JPH11116622A - 硫黄変性クロロプレン重合体の製造方法 - Google Patents
硫黄変性クロロプレン重合体の製造方法Info
- Publication number
- JPH11116622A JPH11116622A JP29645797A JP29645797A JPH11116622A JP H11116622 A JPH11116622 A JP H11116622A JP 29645797 A JP29645797 A JP 29645797A JP 29645797 A JP29645797 A JP 29645797A JP H11116622 A JPH11116622 A JP H11116622A
- Authority
- JP
- Japan
- Prior art keywords
- weight
- sulfur
- polymerization
- disulfide
- butadiene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- YACLQRRMGMJLJV-UHFFFAOYSA-N chloroprene Chemical class ClC(=C)C=C YACLQRRMGMJLJV-UHFFFAOYSA-N 0.000 title claims abstract description 36
- 229920000642 polymer Polymers 0.000 title claims abstract description 35
- 238000004519 manufacturing process Methods 0.000 title claims description 10
- 238000006116 polymerization reaction Methods 0.000 claims abstract description 26
- 239000000178 monomer Substances 0.000 claims abstract description 20
- BWGNESOTFCXPMA-UHFFFAOYSA-N Dihydrogen disulfide Chemical compound SS BWGNESOTFCXPMA-UHFFFAOYSA-N 0.000 claims abstract description 18
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 18
- 229910052717 sulfur Inorganic materials 0.000 claims abstract description 14
- 239000011593 sulfur Substances 0.000 claims abstract description 14
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 7
- 238000000034 method Methods 0.000 claims description 12
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims description 7
- 125000004432 carbon atom Chemical group C* 0.000 claims description 5
- BTXXTMOWISPQSJ-UHFFFAOYSA-N 4,4,4-trifluorobutan-2-one Chemical compound CC(=O)CC(F)(F)F BTXXTMOWISPQSJ-UHFFFAOYSA-N 0.000 claims description 4
- BQACOLQNOUYJCE-FYZZASKESA-N Abietic acid Natural products CC(C)C1=CC2=CC[C@]3(C)[C@](C)(CCC[C@@]3(C)C(=O)O)[C@H]2CC1 BQACOLQNOUYJCE-FYZZASKESA-N 0.000 claims description 4
- 239000000344 soap Substances 0.000 claims description 4
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 claims description 3
- 239000003995 emulsifying agent Substances 0.000 claims description 3
- 238000007720 emulsion polymerization reaction Methods 0.000 claims description 3
- 230000014509 gene expression Effects 0.000 claims description 3
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 claims description 3
- 238000005299 abrasion Methods 0.000 abstract description 16
- 238000011191 terminal modification Methods 0.000 abstract description 4
- 238000007334 copolymerization reaction Methods 0.000 abstract description 3
- CSNJTIWCTNEOSW-UHFFFAOYSA-N carbamothioylsulfanyl carbamodithioate Chemical compound NC(=S)SSC(N)=S CSNJTIWCTNEOSW-UHFFFAOYSA-N 0.000 abstract 1
- 239000000853 adhesive Substances 0.000 description 15
- 230000001070 adhesive effect Effects 0.000 description 15
- AUZONCFQVSMFAP-UHFFFAOYSA-N disulfiram Chemical compound CCN(CC)C(=S)SSC(=S)N(CC)CC AUZONCFQVSMFAP-UHFFFAOYSA-N 0.000 description 8
- 239000004014 plasticizer Substances 0.000 description 8
- 238000004073 vulcanization Methods 0.000 description 8
