JPWO2018141746A5 - - Google Patents

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JPWO2018141746A5
JPWO2018141746A5 JP2019541234A JP2019541234A JPWO2018141746A5 JP WO2018141746 A5 JPWO2018141746 A5 JP WO2018141746A5 JP 2019541234 A JP2019541234 A JP 2019541234A JP 2019541234 A JP2019541234 A JP 2019541234A JP WO2018141746 A5 JPWO2018141746 A5 JP WO2018141746A5
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weight
binder composition
curable binder
assembly
sugar
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JP2020507643A (en
JP7175902B2 (en
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Priority claimed from GBGB1701569.4A external-priority patent/GB201701569D0/en
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本発明の結合剤組成物は、その後に電池用セパレーターにおいて、ルーフィング膜もしくは屋根板などのルーフ製品用の基材または他のとして応用することができる、不織繊維ベール、例えばガラス繊維ベールを製造するために使用することもできる。 The binder composition of the present invention subsequently comprises a non-woven fiber veil, such as a glass fiber veil, which can be subsequently applied as a base material or other film for roofing products such as roofing films or roofing plates in battery separators. It can also be used for manufacturing.

本発明の結合剤組成物に関する乾燥結合強度は、両組成物とも同じ総糖量を有する、標準的なグルコースをベースとする結合剤組成物と比べて、著しく改善していることがさらに見いだされた。
本発明の好ましい実施形態によれば、例えば、以下が提供される。
(項1)
炭水化物成分およびアンモニアとの無機酸の塩を含む硬化性結合剤組成物であって、前記炭水化物成分が、少なくとも部分的にデキストロースおよびキシロースを含む単糖、二糖ならびに多糖を含むセルロース加水分解物の糖である、硬化性結合剤組成物。
(項2)
前記セルロース加水分解物の糖が、前記糖成分の10~100重量%を構成する、上記項1に記載の硬化性結合剤組成物。
(項3)
前記組成物が水性であり、全水性結合剤組成物の重量に基づき、5~95重量%、好ましくは8~90重量%、より好ましくは10~85重量%の、より詳細には、全水性結合剤組成物の重量に基づき、5~25重量%、好ましくは8~20重量%、より好ましくは10~20重量%、もしくはさらには12~18重量%の範囲の、または全水性結合剤組成物の重量に基づき、50~95重量%、好ましくは50~90重量%、より好ましくは55~85重量%、もしくはさらには60~80重量%の範囲の固形分を含む、上記項1または2に記載の硬化性結合剤組成物。
(項4)
前記炭水化物成分が、1~95重量%のグルコースおよび0.5~15重量%のキシロース、好ましくは1~10重量%のキシロースを含み、その残りが、フルクトース、マンノース、ガラクトースおよび/または多糖フラクションである、前記上記項のいずれかに記載の硬化性結合剤組成物。
(項5)
前記多糖フラクションが、アラビナン、ガラクタンおよび/またはマンナンを含む、上記項4に記載の硬化性結合剤組成物。
(項6)
前記多糖の含有量が、1~90重量%の間、好ましくは3~20重量%の間、または3~15重量%の間、または3~10重量%の間で変動する、上記項5に記載の硬化性結合剤組成物。
(項7)
前記多糖フラクションが、2~20、好ましくは2~15で変動する、異なる重合度の多糖のブレンドであり、平均重合度が、3~7の間、好ましくは3~5の間を含む、上記項4から6のいずれかに記載の硬化性結合剤組成物。
(項8)
当技術分野で公知のカップリング剤、染料、抗真菌剤、抗細菌剤、疎水物質および他の添加剤をさらに含む、前記上記項のいずれかに記載の硬化性結合剤組成物。
(項9)
ケイ素含有カップリング剤を、前記結合剤組成物中、固形分の重量に基づき、好ましくは約0.1~約1重量%の範囲で含む、上記項8に記載の硬化性結合剤組成物。
(項10)
上記項1から9のいずれかに記載の硬化性結合剤組成物によって、および/または上記項1から9のいずれかに記載の前記硬化性結合剤組成物の前記炭水化物成分と無機アンモニア塩との縮合から得られる反応生成物、または上記項1から9のいずれかに記載の水性硬化性結合剤組成物を硬化条件に供することにより得られた結合剤によって、一緒に結合された鉱物繊維、合成繊維または天然繊維、セルロース粒子もしくはシート材料を含む、物質のアセンブリ。
(項11)
繊維マットに組織化されて断熱製品に加工されるように一緒に結合された、例えばガラスウールまたは石綿に基づき70~99重量%の範囲の量で鉱物繊維を含む断熱製品である、上記項10に記載の物質のアセンブリ。
(項12)
電池用セパレーターにおいての、ルーフィング膜もしくは屋根板などのルーフ製品用の基材または他の膜としての使用のための、不織繊維ベール、例えばガラス繊維ベールである、上記項10に記載の物質のアセンブリ。
(項13)
結合粒子、例えば、砂粒子もしくはセルロース粒子、例えば、セルロース系繊維、おが屑、木材層もしくはシート、木材パルプ、およびファイバーボード、パーティクルボード、配向性ストランドボードもしくは合板を含む複合木材ボードを製造するために一般に使用される他の材料であり、結合剤含有量が、前記アセンブリの総重量に基づき、約5~30重量%、特に9~20重量%の範囲である、上記項10に記載の物質のアセンブリ。
(項14)
