KR100733755B1 - 메탈로센 화합물, 그의 제조 방법 및 올레핀 중합을 위한촉매시스템에서의 그의 용도 - Google Patents

메탈로센 화합물, 그의 제조 방법 및 올레핀 중합을 위한촉매시스템에서의 그의 용도 Download PDF

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KR100733755B1
KR100733755B1 KR1020017010350A KR20017010350A KR100733755B1 KR 100733755 B1 KR100733755 B1 KR 100733755B1 KR 1020017010350 A KR1020017010350 A KR 1020017010350A KR 20017010350 A KR20017010350 A KR 20017010350A KR 100733755 B1 KR100733755 B1 KR 100733755B1
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methyl
zirconium dichloride
formula
delete delete
phenylcyclopentadienyl
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KR20010102158A (ko
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에웬존에이
엘더마이클제이
존스로버트엘
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바셀 테크놀로지 캄파니 비이브이
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D333/00—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom
    • C07D333/50—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom condensed with carbocyclic rings or ring systems
    • C07D333/78—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom condensed with carbocyclic rings or ring systems condensed with rings other than six-membered or with ring systems containing such rings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/08—Butenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2420/00—Metallocene catalysts
    • C08F2420/06—Cp analog where at least one of the carbon atoms of the non-coordinating part of the condensed ring is replaced by a heteroatom
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
KR1020017010350A 1999-12-15 2000-12-07 메탈로센 화합물, 그의 제조 방법 및 올레핀 중합을 위한촉매시스템에서의 그의 용도 Expired - Fee Related KR100733755B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US09/461,858 US6444833B1 (en) 1999-12-15 1999-12-15 Metallocene compounds, process for their preparation and their use in catalytic systems for the polymerization of olefins
US09/461,858 1999-12-15

Publications (2)

Publication Number Publication Date
KR20010102158A KR20010102158A (ko) 2001-11-15
KR100733755B1 true KR100733755B1 (ko) 2007-06-29

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KR1020017010350A Expired - Fee Related KR100733755B1 (ko) 1999-12-15 2000-12-07 메탈로센 화합물, 그의 제조 방법 및 올레핀 중합을 위한촉매시스템에서의 그의 용도

Country Status (15)

Country Link
US (2) US6444833B1 (enExample)
EP (1) EP1153047B1 (enExample)
JP (1) JP4838475B2 (enExample)
KR (1) KR100733755B1 (enExample)
CN (1) CN1161388C (enExample)
AR (1) AR027903A1 (enExample)
AT (1) ATE434631T1 (enExample)
AU (1) AU778205B2 (enExample)
BR (1) BR0010043A (enExample)
CA (1) CA2362093A1 (enExample)
DE (1) DE60042447D1 (enExample)
PL (1) PL349318A1 (enExample)
RU (1) RU2245341C2 (enExample)
WO (1) WO2001044318A1 (enExample)
ZA (1) ZA200106367B (enExample)

