JPWO2020095968A1 - 潤滑油組成物 - Google Patents
潤滑油組成物 Download PDFInfo
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- JPWO2020095968A1 JPWO2020095968A1 JP2020555566A JP2020555566A JPWO2020095968A1 JP WO2020095968 A1 JPWO2020095968 A1 JP WO2020095968A1 JP 2020555566 A JP2020555566 A JP 2020555566A JP 2020555566 A JP2020555566 A JP 2020555566A JP WO2020095968 A1 JPWO2020095968 A1 JP WO2020095968A1
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- Prior art keywords
- lubricating oil
- mass
- composition
- group
- oil composition
- Prior art date
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- 239000000203 mixture Substances 0.000 title claims abstract description 219
- 239000010687 lubricating oil Substances 0.000 title claims abstract description 148
- -1 imide succinate Chemical class 0.000 claims abstract description 127
- 239000002199 base oil Substances 0.000 claims abstract description 66
- 229910052751 metal Inorganic materials 0.000 claims abstract description 62
- 239000002184 metal Substances 0.000 claims abstract description 59
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims abstract description 50
- 239000003607 modifier Substances 0.000 claims abstract description 42
- 239000012459 cleaning agent Substances 0.000 claims abstract description 36
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 35
- 229910052757 nitrogen Inorganic materials 0.000 claims abstract description 30
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 21
- AVVIDTZRJBSXML-UHFFFAOYSA-L calcium;2-carboxyphenolate;dihydrate Chemical compound O.O.[Ca+2].OC1=CC=CC=C1C([O-])=O.OC1=CC=CC=C1C([O-])=O AVVIDTZRJBSXML-UHFFFAOYSA-L 0.000 claims abstract description 19
- 239000002270 dispersing agent Substances 0.000 claims abstract description 19
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000011575 calcium Substances 0.000 claims abstract description 11
- 229910052791 calcium Inorganic materials 0.000 claims abstract description 11
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 claims abstract description 11
- 125000004432 carbon atom Chemical group C* 0.000 claims description 92
- 239000003921 oil Substances 0.000 claims description 61
- KZNICNPSHKQLFF-UHFFFAOYSA-N succinimide Chemical compound O=C1CCC(=O)N1 KZNICNPSHKQLFF-UHFFFAOYSA-N 0.000 claims description 58
- 125000000217 alkyl group Chemical group 0.000 claims description 45
- 125000003342 alkenyl group Chemical group 0.000 claims description 33
- 229920000768 polyamine Polymers 0.000 claims description 32
- 229960002317 succinimide Drugs 0.000 claims description 32
- 229910052717 sulfur Inorganic materials 0.000 claims description 21
- 230000005540 biological transmission Effects 0.000 claims description 18
- 125000001183 hydrocarbyl group Chemical group 0.000 claims description 16
- 230000001050 lubricating effect Effects 0.000 claims description 16
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 claims description 12
- 238000000034 method Methods 0.000 claims description 12
- 150000008064 anhydrides Chemical class 0.000 claims description 11
- 239000000344 soap Substances 0.000 claims description 11
- 239000001384 succinic acid Substances 0.000 claims description 11
- 238000006482 condensation reaction Methods 0.000 claims description 9
- 150000003949 imides Chemical class 0.000 claims description 9
- YGSDEFSMJLZEOE-UHFFFAOYSA-M salicylate Chemical compound OC1=CC=CC=C1C([O-])=O YGSDEFSMJLZEOE-UHFFFAOYSA-M 0.000 claims description 9
- 229960001860 salicylate Drugs 0.000 claims description 8
- 239000007795 chemical reaction product Substances 0.000 claims description 7
- 239000003599 detergent Substances 0.000 claims description 5
- 239000000047 product Substances 0.000 claims description 5
- 238000010525 oxidative degradation reaction Methods 0.000 claims description 4
- 125000004430 oxygen atom Chemical group O* 0.000 claims description 4
- 125000004434 sulfur atom Chemical group 0.000 claims description 4
- 101100208720 Homo sapiens USP5 gene Proteins 0.000 claims 1
- 102100021017 Ubiquitin carboxyl-terminal hydrolase 5 Human genes 0.000 claims 1
- 150000001875 compounds Chemical class 0.000 description 68
- 235000019198 oils Nutrition 0.000 description 60
- 230000001590 oxidative effect Effects 0.000 description 41
- 230000006866 deterioration Effects 0.000 description 36
- 239000003795 chemical substances by application Substances 0.000 description 31
