JPH0667475B2 - 酸化エチレン用銀含有触媒の製造方法 - Google Patents
酸化エチレン用銀含有触媒の製造方法Info
- Publication number
- JPH0667475B2 JPH0667475B2 JP1024136A JP2413689A JPH0667475B2 JP H0667475 B2 JPH0667475 B2 JP H0667475B2 JP 1024136 A JP1024136 A JP 1024136A JP 2413689 A JP2413689 A JP 2413689A JP H0667475 B2 JPH0667475 B2 JP H0667475B2
- Authority
- JP
- Japan
- Prior art keywords
- alumina
- silver
- catalyst
- carrier
- ethylene oxide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D301/00—Preparation of oxiranes
- C07D301/02—Synthesis of the oxirane ring
- C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
- C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
- C07D301/08—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
- C07D301/10—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase with catalysts containing silver or gold
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/48—Silver or gold
- B01J23/50—Silver
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/66—Silver or gold
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
- B01J37/0018—Addition of a binding agent or of material, later completely removed among others as result of heat treatment, leaching or washing,(e.g. forming of pores; protective layer, desintegrating by heat)
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Catalysts (AREA)
- Epoxy Compounds (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN88100400A CN1009437B (zh) | 1988-02-03 | 1988-02-03 | 乙烯氧化制环氧乙烷高效银催化剂 |
CN88100400.6 | 1988-02-03 |
Publications (2)
Publication Number | Publication Date |
---|---|
JPH0256246A JPH0256246A (ja) | 1990-02-26 |
JPH0667475B2 true JPH0667475B2 (ja) | 1994-08-31 |
Family
ID=4831321
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP1024136A Expired - Lifetime JPH0667475B2 (ja) | 1988-02-03 | 1989-02-03 | 酸化エチレン用銀含有触媒の製造方法 |
Country Status (6)
Families Citing this family (71)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE59003342D1 (de) * | 1989-11-09 | 1993-12-09 | Huels Chemische Werke Ag | Silberkatalysator für die Oxidation von Ethylen und Verfahren zu seiner Herstellung. |
US5173469A (en) * | 1989-11-09 | 1992-12-22 | Huels Aktiengesellschaft | Silver catalyst suitable for oxidation of ethylene and process for the production of the catalyst |
DE4106508A1 (de) * | 1991-03-01 | 1992-09-03 | Basf Ag | Silberkatalysator |
DE4311608A1 (de) * | 1993-04-08 | 1994-12-15 | Huels Chemische Werke Ag | Silberkatalysator zur Oxidation von Ethylen zu Ethylenoxid und Verfahren zur Herstellung von Ethylenoxid |
US5380697A (en) * | 1993-09-08 | 1995-01-10 | Shell Oil Company | Ethylene oxide catalyst and process |
DE69600628T2 (de) * | 1995-02-01 | 1999-02-25 | Shell Internationale Research Maatschappij B.V., Den Haag/S'gravenhage | Alkylenoxidkatalysator und verfahren |
US5739075A (en) * | 1995-10-06 | 1998-04-14 | Shell Oil Company | Process for preparing ethylene oxide catalysts |
US5801259A (en) * | 1996-04-30 | 1998-09-01 | Shell Oil Company | Ethylene oxide catalyst and process |
AU754631B2 (en) * | 1998-11-17 | 2002-11-21 | Nippon Shokubai Co., Ltd. | Carrier for catalyst for use in production of ethylene oxide, catalyst for use in production of ethylene oxide, and method for production of ethylene oxide |
US6831037B2 (en) * | 2002-02-25 | 2004-12-14 | Saint-Gobain Norpro Corporation | Catalyst carriers |
BR0307958B1 (pt) * | 2002-02-25 | 2013-07-09 | catalisador de prata suportado, processo para preparação do mesmo, processo para epoxidação de uma olefina e método para produção de um 1,2-diol, um 1,2-diol éter ou uma alcanolamina | |
US6987080B2 (en) * | 2002-03-01 | 2006-01-17 | Scientific Design Company, Inc. | Ethylene oxide catalyst carrier preparation |