Families Citing this family (103)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ZA9710211B (en) * 1996-11-15 1998-06-03 Montell Technology Company Bv Heterocyclic metallocenes and polymerization catalysts.
ES2202169T3 (es) * 1999-09-22 2004-04-01 Basell Polyolefine Gmbh Sistema catalitico y procedimiento para la polimerizacion de olefinas.
US6444833B1 (en) * 1999-12-15 2002-09-03 Basell Technology Company Bv Metallocene compounds, process for their preparation and their use in catalytic systems for the polymerization of olefins
CA2363265A1 (en) * 1999-12-28 2001-07-05 Basell Technology Company B.V. Heterocyclic metallocene compounds and use thereof in catalyst systems for producing olefin polymers
EP1446429B1 (en) * 2001-06-12 2009-10-07 Basell Polyolefine GmbH Process for the polymerization of 1-butene
WO2002100908A1 (en) * 2001-06-12 2002-12-19 Basell Polyolefine Gmbh Process for the polymerization of 1-butene
JP2005501841A (ja) * 2001-08-01 2005-01-20 バセル ポリオレフィン ジーエムビーエイチ 複素環式ペンタレン誘導体の製造方法
DE10145453A1 (de) * 2001-09-14 2003-06-05 Basell Polyolefine Gmbh Monocyclopentadienylkomplexe mit einem kondensierten Heterocyclus
ATE412016T1 (de) * 2001-09-14 2008-11-15 Basell Polyolefine Gmbh Verfahren zur polymerisation von olefinen
WO2003045964A1 (en) * 2001-11-30 2003-06-05 Basell Polyolefine Gmbh Metallocene compounds and process for the preparation of propylene polymers
JP4062929B2 (ja) * 2002-02-08 2008-03-19 住友化学株式会社 遷移金属錯体、配位子、オレフィン重合用触媒およびオレフィン重合体の製造方法
CA2487512A1 (en) * 2002-06-26 2004-01-08 Basell Poliolefine Italia S.P.A. Impact-resistant polyolefin compositions
AU2003242663A1 (en) * 2002-06-26 2004-01-19 Basell Poliolefine Italia S.P.A. Impact-resistant polyolefin compositions
WO2004022613A1 (en) * 2002-09-06 2004-03-18 Basell Polyolefine Gmbh Process for the copolymerization of ethylene
US8008412B2 (en) 2002-09-20 2011-08-30 Exxonmobil Chemical Patents Inc. Polymer production at supersolution conditions
US7319125B2 (en) 2002-09-20 2008-01-15 Exxonmobil Chemical Patents Inc. Supercritical polymerization process and polymers produced therefrom
US7807769B2 (en) * 2002-09-20 2010-10-05 Exxonmobil Chemical Patents Inc. Isotactic polypropylene produced from supercritical polymerization process
JP2006502260A (ja) * 2002-10-10 2006-01-19 バセル ポリオレフィン ジーエムビーエイチ エチレンの共重合方法
DE10250062A1 (de) * 2002-10-25 2004-05-06 Basell Polyolefine Gmbh Verfahren zur racemoselektiven Darstellung von verbrückten Metallocenkomplexen mit unsubstituierten oder 2-substituierten Indenylliganden
KR101021829B1 (ko) * 2002-12-04 2011-03-17 바젤 폴리올레핀 게엠베하 1-부텐 공중합체 및 이들의 제조 방법
US7589160B2 (en) * 2002-12-04 2009-09-15 Basell Polyolefine Gmbh Process for preparing 1-butene polymers
DE60329523D1 (de) * 2002-12-04 2009-11-12 Basell Polyolefine Gmbh 1-Buten-Copolymere und Herstellungsverfahren dafür
DE10260095A1 (de) * 2002-12-19 2004-07-01 Basell Polyolefine Gmbh Verfahren zur Herstellung von heterocyclischen Ketonen
US6927264B2 (en) 2003-05-28 2005-08-09 Dow Global Technologies Inc. Metal complexes and polymerization process using same
US7122606B2 (en) 2003-07-04 2006-10-17 Basell Polyolefine Gmbh Olefin polymerization process
BRPI0413958A (pt) * 2003-09-11 2006-10-31 Basell Polyolefine Gmbh processo multi-etapas para preparar copolìmeros heterofásicos de propileno
WO2005023891A1 (en) * 2003-09-11 2005-03-17 Basell Polyolefine Gmbh Multistep process for preparing heterophasic propylene copolymers
BRPI0413961A (pt) * 2003-09-11 2006-10-31 Basell Polyolefine Gmbh processo multi-etapas para preparar copolìmeros heterofásicos de propileno
EP1564226A1 (en) 2004-02-16 2005-08-17 Stichting Dutch Polymer Institute Titanocene-based catalyst system
WO2005095468A2 (en) 2004-03-12 2005-10-13 Basell Polyolefine Gmbh Catalyst system for the polymerization of olefin
EP1723184A1 (en) 2004-03-12 2006-11-22 Basell Polyolefine GmbH Process for polymerizing 1-hexene or higher alpha-olefins
ATE482983T1 (de) * 2004-03-12 2010-10-15 Basell Polyolefine Gmbh Verfahren zur polymerisation von 1-hexen oder höheren alpha-olefinen
US8178636B2 (en) * 2004-05-04 2012-05-15 Basell Polyolefine Gmbh Process for the preparation of atactic 1-butene polymers