- 235000014113 dietary fatty acids Nutrition 0.000 description 22
- 239000000194 fatty acid Substances 0.000 description 22
- 229930195729 fatty acid Natural products 0.000 description 22
- 238000010292 electrical insulation Methods 0.000 description 21
- 125000001931 aliphatic group Chemical group 0.000 description 20
- 150000004665 fatty acids Chemical class 0.000 description 20
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 17
- 239000011593 sulfur Substances 0.000 description 17
- 230000000415 inactivating effect Effects 0.000 description 16
- 150000001412 amines Chemical class 0.000 description 15
- 239000005078 molybdenum compound Substances 0.000 description 15
- 150000002752 molybdenum compounds Chemical class 0.000 description 15
- 238000012360 testing method Methods 0.000 description 15
- 239000002253 acid Substances 0.000 description 13
- 239000001257 hydrogen Substances 0.000 description 13
- 229910052739 hydrogen Inorganic materials 0.000 description 13
- 150000003839 salts Chemical class 0.000 description 13
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 12
- 229910052698 phosphorus Inorganic materials 0.000 description 12
- 239000011574 phosphorus Substances 0.000 description 12
- 239000008186 active pharmaceutical agent Substances 0.000 description 10
- 150000001408 amides Chemical class 0.000 description 10
- 239000007859 condensation product Substances 0.000 description 9
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 8
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 8
- 239000000654 additive Substances 0.000 description 8
- 239000002585 base Substances 0.000 description 8
- 150000002148 esters Chemical class 0.000 description 8
- 239000002994 raw material Substances 0.000 description 8
- 150000004982 aromatic amines Chemical class 0.000 description 7
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 7
- 238000001816 cooling Methods 0.000 description 7
- 239000002480 mineral oil Substances 0.000 description 7
- 235000010446 mineral oil Nutrition 0.000 description 7
- 239000001301 oxygen Substances 0.000 description 7
- 229910052760 oxygen Inorganic materials 0.000 description 7
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical compound CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 description 6
- 230000000996 additive effect Effects 0.000 description 6
- 150000001336 alkenes Chemical class 0.000 description 6
- 150000004678 hydrides Chemical class 0.000 description 6
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 6
- CWQXQMHSOZUFJS-UHFFFAOYSA-N molybdenum disulfide Chemical compound S=[Mo]=S CWQXQMHSOZUFJS-UHFFFAOYSA-N 0.000 description 6
- 230000003449 preventive effect Effects 0.000 description 6
- 125000001424 substituent group Chemical group 0.000 description 6
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 6
- 125000005090 alkenylcarbonyl group Chemical group 0.000 description 5
- 125000004448 alkyl carbonyl group Chemical group 0.000 description 5
- 239000002518 antifoaming agent Substances 0.000 description 5
- 230000007797 corrosion Effects 0.000 description 5
- 238000005260 corrosion Methods 0.000 description 5
- 239000003995 emulsifying agent Substances 0.000 description 5
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 5
- 239000003112 inhibitor Substances 0.000 description 5
- 230000004048 modification Effects 0.000 description 5
- 238000012986 modification Methods 0.000 description 5
- 229910052750 molybdenum Inorganic materials 0.000 description 5
- 239000011733 molybdenum Substances 0.000 description 5
- 239000001993 wax Substances 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 4
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 4
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 4
- XQVWYOYUZDUNRW-UHFFFAOYSA-N N-Phenyl-1-naphthylamine Chemical compound C=1C=CC2=CC=CC=C2C=1NC1=CC=CC=C1 XQVWYOYUZDUNRW-UHFFFAOYSA-N 0.000 description 4
- 125000002947 alkylene group Chemical group 0.000 description 4
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 4
- 150000001413 amino acids Chemical class 0.000 description 4
- 125000003277 amino group Chemical group 0.000 description 4
- DMBHHRLKUKUOEG-UHFFFAOYSA-N diphenylamine Chemical class C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 description 4
- 125000000816 ethylene group Chemical group [H]C([H])([*:1])C([H])([H])[*:2] 0.000 description 4
