KR101105957B1 - 생물학적으로 생성된 1,3-프로판디올의 정제 - Google Patents

생물학적으로 생성된 1,3-프로판디올의 정제 Download PDF

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Publication number
KR101105957B1
KR101105957B1 KR1020057020976A KR20057020976A KR101105957B1 KR 101105957 B1 KR101105957 B1 KR 101105957B1 KR 1020057020976 A KR1020057020976 A KR 1020057020976A KR 20057020976 A KR20057020976 A KR 20057020976A KR 101105957 B1 KR101105957 B1 KR 101105957B1
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South Korea
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product
propanediol
ion exchange
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Korean (ko)
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KR20060052677A (ko
Inventor
데니스 마이클 아드케슨
알버트 더블유. 알솝
타일러 티 아메스
루이스 알베르토 추
제임스 엠. 디즈니
브라이언 씨. 드라비스
패트릭 피츠기본
제임스 엠. 가디
에프. 글렌 갈라거
윌리암 에프. 렌하트
제퍼슨 씨. 리벤스
마이클 엘. 루이벤
메이스 씨판
로버트 이. 트로터
그레고리 엠. 웬트
유진 케이. 유
Original Assignee
테이트 앤드 라일 인그레디언츠 아메리카스, 인크.
이 아이 듀폰 디 네모아 앤드 캄파니
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Publication of KR20060052677A publication Critical patent/KR20060052677A/ko
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/02—Reverse osmosis; Hyperfiltration ; Nanofiltration
    • B01D61/027—Nanofiltration
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D3/00—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D3/00—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
    • B01D3/001—Processes specially adapted for distillation or rectification of fermented solutions
    • B01D3/002—Processes specially adapted for distillation or rectification of fermented solutions by continuous methods
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D3/00—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
    • B01D3/14—Fractional distillation or use of a fractionation or rectification column
    • B01D3/143—Fractional distillation or use of a fractionation or rectification column by two or more of a fractionation, separation or rectification step
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D3/00—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
    • B01D3/14—Fractional distillation or use of a fractionation or rectification column
    • B01D3/143—Fractional distillation or use of a fractionation or rectification column by two or more of a fractionation, separation or rectification step
    • B01D3/145—One step being separation by permeation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/02—Reverse osmosis; Hyperfiltration ; Nanofiltration
    • B01D61/04—Feed pretreatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/14—Ultrafiltration; Microfiltration
    • B01D61/149—Multistep processes comprising different kinds of membrane processes selected from ultrafiltration or microfiltration
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/58—Multistep processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82B—NANOSTRUCTURES FORMED BY MANIPULATION OF INDIVIDUAL ATOMS, MOLECULES, OR LIMITED COLLECTIONS OF ATOMS OR MOLECULES AS DISCRETE UNITS; MANUFACTURE OR TREATMENT THEREOF
    • B82B3/00—Manufacture or treatment of nanostructures by manipulation of individual atoms or molecules, or limited collections of atoms or molecules as discrete units
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/14—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group
    • C07C29/141—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group with hydrogen or hydrogen-containing gases
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/74—Separation; Purification; Use of additives, e.g. for stabilisation
    • C07C29/76—Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/74—Separation; Purification; Use of additives, e.g. for stabilisation
