JPH044650B2 - - Google Patents
Info
- Publication number
- JPH044650B2 JPH044650B2 JP59227934A JP22793484A JPH044650B2 JP H044650 B2 JPH044650 B2 JP H044650B2 JP 59227934 A JP59227934 A JP 59227934A JP 22793484 A JP22793484 A JP 22793484A JP H044650 B2 JPH044650 B2 JP H044650B2
- Authority
- JP
- Japan
- Prior art keywords
- magnetic
- group
- parts
- resins
- urea
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 230000005291 magnetic effect Effects 0.000 claims description 50
- 229920005989 resin Polymers 0.000 claims description 44
- 239000011347 resin Substances 0.000 claims description 44
- 239000011230 binding agent Substances 0.000 claims description 27
- 239000006247 magnetic powder Substances 0.000 claims description 24
- 239000004202 carbamide Substances 0.000 claims description 22
- 229920003226 polyurethane urea Polymers 0.000 claims description 17
- 150000001875 compounds Chemical class 0.000 claims description 16
- 229910052783 alkali metal Chemical group 0.000 claims description 15
- 150000001340 alkali metals Chemical group 0.000 claims description 15
- 238000006243 chemical reaction Methods 0.000 claims description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 12
- 229910052739 hydrogen Inorganic materials 0.000 claims description 8
- 239000001257 hydrogen Substances 0.000 claims description 8
- 229920001228 polyisocyanate Polymers 0.000 claims description 7
- 239000005056 polyisocyanate Substances 0.000 claims description 7
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 5
- 239000012948 isocyanate Substances 0.000 claims description 3
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 claims description 3
- 150000002513 isocyanates Chemical class 0.000 claims description 3
- 239000007795 chemical reaction product Substances 0.000 claims description 2
- -1 hydrogen compound Chemical class 0.000 description 29
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Natural products NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 24
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 22
- 150000002009 diols Chemical class 0.000 description 19
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 16
- 125000000896 monocarboxylic acid group Chemical group 0.000 description 11
- 229920000728 polyester Polymers 0.000 description 11
- 229920005906 polyester polyol Polymers 0.000 description 11
- 125000004432 carbon atom Chemical group C* 0.000 description 10
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 10
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 9
- 239000000203 mixture Substances 0.000 description 9
- 239000000843 powder Substances 0.000 description 9
- 239000011734 sodium Substances 0.000 description 9
- 229920001577 copolymer Polymers 0.000 description 8
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 8
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 8
- 239000007787 solid Substances 0.000 description 8
- 239000004721 Polyphenylene oxide Substances 0.000 description 7
- 239000003054 catalyst Substances 0.000 description 7
- 229920000570 polyether Polymers 0.000 description 7
- 229920005862 polyol Polymers 0.000 description 7
- 150000003077 polyols Chemical class 0.000 description 7
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 6
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 6
- 235000014113 dietary fatty acids Nutrition 0.000 description 6
- 125000005442 diisocyanate group Chemical group 0.000 description 6
- 229930195729 fatty acid Natural products 0.000 description 6
- 239000000194 fatty acid Substances 0.000 description 6
- 150000002334 glycols Chemical class 0.000 description 6
- VLKZOEOYAKHREP-UHFFFAOYSA-N hexane Substances CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 6
- 239000003973 paint Substances 0.000 description 6
- 125000000217 alkyl group Chemical group 0.000 description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 5
- 230000006872 improvement Effects 0.000 description 5
- 229920002554 vinyl polymer Polymers 0.000 description 5
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 description 4
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical group OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 4
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 4
- 238000000576 coating method Methods 0.000 description 4
- 239000006185 dispersion Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 150000002148 esters Chemical class 0.000 description 4
- 150000004665 fatty acids Chemical class 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 230000000704 physical effect Effects 0.000 description 4
- 229920000098 polyolefin Polymers 0.000 description 4
- 229920002635 polyurethane Polymers 0.000 description 4
- 239000004814 polyurethane Substances 0.000 description 4
- 239000002994 raw material Substances 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- SJRJJKPEHAURKC-UHFFFAOYSA-N N-Methylmorpholine Chemical compound CN1CCOCC1 SJRJJKPEHAURKC-UHFFFAOYSA-N 0.000 description 3
- 239000004743 Polypropylene Substances 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 229920001807 Urea-formaldehyde Polymers 0.000 description 3
