CN1252021C - 通过煅烧含金属的碱性离子交换树脂来回收金属的方法 - Google Patents

通过煅烧含金属的碱性离子交换树脂来回收金属的方法 Download PDF

Info

Publication number
CN1252021C
CN1252021C CNB018151981A CN01815198A CN1252021C CN 1252021 C CN1252021 C CN 1252021C CN B018151981 A CNB018151981 A CN B018151981A CN 01815198 A CN01815198 A CN 01815198A CN 1252021 C CN1252021 C CN 1252021C
Authority
CN
China
Prior art keywords
rhodium
metal
ion exchange
resin
reaction product
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CNB018151981A
Other languages
English (en)
Chinese (zh)
Other versions
CN1452605A (zh
Inventor
A·C·R·布朗
R·皮尔斯
G·雷诺兹
D·R·伯纳姆
D·J·皮卡德
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
Johnson Matthey PLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Johnson Matthey PLC filed Critical Johnson Matthey PLC
Publication of CN1452605A publication Critical patent/CN1452605A/zh
Application granted granted Critical
Publication of CN1252021C publication Critical patent/CN1252021C/zh
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/20—Carbonyls
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/78—Separation; Purification; Stabilisation; Use of additives
    • C07C45/79—Separation; Purification; Stabilisation; Use of additives by solid-liquid treatment; by chemisorption
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation
    • B01J31/4015—Regeneration or reactivation of catalysts containing metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation
    • B01J31/4015—Regeneration or reactivation of catalysts containing metals
    • B01J31/4023—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper
    • B01J31/403—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing iron group metals or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation
    • B01J31/4015—Regeneration or reactivation of catalysts containing metals
    • B01J31/4023—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper
    • B01J31/4038—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing noble metals
    • B01J31/4046—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing noble metals containing rhodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B01J38/74—Regeneration or reactivation of catalysts, in general utilising ion-exchange
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J41/00—Anion exchange; Use of material as anion exchangers; Treatment of material for improving the anion exchange properties
    • B01J41/04—Processes using organic exchangers
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G55/00—Compounds of ruthenium, rhodium, palladium, osmium, iridium, or platinum
    • C01G55/001—Preparation involving a liquid-liquid extraction, an adsorption or an ion-exchange
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B11/00—Obtaining noble metals
    • C22B11/02—Obtaining noble metals by dry processes
    • C22B11/021—Recovery of noble metals from waste materials
    • C22B11/026—Recovery of noble metals from waste materials from spent catalysts
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B11/00—Obtaining noble metals
    • C22B11/04—Obtaining noble metals by wet processes
    • C22B11/042—Recovery of noble metals from waste materials
    • C22B11/048—Recovery of noble metals from waste materials from spent catalysts
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
    • C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
    • C22B3/42—Treatment or purification of solutions, e.g. obtained by leaching by ion-exchange extraction
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/822—Rhodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/845—Cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06—Halogens; Compounds thereof
    • B01J27/08—Halides
    • B01J27/10—Chlorides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/06—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing polymers
    • B01J31/08—Ion-exchange resins
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00—Technologies related to metal processing
    • Y02P10/20—Recycling
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Inorganic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Geology (AREA)
  • Environmental & Geological Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Manufacture And Refinement Of Metals (AREA)
  • Processing Of Solid Wastes (AREA)
CNB018151981A 2000-09-05 2001-08-22 通过煅烧含金属的碱性离子交换树脂来回收金属的方法 Expired - Fee Related CN1252021C (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB0021715.8 2000-09-05
GB0021715A GB0021715D0 (en) 2000-09-05 2000-09-05 Recovery of metals

Publications (2)

Publication Number Publication Date
CN1452605A CN1452605A (zh) 2003-10-29
CN1252021C true CN1252021C (zh) 2006-04-19

Family

ID=9898829

Family Applications (1)

Application Number Title Priority Date Filing Date
CNB018151981A Expired - Fee Related CN1252021C (zh) 2000-09-05 2001-08-22 通过煅烧含金属的碱性离子交换树脂来回收金属的方法

Country Status (17)