EP1532125B1 (en) * | 2002-06-28 | 2006-03-22 | Shell Internationale Researchmaatschappij B.V. | A method for the start-up of an epoxidation process, a catalyst and a process for the epoxidation of an olefin |
US20040224841A1 (en) | 2003-05-07 | 2004-11-11 | Marek Matusz | Silver-containing catalysts, the manufacture of such silver-containing catalysts, and the use thereof |
MX260863B (es) * | 2003-05-07 | 2008-09-26 | Shell Int Research | Catalizadores que contienen plata, su elaboracion y uso de los mismos. |
US8148555B2 (en) * | 2003-06-26 | 2012-04-03 | Shell Oil Company | Method for improving the selectivity of a catalyst and a process for the epoxidation of an olefin |
US20060293180A1 (en) * | 2003-08-22 | 2006-12-28 | Thorsteinson Erlind M | Modified alumina carriers and silver-based catalysts for the production of alkylene oxides |
RU2360735C2 (ru) | 2003-10-16 | 2009-07-10 | Дау Текнолоджи Инвестментс Ллс | Катализаторы для получения алкиленоксидов, имеющие улучшенную стабильность, эффективность и/или активность |
TW200600190A (en) | 2004-04-01 | 2006-01-01 | Shell Int Research | Process for preparing a silver catalyst, the catalyst, and use thereof in olefin oxidation |
BRPI0512172A (pt) * | 2004-06-18 | 2008-02-12 | Shell Int Research | processo para a produção de óxido de olefina, 1,2-diol, éter de 1,2-diol ou alcanolamina |
ATE554080T1 (de) | 2004-06-18 | 2012-05-15 | Shell Int Research | Verfahren zur herstellung eines olefinoxids, 1,2- diols, a 1,2-diolethers oder alkanolamins |
KR20070045316A (ko) * | 2004-08-12 | 2007-05-02 | 셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이 | 성형된 촉매의 제조방법, 성형된 촉매 및 이 촉매의 용도 |
US8536083B2 (en) * | 2004-09-01 | 2013-09-17 | Shell Oil Company | Olefin epoxidation process, a catalyst for use in the process, a carrier for use in preparing the catalyst, and a process for preparing the carrier |
WO2006028940A2 (en) * | 2004-09-01 | 2006-03-16 | Shell Internationale Research Maatschappij B.V. | An olefin epoxidation process, a catalyst for use in the process, a carrier for use in preparing the catalyst, and a process for preparing the carrier |
BRPI0515905A (pt) | 2004-09-24 | 2008-08-12 | Shell Int Research | processo para selecionar partìculas moldadas, um processo para instalar um sistema, um processo para reagir uma carga de alimentação gasosa em um tal sistema, um produto de programa de computação e um sistema de computação |
EP1850955A1 (en) * | 2005-02-21 | 2007-11-07 | Shell Internationale Researchmaatschappij B.V. | An olefin epoxidation process, a catalyst for use in the process, a carrier for use in making the catalyst, and a process for making the carrier |
US7507844B2 (en) * | 2005-05-09 | 2009-03-24 | Sd Lizenzverwertungsgesellschaft Mbh & Co. Kg | Nanometer scale restructuring of alumina carrier surface and catalysts for the production of alkene oxides |
RU2007149318A (ru) * | 2005-06-07 | 2009-07-20 | Шелл Интернэшнл Рисерч Маатсхаппий Б.В. (NL) | Кктализатор, способ приготовления катализатора и способ получения оксида олефина, 1, 2-диола, эфира 1, 2-диола или алканоламина |
MX2007015465A (es) | 2005-06-07 | 2008-02-25 | Saint Gobain Ceramics | Un portador catalizador y un procedimiento para preparar el portador catalizador. |
US8791280B2 (en) * | 2005-08-10 | 2014-07-29 | Sd Lizenzverwertungsgesellschaft Mbh & Co. Kg | Process for preparation of catalyst carrier and its use in catalyst preparation |
PL2046696T3 (pl) | 2006-07-21 | 2013-04-30 | Dow Global Technologies Llc | Ulepszony filtr cząstek stałych do silnika wysokoprężnego |
JP4267015B2 (ja) * | 2006-09-29 | 2009-05-27 | 株式会社日本触媒 | エチレンオキシド製造用触媒およびエチレンオキシドの製造方法 |