    • C07C29/76—Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment
    • C07C29/80—Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment by distillation
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
    • C12P7/00—Preparation of oxygen-containing organic compounds
    • C12P7/02—Preparation of oxygen-containing organic compounds containing a hydroxy group
    • C12P7/04—Preparation of oxygen-containing organic compounds containing a hydroxy group acyclic
    • C12P7/18—Preparation of oxygen-containing organic compounds containing a hydroxy group acyclic polyhydric
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2311/00—Details relating to membrane separation process operations and control
    • B01D2311/04—Specific process operations in the feed stream; Feed pretreatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/14—Ultrafiltration; Microfiltration
    • B01D61/145—Ultrafiltration
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/14—Ultrafiltration; Microfiltration
    • B01D61/145—Ultrafiltration
    • B01D61/146—Ultrafiltration comprising multiple ultrafiltration steps
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/14—Ultrafiltration; Microfiltration
    • B01D61/147—Microfiltration
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/14—Ultrafiltration; Microfiltration
    • B01D61/147—Microfiltration
    • B01D61/1471—Microfiltration comprising multiple microfiltration steps

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Water Supply & Treatment (AREA)
  • Nanotechnology (AREA)
  • Wood Science & Technology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Zoology (AREA)
  • Biochemistry (AREA)
  • Microbiology (AREA)
  • General Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Biotechnology (AREA)
  • Bioinformatics & Cheminformatics (AREA)
  • General Engineering & Computer Science (AREA)
  • General Health & Medical Sciences (AREA)
  • Genetics & Genomics (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Preparation Of Compounds By Using Micro-Organisms (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
KR1020057020976A 2003-05-06 2004-05-05 생물학적으로 생성된 1,3-프로판디올의 정제 Expired - Fee Related KR101105957B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US46823103P 2003-05-06 2003-05-06
US60/468,231 2003-05-06
PCT/US2004/014043 WO2004101479A2 (en) 2003-05-06 2004-05-05 Purification of biologically-produced 1,3-propanediol

Publications (2)

Publication Number Publication Date
KR20060052677A KR20060052677A (ko) 2006-05-19
KR101105957B1 true KR101105957B1 (ko) 2012-01-18

Family

ID=33452192

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1020057020976A Expired - Fee Related KR101105957B1 (ko) 2003-05-06 2004-05-05 생물학적으로 생성된 1,3-프로판디올의 정제

Country Status (10)

Country Link
US (3) US7919658B2 (enExample)
EP (2) EP2239334A1 (enExample)
JP (2) JP4814794B2 (enExample)
KR (1) KR101105957B1 (enExample)
CN (1) CN100478446C (enExample)
BR (1) BRPI0410685B8 (enExample)
CA (1) CA2522928C (enExample)
DE (1) DE602004028359D1 (enExample)
TW (1) TW200506063A (enExample)
WO (1) WO2004101479A2 (enExample)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108117481A (zh) * 2016-11-29 2018-06-05 中国石油化工股份有限公司 一种从发酵液中分离提取1,3-丙二醇的方法
WO2025258949A1 (ko) * 2024-06-10 2025-12-18 지에스칼텍스 주식회사 다가 알코올의 정제 방법

Families Citing this family (139)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20040225107A1 (en) * 2003-05-06 2004-11-11 Sunkara Hari Babu Polytrimethylene ether glycol with excellent quality from biochemically-derived 1,3-propanediol
JP4814794B2 (ja) * 2003-05-06 2011-11-16 イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー 生物学的に生産された１，３−プロパンジオールの精製
US7888405B2 (en) 2004-01-30 2011-02-15 E. I. Du Pont De Nemours And Company Aliphatic-aromatic polyesters, and articles made therefrom