上記項10から13のいずれかに記載の物質のアセンブリの調製方法であって、(i)(a)少なくとも部分的にセルロース加水分解物の糖である炭水化物成分を提供するステップ、(ii)適量の(b)無機アンモニウム塩を提供するステップ、(iii)粒子状物、繊維状もしくはセルロース系粒子状材料、またはシート材料上に、(b)により架橋された(a)であり得る、(a)および(b)を含む水性組成物として、(a)および(b)を逐次的または同時に付与して、樹脂加工材料を生成するステップ、ならびに(v)得られた樹脂加工材料を硬化条件に供して、過剰な水を蒸発させるステップを含む、方法。
(項15)
硬化が、90~200℃の範囲、好ましくは140℃超、より好ましくは190℃未満、通常、160~180℃の間の温度で行われる、上記項14に記載の方法。
(項16)
炭水化物成分およびアンモニアとの無機酸の塩を含む硬化性結合剤組成物中の糖成分としてのセルロース加水分解物の糖の使用であって、前記硬化性結合剤組成物によって、ならびに/または前記硬化性結合剤組成物の前記炭水化物成分と無機アンモニア塩との縮合および/もしくは硬化から得られる反応生成物によって、一緒に結合された鉱物繊維、合成繊維もしくは天然繊維、セルロース粒子、またはシート材料を含む物質のアセンブリの乾燥および/または湿潤強度を改善するための、使用。
It was further found that the dry binding strength of the binder compositions of the present invention was significantly improved compared to standard glucose-based binder compositions having the same total sugar content in both compositions. rice field.
According to a preferred embodiment of the invention, for example, the following are provided.
(Item 1)
A curable binder composition comprising a carbohydrate component and a salt of an inorganic acid with ammonia, wherein the carbohydrate component is a cellulose hydrolyzate containing at least partially dextrose and xylose-containing monosaccharides, disaccharides and polysaccharides. A curable binder composition that is a sugar.
(Item 2)
Item 2. The curable binder composition according to Item 1, wherein the sugar of the cellulose hydrolyzate constitutes 10 to 100% by weight of the sugar component.
(Item 3)
The composition is aqueous, 5 to 95% by weight, preferably 8 to 90% by weight, more preferably 10 to 85% by weight, more particularly totally aqueous, based on the weight of the total aqueous binder composition. Based on the weight of the binder composition, the composition is in the range of 5-25% by weight, preferably 8-20% by weight, more preferably 10-20% by weight, or even 12-18% by weight, or the total aqueous binder composition. Item 1 or 2 above, which comprises a solid content in the range of 50-95% by weight, preferably 50-90% by weight, more preferably 55-85% by weight, or even 60-80% by weight, based on the weight of the object. The curable binder composition according to.
(Item 4)
The carbohydrate component comprises 1-95% by weight glucose and 0.5-15% by weight xylose, preferably 1-10% by weight xylose, the rest of which is fructose, mannose, galactose and / or polysaccharide fraction. The curable binder composition according to any one of the above items.
(Item 5)
Item 4. The curable binder composition according to Item 4, wherein the polysaccharide fraction comprises arabinane, galactan and / or mannan.
(Item 6)
Item 5 above, wherein the content of the polysaccharide varies between 1 and 90% by weight, preferably between 3 and 20% by weight, or between 3 and 15% by weight, or between 3 and 10% by weight. The curable binder composition according to the above.
(Item 7)
The polysaccharide fraction is a blend of polysaccharides having different degrees of polymerization, varying from 2 to 20, preferably from 2 to 15, with an average degree of polymerization of between 3 and 7, preferably between 3 and 5. Item 6. The curable binder composition according to any one of Items 4 to 6.
