KR100912331B1 - 올레핀 히드로시안화를 위한 니켈/인 리간드 촉매의 제조방법 - Google Patents

올레핀 히드로시안화를 위한 니켈/인 리간드 촉매의 제조방법 Download PDF

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Publication number
KR100912331B1
KR100912331B1 KR1020047007924A KR20047007924A KR100912331B1 KR 100912331 B1 KR100912331 B1 KR 100912331B1 KR 1020047007924 A KR1020047007924 A KR 1020047007924A KR 20047007924 A KR20047007924 A KR 20047007924A KR 100912331 B1 KR100912331 B1 KR 100912331B1
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South Korea
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alkyl
nicl
nickel chloride
alkoxy
same
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KR20040060989A (ko
Inventor
루이스 에이 추
노만 헤론
케네스 쥐 모로이
루시 엠. 클락슨
로날드 제이. 맥키니
제루 테키
Original Assignee
인비스타 테크놀러지스 에스.에이.알.엘.
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • B01J31/28—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24 of the platinum group metals, iron group metals or copper
    • B01J31/30—Halides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06—Halogens; Compounds thereof
    • B01J27/128—Halogens; Compounds thereof with iron group metals or platinum group metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/185—Phosphites ((RO)3P), their isomeric phosphonates (R(RO)2P=O) and RO-substitution derivatives thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/1875—Phosphinites (R2P(OR), their isomeric phosphine oxides (R3P=O) and RO-substitution derivatives thereof)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/16—Reducing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G53/00—Compounds of nickel
    • C01G53/08—Halides; Oxyhalides
    • C01G53/09—Chlorides; Oxychlorides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/04—Nickel compounds
    • C07F15/045—Nickel compounds without a metal-carbon linkage
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/847—Nickel
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/80—Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70
    • C01P2002/88—Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70 by thermal analysis data, e.g. TGA, DTA, DSC
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/60—Particles characterised by their size
    • C01P2004/64—Nanometer sized, i.e. from 1-100 nanometer
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/12—Surface area
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/80—Compositional purity
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/80—Compositional purity
    • C01P2006/82—Compositional purity water content

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Nanotechnology (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • Composite Materials (AREA)
  • General Physics & Mathematics (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
KR1020047007924A 2001-11-26 2002-11-14 올레핀 히드로시안화를 위한 니켈/인 리간드 촉매의 제조방법 Expired - Fee Related KR100912331B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US09/994,102 2001-11-26
US09/994,102 US6893996B2 (en) 2001-11-26 2001-11-26 Process for the preparation of a nickel/phosphorous ligand catalyst for olefin hydrocyanation
PCT/US2002/036468 WO2003045555A2 (en) 2001-11-26 2002-11-14 Process for the preparation of a nickel/phosphorus ligand catalyst for olefin hydrocyanation

Related Child Applications (1)

Application Number Title Priority Date Filing Date
KR1020097006558A Division KR20090048517A (ko) 2001-11-26 2002-11-14 올레핀 히드로시안화를 위한 니켈/인 리간드 촉매의 제조 방법

Publications (2)

Publication Number Publication Date
KR20040060989A KR20040060989A (ko) 2004-07-06
KR100912331B1 true KR100912331B1 (ko) 2009-08-14

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Family Applications (2)

Application Number Title Priority Date Filing Date
KR1020097006558A Ceased KR20090048517A (ko) 2001-11-26 2002-11-14 올레핀 히드로시안화를 위한 니켈/인 리간드 촉매의 제조 방법
KR1020047007924A Expired - Fee Related KR100912331B1 (ko) 2001-11-26 2002-11-14 올레핀 히드로시안화를 위한 니켈/인 리간드 촉매의 제조방법

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KR1020097006558A Ceased KR20090048517A (ko) 2001-11-26 2002-11-14 올레핀 히드로시안화를 위한 니켈/인 리간드 촉매의 제조 방법

Country Status (17)

Country Link
US (1) US6893996B2 (enExample)
EP (2) EP1450949B1 (enExample)
JP (2) JP2005510346A (enExample)
KR (2) KR20090048517A (enExample)
CN (2) CN1293944C (enExample)
AT (1) ATE307669T1 (enExample)
AU (1) AU2002356942A1 (enExample)
BR (1) BR0214260B1 (enExample)
CA (1) CA2468293A1 (enExample)
DE (1) DE60206958T2 (enExample)
ES (1) ES2250748T3 (enExample)
MX (1) MXPA04004942A (enExample)
MY (1) MY129876A (enExample)
PL (1) PL371463A1 (enExample)
RU (1) RU2301704C2 (enExample)
TW (1) TW592817B (enExample)
WO (1) WO2003045555A2 (enExample)