US20080103217A1 (en) * 2006-10-31 2008-05-01 Hari Babu Sunkara Polyether ester elastomer composition
US7396896B2 (en) * 2004-12-21 2008-07-08 E.I. Dupont De Nemours And Company Poly(trimethylene terephthalate) composition and shaped articles prepared therefrom
US7629396B2 (en) * 2005-02-23 2009-12-08 E.I. Du Pont De Nemours And Company Silicon-containing polytrimethylene homo- for copolyether composition
US20060189711A1 (en) * 2005-02-23 2006-08-24 Ng Howard C Silicon-containing polytrimethylene homo- or copolyether composition
JP5652986B2 (ja) * 2005-04-22 2015-01-14 三菱化学株式会社 ポリエステルペレット及びその貯蔵方法
EP3919543A3 (en) * 2005-04-22 2022-03-16 Mitsubishi Chemical Corporation Biomass-resource-derived polyester and production process thereof
JP2006328377A (ja) * 2005-04-26 2006-12-07 Mitsubishi Chemicals Corp ポリエステルペレットの貯蔵方法
JP2006328378A (ja) * 2005-04-26 2006-12-07 Mitsubishi Chemicals Corp ポリエステルの製造方法
JP2006328374A (ja) * 2005-04-26 2006-12-07 Mitsubishi Chemicals Corp ポリエステルの製造方法
JP2006328370A (ja) * 2005-04-26 2006-12-07 Mitsubishi Chemicals Corp ポリエステルの製造方法
US7161045B1 (en) 2005-08-16 2007-01-09 E. I. Du Pont De Nemours And Company Process for manufacture of polytrimethylene ether glycol
US7157607B1 (en) 2005-08-16 2007-01-02 E. I. Du Pont De Nemours And Company Manufacture of polytrimethylene ether glycol
JP5074678B2 (ja) * 2005-08-26 2012-11-14 株式会社堀場製作所 塩分ミスト除去装置およびこれを用いた分析装置
US7357985B2 (en) * 2005-09-19 2008-04-15 E.I. Du Pont De Nemours And Company High crimp bicomponent fibers
US20070129524A1 (en) * 2005-12-06 2007-06-07 Sunkara Hari B Thermoplastic polyurethanes comprising polytrimethylene ether soft segments
US20070128459A1 (en) * 2005-12-07 2007-06-07 Kurian Joseph V Poly(trimethylene terephthalate)/poly(alpha-hydroxy acid) films
US7666501B2 (en) * 2005-12-07 2010-02-23 E. I. Du Pont De Nemours And Company Poly(trimethylene terephthalate)/poly(alpha-hydroxy acid) bi-constituent filaments
US20070129503A1 (en) * 2005-12-07 2007-06-07 Kurian Joseph V Poly(trimethylene terephthalate)/poly(alpha-hydroxy acid) molded, shaped articles
US7164046B1 (en) 2006-01-20 2007-01-16 E. I. Du Pont De Nemours And Company Manufacture of polytrimethylene ether glycol
US7388115B2 (en) * 2006-01-20 2008-06-17 E. I. Du Pont De Nemours And Company Manufacture of polytrimethylene ether glycol
US20070203371A1 (en) * 2006-01-23 2007-08-30 Sunkara Hari B Process for producing polytrimethylene ether glycol
TW200732292A (en) * 2006-02-01 2007-09-01 Shell Int Research A method of treating an aldehyde mixture, use of the treated aldehyde, and an alcohol
US20070275139A1 (en) * 2006-02-10 2007-11-29 Melissa Joerger Food compositions comprising renewably-based, biodegradable1,3-propanediol
EP1991515A4 (en) * 2006-02-10 2013-03-06 Dupont Tate & Lyle Bio Products Company Llc BIOLOGICAL SOURCE AND ITS CONJUGATES AS NATURAL AND NON-BREATHING SOLVENTS FOR BIOMASS EXTRACTS, SCENT CONCENTRATES AND OILS
JP2009532506A (ja) * 2006-02-10 2009-09-10 デユポン・テイト・アンド・ライル・バイオ・プロダクツ・カンパニー・エルエルシー 生物学的ベースの１，３−プロパンジオールのモノエステルおよびジエステルを含む組成物
WO2007095255A2 (en) 2006-02-10 2007-08-23 Dupont Tate & Lyle Bio Products Company, Llc Biodegradable compositions comprising renewably-based, biodegradable 1.3-propanediol
WO2007136586A2 (en) * 2006-05-17 2007-11-29 E. I. Du Pont De Nemours And Company Personal care compositions
US20080039582A1 (en) * 2006-07-28 2008-02-14 Hari Babu Sunkara Polytrimethylene ether-based polyurethane ionomers
JP5245227B2 (ja) * 2006-08-23 2013-07-24 三菱瓦斯化学株式会社 疎水性化合物の起泡による分離法
US20080175875A1 (en) * 2006-09-25 2008-07-24 Hari Babu Sunkara Cosmetic compositions
MX2008012560A (es) * 2006-10-27 2008-10-14 Archer Daniels Midland Co Procesos para aislar o purificar propilenglicol, etilenglicol y productos producidos de los mismos.