- 239000000446 fuel Substances 0.000 description 4
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 150000002894 organic compounds Chemical class 0.000 description 4
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 4
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 4
- 238000005096 rolling process Methods 0.000 description 4
- 150000003852 triazoles Chemical class 0.000 description 4
- BWGNESOTFCXPMA-UHFFFAOYSA-N Dihydrogen disulfide Chemical compound SS BWGNESOTFCXPMA-UHFFFAOYSA-N 0.000 description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 3
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 3
- 125000003158 alcohol group Chemical group 0.000 description 3
- ARCGXLSVLAOJQL-UHFFFAOYSA-N anhydrous trimellitic acid Natural products OC(=O)C1=CC=C(C(O)=O)C(C(O)=O)=C1 ARCGXLSVLAOJQL-UHFFFAOYSA-N 0.000 description 3
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 3
- 239000012964 benzotriazole Substances 0.000 description 3
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 3
- 239000004327 boric acid Substances 0.000 description 3
- 235000013877 carbamide Nutrition 0.000 description 3
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 3
- 239000003086 colorant Substances 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 3
- 230000002708 enhancing effect Effects 0.000 description 3
- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 3
- 125000001841 imino group Chemical group [H]N=* 0.000 description 3
- 238000005461 lubrication Methods 0.000 description 3
- 150000002751 molybdenum Chemical class 0.000 description 3
- 239000010705 motor oil Substances 0.000 description 3
- 125000004433 nitrogen atom Chemical group N* 0.000 description 3
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- 239000002530 phenolic antioxidant Substances 0.000 description 3
- 229920013639 polyalphaolefin Polymers 0.000 description 3
- 229920000193 polymethacrylate Polymers 0.000 description 3
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 3
- KDYFGRWQOYBRFD-UHFFFAOYSA-L succinate(2-) Chemical compound [O-]C(=O)CCC([O-])=O KDYFGRWQOYBRFD-UHFFFAOYSA-L 0.000 description 3
- 229940014800 succinic anhydride Drugs 0.000 description 3
- 239000004711 α-olefin Substances 0.000 description 3
- YXIWHUQXZSMYRE-UHFFFAOYSA-N 1,3-benzothiazole-2-thiol Chemical compound C1=CC=C2SC(S)=NC2=C1 YXIWHUQXZSMYRE-UHFFFAOYSA-N 0.000 description 2
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 2
- AFFLGGQVNFXPEV-UHFFFAOYSA-N 1-decene Chemical compound CCCCCCCCC=C AFFLGGQVNFXPEV-UHFFFAOYSA-N 0.000 description 2
- RUFPHBVGCFYCNW-UHFFFAOYSA-N 1-naphthylamine Chemical class C1=CC=C2C(N)=CC=CC2=C1 RUFPHBVGCFYCNW-UHFFFAOYSA-N 0.000 description 2
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 2
- VILCJCGEZXAXTO-UHFFFAOYSA-N 2,2,2-tetramine Chemical compound NCCNCCNCCN VILCJCGEZXAXTO-UHFFFAOYSA-N 0.000 description 2
- BVUXDWXKPROUDO-UHFFFAOYSA-N 2,6-di-tert-butyl-4-ethylphenol Chemical compound CCC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 BVUXDWXKPROUDO-UHFFFAOYSA-N 0.000 description 2
- SZAQZZKNQILGPU-UHFFFAOYSA-N 2-[1-(2-hydroxy-3,5-dimethylphenyl)-2-methylpropyl]-4,6-dimethylphenol Chemical compound C=1C(C)=CC(C)=C(O)C=1C(C(C)C)C1=CC(C)=CC(C)=C1O SZAQZZKNQILGPU-UHFFFAOYSA-N 0.000 description 2
- BKZXZGWHTRCFPX-UHFFFAOYSA-N 2-tert-butyl-6-methylphenol Chemical compound CC1=CC=CC(C(C)(C)C)=C1O BKZXZGWHTRCFPX-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 229920000089 Cyclic olefin copolymer Polymers 0.000 description 2
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
- 239000005977 Ethylene Substances 0.000 description 2
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 description 2
- 229920002367 Polyisobutene Polymers 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 150000001447 alkali salts Chemical class 0.000 description 2
- 230000029936 alkylation Effects 0.000 description 2
- 238000005804 alkylation reaction Methods 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 239000001569 carbon dioxide Substances 0.000 description 2
- 229910002092 carbon dioxide Inorganic materials 0.000 description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- 238000004517 catalytic hydrocracking Methods 0.000 description 2
- 239000010724 circulating oil Substances 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- 150000005690 diesters Chemical class 0.000 description 2
