—Controlling multiple zones along the direction of flow, e.g. pre-heating and after-cooling
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C01B2203/0233—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a steam reforming step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/06—Integration with other chemical processes
    • C01B2203/066—Integration with other chemical processes with fuel cells
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08—Methods of heating or cooling
    • C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
    • C01B2203/0811—Methods of heating the process for making hydrogen or synthesis gas by combustion of fuel
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • General Health & Medical Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Sustainable Energy (AREA)
  • General Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Fluid Mechanics (AREA)
  • Electrochemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Sustainable Development (AREA)
  • Manufacturing & Machinery (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Fuel Cell (AREA)
KR1020067015335A 2004-01-30 2005-01-24 개질기 Expired - Fee Related KR101121315B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP2004024552 2004-01-30
JPJP-P-2004-00024552 2004-01-30
PCT/JP2005/000859 WO2005073126A1 (ja) 2004-01-30 2005-01-24 改質器

Publications (2)

Publication Number Publication Date
KR20060132884A KR20060132884A (ko) 2006-12-22
KR101121315B1 true KR101121315B1 (ko) 2012-03-23

Family

ID=34823943

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1020067015335A Expired - Fee Related KR101121315B1 (ko) 2004-01-30 2005-01-24 개질기

Country Status (8)

Country Link
US (1) US8038960B2 (enExample)
EP (1) EP1712519A4 (enExample)
JP (1) JP4714023B2 (enExample)
KR (1) KR101121315B1 (enExample)
CN (1) CN1914118B (enExample)
CA (1) CA2553406A1 (enExample)
TW (1) TW200531339A (enExample)
WO (1) WO2005073126A1 (enExample)

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BRPI0608336B1 (pt) * 2005-03-10 2018-09-11 Shell Int Research sistema de processamento, sistema de aquecimento direto de quatro tubos para queima de um combustível e aquecimento direto de um fluido de processamento e método
CN101163918A (zh) * 2005-03-10 2008-04-16 国际壳牌研究有限公司 一种用于燃料燃烧和加热工艺流体的传热系统以及使用该系统的工艺
MX2007010987A (es) 2005-03-10 2007-09-25 Shell Int Research Metodo para iniciar un sistema de calentamiento directo para la combustion sin flama de combustible, y el calentamiento directo de un fluido de proceso.
JP4852295B2 (ja) * 2005-10-25 2012-01-11 出光興産株式会社 改質器及び燃料電池システム
KR101240704B1 (ko) 2006-01-17 2013-03-07 삼성에스디아이 주식회사 이동가능한 열원을 갖는 연료개질 시스템 및 이를 구비한연료전지 시스템
US7506685B2 (en) * 2006-03-29 2009-03-24 Pioneer Energy, Inc. Apparatus and method for extracting petroleum from underground sites using reformed gases
CA2669752A1 (en) * 2006-11-08 2008-05-15 Idemitsu Kosan Co., Ltd. Reformer, reforming unit, and fuel cell system
JP2008120606A (ja) * 2006-11-08 2008-05-29 Idemitsu Kosan Co Ltd 改質器、改質ユニットおよび燃料電池システム
KR100824526B1 (ko) * 2007-01-12 2008-04-22 삼성에스디아이 주식회사 복사 에너지를 이용하는 연료 개질장치
JP5095264B2 (ja) * 2007-05-16 2012-12-12 Ｊｘ日鉱日石エネルギー株式会社 改質器および間接内部改質型高温型燃料電池
WO2009014979A2 (en) * 2007-07-20 2009-01-29 Shell Oil Company A flameless combustion heater
JP2010534311A (ja) * 2007-07-20 2010-11-04 シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー 無炎燃焼加熱器
KR101266673B1 (ko) * 2007-11-01 2013-05-28 에스케이이노베이션 주식회사 수증기 개질방식에 의한 수소발생장치
KR101292737B1 (ko) * 2007-11-02 2013-08-05 에스케이이노베이션 주식회사 수증기 개질반응을 이용한 수소발생장치
RU2454604C2 (ru) * 2008-02-01 2012-06-27 АйЭйчАй КОРПОРЕЙШН Пламенный нагреватель
KR101624359B1 (ko) * 2010-02-09 2016-05-26 에스케이이노베이션 주식회사 배기가스 배출이 개선된 수증기 개질 반응을 이용한 수소발생장치
EP2555852B1 (en) * 2010-04-05 2015-09-16 Generon IGS, Inc. Integrated membrane module for gas dehydration and gas separation
JP5673816B2 (ja) * 2011-06-01 2015-02-18 日産自動車株式会社 改質器
CA2856558C (en) * 2011-12-06 2019-06-11 Hy9 Corporation Catalyst-containing reactor system and associated methods
CA2876374C (en) 2012-06-14 2020-09-01 Nuvera Fuel Cells, Inc. Steam reformers for the production of hydrogen reformate and uses thereof
JP6612166B2 (ja) * 2016-03-29 2019-11-27 東京瓦斯株式会社 燃料処理装置及び燃料電池モジュール
JP6506856B2 (ja) * 2016-06-16 2019-04-24 京セラ株式会社 改質器、セルスタック装置、燃料電池モジュールおよび燃料電池装置
CN109798508B (zh) * 2017-11-17 2020-11-03 韩国能量技术研究院 原料预热部一体型水蒸气改质器及含其的氢制备系统
US10933369B2 (en) * 2018-05-25 2021-03-02 Generon Igs, Inc. Gas dehydration membrane module with integral filter
KR102315289B1 (ko) * 2019-12-18 2021-10-20 에이치앤파워(주) 다중 개질 반응기 구성이 가능한 수증기 개질장치
TWI759922B (zh) 2020-10-23 2022-04-01 財團法人工業技術研究院 具燃燒重組功能之燃燒噴嘴