Country Link
US (1) US20040102658A1 (enExample)
EP (1) EP1315693B1 (enExample)
JP (1) JP5534631B2 (enExample)
KR (1) KR100741261B1 (enExample)
CN (1) CN1252021C (enExample)
AT (1) ATE308498T1 (enExample)
AU (1) AU2001282315A1 (enExample)
BR (1) BR0113685B1 (enExample)
CA (1) CA2422477C (enExample)
CZ (1) CZ303102B6 (enExample)
DE (1) DE60114647T2 (enExample)
GB (1) GB0021715D0 (enExample)
NO (1) NO328970B1 (enExample)
PL (1) PL202055B1 (enExample)
TW (1) TWI229069B (enExample)
WO (1) WO2002020451A1 (enExample)
ZA (1) ZA200301323B (enExample)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20050098313A (ko) 2003-02-11 2005-10-11 플러스 케미칼스 비.브이. 제어된 범위의 심바스타틴 이량체 함량을 갖는심바스타틴의 제조 방법
DE10357718A1 (de) 2003-12-09 2005-07-21 Basf Ag Verfahren zur Herstellung von Tricyclodecandialdehyd
TW200624151A (en) * 2004-11-12 2006-07-16 Monsanto Technology Llc Recovery of noble metals from aqueous process streams
US7902398B2 (en) 2007-04-25 2011-03-08 Celanese International Corporation Method and apparatus for carbonylation with reduced catalyst loss
DE102008057857B4 (de) * 2008-11-18 2014-09-11 Oxea Gmbh Verfahren zur Rückgewinnung von Rhodium aus Rhodiumkomplexverbindungen enthaltenden wässrigen Lösungen
DE102009001230A1 (de) 2009-02-27 2010-09-02 Evonik Oxeno Gmbh Verfahren zur Abtrennung und teilweiser Rückführung von Übergangsmetallen bzw. deren katalytisch wirksamen Komplexverbindungen aus Prozessströmen
KR101224503B1 (ko) * 2011-03-09 2013-02-04 (주)알티아이엔지니어링 백금족 금속 함유 산업폐기물로부터 백금족 금속을 회수하는 방법
JP6835318B2 (ja) * 2015-02-01 2021-02-24 ヴェオリア ニュークリア ソリューションズ インコーポレイテッドＶｅｏｌｉａ Ｎｕｃｌｅａｒ Ｓｏｌｕｔｉｏｎｓ Ｉｎｃ． 使用済みイオン交換媒体を処理するためのシステム及び方法
TWI709566B (zh) 2015-09-30 2020-11-11 美商陶氏科技投資公司 用於製造有機磷化合物的方法
KR101668727B1 (ko) 2015-11-25 2016-10-25 한국원자력연구원 방사성 핵종을 포함하는 폐이온 교환수지 처리방법 및 장치
TWI874467B (zh) 2019-11-05 2025-03-01 美商陶氏科技投資有限公司 用於自ｃ６或更高碳數烯烴氫甲醯化製程之催化劑淨化流回收銠之方法
CN111439875B (zh) * 2020-03-31 2022-05-31 东莞市逸轩环保科技有限公司 一种电镀铑钌清洗废水的铑钌资源化回收及水回用工艺

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1954315C3 (de) * 1969-10-29 1975-08-14 Basf Ag, 6700 Ludwigshafen Verfahren zur Abtrennung von Metallcarbonylkatalysatoren aus Oxoreaktionsge mischen
JPS5845411B2 (ja) * 1978-05-10 1983-10-08 東亜燃料工業株式会社 ヒドロホルミル化方法
US4388279A (en) * 1981-06-03 1983-06-14 Uop Inc. Recovery of metal values from organic reaction products
US4599206A (en) * 1984-02-17 1986-07-08 Union Carbide Corporation Transition metal complex catalyzed reactions
US4748261A (en) * 1985-09-05 1988-05-31 Union Carbide Corporation Bis-phosphite compounds
US5114473A (en) * 1988-08-25 1992-05-19 Union Carbide Chemicals And Plastics Technology Corporation Transition metal recovery
JPH03253523A (ja) * 1990-03-01 1991-11-12 Mitsubishi Kasei Corp 第８族貴金属の分離回収法
JP2826159B2 (ja) * 1990-03-30 1998-11-18 田中貴金属工業株式会社 ロジウムの回収精製方法
JPH04143231A (ja) * 1990-10-05 1992-05-18 Tanaka Kikinzoku Kogyo Kk ロジウムの回収方法
US5208194A (en) 1992-02-25 1993-05-04 Arco Chemical Technology, L.P. Recovery of group VIII transition metals from organic solutions using acidic ion-exchange resins
US5312996A (en) * 1992-06-29 1994-05-17 Union Carbide Chemicals & Plastics Technology Corporation Hydroformylation process for producing 1,6-hexanedials
JPH0790401A (ja) * 1993-09-20 1995-04-04 N E Chemcat Corp ロジウムの回収方法
JPH09173834A (ja) * 1995-12-21 1997-07-08 Chiyoda Corp 貴金属吸着剤及び貴金属の回収方法

