JPH05202300A - 精製したインジゴの製造方法 - Google Patents
精製したインジゴの製造方法Info
- Publication number
- JPH05202300A JPH05202300A JP4187817A JP18781792A JPH05202300A JP H05202300 A JPH05202300 A JP H05202300A JP 4187817 A JP4187817 A JP 4187817A JP 18781792 A JP18781792 A JP 18781792A JP H05202300 A JPH05202300 A JP H05202300A
- Authority
- JP
- Japan
- Prior art keywords
- solution
- indigo
- indoxylate
- stripping
- inert gas
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 235000000177 Indigofera tinctoria Nutrition 0.000 title claims abstract description 38
- 229940097275 indigo Drugs 0.000 title claims abstract description 38
- COHYTHOBJLSHDF-UHFFFAOYSA-N indigo powder Natural products N1C2=CC=CC=C2C(=O)C1=C1C(=O)C2=CC=CC=C2N1 COHYTHOBJLSHDF-UHFFFAOYSA-N 0.000 title claims abstract description 38
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 7
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims abstract description 16
- 238000000034 method Methods 0.000 claims abstract description 14
- 239000011261 inert gas Substances 0.000 claims abstract description 11
- 239000012535 impurity Substances 0.000 claims abstract description 9
- 230000003647 oxidation Effects 0.000 claims abstract description 8
- 238000007254 oxidation reaction Methods 0.000 claims abstract description 8
- 238000004821 distillation Methods 0.000 claims abstract description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000001301 oxygen Substances 0.000 claims abstract description 5
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 5
- 239000000243 solution Substances 0.000 claims description 42
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 7
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 6
- 239000007864 aqueous solution Substances 0.000 claims description 3
- 230000001590 oxidative effect Effects 0.000 claims description 3
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 18
- AFBPFSWMIHJQDM-UHFFFAOYSA-N N-methylaniline Chemical compound CNC1=CC=CC=C1 AFBPFSWMIHJQDM-UHFFFAOYSA-N 0.000 description 15
- 239000000975 dye Substances 0.000 description 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- 150000004982 aromatic amines Chemical class 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 238000007796 conventional method Methods 0.000 description 2
- 238000012856 packing Methods 0.000 description 2
- 238000000746 purification Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- 239000002253 acid Substances 0.000 description 1
- DFZMIRCMSFHUGJ-UHFFFAOYSA-N chembl2314658 Chemical compound C1=CC=C2C(C=3C(C4=CC=CC=C4N=3)=O)=CNC2=C1 DFZMIRCMSFHUGJ-UHFFFAOYSA-N 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 229910052756 noble gas Inorganic materials 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 238000005375 photometry Methods 0.000 description 1
- 238000001256 steam distillation Methods 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000004758 synthetic textile Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B7/00—Indigoid dyes
- C09B7/02—Bis-indole indigos
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Indole Compounds (AREA)
- Treatment Of Water By Oxidation Or Reduction (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US07/731657 | 1991-07-17 | ||
| US07/731,657 US5116996A (en) | 1991-07-17 | 1991-07-17 | Purification of indigo |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH05202300A true JPH05202300A (ja) | 1993-08-10 |
Family
ID=24940442