DE102004027332A1 (de) * 2004-06-04 2005-12-22 Basell Polyolefine Gmbh Übergangsmetallverbindung, Ligandsystem, Katalysatorsystem und Verfahren zur Herstellung von Polyolefinen
CA2576840A1 (en) 2004-07-08 2006-03-09 Patrick Brant Polymer production at supercritical conditions
JP5006783B2 (ja) 2004-07-13 2012-08-22 バーゼル・ポリオレフィン・ゲーエムベーハー メタロセン化合物、それらの調製で使用される配位子、１−ブテンポリマーの調製法、およびその方法から得られる１−ブテンポリマー
US7776978B2 (en) * 2004-07-22 2010-08-17 Basell Polyolefine Gmbh Process for producing fractionable 1-butene polymers
RU2007106716A (ru) * 2004-07-22 2008-08-27 Базелль Полиолефине Гмбх (De) Способ получения фракционируемых полимеров 1-бутена
DE602005026837D1 (de) * 2004-10-21 2011-04-21 Basell Polyolefine Gmbh 1-buten-polymer und herstellungsverfahren dafür
EP1655314A1 (en) * 2004-11-09 2006-05-10 Basell Polyolefine GmbH Process for the preparation of 1-butene/propylene copolymers
JP2008519151A (ja) * 2004-11-09 2008-06-05 バーゼル・ポリオレフィン・ゲーエムベーハー １−ブテン／プロピレンコポリマーの製造方法
DE102004056104A1 (de) * 2004-11-19 2006-05-24 Basell Polyolefine Gmbh Verfahren zur Herstellung von niedermolekularen Olefinpolymeren, Organoübergangsmetallverbindungen, Biscyclopentadienylligandsysteme und Katalysatorsysteme
CN101061142B (zh) * 2004-11-22 2012-04-18 巴塞尔聚烯烃股份有限公司 基于丙烯的三元共聚物
US20080160862A1 (en) * 2004-12-13 2008-07-03 Basell Poliolefine Italia S.R.L. Polyolefin Composition, Fibres and Nonwoven Fabrics
WO2006067214A1 (en) * 2004-12-23 2006-06-29 Basell Poliolefine Italia S.R.L. Fibres having elastic properties
KR100753477B1 (ko) * 2005-01-31 2007-08-31 주식회사 엘지화학 혼합 담지 메탈로센 촉매, 그 제조방법 및 이를 이용하여제조된 폴리올레핀 및 그 제조 방법
US7803887B2 (en) * 2005-03-18 2010-09-28 Basell Polyolefine Gmbh Metallocene compounds
RU2410388C2 (ru) * 2005-03-18 2011-01-27 Базелль Полиолефине Гмбх Металлоценовые соединения
US7728086B2 (en) * 2005-03-23 2010-06-01 Basell Polyolefine Gmbh Process for the polymerization of olefins
EP1861435B1 (en) * 2005-03-23 2016-01-13 Basell Polyolefine GmbH Process for the polymerization of olefins
EP1877453A1 (en) * 2005-05-03 2008-01-16 Basell Polyolefine GmbH Process for the polymerization of alpha olefins
US7985799B2 (en) 2005-05-11 2011-07-26 Basell Poliolefine Italia S.R.L. Polymerization process for preparing polyolefin blends
WO2007003528A2 (en) * 2005-06-30 2007-01-11 Basell Polyolefine Gmbh Metallocene compounds
DE602007003743D1 (de) * 2006-08-30 2010-01-21 Basell Polyolefine Gmbh 1-buten-propylen-copolymer-zusammensetzungen
KR101374142B1 (ko) * 2006-08-30 2014-03-17 바젤 폴리올레핀 게엠베하 1-부텐 프로필렌 공중합체 조성물
US8143352B2 (en) 2006-12-20 2012-03-27 Exxonmobil Research And Engineering Company Process for fluid phase in-line blending of polymers
US8242237B2 (en) * 2006-12-20 2012-08-14 Exxonmobil Chemical Patents Inc. Phase separator and monomer recycle for supercritical polymerization process
US8080610B2 (en) 2007-03-06 2011-12-20 Exxonmobil Research And Engineering Company Monomer recycle process for fluid phase in-line blending of polymers
WO2008150572A1 (en) 2007-06-04 2008-12-11 Exxonmobil Chemical Patents Inc. Super-solution homogeneous propylene polymerization
DE102007036792A1 (de) * 2007-08-03 2009-02-05 Clariant International Limited Hochkristalline Polypropylenwachse
US7910637B2 (en) 2007-09-13 2011-03-22 Exxonmobil Research And Engineering Company In-line blending of plasticizers with a base polymer
CN101855249B (zh) 2007-09-13 2013-02-13 埃克森美孚研究工程公司 在线生产增塑聚合物和增塑聚合物共混物的方法
US8431661B2 (en) 2010-10-21 2013-04-30 Exxonmobil Chemical Patents Inc. Polyethylene and process for production thereof
US8436114B2 (en) 2010-10-21 2013-05-07 Exxonmobil Chemical Patents Inc. Polyethylene and process for production thereof
US7910679B2 (en) 2007-12-20 2011-03-22 Exxonmobil Research And Engineering Company Bulk homogeneous polymerization process for ethylene propylene copolymers
WO2009082463A1 (en) 2007-12-20 2009-07-02 Exxonmobil Research And Engineering Company In-line process to produce pellet-stable polyolefins
EP2450403A1 (en) 2007-12-20 2012-05-09 ExxonMobil Research and Engineering Company Polypropylene ethylene-propylene copolymer blends and in-line process to produce them