US7531593B2 (en) 2006-10-31 2009-05-12 E.I. Du Pont De Nemours And Company Thermoplastic elastomer blend composition
US20080108845A1 (en) * 2006-11-07 2008-05-08 Hari Babu Sunkara Polytrimethylene ether glycol esters
US20080176957A1 (en) * 2006-11-15 2008-07-24 Dupont Tate & Lyle Bio Products Company, Llc Preservative compositions comprising renewably-based, biodegradable 1,3-propanediol
US20080135662A1 (en) * 2006-12-06 2008-06-12 Chang Jing C Melt-spun elastoester multifilament yarns
US20090131625A1 (en) * 2007-11-21 2009-05-21 Kurian Joseph V Processes for making elastomeric polyester esters from post-consumer polyester
CN100999742B (zh) * 2007-01-09 2011-05-11 清华大学 一种发酵生产1，3-丙二醇的高产工艺
US7714174B2 (en) * 2007-03-27 2010-05-11 E. I. Du Pont De Nemours And Company Lower-color polytrimethylene ether glycol using hydride compounds
CN101657515B (zh) * 2007-04-03 2013-04-17 纳幕尔杜邦公司 使用多元醇与离子液体的混合物的热传递体系
CN101066906B (zh) * 2007-05-24 2010-09-08 江苏汉邦科技有限公司 四区模拟移动床分离纯化发酵液中的1,3-丙二醇的方法
WO2008156612A1 (en) * 2007-06-15 2008-12-24 Cargill, Incorporated Process for the purification of crude glycerol compositions
JP2009013094A (ja) * 2007-07-03 2009-01-22 Teijin Fibers Ltd グリコールの製造方法
CN101117306B (zh) * 2007-07-20 2011-01-19 三达膜科技（厦门）有限公司 一种1,3-丙二醇发酵液的除杂和脱盐方法
US20090043021A1 (en) * 2007-08-06 2009-02-12 Jing-Chung Chang Flame retardant polytrimethylene terephthalate composition
US20090043016A1 (en) * 2007-08-06 2009-02-12 Jing-Chung Chang Flame retardant polytrimethylene terephthalate composition
US7855244B2 (en) * 2007-08-06 2010-12-21 E.I. Du Pont De Nemours And Company Flame retardant polytrimethylene terephthalate composition
US20090043019A1 (en) * 2007-08-06 2009-02-12 Jing-Chung Chang Flame retardant polytrimethylene terephthalate composition
US20090043017A1 (en) * 2007-08-06 2009-02-12 Jing-Chung Chang Flame retardant polytrimethylene terephthalate composition
US20090054282A1 (en) * 2007-08-24 2009-02-26 E.I. Dupont De Nemours And Company Lubrication oil compositions
US20090054283A1 (en) * 2007-08-24 2009-02-26 E.I. Dupont De Nemours And Company Lubrication oil compositions
BRPI0815243A2 (pt) * 2007-08-24 2019-09-24 Du Pont composição de óleo lubrificante
JP2010537001A (ja) * 2007-08-24 2010-12-02 イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー 潤滑油組成物
US8703681B2 (en) 2007-08-24 2014-04-22 E I Du Pont De Nemours And Company Lubrication oil compositions
DE102007048277A1 (de) * 2007-10-08 2009-04-09 Agraferm Technologies Ag Verfahren und Vorrichtung zur mikrobiellen Herstellung eines bestimmten Produktes und Methan
WO2009048445A2 (en) 2007-10-09 2009-04-16 E. I. Du Pont De Nemours And Company Deodorant compositions
US7919017B2 (en) * 2007-11-12 2011-04-05 E. I. Du Pont De Nemours And Company Electrical insulation fluids for use in electrical apparatus
EP2220018B1 (en) * 2007-11-30 2012-07-04 Metabolic Explorer Method for purifying an alcohol from a fermentation broth
US20090197781A1 (en) 2008-01-31 2009-08-06 Hari Babu Sunkara Wellbore Fluids Comprising Poly(trimethylene ether) glycol Polymers
JP5343628B2 (ja) * 2008-03-04 2013-11-13 東レ株式会社 光透過性に優れたバイオ材料由来グリコールの製造方法及びそれから得られるポリエステルの製造方法