- 239000004636 vulcanized rubber Substances 0.000 description 8
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- RSWGJHLUYNHPMX-ONCXSQPRSA-N abietic acid Chemical compound C([C@@H]12)CC(C(C)C)=CC1=CC[C@@H]1[C@]2(C)CCC[C@@]1(C)C(O)=O RSWGJHLUYNHPMX-ONCXSQPRSA-N 0.000 description 6
- 238000012360 testing method Methods 0.000 description 5
- 238000005452 bending Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 238000004458 analytical method Methods 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 238000007796 conventional method Methods 0.000 description 3
- 239000000839 emulsion Substances 0.000 description 3
- 238000011156 evaluation Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- WJFKNYWRSNBZNX-UHFFFAOYSA-N 10H-phenothiazine Chemical compound C1=CC=C2NC3=CC=CC=C3SC2=C1 WJFKNYWRSNBZNX-UHFFFAOYSA-N 0.000 description 2
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- -1 ammonium persulfate Chemical class 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 150000002019 disulfides Chemical class 0.000 description 2
- 230000001804 emulsifying effect Effects 0.000 description 2
- 238000010556 emulsion polymerization method Methods 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229950000688 phenothiazine Drugs 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 2
- 159000000000 sodium salts Chemical class 0.000 description 2
- 230000000007 visual effect Effects 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- PCPYTNCQOSFKGG-ONEGZZNKSA-N (1e)-1-chlorobuta-1,3-diene Chemical compound Cl\C=C\C=C PCPYTNCQOSFKGG-ONEGZZNKSA-N 0.000 description 1
- LIFLRQVHKGGNSG-UHFFFAOYSA-N 2,3-dichlorobuta-1,3-diene Chemical compound ClC(=C)C(Cl)=C LIFLRQVHKGGNSG-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- YFHKLSPMRRWLKI-UHFFFAOYSA-N 2-tert-butyl-4-(3-tert-butyl-4-hydroxy-5-methylphenyl)sulfanyl-6-methylphenol Chemical compound CC(C)(C)C1=C(O)C(C)=CC(SC=2C=C(C(O)=C(C)C=2)C(C)(C)C)=C1 YFHKLSPMRRWLKI-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- 239000004342 Benzoyl peroxide Substances 0.000 description 1
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
- 229920001174 Diethylhydroxylamine Polymers 0.000 description 1
- FVIGODVHAVLZOO-UHFFFAOYSA-N Dixanthogen Chemical compound CCOC(=S)SSC(=S)OCC FVIGODVHAVLZOO-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- 244000137852 Petrea volubilis Species 0.000 description 1
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium peroxydisulfate Substances [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 1
- VAZSKTXWXKYQJF-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)OOS([O-])=O VAZSKTXWXKYQJF-UHFFFAOYSA-N 0.000 description 1
- 229910001870 ammonium persulfate Inorganic materials 0.000 description 1
- 235000019400 benzoyl peroxide Nutrition 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- PGAXJQVAHDTGBB-UHFFFAOYSA-N dibutylcarbamothioylsulfanyl n,n-dibutylcarbamodithioate Chemical compound CCCCN(CCCC)C(=S)SSC(=S)N(CCCC)CCCC PGAXJQVAHDTGBB-UHFFFAOYSA-N 0.000 description 1
