KR100820273B1 - 알데하이드의 시안화 방법 - Google Patents

알데하이드의 시안화 방법 Download PDF

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Publication number
KR100820273B1
KR100820273B1 KR1020037001417A KR20037001417A KR100820273B1 KR 100820273 B1 KR100820273 B1 KR 100820273B1 KR 1020037001417 A KR1020037001417 A KR 1020037001417A KR 20037001417 A KR20037001417 A KR 20037001417A KR 100820273 B1 KR100820273 B1 KR 100820273B1
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South Korea
Prior art keywords
cyanide
catalyst
vanadium
titanium
alkyl
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Expired - Fee Related
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KR1020037001417A
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English (en)
Korean (ko)
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KR20030022339A (ko
Inventor
노스마이클
벨로콘유리
Original Assignee
킹즈 컬리지 런던, 언 인스티튜션 인코포레이티드 바이 로얄 챠터
네스메이아노브 인스티튜트 오브 오르가노엘리먼트 컴파운즈
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Publication of KR20030022339A publication Critical patent/KR20030022339A/ko
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
    • B01J31/2243—At least one oxygen and one nitrogen atom present as complexing atoms in an at least bidentate or bridging ligand
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B43/00—Formation or introduction of functional groups containing nitrogen
    • C07B43/08—Formation or introduction of functional groups containing nitrogen of cyano groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B53/00—Asymmetric syntheses
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C253/00—Preparation of carboxylic acid nitriles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/34—Other additions, e.g. Monsanto-type carbonylations, addition to 1,2-C=X or 1,2-C-X triplebonds, additions to 1,4-C=C-C=X or 1,4-C=-C-X triple bonds with X, e.g. O, S, NH/N
    • B01J2231/341—1,2-additions, e.g. aldol or Knoevenagel condensations
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0202—Polynuclearity
    • B01J2531/0205—Bi- or polynuclear complexes, i.e. comprising two or more metal coordination centres, without metal-metal bonds, e.g. Cp(Lx)Zr-imidazole-Zr(Lx)Cp
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0238—Complexes comprising multidentate ligands, i.e. more than 2 ionic or coordinative bonds from the central metal to the ligand, the latter having at least two donor atoms, e.g. N, O, S, P
    • B01J2531/0241—Rigid ligands, e.g. extended sp2-carbon frameworks or geminal di- or trisubstitution
    • B01J2531/0252—Salen ligands or analogues, e.g. derived from ethylenediamine and salicylaldehyde
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/46—Titanium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/50—Complexes comprising metals of Group V (VA or VB) as the central metal
    • B01J2531/56—Vanadium

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
  • Manufacture And Refinement Of Metals (AREA)
KR1020037001417A 2000-08-02 2001-08-01 알데하이드의 시안화 방법 Expired - Fee Related KR100820273B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
GB0018973.8 2000-08-02
GBGB0018973.8A GB0018973D0 (en) 2000-08-02 2000-08-02 Synthesis of chiral cyanohydrins
PCT/GB2001/003456 WO2002010095A2 (en) 2000-08-02 2001-08-01 Process for the cyanation of aldehydes

Publications (2)

Publication Number Publication Date
KR20030022339A KR20030022339A (ko) 2003-03-15
KR100820273B1 true KR100820273B1 (ko) 2008-04-07

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
KR1020037001417A Expired - Fee Related KR100820273B1 (ko) 2000-08-02 2001-08-01 알데하이드의 시안화 방법

Country Status (16)