WO2009137443A1 (en) 2008-05-07 2009-11-12 E. I. Du Pont De Nemours And Company Plasticizers comprising poly(trimethylene ether) glycol esters
JP5536074B2 (ja) * 2008-10-03 2014-07-02 メタボリック エクスプローラー 流下液膜式蒸発器、拭き取り膜式蒸発器、薄膜蒸発器、または短経路蒸発器を用いて発酵ブロスからアルコールを精製するための方法
US20110172329A1 (en) * 2008-10-16 2011-07-14 E.I. Du Pont De Nemours And Company Flame retardant poly(trimethylene terephthalate) composition
JP5625334B2 (ja) * 2008-11-28 2014-11-19 東レ株式会社 ジオールまたはトリオールの製造方法
EP2358782A1 (en) 2008-12-15 2011-08-24 E. I. du Pont de Nemours and Company Copolyesters with enhanced tear strength
AU2009333397A1 (en) 2008-12-15 2010-07-08 E. I. Du Pont De Nemours And Company Copolyesters with enhanced tear strength
JP2012512279A (ja) 2008-12-15 2012-05-31 イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー 脂肪族−芳香族コポリエーテルエステルの重合
WO2010075023A1 (en) 2008-12-15 2010-07-01 E. I. Du Pont De Nemours And Company Copolyesters with enhanced tear strength
US20100152329A1 (en) 2008-12-17 2010-06-17 E. I. Du Pont De Nemours And Company Poly(trimethylene terephthalate) polymer blends that have reduced whitening
US20100152411A1 (en) 2008-12-17 2010-06-17 E.I. Du Pont De Nemours And Company Poly(trimethylene terephthalate) with reduced whitening
WO2010077937A1 (en) 2008-12-17 2010-07-08 E. I. Du Pont De Nemours And Company Reduction of whitening of poly(trimethylene terephthalate) parts by solvent exposure
JP5293157B2 (ja) * 2008-12-22 2013-09-18 東レ株式会社 ブタノールの製造方法
CA2754231A1 (en) 2009-03-03 2010-09-10 E.I. Du Pont De Nemours And Company Poly(trimethylene terephthalate) pellets with reduced oligomers and method to measure oligomer reduction
SG176654A1 (en) * 2009-06-04 2012-01-30 Genomatica Inc Process of separating components of a fermentation broth
WO2011038178A1 (en) 2009-09-24 2011-03-31 E. I. Du Pont De Nemours And Company Poly(hydroxyalkanoic acid) plasticized with poly(trimethylene ether) glycol
US20110112331A1 (en) * 2009-11-09 2011-05-12 E.I. Du Pont De Nemours And Company Method for phase separation of polytrimethylene ether glycol in salt solution
WO2011062600A1 (en) 2009-11-19 2011-05-26 E. I. Du Pont De Nemours And Company Polycondensation with a kneader reactor
WO2011076690A1 (en) 2009-12-22 2011-06-30 Metabolic Explorer Method for purifying 1,2-propanediol from a fermentation broth
TWI500768B (zh) 2010-07-05 2015-09-21 Metabolic Explorer Sa 由蔗糖製備１，３－丙二醇之方法
CN103119142B (zh) 2010-09-24 2015-12-02 陶氏环球技术有限责任公司 用于润滑剂的非芳族系抗氧化剂
WO2012071241A1 (en) 2010-11-22 2012-05-31 E. I. Du Pont De Nemours And Company Block copolymers comprising poly(1,3-trimethylene terephthalate) and poly(1,3-trimethylene 2,6-naphthalate)
TR201010403A2 (tr) * 2010-12-13 2012-07-23 Bsh Ev Aletleri̇ San. Ve Ti̇c. A.Ş. BEYAZ EŞYA KAPI İÇ KASASI VE DEKORATİF DlŞ YÜZEY MESAFE ELEMANI
US8247526B2 (en) 2010-12-20 2012-08-21 E I Du Pont De Nemours And Company Process for the preparation of polyalkylene ether glycol
KR20140052934A (ko) 2011-02-22 2014-05-07 도레이 카부시키가이샤 디올 조성물 및 폴리에스테르
US9018424B2 (en) 2011-03-30 2015-04-28 Toray Industries, Inc. Method of producing diol or triol
US8558037B2 (en) 2011-03-30 2013-10-15 Toray Industries, Inc. Method of producing butanol