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP4187817A Withdrawn JPH05202300A (ja) | 1991-07-17 | 1992-07-15 | 精製したインジゴの製造方法 |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US5116996A (enExample) |
| EP (1) | EP0523532B1 (enExample) |
| JP (1) | JPH05202300A (enExample) |
| CN (1) | CN1043651C (enExample) |
| BR (1) | BR9202583A (enExample) |
| DE (1) | DE59208937D1 (enExample) |
| ES (1) | ES2107483T3 (enExample) |
| TW (1) | TW224125B (enExample) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2020530517A (ja) * | 2017-08-11 | 2020-10-22 | アルフローマ アイピー ゲゼルシャフト ミット ベシュレンクテル ハフツング | アニリン不含ロイコインジゴ塩溶液を製造するための方法およびデバイス |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4220804A1 (de) * | 1992-06-25 | 1994-01-05 | Basf Ag | Verfahren zur Reinigung von Indigo |
| DE4336032A1 (de) * | 1993-10-22 | 1995-04-27 | Basf Ag | Verfahren zur Reinigung von Indigo |
| CN103387530A (zh) * | 2012-05-09 | 2013-11-13 | 李立奇 | 5-溴吲哚的制备方法 |
| CN103556420B (zh) * | 2013-10-30 | 2015-11-18 | 江苏泰丰化工有限公司 | 一种从靛蓝后处理洗涤过程中回收混合碱液的方法 |
| PT3569660T (pt) * | 2018-05-18 | 2021-12-17 | Archroma Ip Gmbh | Método para fazer soluções de sal de leucoíndigo sem anilina |
| BR102019025172A2 (pt) * | 2019-11-28 | 2021-06-08 | Bann Química Ltda. | processo de purificação de soluções de sal de leucoíndigo e uso de um gás inerte |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2734951C2 (de) * | 1977-08-03 | 1979-08-09 | Basf Farben + Fasern Ag, 2000 Hamburg | Verfahren zur Nachbehandlung von 4,4', 7,7'-Tetrachlorthioindigo |
| JPS54124027A (en) * | 1978-03-22 | 1979-09-26 | Mitsui Petrochem Ind Ltd | Preparation of indigo |
| DE3101883A1 (de) * | 1981-01-22 | 1982-08-26 | Basf Ag, 6700 Ludwigshafen | Verfahren zur herstellung von 4,4',7,7'-tetrachlorthioindigo |
| CA1334097C (en) * | 1988-03-17 | 1995-01-24 | Usaji Takaki | Process for the preparation of indigo compounds |
-
1991
- 1991-07-17 US US07/731,657 patent/US5116996A/en not_active Expired - Lifetime
-
1992
- 1992-06-03 TW TW081104381A patent/TW224125B/zh active
- 1992-07-08 DE DE59208937T patent/DE59208937D1/de not_active Expired - Lifetime
- 1992-07-08 ES ES92111596T patent/ES2107483T3/es not_active Expired - Lifetime
- 1992-07-08 EP EP92111596A patent/EP0523532B1/de not_active Expired - Lifetime
- 1992-07-10 BR BR929202583A patent/BR9202583A/pt not_active IP Right Cessation
- 1992-07-15 JP JP4187817A patent/JPH05202300A/ja not_active Withdrawn
- 1992-07-17 CN CN92105910A patent/CN1043651C/zh not_active Expired - Lifetime
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2020530517A (ja) * | 2017-08-11 | 2020-10-22 | アルフローマ アイピー ゲゼルシャフト ミット ベシュレンクテル ハフツング | アニリン不含ロイコインジゴ塩溶液を製造するための方法およびデバイス |
| JP2023014157A (ja) * | 2017-08-11 | 2023-01-26 | アルフローマ アイピー ゲゼルシャフト ミット ベシュレンクテル ハフツング | アニリン不含ロイコインジゴ塩溶液を製造するための方法およびデバイス |
Also Published As
| Publication number | Publication date |
|---|---|
| EP0523532B1 (de) | 1997-10-01 |
| ES2107483T3 (es) | 1997-12-01 |
| CN1043651C (zh) | 1999-06-16 |
| CN1068581A (zh) | 1993-02-03 |
| BR9202583A (pt) | 1993-03-16 |
| EP0523532A2 (de) | 1993-01-20 |
| EP0523532A3 (en) | 1994-11-17 |
| DE59208937D1 (de) | 1997-11-06 |
| TW224125B (enExample) | 1994-05-21 |
| US5116996A (en) | 1992-05-26 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A300 | Application deemed to be withdrawn because no request for examination was validly filed |
Free format text: JAPANESE INTERMEDIATE CODE: A300 Effective date: 19991005 |