- QXYJCZRRLLQGCR-UHFFFAOYSA-N dioxomolybdenum Chemical compound O=[Mo]=O QXYJCZRRLLQGCR-UHFFFAOYSA-N 0.000 description 2
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- 125000000524 functional group Chemical group 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 125000000743 hydrocarbylene group Chemical group 0.000 description 2
- 239000000314 lubricant Substances 0.000 description 2
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 2
- JKQOBWVOAYFWKG-UHFFFAOYSA-N molybdenum trioxide Chemical compound O=[Mo](=O)=O JKQOBWVOAYFWKG-UHFFFAOYSA-N 0.000 description 2
- LSHROXHEILXKHM-UHFFFAOYSA-N n'-[2-[2-[2-(2-aminoethylamino)ethylamino]ethylamino]ethyl]ethane-1,2-diamine Chemical compound NCCNCCNCCNCCNCCN LSHROXHEILXKHM-UHFFFAOYSA-N 0.000 description 2
- 150000007524 organic acids Chemical class 0.000 description 2
- 239000003208 petroleum Substances 0.000 description 2
- 150000003139 primary aliphatic amines Chemical class 0.000 description 2
- CYIDZMCFTVVTJO-UHFFFAOYSA-N pyromellitic acid Chemical compound OC(=O)C1=CC(C(O)=O)=C(C(O)=O)C=C1C(O)=O CYIDZMCFTVVTJO-UHFFFAOYSA-N 0.000 description 2
- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 description 2
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- 239000002904 solvent Substances 0.000 description 2
- 239000007858 starting material Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- FAGUFWYHJQFNRV-UHFFFAOYSA-N tetraethylenepentamine Chemical compound NCCNCCNCCNCCN FAGUFWYHJQFNRV-UHFFFAOYSA-N 0.000 description 2
- 125000000923 (C1-C30) alkyl group Chemical group 0.000 description 1
- QMMJWQMCMRUYTG-UHFFFAOYSA-N 1,2,4,5-tetrachloro-3-(trifluoromethyl)benzene Chemical compound FC(F)(F)C1=C(Cl)C(Cl)=CC(Cl)=C1Cl QMMJWQMCMRUYTG-UHFFFAOYSA-N 0.000 description 1
- MBIZXFATKUQOOA-UHFFFAOYSA-N 1,3,4-thiadiazole Chemical compound C1=NN=CS1 MBIZXFATKUQOOA-UHFFFAOYSA-N 0.000 description 1
- RZRNAYUHWVFMIP-KTKRTIGZSA-N 1-oleoylglycerol Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCC(O)CO RZRNAYUHWVFMIP-KTKRTIGZSA-N 0.000 description 1
- HYZJCKYKOHLVJF-UHFFFAOYSA-N 1H-benzimidazole Chemical compound C1=CC=C2NC=NC2=C1 HYZJCKYKOHLVJF-UHFFFAOYSA-N 0.000 description 1
- KGRVJHAUYBGFFP-UHFFFAOYSA-N 2,2'-Methylenebis(4-methyl-6-tert-butylphenol) Chemical compound CC(C)(C)C1=CC(C)=CC(CC=2C(=C(C=C(C)C=2)C(C)(C)C)O)=C1O KGRVJHAUYBGFFP-UHFFFAOYSA-N 0.000 description 1
- VDVUCLWJZJHFAV-UHFFFAOYSA-N 2,2,6,6-tetramethylpiperidin-4-ol Chemical compound CC1(C)CC(O)CC(C)(C)N1 VDVUCLWJZJHFAV-UHFFFAOYSA-N 0.000 description 1
- RKMGAJGJIURJSJ-UHFFFAOYSA-N 2,2,6,6-tetramethylpiperidine Chemical group CC1(C)CCCC(C)(C)N1 RKMGAJGJIURJSJ-UHFFFAOYSA-N 0.000 description 1
- OPLCSTZDXXUYDU-UHFFFAOYSA-N 2,4-dimethyl-6-tert-butylphenol Chemical compound CC1=CC(C)=C(O)C(C(C)(C)C)=C1 OPLCSTZDXXUYDU-UHFFFAOYSA-N 0.000 description 1
- DKCPKDPYUFEZCP-UHFFFAOYSA-N 2,6-di-tert-butylphenol Chemical compound CC(C)(C)C1=CC=CC(C(C)(C)C)=C1O DKCPKDPYUFEZCP-UHFFFAOYSA-N 0.000 description 1
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- UDFARPRXWMDFQU-UHFFFAOYSA-N 2,6-ditert-butyl-4-[(3,5-ditert-butyl-4-hydroxyphenyl)methylsulfanylmethyl]phenol Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CSCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 UDFARPRXWMDFQU-UHFFFAOYSA-N 0.000 description 1
- VRMHHVOBVLFRFB-UHFFFAOYSA-N 2-(2-cyanoethylsulfanylmethyl)benzoic acid Chemical compound OC(=O)C1=CC=CC=C1CSCCC#N VRMHHVOBVLFRFB-UHFFFAOYSA-N 0.000 description 1
- VFBJXXJYHWLXRM-UHFFFAOYSA-N 2-[2-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]ethylsulfanyl]ethyl 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCCSCCOC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 VFBJXXJYHWLXRM-UHFFFAOYSA-N 0.000 description 1
- AKNMPWVTPUHKCG-UHFFFAOYSA-N 2-cyclohexyl-6-[(3-cyclohexyl-2-hydroxy-5-methylphenyl)methyl]-4-methylphenol Chemical compound OC=1C(C2CCCCC2)=CC(C)=CC=1CC(C=1O)=CC(C)=CC=1C1CCCCC1 AKNMPWVTPUHKCG-UHFFFAOYSA-N 0.000 description 1
- LLEFDCACDRGBKD-UHFFFAOYSA-N 2-ethyl-2-(hydroxymethyl)propane-1,3-diol;nonanoic acid Chemical compound CCC(CO)(CO)CO.CCCCCCCCC(O)=O LLEFDCACDRGBKD-UHFFFAOYSA-N 0.000 description 1
- FOKDITTZHHDEHD-PFONDFGASA-N 2-ethylhexyl (z)-octadec-9-enoate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCC(CC)CCCC FOKDITTZHHDEHD-PFONDFGASA-N 0.000 description 1