WO2012130316A1 (en) 2011-03-31 2012-10-04 Metabolic Explorer Method for purifying mpg (monopropylene glycol) from a fermentation broth
CN103492542B (zh) 2011-04-13 2016-05-25 Elc管理公司 适用于个人护理组合物的温和型阴离子表面活性剂
AU2012242887B2 (en) 2011-04-13 2015-05-07 Elc Management Llc Conditioning agents for personal care compositions
WO2012155074A1 (en) * 2011-05-12 2012-11-15 Virent, Inc. Process for purifying lignocellulosic feedstocks
US8629243B2 (en) 2011-08-16 2014-01-14 E I Du Pont De Nemours And Company Variant sucrose transporter polypeptides that enable faster sucrose utilization in bacteria
EP2684906B1 (en) 2011-09-06 2016-04-06 Toray Industries, Inc. Polyester with excellent heat resistance and method for producing same
EP2767589B1 (en) * 2011-10-14 2017-12-20 Toray Industries, Inc. Process for producing 2,3-butanediol
JP5755995B2 (ja) * 2011-10-26 2015-07-29 株式会社日立製作所 超臨界水を用いた反応プロセス
US20130206580A1 (en) * 2011-12-08 2013-08-15 Oakwood Foods. LLC d/b/a Oakwood Technologies Continuous coolant purification process and device
US8759559B2 (en) 2012-04-18 2014-06-24 E I Du Pont De Nemours And Company Processes for preparing polytrimethylene ether glycol esters
EP2843061B1 (en) * 2012-04-26 2017-06-07 Toray Industries, Inc. Method for producing sugar solution
EA030870B1 (ru) * 2012-06-05 2018-10-31 Дженоматика, Инк. Способы получения сложного полиэфира и полиуретана
WO2013183592A1 (ja) 2012-06-05 2013-12-12 三菱化学株式会社 １，４－ブタンジオールの製造方法
JP2012245519A (ja) * 2012-07-17 2012-12-13 Horiba Ltd 塩分ミスト除去装置およびこれを用いた分析装置
EP2890769B1 (en) * 2012-08-29 2019-08-21 Archer Daniels Midland Company Removal of organic salts from bio-derived glycol products
FI2937328T4 (fi) 2012-12-19 2025-06-11 Toray Industries Alkoholin valmistusmenetelmä
JP6048159B2 (ja) * 2013-01-22 2016-12-21 三菱化学株式会社 ポリウレタンの製造方法
EP4403543A3 (en) * 2013-03-15 2024-11-20 Genomatica, Inc. Process and systems for obtaining 1,4-butanediol from fermentation broths
JP2015017087A (ja) * 2013-06-13 2015-01-29 三菱化学株式会社 ジオールの製造方法
EP3041942B1 (en) * 2013-09-03 2020-07-01 PTT Global Chemical Public Company Limited A process for manufacturing acrylic acid, acrylonitrile and 1,4-butanediol from 1,3-propanediol
US9309205B2 (en) * 2013-10-28 2016-04-12 Wincom, Inc. Filtration process for purifying liquid azole heteroaromatic compound-containing mixtures
EP2896628B1 (en) 2014-01-20 2018-09-19 Jennewein Biotechnologie GmbH Process for efficient purification of neutral human milk oligosaccharides (HMOs) from microbial fermentation
EP3919565A1 (en) 2014-02-24 2021-12-08 DuPont Industrial Biosciences USA, LLC Plasticized polyamide compositions
JP6486020B2 (ja) * 2014-05-30 2019-03-20 三菱ケミカル株式会社 ２，３−ブタンジオールの製造方法
US10086339B2 (en) 2015-03-10 2018-10-02 The University Of Connecticut Polymers and membranes for separation of polar organic compounds from aqueous mixtures and methods of using
WO2016186122A1 (ja) * 2015-05-20 2016-11-24 東洋紡株式会社 ポリエステル樹脂
US9968531B2 (en) 2015-08-05 2018-05-15 Dupont Tate & Lyle Bio Products Company, Llc Deodorants containing 1,3-propanediol
FR3047171A1 (fr) 2016-01-29 2017-08-04 Plant Advanced Tech Pat Esters de dipropylene glycol des acides dicafeoylquiniques, extrait vegetal les contenant, procede d'obtention et utilisations