Also Published As

Publication number Publication date
EP1315693A1 (en) 2003-06-04
CN1452605A (zh) 2003-10-29
BR0113685B1 (pt) 2012-07-24
GB0021715D0 (en) 2000-10-18
KR100741261B1 (ko) 2007-07-19
JP2004508464A (ja) 2004-03-18
PL202055B1 (pl) 2009-05-29
CA2422477A1 (en) 2002-03-14
TWI229069B (en) 2005-03-11
ATE308498T1 (de) 2005-11-15
WO2002020451A1 (en) 2002-03-14
US20040102658A1 (en) 2004-05-27
PL360580A1 (en) 2004-09-06
EP1315693B1 (en) 2005-11-02
CZ2003619A3 (cs) 2003-06-18
CZ303102B6 (cs) 2012-04-04
AU2001282315A1 (en) 2002-03-22
ZA200301323B (en) 2004-02-05
JP5534631B2 (ja) 2014-07-02
NO20031007L (no) 2003-05-02
DE60114647T2 (de) 2006-07-27
NO20031007D0 (no) 2003-03-04
DE60114647D1 (de) 2005-12-08
BR0113685A (pt) 2003-07-15
KR20030036749A (ko) 2003-05-09
NO328970B1 (no) 2010-07-05
CA2422477C (en) 2010-01-26

Similar Documents

Publication Publication Date Title
CN1252021C (zh) 通过煅烧含金属的碱性离子交换树脂来回收金属的方法
TWI527793B (zh) 回收鹵素促進劑和移除過錳酸鹽還原化合物的製程
JP5584225B2 (ja) 改良されたアルデヒド除去率を有するメタノールカルボニル化
CN105348066A (zh) 具有减少的催化剂损失的用于羰基化的改进的方法和装置
SU898951A3 (ru) Способ регенерации родийсодержащего катализатора гидроформилировани олефинов
JP2004523539A5 (enExample)
WO2014199593A1 (ja) アルデヒド吸着材、アルデヒドの除去方法、酢酸の製造方法及びアルデヒド吸着材の再生方法
JPH0237215B2 (enExample)
CN1231295C (zh) 回收均相金属氢化物催化剂的方法
CN1119308C (zh) 改进的采用活性铑催化剂分离和循环的加氢甲酰化方法
KR960003546B1 (ko) 귀금속과 삼차 포스핀(tertiary phasphines)의 회수방법
JP4077253B2 (ja) カルボニル化合物の製造方法
US12440832B2 (en) Liquid phase removal of trace of iodide from an organic media using tertiary amine ion exchange adsorbent
CN1145602C (zh) 从3-羟基丙醛水溶液除去羰基钴或羰基铑化合物的方法
JP2003528841A (ja) ヒドロホルミル化の反応生成物からロジウムを回収する方法
CN104028311B (zh) 一种丁辛醇羰基合成催化剂化学再生方法
US20020039551A1 (en) pH control method of reducing nitrogen oxides emission
JPH0660124B2 (ja) カルボニル化反応中に生成するタ−ルの選択的除去法
HK1150827A (en) Improved method and apparatus for carbonylation with reduced catalyst loss

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
C41 Transfer of patent application or patent right or utility model
TR01 Transfer of patent right

Effective date of registration: 20160929

Address after: Ludwigshafen, Germany

Patentee after: BASF SE

Address before: London, England

Patentee before: Johnson Matthey PLC

CF01 Termination of patent right due to non-payment of annual fee
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20060419

Termination date: 20200822