- YFHKLSPMRRWLKI-UHFFFAOYSA-N 2-tert-butyl-4-(3-tert-butyl-4-hydroxy-5-methylphenyl)sulfanyl-6-methylphenol Chemical compound CC(C)(C)C1=C(O)C(C)=CC(SC=2C=C(C(O)=C(C)C=2)C(C)(C)C)=C1 YFHKLSPMRRWLKI-UHFFFAOYSA-N 0.000 description 1
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- 150000005846 sugar alcohols Polymers 0.000 description 1
- 125000000446 sulfanediyl group Chemical group *S* 0.000 description 1
- 150000003464 sulfur compounds Chemical class 0.000 description 1
- KXTZPAQXYKUVLD-UHFFFAOYSA-N tetradecanehydrazide Chemical compound CCCCCCCCCCCCCC(=O)NN KXTZPAQXYKUVLD-UHFFFAOYSA-N 0.000 description 1
- IPOBMWQSKXACEW-UHFFFAOYSA-N tetradecylurea Chemical compound CCCCCCCCCCCCCCNC(N)=O IPOBMWQSKXACEW-UHFFFAOYSA-N 0.000 description 1
- VLLMWSRANPNYQX-UHFFFAOYSA-N thiadiazole Chemical compound C1=CSN=N1.C1=CSN=N1 VLLMWSRANPNYQX-UHFFFAOYSA-N 0.000 description 1
- MCSPQTFLIAPWRZ-UHFFFAOYSA-N tridecanehydrazide Chemical compound CCCCCCCCCCCCC(=O)NN MCSPQTFLIAPWRZ-UHFFFAOYSA-N 0.000 description 1
- 125000002889 tridecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- VIFASLUWVPBABR-UHFFFAOYSA-N tridecylurea Chemical compound CCCCCCCCCCCCCNC(N)=O VIFASLUWVPBABR-UHFFFAOYSA-N 0.000 description 1
- 150000005691 triesters Chemical class 0.000 description 1
- 125000002948 undecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000005292 vacuum distillation Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000013585 weight reducing agent Substances 0.000 description 1
- 239000012991 xanthate Substances 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Classifications
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
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- C10M141/10—Lubricating compositions characterised by the additive being a mixture of two or more compounds covered by more than one of the main groups C10M125/00 - C10M139/00, each of these compounds being essential at least one of them being an organic phosphorus-containing compound
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- C10M129/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen
- C10M129/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen having a carbon chain of less than 30 atoms
- C10M129/26—Carboxylic acids; Salts thereof
- C10M129/48—Carboxylic acids; Salts thereof having carboxyl groups bound to a carbon atom of a six-membered aromatic ring
- C10M129/54—Carboxylic acids; Salts thereof having carboxyl groups bound to a carbon atom of a six-membered aromatic ring containing hydroxy groups
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- C10M133/12—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to a carbon atom of a six-membered aromatic ring
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- C10M133/38—Heterocyclic nitrogen compounds
- C10M133/44—Five-membered ring containing nitrogen and carbon only
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- C10M135/10—Sulfonic acids or derivatives thereof
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- C10M137/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing phosphorus having no phosphorus-to-carbon bond
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- C10M169/04—Mixtures of base-materials and additives
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- C10M2203/1025—Aliphatic fractions used as base material
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- C10M2205/0285—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers containing aliphatic monomers having more than four carbon atoms used as base material
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2070/00—Specific manufacturing methods for lubricant compositions
Abstract
Description
[1] 潤滑油基油と、(A)カルシウムサリシレート清浄剤を、組成物全量基準でカルシウム量として0.005〜0.03質量%と、(B)コハク酸イミド系無灰分散剤を、組成物全量基準で窒素量として0.005〜0.25質量%と、(C1)窒素を含有する酸化防止剤を、組成物全量基準で窒素量として0.005〜0.15質量%とを含有し、(D)窒素を含有する摩擦調整剤を、組成物全量基準で窒素量として0.03質量%以下含有するか又は含有せず、金属系清浄剤の総含有量が、組成物全量基準で金属量として0.005〜0.03質量%であることを特徴とする、潤滑油組成物。
本発明の潤滑油組成物(以下において「潤滑油組成物」又は単に「組成物」ということがある。)における潤滑油基油としては、1種以上の鉱油系基油、もしくは1種以上の合成系基油、またはそれらの混合基油を用いることができる。一の実施形態において、API基油分類のグループII基油、グループIII基油、グループIV基油、若しくはグループV基油、又はそれらの混合基油を好ましく用いることができる。APIグループII基油は、硫黄分が0.03質量%以下、飽和分が90質量%以上、且つ粘度指数が80以上120未満の鉱油系基油である。APIグループIII基油は、硫黄分が0.03質量%以下、飽和分が90質量%以上、且つ粘度指数が120以上の鉱油系基油である。APIグループIV基油はポリα−オレフィン基油である。APIグループV基油は上記グループI〜IV以外の基油であって、その好ましい例としてはエステル系基油を挙げることができる。