CN103101943B (zh) * | 2006-11-01 | 2015-10-07 | 陶氏环球技术公司 | α-氧化铝的成形多孔体及其制备方法 |
AR066468A1 (es) | 2007-05-09 | 2009-08-19 | Shell Int Research | Un catalizador de epoxidacion, un proceso para preparar el mismo, y un proceso para producir un oxido de olefina , un 1,2- diol, un 1,2 - diol eter, un 1,2- carbonato, o una alcanolamina |
US7507845B1 (en) * | 2007-08-27 | 2009-03-24 | Sd Lizenzverwertungsgesellschaft Mbh & Co Kg | Process for production of an olefin oxide |
US7714152B2 (en) * | 2007-08-30 | 2010-05-11 | Sd Lizenzverwertungsgesellschaft Mbh & Co. Kg | Carrier for olefin oxide catalyst |
WO2009119416A1 (ja) * | 2008-03-26 | 2009-10-01 | 株式会社日本触媒 | エチレンオキシド製造用触媒および該触媒を用いたエチレンオキシドの製造方法 |
BRPI0912381A2 (pt) * | 2008-05-07 | 2017-07-04 | Shell Int Research | processo para a partida de um processo de epoxidação, processo para a produção de óxido de etileno, 1,2-diol, 1, 2-diol éter, 1, 2-carbonato, ou uma alcanolamina |
BRPI0912391B1 (pt) | 2008-05-07 | 2018-04-17 | Shell Internationale Research Maatschappij B.V. | Processo para epoxidação de uma olefina |
BRPI0915854A2 (pt) * | 2008-07-14 | 2015-08-04 | Basf Se | Processo para preparar óxido de etileno |
JP5101428B2 (ja) * | 2008-08-05 | 2012-12-19 | 株式会社日本触媒 | エチレンオキシド製造用触媒の充填方法、エチレンオキシド製造用反応器およびエチレンオキシドの製造方法 |
SG194340A1 (en) * | 2009-04-21 | 2013-11-29 | Dow Technology Investments Llc | Epoxidation reactions and operating conditions thereof |
SG175762A1 (en) | 2009-04-21 | 2011-12-29 | Dow Technology Investments Llc | Methods for enhancing the efficiency of rhenium-promoted epoxidation catalysts and epoxidation methods utilizing these |
US8524927B2 (en) | 2009-07-13 | 2013-09-03 | Velocys, Inc. | Process for making ethylene oxide using microchannel process technology |
KR101786935B1 (ko) | 2009-12-28 | 2017-10-18 | 다우 테크놀로지 인베스트먼츠 엘엘씨. | 알킬렌 옥사이드의 제조시 은 촉매 상의 은 클로라이드의 생성을 제어하는 방법 |
CN102905782B (zh) | 2010-03-17 | 2015-04-08 | 陶氏技术投资有限责任公司 | 乙烯部分氧化生产环氧乙烷的固定床催化反应器 |
CN102397795B (zh) * | 2010-09-13 | 2014-03-19 | 中国石油化工股份有限公司 | 环氧乙烷生产用银催化剂的载体、其制备方法、由其制成的银催化剂及其应用 |
CN102441435B (zh) | 2010-09-30 | 2014-01-01 | 中国石油化工股份有限公司 | 制备银催化剂用氧化铝载体的方法、由此得到的载体及其应用 |
CN102463141B (zh) | 2010-11-02 | 2015-05-06 | 中国石油化工股份有限公司 | 一种氧化铝载体、其制备方法、由其制成的银催化剂及其应用 |
SG190714A1 (en) | 2010-12-10 | 2013-07-31 | Dow Technology Investments Llc | Method of reducing the value of an alkylene oxide production parameter in a process of making an alkylene oxide using a high efficiency catalyst |
CA2819233C (en) | 2010-12-15 | 2019-11-26 | Dow Technology Investments Llc | Method of starting-up a process of producing an alkylene oxide using a high-efficiency catalyst |
EP2715311B1 (en) | 2011-05-30 | 2023-03-15 | Dow Technology Investments LLC | Methods for testing structures, and selection methods using these |
EP2718009B1 (en) | 2011-06-06 | 2021-09-08 | Dow Technology Investments LLC | Methods for producing epoxidation catalysts |
CN107020094B (zh) | 2011-10-31 | 2019-10-11 | 陶氏技术投资有限责任公司 | 生产环氧化催化剂的方法和利用所述环氧化催化剂的环氧化方法 |
WO2013086081A1 (en) | 2011-12-09 | 2013-06-13 | Dow Technology Investments Llc | Method of maintaining the value of an alkylene oxide production parameter in a process of making an alkylene oxide using a high efficiency catalyst |
US9649621B2 (en) | 2011-12-19 | 2017-05-16 | Dow Technology Investments Llc | Method of formulating alkylene oxide catalyst in relation to catalyst reference properties |
US9468906B2 (en) | 2012-03-02 | 2016-10-18 | Basf Se | Porous inorganic body |
JP2015516929A (ja) * | 2012-03-02 | 2015-06-18 | ビーエーエスエフ ソシエタス・ヨーロピアBasf Se | 多孔性無機体 |
EP2830759A1 (en) | 2012-03-27 | 2015-02-04 | Dow Technology Investments LLC | Method of making a manganese containing supported silver catalyst intermediate |