Country Link
EP (1) EP1307427B3 (enExample)
JP (1) JP2004505097A (enExample)
KR (1) KR100820273B1 (enExample)
CN (1) CN100406433C (enExample)
AT (1) ATE323069T1 (enExample)
AU (1) AU2001275740A1 (enExample)
CA (1) CA2418116A1 (enExample)
CZ (1) CZ2003276A3 (enExample)
DE (2) DE60118752T4 (enExample)
DK (1) DK1307427T5 (enExample)
ES (1) ES2262665T7 (enExample)
GB (1) GB0018973D0 (enExample)
HU (1) HUP0301824A3 (enExample)
MX (1) MXPA03000903A (enExample)
PT (1) PT1307427E (enExample)
WO (1) WO2002010095A2 (enExample)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB0212017D0 (en) * 2002-05-24 2002-07-03 King S College London Catalyst and process
GB0103857D0 (en) 2001-02-16 2001-04-04 Avecia Ltd Preparation of chloromandelic acid
DE10131810A1 (de) * 2001-06-30 2003-02-27 Clariant Gmbh Verfahren zur Herstellung von optisch aktiven Cyanhydrinen und deren korrespondierenden Säuren
DE10131811A1 (de) * 2001-06-30 2003-04-03 Clariant Gmbh Optisch aktive Katalysatoren
US8828902B2 (en) 2001-07-12 2014-09-09 Reaxa Limited Microencapsulated catalyst methods of preparation and method of use thereof
DE10259162A1 (de) * 2002-12-18 2004-07-08 Clariant Gmbh Optisch aktive Komplexe enthaltende Mischungen
ATE444281T1 (de) 2004-10-15 2009-10-15 Mitsui Chemicals Inc Titanverbindung und verfahren zur herstellung optisch aktiver cyanhydrine
WO2007105658A1 (ja) * 2006-03-10 2007-09-20 Nissan Chemical Industries, Ltd. 光学活性クロメンオキシド化合物の製造方法
CN101437827B (zh) * 2006-03-10 2012-08-29 日产化学工业株式会社 光学活性色烯氧化物化合物的制造方法
WO2008121074A1 (en) * 2007-03-29 2008-10-09 Agency For Science, Technology And Research Method of producing an optically active cyanohydrin derivative
CN102234291B (zh) * 2010-04-23 2014-10-15 中国科学院上海有机化学研究所 桥连双希夫碱钛络合物、合成方法及其应用
CN106552671A (zh) * 2015-09-25 2017-04-05 沈阳中化农药化工研发有限公司 一种多相催化剂及其制备和应用
CN116987004B (zh) * 2023-09-27 2023-12-12 新华制药（寿光）有限公司 一种3-(3,4-二甲氧基苯基)-2-氨基-2-甲基丙腈的合成方法

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2919974A1 (de) * 1979-05-17 1980-11-27 Hoechst Ag Verfahren zur herstellung von cyanhydrinacylaten von aldehyden
JPH0429965A (ja) * 1990-05-28 1992-01-31 Katakura Chitsukarin Kk α―Ｎ―アルキルアミノニトリル誘導体鏡像異性体の製造方法
JP3303327B2 (ja) * 1992-03-18 2002-07-22 住友化学工業株式会社 不斉誘起触媒
US5349079A (en) * 1992-12-14 1994-09-20 Akzo Nobel Nv Process for forming α-aminonitriles from carbonyl compound and fatty amine hydrohalide
JPH06271522A (ja) * 1993-01-21 1994-09-27 Sumitomo Chem Co Ltd 光学活性シアノヒドリンエステルの製造方法
JPH0770040A (ja) * 1993-06-22 1995-03-14 Sumitomo Chem Co Ltd 光学活性シアノヒドリンエステルの製造法

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
Inorganic Chemistry, 1975, 14(3), 660-664.*

Also Published As

Publication number Publication date
DK1307427T3 (da) 2006-07-31
KR20030022339A (ko) 2003-03-15
GB0018973D0 (en) 2000-09-20
WO2002010095A2 (en) 2002-02-07
JP2004505097A (ja) 2004-02-19
WO2002010095A3 (en) 2002-04-18
DE60118752T2 (de) 2007-03-15
MXPA03000903A (es) 2004-08-02
HUP0301824A3 (en) 2005-11-28
ES2262665T3 (es) 2006-12-01
PT1307427E (pt) 2006-07-31
CN100406433C (zh) 2008-07-30
EP1307427B3 (en) 2009-04-29
ATE323069T1 (de) 2006-04-15
ES2262665T7 (es) 2009-11-05
HK1062008A1 (zh) 2004-10-15
CA2418116A1 (en) 2002-02-07
DE60118752D1 (de) 2006-05-24
AU2001275740A1 (en) 2002-02-13
EP1307427A2 (en) 2003-05-07
CN1468212A (zh) 2004-01-14
DK1307427T5 (da) 2009-06-15
CZ2003276A3 (cs) 2003-05-14
EP1307427B1 (en) 2006-04-12
DE60118752T4 (de) 2009-10-22
HUP0301824A2 (hu) 2003-09-29

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