本発明の潤滑油組成物は、(A)カルシウムサリシレート清浄剤(以下において単に「(A)成分」ということがある。)を含有する。(A)成分としては、カルシウムサリシレートまたはその塩基性塩もしくは過塩基性塩を用いることができる。(A)成分としては1種のカルシウムサリシレート清浄剤を単独で用いてもよく、2種以上のカルシウムサリシレート清浄剤を組み合わせて用いてもよい。カルシウムサリシレートの例としては、以下の一般式(1)で表される化合物を挙げることができる。
本発明の潤滑油組成物は、(B)コハク酸イミド系無灰分散剤(以下において「(B)成分」ということがある。)を含有する。(B)成分としては、ホウ素化コハク酸イミド系無灰分散剤を用いてもよく、非ホウ素化コハク酸イミド系無灰分散剤を用いてもよく、両者を組み合わせて用いてもよい。ただし酸化劣化油の電気絶縁性をさらに高める観点からは、(B)成分は非ホウ素化コハク酸イミド系無灰分散剤を含むことが好ましい。
一般式(2)及び(3)におけるアルキル基またはアルケニル基(R2〜R4)の好適な数平均分子量は1000〜3500である。
本発明の潤滑油組成物は、(C)窒素を含有する酸化防止剤(以下において「(C)成分」ということがある。)を含有する。(C)成分としては1種の化合物を単独で用いてもよく、2種以上の化合物を組み合わせて用いても良い。(C)成分としては、芳香族アミン系酸化防止剤、ヒンダードアミン系酸化防止剤等の公知のアミン系酸化防止剤を特に制限なく用いることができる。芳香族アミン系酸化防止剤の例としては、アルキル化α−ナフチルアミン等の第1級芳香族アミン化合物;及び、アルキル化ジフェニルアミン、フェニル−α−ナフチルアミン、アルキル化フェニル−α−ナフチルアミン、フェニル−β−ナフチルアミン等の第2級芳香族アミン化合物;を挙げることができる。芳香族アミン系酸化防止剤としては、アルキル化ジフェニルアミン、若しくはアルキル化フェニル−α−ナフチルアミン、又はそれらの組み合わせを好ましく用いることができる。(C)成分としては、1種以上の芳香族アミン系酸化防止剤を用いてもよく、1種以上のヒンダードアミン系酸化防止剤を用いてもよく、1種以上の芳香族アミン系酸化防止剤と1種以上のヒンダードアミン系酸化防止剤とを組み合わせて用いてもよい。
一の実施形態において、潤滑油組成物は、窒素を含有する摩擦調整剤(以下において単に「(D)成分」ということがある。)を含み得る。窒素を含有する摩擦調整剤の例としては、後述する(D1)コハク酸イミド系摩擦調整剤のほか、アミン系摩擦調整剤、アミド系摩擦調整剤等の油性剤系摩擦調整剤を挙げることができる。(D)成分は、炭素数8〜36の脂肪族ヒドロカルビル基を有する脂肪族アミン化合物であってコハク酸イミド系無灰分散剤((B)成分)およびアミン系酸化防止剤((C)成分)以外の化合物、並びに、炭素数8〜36の脂肪族ヒドロカルビル又は脂肪族ヒドロカルビルカルボニル基とアミド結合とを有する化合物であってコハク酸イミド系無灰分散剤((B)成分)およびアミン系酸化防止剤((C)成分)以外の化合物を包含する。
脂肪酸アミド摩擦調整剤の例としては、ラウリン酸アミド、ミリスチン酸アミド、パルミチン酸アミド、ステアリン酸アミド、オレイン酸アミド、ヤシ油脂肪酸アミド、炭素数12〜13の合成混合脂肪酸アミド、等を挙げることができる。
一の好ましい実施形態において、潤滑油組成物は、(D)成分として(D1)コハク酸イミド系摩擦調整剤(以下において「(D1)成分」ということがある。)を含み得る。(D1)成分の例としては、炭素数8〜36のアルキル又はアルケニル基を有するビスコハク酸イミド化合物およびモノコハク酸イミド化合物、並びにそれらの誘導体(変性化合物)を挙げることができる。そのようなコハク酸イミド化合物は、例えば下記一般式(6)又は(7)で表される。
一の好ましい実施形態において、潤滑油組成物は、下記一般式(8)で表される亜リン酸エステル化合物(以下において「(E)成分」ということがある。)をさらに含み得る。(E)成分としては1種の亜リン酸エステル化合物を単独で用いてもよく、2種以上の亜リン酸エステル化合物を組み合わせて用いてもよい。
一の好ましい実施形態において、潤滑油組成物はトリルトリアゾール系金属不活性化剤および/またはベンゾトリアゾール系金属不活性化剤(以下において「(F)成分」ということがある。)をさらに含み得る。(F)成分としては、潤滑油において用いられるトリルトリアゾール系金属不活性化剤および/またはベンゾトリアゾール系金属不活性化剤を特に制限なく用いることができる。(F)成分は1種の化合物を単独で用いてもよく、2種以上の化合物を組み合わせて用いてもよい。
一の実施形態において、潤滑油組成物は、粘度指数向上剤、流動点降下剤、(C)成分以外の酸化防止剤、(E)成分以外の摩耗防止剤または極圧剤、(D)成分以外の摩擦調整剤、(F)成分以外の腐食防止剤、(F)成分以外の金属不活性化剤、防錆剤、抗乳化剤、消泡剤、及び着色剤から選ばれる1種以上の添加剤をさらに含み得る。
潤滑油組成物は(E)成分以外のリン含有添加剤を含有してもよく、含有しなくてもよいが、潤滑油組成物中の全リン含有量が組成物全量基準で0.06質量%以下であることが好ましい。潤滑油組成物中の全リン含有量が上記上限値以下であることにより、新油の電気絶縁性、および酸化劣化後の組成物の電気絶縁性をさらに高めることが可能になる。一の実施形態において、潤滑油組成物中の(E)成分以外のリン含有添加剤の総含有量は、組成物全量基準でリン分として好ましくは0〜0.05質量%、より好ましくは0〜0.03質量%、さらに好ましくは0〜0.02質量%である。(E)成分以外のリン含有添加剤の総含有量が上記上限値以下であることにより、新油の電気絶縁性、および酸化劣化後の組成物の電気絶縁性をさらに高めることが可能になる。
潤滑油組成物は、金属系清浄剤以外の金属含有添加剤(例えば有機モリブデン化合物やジアルキルジチオリン酸亜鉛等。)を含有してもよく、含有しなくてもよいが、潤滑油組成物中の金属元素の総含有量は、組成物全量基準で金属量として0.03質量%以下であることが好ましい。潤滑油組成物中の金属元素の総含有量が上記上限値以下であることにより、新油の電気絶縁性、および酸化劣化後の組成物の電気絶縁性をさらに高めることが可能になる。一の実施形態において、潤滑油組成物中の金属系清浄剤以外の金属含有添加剤の総含有量は、組成物全量基準で金属量として好ましくは0.010質量%以下、より好ましくは0.0075質量%以下、さらに好ましくは0.0050質量%以下である。金属系清浄剤以外の金属含有添加剤の総含有量が上記上限値以下であることにより、新油の電気絶縁性、および酸化劣化後の組成物の電気絶縁性をさらに高めることが可能になる。
潤滑油組成物の100℃における動粘度は、好ましくは1.8〜4.0mm2/sである。組成物の100℃における動粘度が上記上限値以下であることにより、省燃費性を高めることが可能になる。また組成物の100℃における動粘度が上記下限値以上であることにより、耐焼付き性、耐摩耗性、耐疲労性、新油の電気絶縁性、および酸化劣化後の組成物の電気絶縁性をさらに高めることが可能になる。
本発明の潤滑油組成物は、耐疲労性および酸化劣化後の組成物の電気絶縁性をバランス良く備えているので、電動モーター油、変速機油、電動モーターと変速機(歯車機構)との共通潤滑油、または電動モーターと変速機(歯車機構)とを備える電動ドライブモジュールの潤滑油として好ましく用いることができる。一の実施形態において、本発明の潤滑油組成物は、電動モーターを備える自動車において、電動モーターの潤滑に好ましく用いることができる。他の一の実施形態において、本発明の潤滑油組成物は、電動モーター及び変速機(歯車機構)を備える自動車において、電動モーター及び変速機(歯車機構)の潤滑に好ましく用いることができる。
表1〜6に示されるように、本発明の潤滑油組成物(実施例1〜27)、及び比較用の潤滑油組成物(比較例1〜5)をそれぞれ調製した。表中、基油について「mass%」は基油全量基準での(基油の全量を100質量%とする)質量%を意味し、他の成分について「mass%」は組成物全量基準での(組成物の全量を100質量%とする)質量%を意味し、「mass ppm」は組成物全量基準での質量ppmを意味する。成分の詳細は次の通りである。
O−1:水素化精製鉱油(Group II、動粘度(40℃):7.7mm2/s、動粘度(100℃):2.3mm2/s、粘度指数:118、硫黄分:1質量ppm未満)
O−2:水素化精製鉱油(Group III、動粘度(40℃):19.5mm2/s、動粘度(100℃):4.2mm2/s、粘度指数:125、硫黄分:1質量ppm未満)
O−3:ワックス異性化基油(Group III、動粘度(40℃):9.3mm2/s、動粘度(100℃):2.7mm2/s、粘度指数:125、硫黄分:1質量ppm未満)
O−4:ワックス異性化基油(Group III、動粘度(40℃):15.7mm2/s、動粘度(100℃):3.8mm2/s、粘度指数:143、硫黄分:1質量ppm未満)
O−5:ポリα−オレフィン(Group IV、動粘度(40℃):5.0mm2/s、動粘度(100℃):1.7mm2/s)
O−6:ポリα−オレフィン(Group IV、動粘度(40℃):18.4mm2/s、動粘度(100℃):4.1mm2/s、粘度指数:124)
O−7:モノエステル基油(Group V、動粘度(40℃):8.5mm2/s、動粘度(100℃):2.7mm2/s、粘度指数:177)
A−1:カルシウムサリシレート清浄剤、塩基価325mgKOH/g、金属比2.3
A−2*:カルシウムスルホネート清浄剤、塩基価300mgKOH/g、金属比2.2
なお本明細書において、金属系清浄剤の金属比は、
金属比=金属元素の価数×金属元素含有量(mol)/石けん基含有量(mol)
として定義され、金属系清浄剤が完全な中性塩であるときに1となる。式中、石けん基含有量(mol)は、金属系清浄剤の石けん基の負電荷の総和(mol)と等価である。石けん基は、石けん分を構成する有機酸の共役塩基(サリシレート清浄剤にあっては例えばアルキルサリシレートアニオン、スルホネート清浄剤にあっては例えばアルキルベンゼンスルホネートアニオン、フェネート清浄剤にあっては例えばアルキルフェネートアニオン。)を意味する。