- FVCOIAYSJZGECG-UHFFFAOYSA-N diethylhydroxylamine Chemical compound CCN(O)CC FVCOIAYSJZGECG-UHFFFAOYSA-N 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 229960002377 dixanthogen Drugs 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- WSFSSNUMVMOOMR-UHFFFAOYSA-N formaldehyde Natural products O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 1
- NVVZQXQBYZPMLJ-UHFFFAOYSA-N formaldehyde;naphthalene-1-sulfonic acid Chemical compound O=C.C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 NVVZQXQBYZPMLJ-UHFFFAOYSA-N 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 230000020169 heat generation Effects 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000013011 mating Effects 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000000691 measurement method Methods 0.000 description 1
- 239000008267 milk Substances 0.000 description 1
- 210000004080 milk Anatomy 0.000 description 1
- 235000013336 milk Nutrition 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- KVBGVZZKJNLNJU-UHFFFAOYSA-N naphthalene-2-sulfonic acid Chemical compound C1=CC=CC2=CC(S(=O)(=O)O)=CC=C21 KVBGVZZKJNLNJU-UHFFFAOYSA-N 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- ZWWQICJTBOCQLA-UHFFFAOYSA-N o-propan-2-yl (propan-2-yloxycarbothioyldisulfanyl)methanethioate Chemical compound CC(C)OC(=S)SSC(=S)OC(C)C ZWWQICJTBOCQLA-UHFFFAOYSA-N 0.000 description 1
- NWVVVBRKAWDGAB-UHFFFAOYSA-N p-methoxyphenol Chemical compound COC1=CC=C(O)C=C1 NWVVVBRKAWDGAB-UHFFFAOYSA-N 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 239000003505 polymerization initiator Substances 0.000 description 1
- 159000000001 potassium salts Chemical class 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000004445 quantitative analysis Methods 0.000 description 1
- 239000007870 radical polymerization initiator Substances 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 1
- 229910052979 sodium sulfide Inorganic materials 0.000 description 1
- GRVFOGOEDUUMBP-UHFFFAOYSA-N sodium sulfide (anhydrous) Chemical compound [Na+].[Na+].[S-2] GRVFOGOEDUUMBP-UHFFFAOYSA-N 0.000 description 1
- HUMLQUKVJARKRN-UHFFFAOYSA-M sodium;n,n-dibutylcarbamodithioate Chemical compound [Na+].CCCCN(C([S-])=S)CCCC HUMLQUKVJARKRN-UHFFFAOYSA-M 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 238000009864 tensile test Methods 0.000 description 1
- KUAZQDVKQLNFPE-UHFFFAOYSA-N thiram Chemical compound CN(C)C(=S)SSC(=S)N(C)C KUAZQDVKQLNFPE-UHFFFAOYSA-N 0.000 description 1
- 229960002447 thiram Drugs 0.000 description 1
- 238000004448 titration Methods 0.000 description 1
Landscapes
- Polymerisation Methods In General (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP29645797A JPH11116622A (ja) | 1997-10-15 | 1997-10-15 | 硫黄変性クロロプレン重合体の製造方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP29645797A JPH11116622A (ja) | 1997-10-15 | 1997-10-15 | 硫黄変性クロロプレン重合体の製造方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH11116622A true JPH11116622A (ja) | 1999-04-27 |