CN105777492A (zh) * 2016-04-19 2016-07-20 中石化上海工程有限公司 1,3-丙二醇的精馏提浓方法
CN105732321A (zh) * 2016-04-19 2016-07-06 中石化上海工程有限公司 1,3-丙二醇的精馏提浓装置
FR3059236B1 (fr) 2016-11-25 2019-05-17 Plant Advanced Technologies Pat Extraits de plantes du genre tagetes et leurs utilisations
CN106748648A (zh) * 2016-12-02 2017-05-31 苏州苏震生物工程有限公司 一种1,3‑丙二醇发酵液脱盐除杂系统及方法
FR3061657B1 (fr) 2017-01-09 2020-01-03 Plant Advanced Technologies Pat Preparation d’un extrait racinaire de filipendula ulmaria et utilisations cosmetiques
JP2020512351A (ja) * 2017-03-31 2020-04-23 ジェノマティカ， インコーポレイテッド 発酵ブロスから１，３−ブタンジオールを取得するためのプロセスおよびシステム
FR3069161B1 (fr) 2017-07-21 2019-08-30 Plant Advanced Technologies Pat Extraits racinaires de polygonum multiflorum et leurs utilisations
FR3072025B1 (fr) 2017-10-06 2019-11-01 Plant Advanced Technologies Pat Extraits racinaires de plantes du genre morus et leurs utilisations
CN107617251A (zh) * 2017-10-19 2018-01-23 苏州苏震生物工程有限公司 一种用于1,3‑丙二醇和2,3‑丁二醇发酵液预处理的设备及工艺
MX2020005449A (es) * 2017-11-27 2020-08-27 Novamont Spa Procedimiento para la produccion de 1,4-butanodiol a partir de fuentes renovables y poliesteres obtenidos del mismo.
US11414365B2 (en) 2018-01-30 2022-08-16 Inolex Investment Corporation Natural 1,2-alkanediols, compositions having natural 1,2-alkanediols and processes for making the same
WO2020006043A1 (en) 2018-06-28 2020-01-02 Dupont Industrial Biosciences Usa, Llc Spun yarn comprising polyester staple fibre and fabric comprising the same
CN113166008B (zh) 2018-09-21 2024-02-06 维尔萨利斯股份公司 用于从发酵液纯化bio-1,3-丁二醇的方法
EP4051008A1 (en) 2019-11-01 2022-09-07 Primient Covation LLC Use and methods of 1,3-propanediol to improve taste and/or off-taste qualities
CN112843762B (zh) * 2019-11-26 2024-05-24 南京华基塔业有限公司 一种由寡聚物制备丙交酯的反应系统及方法
CN114075097B (zh) * 2021-04-21 2024-06-14 广州国宏新材料有限公司 膜过滤处理1,3-丙二醇发酵液的方法和装置
EP4349445A4 (en) * 2021-06-02 2025-05-07 Nippon Shokubai Co., Ltd. TANK IMPLEMENTED IN A PURIFICATION DEVICE
WO2022265429A1 (ko) * 2021-06-16 2022-12-22 지에스칼텍스 주식회사 발효액으로부터 목적한 화합물을 수득하는 방법
CN113337548B (zh) * 2021-08-02 2022-03-22 苏州苏震生物工程有限公司 一种生物基1,3-丙二醇的制备方法
CN114249633B (zh) * 2022-01-05 2023-10-27 江苏扬农化工集团有限公司 一种分离提纯1,3-丙二醇的方法
CN114504872A (zh) * 2022-02-15 2022-05-17 北京袭明科技有限公司 一种高纯电子级乙二醇生产方法及装置
KR102810479B1 (ko) * 2022-08-04 2025-05-21 씨제이제일제당(주) 색가 모니터링을 통한 정제 공정 제어 방법 및 시스템, 및 폴리하이드록시알카노에이트 수지의 제조 방법
EP4586828A1 (en) 2022-09-16 2025-07-23 Primient Covation LLC Compositions comprising and methods of using 1,3-propanediol to improve sweetness and/or reduce bitterness of sweeteners

Family Cites Families (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4380678A (en) 1981-01-21 1983-04-19 Hydrocarbon Research, Inc. Multi-stage aldoses to polyols process
US5194159A (en) 1989-12-27 1993-03-16 Union Carbide Chemicals & Plastics Technology Corporation Treatment of lower glycol-containing operative fluids
US5034134A (en) * 1989-12-27 1991-07-23 Union Carbide Chemicals And Plastics Technology Corporation Treatment of impurity-containing liquid streams in ethylene oxide/glycol processes with semi-permeable membranes
US5223144A (en) * 1990-08-08 1993-06-29 First Brands Corporation Process for treatment of aqueous soluions of polyhydric alcohols