Citations (3)

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JPS6311501A (ja) 1986-07-03 1988-01-19 Fuji Electric Co Ltd 改質装置
JP2001342002A (ja) * 2000-05-30 2001-12-11 Kansai Electric Power Co Inc:The 燃料改質器
JP2003040605A (ja) * 2001-07-31 2003-02-13 Daikin Ind Ltd 改質装置及び燃料電池システム

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JPH02102101A (ja) * 1988-10-12 1990-04-13 Fuji Electric Co Ltd 燃料電池の改質器
KR100209989B1 (ko) * 1996-12-23 1999-07-15 남창우 천연가스형 수소발생장치
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EP1167282B1 (en) 1999-12-28 2007-04-04 Daikin Industries, Ltd. Shift reactor with heat-exchanger
WO2002002459A1 (fr) 2000-07-04 2002-01-10 Sanyo Electric Co., Ltd. Reacteur de reformage de carburant hydrocarbone
JP3808743B2 (ja) * 2000-10-10 2006-08-16 東京瓦斯株式会社 単管円筒式改質器
JP4161612B2 (ja) * 2002-05-15 2008-10-08 株式会社Ｉｈｉ 燃料改質装置の起動方法
JP4782423B2 (ja) * 2002-09-05 2011-09-28 シエル・インターナシヨネイル・リサーチ・マーチヤツピイ・ベー・ウイ 高純度水素の製造装置及び方法
US7341609B2 (en) * 2002-10-03 2008-03-11 Genesis Fueltech, Inc. Reforming and hydrogen purification system
US7517372B2 (en) * 2004-02-26 2009-04-14 General Motors Corporation Integrated fuel processor subsystem with quasi-autothermal reforming

Patent Citations (3)

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Publication number Priority date Publication date Assignee Title
JPS6311501A (ja) 1986-07-03 1988-01-19 Fuji Electric Co Ltd 改質装置
JP2001342002A (ja) * 2000-05-30 2001-12-11 Kansai Electric Power Co Inc:The 燃料改質器
JP2003040605A (ja) * 2001-07-31 2003-02-13 Daikin Ind Ltd 改質装置及び燃料電池システム

Also Published As

Publication number Publication date
TW200531339A (en) 2005-09-16
JP4714023B2 (ja) 2011-06-29
KR20060132884A (ko) 2006-12-22
CA2553406A1 (en) 2005-08-11
JPWO2005073126A1 (ja) 2007-09-06
EP1712519A1 (en) 2006-10-18
TWI357682B (enExample) 2012-02-01
EP1712519A4 (en) 2009-01-14
CN1914118A (zh) 2007-02-14
CN1914118B (zh) 2010-08-11
US20080244973A1 (en) 2008-10-09
US8038960B2 (en) 2011-10-18
WO2005073126A1 (ja) 2005-08-11

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