| JPH11116622A5 JPH11116622A5 (enrdf_load_stackoverflow) | 2005-06-30 |
Family
ID=17833807
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP29645797A Pending JPH11116622A (ja) | 1997-10-15 | 1997-10-15 | 硫黄変性クロロプレン重合体の製造方法 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH11116622A (enrdf_load_stackoverflow) |
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2001131234A (ja) * | 1999-11-01 | 2001-05-15 | Tosoh Corp | 高弾性硫黄変性クロロプレンゴム |
| JP2009197127A (ja) * | 2008-02-21 | 2009-09-03 | Denki Kagaku Kogyo Kk | クロロプレンゴム組成物及び該クロロプレン組成物からなるクロロプレンゴム成形体。 |
| JP2009275124A (ja) * | 2008-05-15 | 2009-11-26 | Denki Kagaku Kogyo Kk | 硫黄変性クロロプレン重合体の製造方法 |
| JP2010100863A (ja) * | 2010-02-12 | 2010-05-06 | Tosoh Corp | 高弾性硫黄変性クロロプレンゴムの製造方法 |
| WO2012070347A1 (ja) * | 2010-11-26 | 2012-05-31 | 電気化学工業株式会社 | 硫黄変性クロロプレンゴム及びその成形体、並びにその製造方法 |
| WO2013105370A1 (ja) * | 2012-01-13 | 2013-07-18 | 電気化学工業株式会社 | 硫黄変性クロロプレンゴム及びその製造方法、並びに成形体 |
| WO2014077236A1 (ja) * | 2012-11-16 | 2014-05-22 | 東ソー株式会社 | キサントゲン変性クロロプレンゴム及びその製造方法 |
| WO2015080075A1 (ja) * | 2013-11-26 | 2015-06-04 | 電気化学工業株式会社 | 硫黄変性ポリクロロプレン |
| JP2015110687A (ja) * | 2012-11-16 | 2015-06-18 | 東ソー株式会社 | キサントゲン変性クロロプレンゴム及びその製造方法 |
| JP2015218225A (ja) * | 2014-05-15 | 2015-12-07 | 東ソー株式会社 | キサントゲン変性クロロプレンゴム及びその製造方法 |
| WO2020137297A1 (ja) * | 2018-12-27 | 2020-07-02 | 昭和電工株式会社 | クロロプレン重合体ラテックス及びその製造方法 |
| JP2021169544A (ja) * | 2020-04-14 | 2021-10-28 | デンカ株式会社 | ゴム組成物、該ゴム組成物の加硫物及び加硫成形体 |
| WO2022130737A1 (ja) * | 2020-12-16 | 2022-06-23 | デンカ株式会社 | クロロプレン重合体組成物、浸漬成形体及びこれらの製造方法 |
-
1997
- 1997-10-15 JP JP29645797A patent/JPH11116622A/ja active Pending
Cited By (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2001131234A (ja) * | 1999-11-01 | 2001-05-15 | Tosoh Corp | 高弾性硫黄変性クロロプレンゴム |
| JP2009197127A (ja) * | 2008-02-21 | 2009-09-03 | Denki Kagaku Kogyo Kk | クロロプレンゴム組成物及び該クロロプレン組成物からなるクロロプレンゴム成形体。 |
| JP2009275124A (ja) * | 2008-05-15 | 2009-11-26 | Denki Kagaku Kogyo Kk | 硫黄変性クロロプレン重合体の製造方法 |
| JP2010100863A (ja) * | 2010-02-12 | 2010-05-06 | Tosoh Corp | 高弾性硫黄変性クロロプレンゴムの製造方法 |
| WO2012070347A1 (ja) * | 2010-11-26 | 2012-05-31 | 電気化学工業株式会社 | 硫黄変性クロロプレンゴム及びその成形体、並びにその製造方法 |
| CN103228679A (zh) * | 2010-11-26 | 2013-07-31 | 电气化学工业株式会社 | 硫改质氯丁二烯橡胶及其成型体和其制备方法 |
| US9328175B2 (en) | 2010-11-26 | 2016-05-03 | Denka Company Limited | Sulfur-modified chloroprene rubber, molding thereof, and production method therefore |
| JP5843266B2 (ja) * | 2010-11-26 | 2016-01-13 | デンカ株式会社 | 硫黄変性クロロプレンゴム及びその成形体、並びにその製造方法 |
| WO2013105370A1 (ja) * | 2012-01-13 | 2013-07-18 | 電気化学工業株式会社 | 硫黄変性クロロプレンゴム及びその製造方法、並びに成形体 |
| JP2013144748A (ja) * | 2012-01-13 | 2013-07-25 | Denki Kagaku Kogyo Kk | 硫黄変性クロロプレンゴム及びその製造方法、並びに成形体 |
| CN104053678A (zh) * | 2012-01-13 | 2014-09-17 | 电气化学工业株式会社 | 硫改性氯丁二烯橡胶及其制备方法和成型体 |
| CN104797606A (zh) * | 2012-11-16 | 2015-07-22 | 东曹株式会社 | 黄原改性氯丁二烯橡胶及其制造方法 |
| JP2015110687A (ja) * | 2012-11-16 | 2015-06-18 | 東ソー株式会社 | キサントゲン変性クロロプレンゴム及びその製造方法 |