B−1:非ホウ素化コハク酸イミド無灰分散剤(重量平均分子量:9000)
B−2:ホウ素化コハク酸イミド無灰分散剤(重量平均分子量:6000)
C−1:芳香族アミン系酸化防止剤
C−2:ヒンダードアミン系酸化防止剤
D−1:コハク酸イミド系摩擦調整剤(一般式(6)においてR10=R11=オクタデセニル基、R12=R13=エチレン基、d=1)
E−1:ビス(3−チアウンデシル)ハイドロジェンホスファイト
F−1:トリルトリアゾール系金属不活性化剤
G−1:フェノール系酸化防止剤
潤滑油組成物のそれぞれについて、新油の体積抵抗率、及び、酸化劣化油の体積抵抗率を測定した。酸化劣化油は、JIS K2514−1に準拠してISOT(Indiana Stirring Oxidation Test)法により油温165℃で150時間、新油を酸化処理することにより得た。新油および酸化劣化油のそれぞれについて、体積抵抗率の測定は、JIS C2101に規定の体積抵抗率試験に準拠し、油温80℃で行った。結果を表1〜6に示している。本試験において80℃における体積抵抗率が高いほど、電気絶縁性が良好であることを意味する。本試験における酸化劣化油の80℃における体積抵抗率は1.0×109Ω・cm以上であることが好ましい。
潤滑油組成物のそれぞれについて、ユニスチール転がり疲労試験機(3連式高温転がり疲れ試験機(TRF−1000/3−01H)、株式会社東京試験機製)を用いて、ユニスチール試験(イギリス石油学会法:IP305/79)によりスラストベアリングの転がり疲労寿命を測定した。スラストニードルベアリング(NSK製FNTA−2542C)の片側の軌道輪を平坦な試験片(材質:SUJ2)で置き換えてなる試験軸受について、荷重7000N、面圧2GPa、回転数1450rpm、油温120℃の条件下で、ころ又は試験片のいずれかが疲労損傷するまでの時間を測定した。なお、ユニスチール転がり疲労試験機に備えられた振動加速度計により測定される試験部の振動加速度が1.5m/s2に達したとき、疲労損傷が発生したと判断した。10回の繰り返し試験における疲労損傷までの時間から、ワイブルプロットにより疲労寿命を50%寿命(L50:累積確率が50%になる時間)として算出した。結果を表1〜6に示している。本試験で測定された50%寿命が長いほど、耐疲労性が良好であることを意味する。
実施例1〜27の潤滑油組成物は、耐疲労性および酸化劣化後の組成物の電気絶縁性において良好な結果を示した。
(A)成分(カルシウムサリシレート清浄剤)に代えてカルシウムスルホネート清浄剤を含有する比較例1及び2の潤滑油組成物は、耐疲労性において劣った結果を示した。
(A)成分の含有量が過大である比較例3の潤滑油組成物は、酸化劣化後の組成物の電気絶縁性において劣った結果を示した。
(B)成分の含有量が過大である比較例4の潤滑油組成物は、酸化劣化後の組成物の電気絶縁性において劣った結果を示した。
(C)成分の含有量が過大である比較例5の潤滑油組成物は、酸化劣化後の組成物の電気絶縁性において劣った結果を示した。
Claims (12)
- 潤滑油基油と、
(A)カルシウムサリシレート清浄剤を、組成物全量基準でカルシウム量として0.005〜0.03質量%と、
(B)コハク酸イミド系無灰分散剤を、組成物全量基準で窒素量として0.005〜0.25質量%と、
(C)窒素を含有する酸化防止剤を、組成物全量基準で窒素量として0.005〜0.15質量%と
を含有し、
(D)窒素を含有する摩擦調整剤を、組成物全量基準で窒素量として0.03質量%以下含有するか、又は含有せず、
金属系清浄剤の総含有量が、組成物全量基準で金属量として0.005〜0.03質量%であることを特徴とする、潤滑油組成物。 - 金属系清浄剤の全石けん基にサリシレートが占める割合が65mol%以上である、請求項1に記載の潤滑油組成物。
- (D1)コハク酸イミド系摩擦調整剤を、組成物全量基準で窒素量として0.001〜0.03質量%含有する、請求項1又は2に記載の潤滑油組成物。
- 前記(D1)成分が、炭素数8〜36のアルキル若しくはアルケニル基を有するアルキル若しくはアルケニルコハク酸又はその無水物と、ポリアミン、そのN−モノC1−36アルキル化物若しくはN−モノC1−36アルケニル化物、若しくはそれらの混合物との縮合反応生成物、若しくはその誘導体、又はそれらの組み合わせである、請求項3に記載の潤滑油組成物。
- 前記(B)成分が、炭素数40〜400のアルキル若しくはアルケニル基を有するアルキル若しくはアルケニルコハク酸若しくはその無水物と、ポリアミンとの縮合反応生成物、若しくはその誘導体、又はそれらの組み合わせである、請求項1〜4のいずれかに記載の潤滑油組成物。
- (F)トリルトリアゾール系金属不活性化剤および/またはベンゾトリアゾール系金属不活性化剤を、組成物全量基準で0.001〜0.1質量%含有する、請求項1〜6のいずれかに記載の潤滑油組成物。
- 前記組成物の40℃における動粘度が4〜20mm2/sであり、
前記組成物の100℃における動粘度が1.8〜4.0mm2/sである、請求項1〜7のいずれかに記載の潤滑油組成物。 - 前記組成物をJIS K2514−1に規定のISOT法により150時間酸化処理することにより得られる酸化劣化油の80℃における体積抵抗率が1.0×109Ω・cm以上である、請求項1〜8のいずれかに記載の潤滑油組成物。
- 電動モーターを備える自動車において、前記電動モーターの潤滑、又は、前記電動モーター及び変速機の潤滑に用いられる、請求項1〜9のいずれかに記載の潤滑油組成物。
- 請求項1〜10のいずれかに記載の潤滑油組成物を用いて、電動モーターを備える自動車の前記電動モーターを潤滑することを特徴とする、電動モーターの潤滑方法。
- 請求項1〜10のいずれかに記載の潤滑油組成物を用いて、電動モーターを備える自動車の前記電動モーター及び変速機を潤滑することを特徴とする、電動モーター及び変速機の潤滑方法。
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US11905488B2 (en) | 2020-10-16 | 2024-02-20 | Infineum International Limited | Transmission fluid compositions for hybrid and electric vehicle applications |
CN115960665A (zh) * | 2021-10-11 | 2023-04-14 | 中国石油化工股份有限公司 | 制备润滑油组合物以及调控或确定其电绝缘性的方法 |
CA3237045A1 (en) * | 2021-11-03 | 2023-05-11 | Chevron Oronite Company Llc | Lubricating oil compositions |
JP2023125591A (ja) * | 2022-02-28 | 2023-09-07 | 出光興産株式会社 | 潤滑油組成物 |
WO2023189696A1 (ja) * | 2022-03-31 | 2023-10-05 | 出光興産株式会社 | 潤滑油組成物 |
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Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH11171892A (ja) * | 1997-10-06 | 1999-06-29 | Idemitsu Kosan Co Ltd | 新規な亜リン酸エステル誘導体 |
JP2003113391A (ja) * | 2001-10-02 | 2003-04-18 | Nippon Oil Corp | 潤滑油組成物 |
WO2007052826A1 (ja) * | 2005-11-02 | 2007-05-10 | Nippon Oil Corporation | 潤滑油組成物 |
JP2008285682A (ja) * | 2001-05-28 | 2008-11-27 | Nissan Motor Co Ltd | 変速機油組成物 |
JP2012207083A (ja) * | 2011-03-29 | 2012-10-25 | Jx Nippon Oil & Energy Corp | 潤滑油組成物 |
JP2016108406A (ja) * | 2014-12-04 | 2016-06-20 | 東燃ゼネラル石油株式会社 | 潤滑油組成物 |
JP2016190953A (ja) * | 2015-03-31 | 2016-11-10 | Jxエネルギー株式会社 | 潤滑油組成物 |
JP2019529675A (ja) * | 2016-10-07 | 2019-10-17 | エクソンモービル リサーチ アンド エンジニアリング カンパニーExxon Research And Engineering Company | 電動車両およびハイブリッド車両のための高伝導率の潤滑油 |
Family Cites Families (34)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6078993A (ja) * | 1983-10-05 | 1985-05-04 | Toho Chem Ind Co Ltd | 有機リン化合物 |
JPH09202890A (ja) | 1995-11-21 | 1997-08-05 | Tonen Corp | 自動変速機用潤滑油組成物 |
JPH09328698A (ja) | 1996-04-10 | 1997-12-22 | Nippon Oil Co Ltd | すべり案内面用潤滑油組成物 |
