KR100741261B1 - 금속을 함유하는 염기성 이온교환수지의 회화에 의한금속의 회수방법 - Google Patents

금속을 함유하는 염기성 이온교환수지의 회화에 의한금속의 회수방법 Download PDF

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KR100741261B1
KR100741261B1 KR1020037003202A KR20037003202A KR100741261B1 KR 100741261 B1 KR100741261 B1 KR 100741261B1 KR 1020037003202 A KR1020037003202 A KR 1020037003202A KR 20037003202 A KR20037003202 A KR 20037003202A KR 100741261 B1 KR100741261 B1 KR 100741261B1
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rhodium
ion exchange
metal
product stream
exchange resin
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KR20030036749A (ko
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앨리스테어 찰머스 람세이 브라운
로날드 피어스
제프리 레이놀즈
데이빗 로버트 번햄
디렉 존 픽카드
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존슨 맛쎄이 퍼블릭 리미티드 컴파니
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/20—Carbonyls
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/78—Separation; Purification; Stabilisation; Use of additives
    • C07C45/79—Separation; Purification; Stabilisation; Use of additives by solid-liquid treatment; by chemisorption
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation
    • B01J31/4015—Regeneration or reactivation of catalysts containing metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation
    • B01J31/4015—Regeneration or reactivation of catalysts containing metals
    • B01J31/4023—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper
    • B01J31/403—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing iron group metals or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation
    • B01J31/4015—Regeneration or reactivation of catalysts containing metals
    • B01J31/4023—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper
    • B01J31/4038—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing noble metals
    • B01J31/4046—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing noble metals containing rhodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B01J38/74—Regeneration or reactivation of catalysts, in general utilising ion-exchange
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J41/00—Anion exchange; Use of material as anion exchangers; Treatment of material for improving the anion exchange properties
    • B01J41/04—Processes using organic exchangers
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G55/00—Compounds of ruthenium, rhodium, palladium, osmium, iridium, or platinum
    • C01G55/001—Preparation involving a liquid-liquid extraction, an adsorption or an ion-exchange
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B11/00—Obtaining noble metals
    • C22B11/02—Obtaining noble metals by dry processes
    • C22B11/021—Recovery of noble metals from waste materials
    • C22B11/026—Recovery of noble metals from waste materials from spent catalysts
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B11/00—Obtaining noble metals
    • C22B11/04—Obtaining noble metals by wet processes
    • C22B11/042—Recovery of noble metals from waste materials
    • C22B11/048—Recovery of noble metals from waste materials from spent catalysts
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
    • C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
    • C22B3/42—Treatment or purification of solutions, e.g. obtained by leaching by ion-exchange extraction
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/822—Rhodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/845—Cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06—Halogens; Compounds thereof
    • B01J27/08—Halides
    • B01J27/10—Chlorides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/06—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing polymers
    • B01J31/08—Ion-exchange resins
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00—Technologies related to metal processing
    • Y02P10/20—Recycling
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Inorganic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Geology (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Manufacture And Refinement Of Metals (AREA)
  • Processing Of Solid Wastes (AREA)
KR1020037003202A 2000-09-05 2001-08-22 금속을 함유하는 염기성 이온교환수지의 회화에 의한금속의 회수방법 Expired - Fee Related KR100741261B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
GB0021715A GB0021715D0 (en) 2000-09-05 2000-09-05 Recovery of metals
GB0021715.8 2000-09-05
PCT/GB2001/003780 WO2002020451A1 (en) 2000-09-05 2001-08-22 Recovery of metals by incineration of metal containing basic ion exchance resin

Publications (2)

Publication Number Publication Date
KR20030036749A KR20030036749A (ko) 2003-05-09
KR100741261B1 true KR100741261B1 (ko) 2007-07-19

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KR1020037003202A Expired - Fee Related KR100741261B1 (ko) 2000-09-05 2001-08-22 금속을 함유하는 염기성 이온교환수지의 회화에 의한금속의 회수방법

Country Status (17)

Country Link
US (1) US20040102658A1 (enExample)
EP (1) EP1315693B1 (enExample)
JP (1) JP5534631B2 (enExample)
KR (1) KR100741261B1 (enExample)
CN (1) CN1252021C (enExample)
AT (1) ATE308498T1 (enExample)
AU (1) AU2001282315A1 (enExample)
BR (1) BR0113685B1 (enExample)
CA (1) CA2422477C (enExample)
CZ (1) CZ303102B6 (enExample)
DE (1) DE60114647T2 (enExample)
GB (1) GB0021715D0 (enExample)
NO (1) NO328970B1 (enExample)
PL (1) PL202055B1 (enExample)
TW (1) TWI229069B (enExample)
WO (1) WO2002020451A1 (enExample)
ZA (1) ZA200301323B (enExample)