(Item 8)
The curable binder composition according to any one of the above items, further comprising a coupling agent, a dye, an antifungal agent, an antibacterial agent, a hydrophobic substance and other additives known in the art.
(Item 9)
Item 2. The curable binder composition according to Item 8, wherein the silicon-containing coupling agent is contained in the binder composition in the range of preferably about 0.1 to about 1% by weight based on the weight of the solid content.
(Item 10)
By the curable binder composition according to any one of Items 1 to 9 and / or the carbohydrate component of the curable binder composition according to any one of Items 1 to 9 and an inorganic ammonia salt. Synthetic fibers bonded together by a reaction product obtained from condensation or a binder obtained by subjecting the aqueous curable binder composition according to any one of Items 1 to 9 to curing conditions. Assembly of materials, including fibers or natural fibers, cellulose particles or sheet materials.
(Item 11)
Item 10. Assembly of materials described in.
(Item 12)
Item 10. The material according to item 10 above, which is a non-woven fiber veil, for example a glass fiber veil, for use as a substrate or other film for roofing products such as roofing films or roofing plates in battery separators. assembly.
(Item 13)
To produce composite wood boards including bound particles such as sand or cellulosic particles such as cellulosic fibers, shavings, wood layers or sheets, wood pulp, and fiberboard, particle board, oriented strand board or plywood. Item 2. The material according to item 10 above, which is another commonly used material and has a binder content in the range of about 5-30% by weight, particularly 9-20% by weight, based on the total weight of the assembly. assembly.
(Item 14)
Item 4. The method for preparing an assembly of a substance according to any one of Items 10 to 13, wherein (i) (a) a step of providing a carbohydrate component which is a sugar of a cellulose hydrolyzate at least partially, (ii) an appropriate amount. (B) The step of providing the inorganic ammonium salt, (iii) may be (a) crosslinked by (b) on a particulate, fibrous or cellulosic particulate material, or sheet material. ) And (b) as an aqueous composition containing (a) and (b) sequentially or simultaneously to produce a resin-processed material, and (v) the obtained resin-processed material as curing conditions. A method comprising the steps of providing and evaporating excess water.
(Item 15)
Item 12. The method according to Item 14, wherein the curing is carried out at a temperature in the range of 90 to 200 ° C., preferably more than 140 ° C., more preferably less than 190 ° C., usually between 160 and 180 ° C.
(Item 16)
Use of cellulose hydrolyzate sugar as a sugar component in a curable binder composition comprising a carbohydrate component and a salt of an inorganic acid with ammonia, by and / or said cure. Includes mineral fibers, synthetic or natural fibers, cellulose particles, or sheet materials bonded together by the reaction product obtained from the condensation and / or curing of the carbohydrate component of the sex binder composition with an inorganic ammonia salt. Use to improve the drying and / or wet strength of material assemblies.

Claims (18)

炭水化物成分およびアンモニアとの無機酸の塩を含む硬化性結合剤組成物であって、前記炭水化物成分が、キストロースおよびキシロースを含む単糖ならびに多糖を含むセルロース加水分解物の糖であるか、またはデキストロースおよびキシロースを含む単糖、ならびに多糖を含むセルロース加水分解物の糖を含む、硬化性結合剤組成物。 A curable binder composition comprising a carbohydrate component and a salt of an inorganic acid with ammonia, wherein the carbohydrate component is a sugar of a monosaccharide containing dextrose and xylose , and a sugar of a cellulose hydrolyzate containing a polysaccharide . Alternatively, a curable binder composition comprising a simple sugar containing dextrose and xylose, and a sugar of a cellulose hydrolyzate containing a polysaccharide . 前記セルロース加水分解物の糖が、前記炭水化物成分の10~100重量%を構成する、請求項1に記載の硬化性結合剤組成物。 The curable binder composition according to claim 1, wherein the sugar of the cellulose hydrolyzate constitutes 10 to 100% by weight of the carbohydrate component. 前記組成物が水性であり、全水性結合剤組成物の重量に基づき、5~95重量%、好ましくは8~90重量%、より好ましくは10~85重量%の、より詳細には、全水性結合剤組成物の重量に基づき、5~25重量%、好ましくは8~20重量%、より好ましくは10~20重量%、もしくはさらには12~18重量%の範囲の、または全水性結合剤組成物の重量に基づき、50~95重量%、好ましくは50~90重量%、より好ましくは55~85重量%、もしくはさらには60~80重量%の範囲の固形分を含む、請求項1または2に記載の硬化性結合剤組成物。 