US8318875B2 (en) 2008-01-18 2012-11-27 Exxonmobil Chemical Patents Inc. Super-solution homogeneous propylene polymerization and polypropylenes made therefrom
BRPI0908411B1 (pt) * 2008-02-29 2018-10-30 Basell Poliolefine Italia Srl composições de poliolefinas
WO2011129594A2 (ko) 2010-04-12 2011-10-20 호남석유화학 주식회사 티오펜-축합고리 사이클로펜타디에닐 리간드를 포함하는 전이금속 화합물을 사용한 올레핀-디엔 공중합체의 제조방법
EP2559713B1 (en) 2010-04-12 2016-08-10 Lotte Chemical Corporation Method for preparing polypropylene using a transition metal compound containing thiophene-fused cyclopentadienyl ligands
WO2011129590A2 (ko) 2010-04-12 2011-10-20 호남석유화학 주식회사 올레핀 중합용 촉매 조성물 및 이를 사용한 폴리올레핀의 제조방법
EP2559711B1 (en) 2010-04-12 2017-06-14 Lotte Chemical Corporation Supported catalyst for polymerizing olefin and method for preparing polyolefin using same
KR100986301B1 (ko) 2010-04-12 2010-10-07 아주대학교산학협력단 테트라하이드로퀴놀린 유도체로부터 유래한 티오펜-축합고리 싸이클로펜타디에닐 4족 금속 화합물 및 이를 이용한 올레핀 중합
EP2630168A4 (en) * 2010-10-21 2014-10-29 Exxonmobil Chem Patents Inc POLYETHYLENE AND METHOD OF MANUFACTURING THEREOF
WO2015009479A1 (en) 2013-07-17 2015-01-22 Exxonmobil Chemical Patents Inc. Substituted metallocene catalysts
EP3022236B1 (en) 2013-07-17 2017-11-15 ExxonMobil Chemical Patents Inc. Process using substituted metallocene catalysts and products therefrom
CN105358589B (zh) 2013-07-17 2018-07-03 埃克森美孚化学专利公司 金属茂和由其衍生的催化剂组合物
US9938364B2 (en) 2013-07-17 2018-04-10 Exxonmobil Chemical Patents Inc. Substituted metallocene catalysts
CN105377905B (zh) 2013-07-17 2018-09-14 埃克森美孚化学专利公司 茂金属和由其衍生的催化剂组合物
CN105358586A (zh) 2013-07-17 2016-02-24 埃克森美孚化学专利公司 环丙基取代的茂金属催化剂
CN104558058B (zh) * 2013-10-12 2017-08-08 中国科学院长春应用化学研究所 茂金属配合物及其制备方法、催化剂组合物
US9321854B2 (en) 2013-10-29 2016-04-26 Exxonmobil Chemical Patents Inc. Aluminum alkyl with C5 cyclic and pendent olefin polymerization catalyst
WO2015065784A1 (en) * 2013-10-29 2015-05-07 Exxonmobil Chemical Patents Inc. Novel aluminum alkyl with c5 cyclic and pendent olefin polymerization catalyst
EP3303423A1 (en) 2015-06-05 2018-04-11 ExxonMobil Chemical Patents Inc. Single reactor production of polymers in gas or slurry phase
US9809664B2 (en) 2015-06-05 2017-11-07 Exxonmobil Chemical Patents Inc. Bimodal propylene polymers and sequential polymerization
US10294316B2 (en) 2015-06-05 2019-05-21 Exxonmobil Chemical Patents Inc. Silica supports with high aluminoxane loading capability
US10280233B2 (en) 2015-06-05 2019-05-07 Exxonmobil Chemical Patents Inc. Catalyst systems and methods of making and using the same
US10329360B2 (en) 2015-06-05 2019-06-25 Exxonmobil Chemical Patents Inc. Catalyst system comprising supported alumoxane and unsupported alumoxane particles
US10280235B2 (en) 2015-06-05 2019-05-07 Exxonmobil Chemical Patents Inc. Catalyst system containing high surface area supports and sequential polymerization to produce heterophasic polymers
WO2016196339A2 (en) 2015-06-05 2016-12-08 Exxonmobil Chemical Patents Inc. Production of heterophasic polymers in gas or slurry phase
US10723821B2 (en) 2015-06-05 2020-07-28 Exxonmobil Chemical Patents Inc. Supported metallocene catalyst systems for polymerization
JP6787188B2 (ja) 2016-03-04 2020-11-18 日本ポリエチレン株式会社 メタロセン化合物、それを含むオレフィン重合用触媒成分およびオレフィン重合用触媒、並びにそのオレフィン重合用触媒を用いたオレフィン重合体の製造方法
WO2017204830A1 (en) 2016-05-27 2017-11-30 Exxonmobil Chemical Patents, Inc. Metallocene catalyst compositions and polymerization process therewith
EP3694811B1 (en) 2017-10-11 2024-04-03 Basell Polyolefine GmbH Supported catalyst system
CN110655623A (zh) * 2019-09-19 2020-01-07 天津大学 采用链穿梭聚合的方法制备无规聚丙烯-等规聚丙烯立构嵌段聚合物
US11472828B2 (en) 2019-10-11 2022-10-18 Exxonmobil Chemical Patents Inc. Indacene based metallocene catalysts useful in the production of propylene polymers
JP7676863B2 (ja) * 2020-03-24 2025-05-15 日本ポリプロ株式会社 オレフィン重合用担持系触媒、及び、当該オレフィン重合用担持系触媒を用いたプロピレン系重合体の製造方法
CN114702532B (zh) * 2021-01-01 2024-08-06 中国石油化工股份有限公司 一种茂金属、含有其的催化剂及其合成和应用
CN116410385B (zh) * 2021-12-31 2025-11-18 中国石油天然气股份有限公司 一种聚烯烃弹性体及其制备方法与所用茂金属催化剂
CN116410238A (zh) * 2021-12-31 2023-07-11 中国石油天然气股份有限公司 含硫手性桥联茂金属化合物及其制备和应用
CN114507305A (zh) * 2022-01-27 2022-05-17 吉林大学 一种茂锆型烯烃聚合催化剂的合成方法
WO2023182216A1 (ja) 2022-03-24 2023-09-28 日本ポリプロ株式会社 分岐状プロピレン系重合体