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Publication number Priority date Publication date Assignee Title
CA2515179A1 (en) 2003-02-11 2004-08-26 Ferenc Korodi Process for preparing simvastatin having controlled ranges of simvastatin dimer content
DE10357718A1 (de) 2003-12-09 2005-07-21 Basf Ag Verfahren zur Herstellung von Tricyclodecandialdehyd
AR054096A1 (es) * 2004-11-12 2007-06-06 Monsanto Technology Llc Recuperacion de metales nobles de corrientes de proceso acuosas y proceso de preparacion de n-(fosfonometil)-glicina
US7902398B2 (en) 2007-04-25 2011-03-08 Celanese International Corporation Method and apparatus for carbonylation with reduced catalyst loss
DE102008057857B4 (de) 2008-11-18 2014-09-11 Oxea Gmbh Verfahren zur Rückgewinnung von Rhodium aus Rhodiumkomplexverbindungen enthaltenden wässrigen Lösungen
DE102009001230A1 (de) 2009-02-27 2010-09-02 Evonik Oxeno Gmbh Verfahren zur Abtrennung und teilweiser Rückführung von Übergangsmetallen bzw. deren katalytisch wirksamen Komplexverbindungen aus Prozessströmen
KR101224503B1 (ko) * 2011-03-09 2013-02-04 (주)알티아이엔지니어링 백금족 금속 함유 산업폐기물로부터 백금족 금속을 회수하는 방법
WO2016123606A1 (en) * 2015-02-01 2016-08-04 Kurion, Inc. Ion specific media removal from vessel for vitrification
TWI709566B (zh) 2015-09-30 2020-11-11 美商陶氏科技投資公司 用於製造有機磷化合物的方法
KR101668727B1 (ko) * 2015-11-25 2016-10-25 한국원자력연구원 방사성 핵종을 포함하는 폐이온 교환수지 처리방법 및 장치
TWI874467B (zh) 2019-11-05 2025-03-01 美商陶氏科技投資有限公司 用於自ｃ６或更高碳數烯烴氫甲醯化製程之催化劑淨化流回收銠之方法
CN111439875B (zh) * 2020-03-31 2022-05-31 东莞市逸轩环保科技有限公司 一种电镀铑钌清洗废水的铑钌资源化回收及水回用工艺

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GB1321275A (en) 1969-10-29 1973-06-27 Basf Ag Separation of metal carbonyl catalysts from oxo reaction mixtures
US5208194A (en) 1992-02-25 1993-05-04 Arco Chemical Technology, L.P. Recovery of group VIII transition metals from organic solutions using acidic ion-exchange resins

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JPS5845411B2 (ja) * 1978-05-10 1983-10-08 東亜燃料工業株式会社 ヒドロホルミル化方法
US4388279A (en) * 1981-06-03 1983-06-14 Uop Inc. Recovery of metal values from organic reaction products
US4599206A (en) * 1984-02-17 1986-07-08 Union Carbide Corporation Transition metal complex catalyzed reactions
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JPH03253523A (ja) * 1990-03-01 1991-11-12 Mitsubishi Kasei Corp 第８族貴金属の分離回収法
JP2826159B2 (ja) * 1990-03-30 1998-11-18 田中貴金属工業株式会社 ロジウムの回収精製方法
JPH04143231A (ja) * 1990-10-05 1992-05-18 Tanaka Kikinzoku Kogyo Kk ロジウムの回収方法
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JPH0790401A (ja) * 1993-09-20 1995-04-04 N E Chemcat Corp ロジウムの回収方法
JPH09173834A (ja) * 1995-12-21 1997-07-08 Chiyoda Corp 貴金属吸着剤及び貴金属の回収方法

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1321275A (en) 1969-10-29 1973-06-27 Basf Ag Separation of metal carbonyl catalysts from oxo reaction mixtures
US5208194A (en) 1992-02-25 1993-05-04 Arco Chemical Technology, L.P. Recovery of group VIII transition metals from organic solutions using acidic ion-exchange resins

Also Published As

Publication number Publication date
CZ2003619A3 (cs) 2003-06-18
PL202055B1 (pl) 2009-05-29
EP1315693B1 (en) 2005-11-02
US20040102658A1 (en) 2004-05-27
CA2422477C (en) 2010-01-26
CN1252021C (zh) 2006-04-19
KR20030036749A (ko) 2003-05-09
GB0021715D0 (en) 2000-10-18
CA2422477A1 (en) 2002-03-14
DE60114647T2 (de) 2006-07-27
ZA200301323B (en) 2004-02-05
PL360580A1 (en) 2004-09-06
JP2004508464A (ja) 2004-03-18
JP5534631B2 (ja) 2014-07-02
TWI229069B (en) 2005-03-11
BR0113685A (pt) 2003-07-15
CZ303102B6 (cs) 2012-04-04
CN1452605A (zh) 2003-10-29
NO20031007L (no) 2003-05-02
NO328970B1 (no) 2010-07-05
EP1315693A1 (en) 2003-06-04
DE60114647D1 (de) 2005-12-08
WO2002020451A1 (en) 2002-03-14
NO20031007D0 (no) 2003-03-04
AU2001282315A1 (en) 2002-03-22
BR0113685B1 (pt) 2012-07-24
ATE308498T1 (de) 2005-11-15

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