The composition is aqueous, 5 to 95% by weight, preferably 8 to 90% by weight, more preferably 10 to 85% by weight, more particularly totally aqueous, based on the weight of the total aqueous binder composition. Based on the weight of the binder composition, the composition is in the range of 5-25% by weight, preferably 8-20% by weight, more preferably 10-20% by weight, or even 12-18% by weight, or the total aqueous binder composition. Claim 1 or 2 comprising a solid content in the range of 50-95% by weight, preferably 50-90% by weight, more preferably 55-85% by weight, or even 60-80% by weight, based on the weight of the object. The curable binder composition according to. 前記炭水化物成分が、1~95重量%のグルコースおよび0.5~15重量%のキシロース、好ましくは1~10重量%のキシロースを含み、その残りが、フルクトース、マンノース、ガラクトースおよび/または多糖フラクションである、求項1~3のいずれかに記載の硬化性結合剤組成物。 The carbohydrate component comprises 1-95% by weight glucose and 0.5-15% by weight xylose, preferably 1-10% by weight xylose, the rest of which is fructose, mannose, galactose and / or polysaccharide fraction. The curable binder composition according to any one of claims 1 to 3 . 前記多糖フラクションが、アラビナン、ガラクタンおよび/またはマンナンを含む、請求項4に記載の硬化性結合剤組成物。 The curable binder composition according to claim 4, wherein the polysaccharide fraction comprises arabinane, galactan and / or mannan. 前記多糖の含有量が、1~90重量%の間、好ましくは3~20重量%の間、または3~15重量%の間、または3~10重量%の間で変動する、請求項5に記載の硬化性結合剤組成物。 5. The content of the polysaccharide varies between 1 and 90% by weight, preferably between 3 and 20% by weight, or between 3 and 15% by weight, or between 3 and 10% by weight, claim 5. The curable binder composition according to the above. 前記多糖フラクションが、2~20、好ましくは2~15で変動する、異なる重合度の多糖のブレンドであり、平均重合度が、3~7の間、好ましくは3~5の間を含む、請求項4から6のいずれかに記載の硬化性結合剤組成物。 Claimed to be a blend of polysaccharides having different degrees of polymerization, wherein the polysaccharide fraction varies from 2 to 20, preferably from 2 to 15, with an average degree of polymerization between 3 and 7, preferably between 3 and 5. Item 6. The curable binder composition according to any one of Items 4 to 6. 当技術分野で公知のカップリング剤、染料、抗真菌剤、抗細菌剤、疎水物質および他の添加剤をさらに含む、求項1~7のいずれかに記載の硬化性結合剤組成物。 The curable binder composition according to any one of claims 1 to 7 , further comprising a coupling agent, a dye, an antifungal agent, an antibacterial agent, a hydrophobic substance and other additives known in the art. ケイ素含有カップリング剤を、前記結合剤組成物中、固形分の重量に基づき、好ましくは約0.1~約1重量%の範囲で含む、請求項8に記載の硬化性結合剤組成物。 The curable binder composition according to claim 8, wherein the silicon-containing coupling agent is contained in the binder composition in the range of preferably about 0.1 to about 1% by weight based on the weight of the solid content. 請求項1から9のいずれかに記載の硬化性結合剤組成物によって、および/または請求項1から9のいずれかに記載の前記硬化性結合剤組成物の前記炭水化物成分と無機アンモニア塩との縮合から得られる反応生成物、または請求項1から9のいずれかに記載の水性硬化性結合剤組成物を硬化条件に供することにより得られた結合剤によって、一緒に結合された鉱物繊維、合成繊維または天然繊維、セルロース粒子もしくはシート材料を含む、物質のアセンブリ。 By the curable binder composition according to any one of claims 1 to 9, and / or the carbohydrate component of the curable binder composition according to any one of claims 1 to 9 and an inorganic ammonia salt. Synthetic fibers bonded together by a reaction product obtained from condensation or a binder obtained by subjecting the aqueous curable binder composition according to any one of claims 1 to 9 to curing conditions. Assembly of materials, including fibers or natural fibers, cellulose particles or sheet materials. 繊維マットに組織化されて断熱製品に加工されるように一緒に結合された、例えばガラスウールまたは石綿に基づき70~99重量%の範囲の量で鉱物繊維を含む断熱製品である、請求項10に記載の物質のアセンブリ。 10. A heat insulating product containing mineral fibers in an amount in the range of 70-99% by weight based on, for example, glass wool or asbestos, which is organized into a fiber mat and bonded together so as to be processed into a heat insulating product. Assembly of materials described in. 不織繊維ベール、例えばガラス繊維ベールである請求項10に記載の物質のアセンブリであって、ここで、前記不織繊維ベールが、
(a)電池用セパレーターにおいて、
(b)ルーフィング膜もしくは屋根板などのルーフ製品の基材として、または
(c)他の膜として
使用のためのものである、質のアセンブリ。
The assembly of the material of claim 10, which is a non-woven fiber veil, eg, a glass fiber veil, wherein the non-woven fiber veil is:
(A) In the battery separator
(B) As a base material for roofing products such as roofing membranes or roofing boards , or
(C) As another membrane
Assembly of material , which is for use in.