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1998022486A1 (en) * 1996-11-15 1998-05-28 Montell Technology Company B.V. Heterocyclic metallocenes and polymerization catalysts

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ZA844157B (en) 1983-06-06 1986-01-29 Exxon Research Engineering Co Process and catalyst for polyolefin density and molecular weight control
JP3293927B2 (ja) 1993-02-19 2002-06-17 三菱化学株式会社 α‐オレフィン重合用触媒成分およびそれを用いたα‐オレフィン重合体の製造法
US6559252B1 (en) 1997-10-29 2003-05-06 Basell Technology Company Bv Catalysts and processes for the polymerization of olefins
HUP0001331A2 (hu) * 1997-11-12 2000-08-28 Montell Technology Company B.V. Metallocének, áthidalt ligandumok, olefinpolimerizációs katalizátorok és eljárás olefinek polimerizálására
DE19804970A1 (de) * 1998-02-07 1999-08-12 Aventis Res & Tech Gmbh & Co Katalysatorsystem
EP1074557A3 (de) * 1999-07-31 2003-02-26 Basell Polyolefine GmbH Übergangsmetallverbindung, Ligandensystem, Katalysatorsystem und seine Verwendung zur Polymerisation von Olefinen
US6444833B1 (en) * 1999-12-15 2002-09-03 Basell Technology Company Bv Metallocene compounds, process for their preparation and their use in catalytic systems for the polymerization of olefins

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1998022486A1 (en) * 1996-11-15 1998-05-28 Montell Technology Company B.V. Heterocyclic metallocenes and polymerization catalysts

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AU778205B2 (en) 2004-11-25
US6444833B1 (en) 2002-09-03
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