US5340909A (en) * 1991-12-18 1994-08-23 Hoechst Celanese Corporation Poly(1,3-propylene terephthalate)
DE4218282A1 (de) 1992-06-03 1993-12-09 Degussa Verfahren zur Herstellung von 1,3-Propandiol
DE4222708A1 (de) * 1992-07-10 1994-01-13 Degussa Verfahren zur Herstellung von 1,3-Propandiol
US5527973A (en) * 1994-12-16 1996-06-18 Kelsey; Donald R. Purification of 1,3-propanediol
US5686276A (en) * 1995-05-12 1997-11-11 E. I. Du Pont De Nemours And Company Bioconversion of a fermentable carbon source to 1,3-propanediol by a single microorganism
AU733534B2 (en) * 1996-11-13 2001-05-17 E.I. Du Pont De Nemours And Company Method for the production of 1,3-propanediol by recombinant microorganisms
CA2625060A1 (en) * 1996-11-13 1998-05-22 E.I. Du Pont De Nemours And Company Method for the production of glycerol by recombinant organisms
JP4200555B2 (ja) * 1997-10-07 2008-12-24 三菱化学株式会社 高純度エリスリトール結晶の製造方法
DE19840277A1 (de) * 1998-09-04 2000-03-09 Degussa Verfahren zur Reduzierung des Gehalts an Acetalen oder Ketalen in alkoholischen Reaktionsgemischen
AU1234400A (en) 1998-10-27 2000-05-15 Cargill Incorporated Method for purifying a polyol product stream
US6245879B1 (en) * 1999-01-29 2001-06-12 Shell Oil Company Purification of 1,3-propanediol in carbonyl-containing stream
US20040198965A1 (en) * 1999-04-20 2004-10-07 Cargill B.V. D-galactose isolation system
CA2386169A1 (en) 1999-09-30 2001-04-12 Cognis Corporation Improved fermentation process
US6361983B1 (en) * 1999-09-30 2002-03-26 E. I. Du Pont De Nemours And Company Process for the isolation of 1,3-propanediol from fermentation broth
US6538164B1 (en) * 1999-09-30 2003-03-25 E. I. Du Pont De Nemours And Company Recovery process for volatile compounds from solids in aqueous solution
KR100677809B1 (ko) * 1999-12-17 2007-02-05 이 아이 듀폰 디 네모아 앤드 캄파니 폴리트리메틸렌 에테르 글리콜 및 그의 공중합체의 제조방법
AU2270901A (en) * 1999-12-17 2001-06-25 E.I. Du Pont De Nemours And Company Continuous process for the preparation of polytrimethylene ether glycol
US6479716B2 (en) * 2000-03-29 2002-11-12 Archer-Daniels-Midland Company Method of recovering 1,3-propanediol from fermentation broth
WO2001073097A2 (en) 2000-03-29 2001-10-04 Archer-Daniels-Midland Company Method of recovering 1,3-propanediol from fermentation broth
BR0318130A (pt) * 2003-02-24 2006-02-07 Shell Int Research Purificação de 1,3-propanodiol por destilação
WO2004101482A2 (en) 2003-05-06 2004-11-25 E.I. Dupont De Nemours And Company Hydrogenation of biochemically derived 1,3-propanediol
US20040225107A1 (en) * 2003-05-06 2004-11-11 Sunkara Hari Babu Polytrimethylene ether glycol with excellent quality from biochemically-derived 1,3-propanediol
JP4814794B2 (ja) * 2003-05-06 2011-11-16 イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー 生物学的に生産された１，３−プロパンジオールの精製
US7714174B2 (en) * 2007-03-27 2010-05-11 E. I. Du Pont De Nemours And Company Lower-color polytrimethylene ether glycol using hydride compounds

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108117481A (zh) * 2016-11-29 2018-06-05 中国石油化工股份有限公司 一种从发酵液中分离提取1,3-丙二醇的方法
WO2025258949A1 (ko) * 2024-06-10 2025-12-18 지에스칼텍스 주식회사 다가 알코올의 정제 방법

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