CN103816941B (zh) * | 2012-11-19 | 2016-03-30 | 中国石油化工股份有限公司 | 一种α-氧化铝载体及其制备方法 |
WO2016196709A1 (en) | 2015-06-02 | 2016-12-08 | Scientific Design Company, Inc. | Porous bodies with enhanced pore architecture |
TWI772322B (zh) | 2016-09-02 | 2022-08-01 | 美商陶氏科技投資有限公司 | 製備環氧化催化劑之方法 |
EP3548471B1 (en) | 2016-12-02 | 2021-05-19 | Shell Internationale Research Maatschappij B.V. | Methods for conditioning an ethylene epoxidation catalyst and associated methods for the production of ethylene oxide |
US10449520B2 (en) | 2017-05-15 | 2019-10-22 | Scientific Design Company, Inc. | Porous bodies with enhanced crush strength |
CN109107553B (zh) * | 2017-06-23 | 2021-04-13 | 中国石油化工股份有限公司 | 氧化铝载体及其制备方法和银催化剂及应用 |
CN107902745B (zh) * | 2017-11-30 | 2021-08-17 | 浙江奇彩环境科技股份有限公司 | 一种垃圾渗滤液浓水的处理方法 |
CA3087028A1 (en) | 2017-12-28 | 2019-07-04 | Dow Technology Investments Llc | Process for preparing an epoxidation catalyst |
US10676401B2 (en) | 2018-04-23 | 2020-06-09 | Scientific Design Company, Inc. | Porous bodies with enhanced pore architecture prepared with oxalic acid |
CN112206798B (zh) * | 2020-10-29 | 2022-03-22 | 润和催化材料(浙江)有限公司 | 一种乙烯氧化制环氧乙烷的银催化剂及其制备方法和应用 |
CN115475609A (zh) * | 2021-06-15 | 2022-12-16 | 中国石油化工股份有限公司 | 一种具有高稳定性的α-氧化铝载体与银催化剂和烯烃环氧化方法 |
WO2025189084A1 (en) * | 2024-03-08 | 2025-09-12 | Scientific Design Llc | Methods of forming substantially all platelet alumina powders and alumina carriers |
Family Cites Families (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3172893A (en) * | 1964-08-27 | 1965-03-09 | Ethylene oxtoationximproved s silver catalyst | |
US4012425A (en) * | 1972-01-07 | 1977-03-15 | Shell Oil Company | Ethylene oxide process |
FR2179967B1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * | 1972-04-13 | 1978-03-03 | Norton Co | |
GB1465523A (en) * | 1973-01-26 | 1977-02-23 | Norton Co | Low surface area alumina |
US4066575A (en) * | 1976-07-26 | 1978-01-03 | Halcon International, Inc. | Process for the preparation of a supported silver catalyst |
FR2396588A1 (fr) * | 1977-07-08 | 1979-02-02 | Ugine Kuhlmann | Catalyseurs a base d'argent pour la production d'oxyde d'olefines |
US4379134A (en) * | 1981-02-13 | 1983-04-05 | Union Carbide Corporation | Process of preparing high purity alumina bodies |
US4575494A (en) * | 1984-02-08 | 1986-03-11 | The Dow Chemical Company | Alumina compositions useful as catalyst supports for ethylene oxidation |
EP0211521B1 (en) * | 1985-07-31 | 1990-03-21 | Imperial Chemical Industries Plc | Process of promoting catalysts for the production of alkylene oxides |
GB8611121D0 (en) * | 1986-05-07 | 1986-06-11 | Shell Int Research | Silver catalyst |
JPH084745B2 (ja) * | 1986-05-09 | 1996-01-24 | 三菱化学株式会社 | エチレンオキシド製造用銀触媒 |
-
1988
- 1988-02-03 CN CN88100400A patent/CN1009437B/zh not_active Expired
-
1989
- 1989-01-31 IN IN98/CAL/89A patent/IN171804B/en unknown
- 1989-02-01 US US07/304,531 patent/US5063195A/en not_active Expired - Lifetime
- 1989-02-02 DE DE68921777T patent/DE68921777T2/de not_active Expired - Lifetime
- 1989-02-02 EP EP89301001A patent/EP0327356B1/en not_active Expired - Lifetime
- 1989-02-03 JP JP1024136A patent/JPH0667475B2/ja not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
DE68921777T2 (de) | 1995-11-23 |
JPH0256246A (ja) | 1990-02-26 |
EP0327356B1 (en) | 1995-03-22 |
EP0327356A1 (en) | 1989-08-09 |
IN171804B (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1993-01-09 |
CN1034678A (zh) | 1989-08-16 |
US5063195A (en) | 1991-11-05 |
DE68921777D1 (de) | 1995-04-27 |
CN1009437B (zh) | 1990-09-05 |
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