| WO2014077236A1 (ja) * | 2012-11-16 | 2014-05-22 | 東ソー株式会社 | キサントゲン変性クロロプレンゴム及びその製造方法 |
| WO2015080075A1 (ja) * | 2013-11-26 | 2015-06-04 | 電気化学工業株式会社 | 硫黄変性ポリクロロプレン |
| KR20160090821A (ko) * | 2013-11-26 | 2016-08-01 | 덴카 주식회사 | 황 변성 폴리클로로프렌 |
| JP2015218225A (ja) * | 2014-05-15 | 2015-12-07 | 東ソー株式会社 | キサントゲン変性クロロプレンゴム及びその製造方法 |
| WO2020137297A1 (ja) * | 2018-12-27 | 2020-07-02 | 昭和電工株式会社 | クロロプレン重合体ラテックス及びその製造方法 |
| CN113227231A (zh) * | 2018-12-27 | 2021-08-06 | 昭和电工株式会社 | 氯丁二烯聚合物胶乳及其制造方法 |
| JPWO2020137297A1 (ja) * | 2018-12-27 | 2021-11-11 | 昭和電工株式会社 | クロロプレン重合体ラテックス及びその製造方法 |
| EP3904441A4 (en) * | 2018-12-27 | 2022-09-28 | Showa Denko K.K. | CHLOROPRENE POLYMER LATEX AND METHOD FOR PRODUCTION |
| CN113227231B (zh) * | 2018-12-27 | 2023-04-18 | 昭和电工株式会社 | 氯丁二烯聚合物胶乳及其制造方法 |
| JP2021169544A (ja) * | 2020-04-14 | 2021-10-28 | デンカ株式会社 | ゴム組成物、該ゴム組成物の加硫物及び加硫成形体 |
| WO2022130737A1 (ja) * | 2020-12-16 | 2022-06-23 | デンカ株式会社 | クロロプレン重合体組成物、浸漬成形体及びこれらの製造方法 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP3445615B2 (ja) | 不飽和ニトリル−共役ジエン共重合体，その製造方法およびゴム組成物 | |
| JP7363975B2 (ja) | ゴム用組成物及びその用途 | |
| JP7192381B2 (ja) | ゴム組成物及びその製造方法 | |
| JPH11116622A (ja) | 硫黄変性クロロプレン重合体の製造方法 | |
| JP2007106994A (ja) | クロロプレン系重合体ラテックス及びその製造方法 | |
| JP3411127B2 (ja) | 硫黄変性クロロプレン重合体の製造方法 | |
| CN104053678A (zh) | 硫改性氯丁二烯橡胶及其制备方法和成型体 | |
| EP3904441B1 (en) | Chloroprene polymer latex and method for producing same | |
| JP4428209B2 (ja) | クロロプレンゴム及びその製造方法、並びにクロロプレンゴム組成物 | |
| WO2021079981A1 (ja) | クロロプレン共重合体ラテックス及びその製造方法 | |
| JP7293719B2 (ja) | ゴム発泡体、その製造方法及びその用途 | |
| JP4665273B2 (ja) | 高弾性硫黄変性クロロプレンゴム | |
| JP3858365B2 (ja) | 耐動的疲労性に優れたクロロプレンゴム組成物用クロロプレンゴム、クロロプレンゴム組成物及びそれを用いてなる自動車用ブーツ | |
| WO2012157658A1 (ja) | 硫黄変性クロロプレンゴム、成形体及び硫黄変性クロロプレンゴムの製造方法 | |
| JP5549856B2 (ja) | 高弾性硫黄変性クロロプレンゴムの製造方法 | |
| JP2009108195A (ja) | 加硫ゴム製造用クロロプレンポリマーラテックス組成物及びその製造方法 | |
| JPH08245841A (ja) | 振動減衰材用クロロプレンゴム組成物及び振動減衰材用クロロプレンゴム成型加硫物 | |
| JP4281587B2 (ja) | クロロプレンゴムの製造方法 | |
| JPS6140241B2 (enrdf_load_stackoverflow) | ||
| JP2021080449A (ja) | ゴム組成物及びその製造方法 | |
| JP2002338745A (ja) | 高弾性硫黄変性クロロプレンゴム混合物 | |
| JP4273711B2 (ja) | 加工安定性に優れたクロロプレンゴム組成物 | |
| JPH08104717A (ja) | 共役ジエン重合ゴムまたは共役ジエン−芳香族ビニル化合物共重合ゴム、その製造方法および加硫性ゴム組成物 | |
| JP3484800B2 (ja) | クロロプレンゴム組成物及び振動減衰材用クロロプレンゴム組成物 | |
| JP2828715B2 (ja) | ゴムホース |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A711 | Notification of change in applicant |
Effective date: 20040928 Free format text: JAPANESE INTERMEDIATE CODE: A712 |
|
| A521 | Written amendment |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20041014 |
|
| A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20041014 |
|
| A521 | Written amendment |
Effective date: 20040930 Free format text: JAPANESE INTERMEDIATE CODE: A821 |
|
| A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20060417 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20060425 |
|
| A02 | Decision of refusal |
Effective date: 20060822 Free format text: JAPANESE INTERMEDIATE CODE: A02 |