結合粒子おが屑、木材層、木材シート、または木材パルプである請求項10に記載の物質のアセンブリであって、結合剤含有量が、前記アセンブリの総重量に基づき、約5~30重量%、特に9~20重量%の範囲である、質のアセンブリ。 An assembly of the material of claim 10, which is bound particles , sawdust, wood layers , wood sheets, or wood pulp, wherein the binder content is about 5-30% by weight based on the total weight of the assembly. Assembly of material , especially in the range of 9-20% by weight. 前記結合粒子が、砂粒子もしくはセルロース粒子である、請求項13に記載の物質のアセンブリ。 13. The assembly of a substance according to claim 13, wherein the bound particles are sand particles or cellulose particles. 前記セルロース粒子が、セルロース系繊維である、請求項13に記載の物質のアセンブリ。 The assembly of the substance according to claim 13, wherein the cellulosic particles are cellulosic fibers. 請求項10から1のいずれかに記載の物質のアセンブリの調製方法であって、(i)(a)ルロース加水分解物の糖であるかまたはセルロース加水分解物の糖を含む炭水化物成分を提供するステップ、(ii)適量の(b)無機アンモニウム塩を提供するステップ、(iii)粒子状物、繊維状もしくはセルロース系粒子状材料、またはシート材料上に、(b)により架橋された(a)であり得る、(a)および(b)を含む水性組成物として、(a)および(b)を逐次的または同時に付与して、樹脂加工材料を生成するステップ、ならびに(v)得られた樹脂加工材料を硬化条件に供して、過剰な水を蒸発させるステップを含む、方法。 The method for preparing an assembly of a substance according to any one of claims 10 to 15 , wherein (i) (a) a sugar of a cellulose hydrolyzate or a carbohydrate component containing a sugar of a cellulose hydrolyzate is used. A step of providing, (ii) a step of providing an appropriate amount of (b) an inorganic ammonium salt, (iii) crosslinked by (b) on a particulate, fibrous or cellulosic particulate material, or sheet material (b). A step of sequentially or simultaneously imparting (a) and (b) as an aqueous composition comprising (a) and (b), which may be a), to produce a resin processed material, and (v) obtained. A method comprising subjecting a processed resin material to a curing condition to evaporate excess water. 硬化が、90~200℃の範囲、好ましくは140℃超、より好ましくは190℃未満、通常、160~180℃の間の温度で行われる、請求項1に記載の方法。 The method according to claim 16 , wherein the curing is carried out at a temperature in the range of 90 to 200 ° C., preferably more than 140 ° C., more preferably less than 190 ° C., usually between 160 and 180 ° C. 炭水化物成分およびアンモニアとの無機酸の塩を含む硬化性結合剤組成物中の糖成分としてのセルロース加水分解物の糖の使用であって、ここで、前記セルロース加水分解物の糖が、デキストロースおよびキシロースを含む単糖、ならびに多糖を含み、
前記硬化性結合剤組成物によって、ならびに/または前記硬化性結合剤組成物の前記炭水化物成分と無機アンモニア塩との縮合および/もしくは硬化から得られる反応生成物によって、一緒に結合された鉱物繊維、合成繊維もしくは天然繊維、セルロース粒子、またはシート材料を含む物質のアセンブリの乾燥および/または湿潤強度を改善するための、使用。
The use of the sugar of a cellulose hydrolyzate as a sugar component in a curable binder composition comprising a carbohydrate component and a salt of an inorganic acid with ammonia , wherein the sugar of the cellulose hydrolyzate is dextrose and. Contains monosaccharides, including xylose, as well as polysaccharides,
Mineral fibers bonded together by the curable binder composition and / or by the reaction product obtained from the condensation and / or curing of the carbohydrate component of the curable binder composition with an inorganic ammonia salt. Use to improve the drying and / or wet strength of an assembly of materials containing synthetic or natural fibers, cellulose particles, or sheet materials.
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