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FR2849027B1 (fr) * 2002-12-23 2005-01-21 Rhodia Polyamide Intermediates Procede de synthese de composes comprenant des fonctions nitriles a partir de composes a insaturations ethyleniques
US6897329B2 (en) 2003-01-14 2005-05-24 Invista North America S.A.R.L. Process for the preparation of nickel/phosphorous ligand catalyst for olefin hydrocyanation
FR2850966B1 (fr) 2003-02-10 2005-03-18 Rhodia Polyamide Intermediates Procede de fabrication de composes dinitriles
FR2854892B1 (fr) * 2003-05-12 2005-06-24 Rhodia Polyamide Intermediates Procede de fabrication de dinitriles
FR2854891B1 (fr) 2003-05-12 2006-07-07 Rhodia Polyamide Intermediates Procede de preparation de dinitriles
DE10351003A1 (de) * 2003-10-30 2005-05-25 Basf Ag Verfahren zur Herstellung von Nickel-Phosphorligand-Komplexen
DE10351000A1 (de) * 2003-10-30 2005-06-09 Basf Ag Verfahren zur Herstellung von Nickel(O)-Phosphorligand-Komplexen
DE10351002A1 (de) * 2003-10-30 2005-05-25 Basf Ag Einsatz von azeotrop-getrockneten Nickel(II)-halogeniden
DE102004004718A1 (de) * 2004-01-29 2005-08-18 Basf Ag Verfahren zur Hydrocyanierung
EP1825914A1 (de) * 2006-02-22 2007-08-29 Basf Aktiengesellschaft Verbessertes Verfahren zur Herstellung von Nickel(0)-Phophorligand-Komplexen
MX2008011640A (es) * 2006-03-17 2008-09-22 Invista Tech Sarl Metodo para la purificacion de triorganofosfitos por tratamiento con un aditivo basico.
US7709673B2 (en) * 2006-07-14 2010-05-04 Invista North America S.A R.L. Process for making 3-pentenenitrile by hydrocyanation of butadiene
US7659422B2 (en) * 2006-07-14 2010-02-09 Invista North America S.A.R.L. Hydrocyanation process with reduced yield losses
US7919646B2 (en) 2006-07-14 2011-04-05 Invista North America S.A R.L. Hydrocyanation of 2-pentenenitrile
US7709674B2 (en) * 2006-07-14 2010-05-04 Invista North America S.A R.L Hydrocyanation process with reduced yield losses
US7880028B2 (en) * 2006-07-14 2011-02-01 Invista North America S.A R.L. Process for making 3-pentenenitrile by hydrocyanation of butadiene
JP5295512B2 (ja) * 2007-03-29 2013-09-18 三井化学株式会社 ゼロ価ニッケルの有機ホスフィン錯体の製造方法
WO2009091790A1 (en) * 2008-01-15 2009-07-23 Invista Technologies S.A.R.L. Hydrocyanation of pentenenitriles
CN101910119B (zh) * 2008-01-15 2013-05-29 因温斯特技术公司 用于制备和精制3-戊烯腈，和用于精制2-甲基-3-丁烯腈的方法
WO2011075494A1 (en) 2009-12-18 2011-06-23 Invista Technologies S.A.R.L. Nickel metal compositions and nickel complexes derived from basic nickel carbonates
ES2448957T3 (es) 2010-07-07 2014-03-17 Invista Technologies S.À.R.L. Procedimiento de producción de nitrilos
EP2614071B1 (en) * 2010-09-07 2015-12-02 Invista Technologies S.a r.l. Preparing a nickel phosphorus ligand complex
EP2718015A2 (en) * 2011-06-10 2014-04-16 Invista Technologies S.à.r.l. Improvement in nickel metal-ligand catalyst formation
US9040735B2 (en) 2011-10-07 2015-05-26 Invista North America S.A.R.L. Process for making nitriles
EP3022172B1 (en) 2013-07-17 2018-10-17 INVISTA Textiles (U.K.) Limited Separating a solvent from a nickel catalyst by distillation
EP3406568A4 (en) * 2016-01-21 2019-08-21 JX Nippon Mining & Metals Corporation ANHYDRIC NICKEL CHLORIDE AND METHOD FOR THE PRODUCTION THEREOF
CN114212836A (zh) * 2021-12-31 2022-03-22 金川集团镍盐有限公司 一种无水氯化镍粉体材料的制备方法
CN114835176A (zh) * 2022-05-30 2022-08-02 金川集团镍盐有限公司 一种球形无水氯化镍产品的制备方法
JP2024097610A (ja) * 2023-01-06 2024-07-19 レアメタルリサイクル環境合同会社 無水塩化ニッケル粉末の製造方法

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US3631191A (en) 1970-04-08 1971-12-28 Du Pont Synthesis of zero valent nickel-tetrakis triaryl phosphite complexes

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US3631191A (en) 1970-04-08 1971-12-28 Du Pont Synthesis of zero valent nickel-tetrakis triaryl phosphite complexes

Also Published As

Publication number Publication date
BR0214260B1 (pt) 2014-07-29
DE60206958T2 (de) 2006-08-03
ES2250748T3 (es) 2006-04-16
WO2003045555A2 (en) 2003-06-05
EP1450949B1 (en) 2005-10-26
KR20090048517A (ko) 2009-05-13
JP2009035482A (ja) 2009-02-19
AU2002356942A1 (en) 2003-06-10
RU2301704C2 (ru) 2007-06-27
CN1293944C (zh) 2007-01-10
CN100445210C (zh) 2008-12-24
BR0214260A (pt) 2004-09-21
US20030100442A1 (en) 2003-05-29
US6893996B2 (en) 2005-05-17
JP2005510346A (ja) 2005-04-21
CA2468293A1 (en) 2003-06-05
EP1450949A2 (en) 2004-09-01
KR20040060989A (ko) 2004-07-06
CN1899972A (zh) 2007-01-24
MY129876A (en) 2007-05-31
EP1604954A1 (en) 2005-12-14
DE60206958D1 (de) 2005-12-01
MXPA04004942A (es) 2004-08-11
RU2004116079A (ru) 2005-03-27
CN1596152A (zh) 2005-03-16
ATE307669T1 (de) 2005-11-15
PL371463A1 (en) 2005-06-13
TW592817B (en) 2004-06-21
WO2003045555A3 (en) 2003-11-06

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