US5840663A (en) * | 1996-12-18 | 1998-11-24 | Exxon Chemical Patents Inc. | Power transmitting fluids improved anti-shudder durability |
EP1022281A4 (en) * | 1997-10-06 | 2002-02-13 | Idemitsu Kosan Co | ORGANOPHOSPHORUS COMPOUNDS CONTAINING SULFUR |
US6103673A (en) | 1998-09-14 | 2000-08-15 | The Lubrizol Corporation | Compositions containing friction modifiers for continuously variable transmissions |
JP4123601B2 (ja) * | 1998-10-22 | 2008-07-23 | 新日本石油株式会社 | 潤滑油組成物 |
US20050250656A1 (en) | 2004-05-04 | 2005-11-10 | Masahiro Ishikawa | Continuously variable transmission fluid |
JP4663288B2 (ja) * | 2004-10-19 | 2011-04-06 | Jx日鉱日石エネルギー株式会社 | 鉛含有金属材料と接触する潤滑油組成物 |
JP5137314B2 (ja) * | 2006-03-31 | 2013-02-06 | Jx日鉱日石エネルギー株式会社 | 潤滑油基油 |
US8026199B2 (en) | 2006-11-10 | 2011-09-27 | Nippon Oil Corporation | Lubricating oil composition |
JP2010521559A (ja) * | 2007-03-13 | 2010-06-24 | ザ ルブリゾル コーポレイション | 多機能性ドライブライン流体 |
US20100113313A1 (en) | 2007-03-28 | 2010-05-06 | Idemitsu Kosan Co., Ltd. | Lubricant composition |
EP2476741B1 (en) | 2007-06-19 | 2015-08-12 | Afton Chemical Corporation | Pyrrolidine-2,5-Dione derivatives for use in lubricants |
EP2231840B1 (en) * | 2007-12-27 | 2013-04-10 | The Lubrizol Corporation | Lubricating composition containing detergent |
JP5642360B2 (ja) | 2009-06-16 | 2014-12-17 | シェブロンジャパン株式会社 | 潤滑油組成物 |
CA2711626C (en) | 2009-07-31 | 2017-11-28 | Chevron Japan Ltd. | Friction modifier and transmission oil |
JP5558384B2 (ja) * | 2011-02-02 | 2014-07-23 | シェブロンジャパン株式会社 | 潤滑油組成物および自動変速機の作動方法 |
WO2013141077A1 (ja) * | 2012-03-21 | 2013-09-26 | 出光興産株式会社 | アルミ合金製エンジン用潤滑油組成物及び潤滑方法 |
BR112015028641A2 (pt) * | 2013-05-14 | 2017-07-25 | Lubrizol Corp | composição e método de lubrificação de uma transmissão de lubrificação |
WO2015045816A1 (ja) * | 2013-09-25 | 2015-04-02 | 出光興産株式会社 | トラクションドライブ変速機用潤滑油組成物 |
CN104845706B (zh) | 2014-02-18 | 2019-06-07 | 吉坤日矿日石能源株式会社 | 变速器用润滑油组合物 |
JP6493829B2 (ja) | 2014-05-30 | 2019-04-03 | Khネオケム株式会社 | ペンタエリスリトールのエステル及びそれに用いるイソトリデカン酸 |
JP6247600B2 (ja) * | 2014-06-16 | 2017-12-13 | Jxtgエネルギー株式会社 | 変速機用潤滑油組成物 |
JP6551727B2 (ja) * | 2015-03-31 | 2019-07-31 | 出光興産株式会社 | 潤滑油組成物 |
JP6453142B2 (ja) * | 2015-03-31 | 2019-01-16 | 三洋化成工業株式会社 | 研磨材及びその製造方法 |
CN111087927B (zh) * | 2015-06-11 | 2021-09-28 | 株式会社自动网络技术研究所 | 金属表面涂覆用组合物和带端子的包覆电线 |
JP6156521B2 (ja) * | 2016-01-07 | 2017-07-05 | コニカミノルタ株式会社 | 有機エレクトロニクス素子、表示装置及び照明装置 |
JP6702611B2 (ja) * | 2016-03-04 | 2020-06-03 | 出光興産株式会社 | 潤滑油組成物、潤滑方法、及び変速機 |
JP6718349B2 (ja) | 2016-09-27 | 2020-07-08 | Jxtgエネルギー株式会社 | 無段変速機用潤滑油組成物 |
US20180100118A1 (en) * | 2016-10-07 | 2018-04-12 | Exxonmobil Research And Engineering Company | Method for controlling electrical conductivity of lubricating oils in electric vehicle powertrains |
JP7274277B2 (ja) * | 2018-10-24 | 2023-05-16 | 出光興産株式会社 | 潤滑油組成物 |
WO2020095968A1 (ja) | 2018-11-06 | 2020-05-14 | Jxtgエネルギー株式会社 | 潤滑油組成物 |
US11066622B2 (en) * | 2019-10-24 | 2021-07-20 | Afton Chemical Corporation | Synergistic lubricants with reduced electrical conductivity |
-
2019
- 2019-11-06 WO PCT/JP2019/043567 patent/WO2020095968A1/ja unknown
- 2019-11-06 CN CN201980069516.2A patent/CN112930389B/zh active Active
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- 2019-11-06 EP EP19881621.7A patent/EP3878930A4/en active Pending
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- 2019-11-06 JP JP2020555568A patent/JPWO2020095970A1/ja active Pending
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- 2019-11-06 EP EP19882330.4A patent/EP3878929A4/en active Pending
- 2019-11-06 WO PCT/JP2019/043568 patent/WO2020095969A1/ja unknown
Patent Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH11171892A (ja) * | 1997-10-06 | 1999-06-29 | Idemitsu Kosan Co Ltd | 新規な亜リン酸エステル誘導体 |
JP2008285682A (ja) * | 2001-05-28 | 2008-11-27 | Nissan Motor Co Ltd | 変速機油組成物 |
JP2003113391A (ja) * | 2001-10-02 | 2003-04-18 | Nippon Oil Corp | 潤滑油組成物 |
WO2007052826A1 (ja) * | 2005-11-02 | 2007-05-10 | Nippon Oil Corporation | 潤滑油組成物 |
JP2012207083A (ja) * | 2011-03-29 | 2012-10-25 | Jx Nippon Oil & Energy Corp | 潤滑油組成物 |
JP2016108406A (ja) * | 2014-12-04 | 2016-06-20 | 東燃ゼネラル石油株式会社 | 潤滑油組成物 |
JP2016190953A (ja) * | 2015-03-31 | 2016-11-10 | Jxエネルギー株式会社 | 潤滑油組成物 |
JP2019529675A (ja) * | 2016-10-07 | 2019-10-17 | エクソンモービル リサーチ アンド エンジニアリング カンパニーExxon Research And Engineering Company | 電動車両およびハイブリッド車両のための高伝導率の潤滑油 |
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