- ZOIORXHNWRGPMV-UHFFFAOYSA-N acetic acid;zinc Chemical compound [Zn].CC(O)=O.CC(O)=O ZOIORXHNWRGPMV-UHFFFAOYSA-N 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 239000001361 adipic acid Substances 0.000 description 3
- 235000011037 adipic acid Nutrition 0.000 description 3
- 230000002776 aggregation Effects 0.000 description 3
- 238000004220 aggregation Methods 0.000 description 3
- 239000002216 antistatic agent Substances 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 229910052593 corundum Inorganic materials 0.000 description 3
- 239000010431 corundum Substances 0.000 description 3
- 150000004985 diamines Chemical class 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 239000002270 dispersing agent Substances 0.000 description 3
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 3
- 239000000314 lubricant Substances 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- UAEPNZWRGJTJPN-UHFFFAOYSA-N methylcyclohexane Chemical compound CC1CCCCC1 UAEPNZWRGJTJPN-UHFFFAOYSA-N 0.000 description 3
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 3
- 229920001610 polycaprolactone Polymers 0.000 description 3
- 239000004632 polycaprolactone Substances 0.000 description 3
- 229920001225 polyester resin Polymers 0.000 description 3
- 239000004645 polyester resin Substances 0.000 description 3
- 238000006116 polymerization reaction Methods 0.000 description 3
- 229920001155 polypropylene Polymers 0.000 description 3
- 229920005749 polyurethane resin Polymers 0.000 description 3
- 239000001632 sodium acetate Substances 0.000 description 3
- 235000017281 sodium acetate Nutrition 0.000 description 3
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Chemical group OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 3
- 239000004094 surface-active agent Substances 0.000 description 3
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 3
- 229920005992 thermoplastic resin Polymers 0.000 description 3
- JOYRKODLDBILNP-UHFFFAOYSA-N urethane group Chemical group NC(=O)OCC JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 3
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 3
- 239000004246 zinc acetate Substances 0.000 description 3
- PTBDIHRZYDMNKB-UHFFFAOYSA-N 2,2-Bis(hydroxymethyl)propionic acid Chemical compound OCC(C)(CO)C(O)=O PTBDIHRZYDMNKB-UHFFFAOYSA-N 0.000 description 2
- VOZKAJLKRJDJLL-UHFFFAOYSA-N 2,4-diaminotoluene Chemical compound CC1=CC=C(N)C=C1N VOZKAJLKRJDJLL-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 239000004970 Chain extender Substances 0.000 description 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- ZRALSGWEFCBTJO-UHFFFAOYSA-N Guanidine Chemical compound NC(N)=N ZRALSGWEFCBTJO-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- 229920000877 Melamine resin Polymers 0.000 description 2
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 2
- 239000000020 Nitrocellulose Substances 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 2
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 description 2
- 238000005299 abrasion Methods 0.000 description 2
- 239000003082 abrasive agent Substances 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 2
- 125000003545 alkoxy group Chemical group 0.000 description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 2
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 2
- 230000000903 blocking effect Effects 0.000 description 2
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 2
- 239000006229 carbon black Substances 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000006297 dehydration reaction Methods 0.000 description 2
- 229910003460 diamond Inorganic materials 0.000 description 2
- 239000010432 diamond Substances 0.000 description 2
- 239000012975 dibutyltin dilaurate Substances 0.000 description 2
- 229920001971 elastomer Polymers 0.000 description 2
- 238000005886 esterification reaction Methods 0.000 description 2
- LZCLXQDLBQLTDK-UHFFFAOYSA-N ethyl 2-hydroxypropanoate Chemical compound CCOC(=O)C(C)O LZCLXQDLBQLTDK-UHFFFAOYSA-N 0.000 description 2
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 2
- 239000003112 inhibitor Substances 0.000 description 2
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 2
- 150000002576 ketones Chemical class 0.000 description 2
- 150000002596 lactones Chemical class 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 230000014759 maintenance of location Effects 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 229920001220 nitrocellulos Polymers 0.000 description 2
- BDJRBEYXGGNYIS-UHFFFAOYSA-N nonanedioic acid Chemical compound OC(=O)CCCCCCCC(O)=O BDJRBEYXGGNYIS-UHFFFAOYSA-N 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920001281 polyalkylene Polymers 0.000 description 2
- 229920006122 polyamide resin Polymers 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 229920000139 polyethylene terephthalate Polymers 0.000 description 2
- 239000005020 polyethylene terephthalate Substances 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 230000003449 preventive effect Effects 0.000 description 2
- KIDHWZJUCRJVML-UHFFFAOYSA-N putrescine Chemical compound NCCCCN KIDHWZJUCRJVML-UHFFFAOYSA-N 0.000 description 2
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 2
- 229920001187 thermosetting polymer Polymers 0.000 description 2
- 238000005809 transesterification reaction Methods 0.000 description 2
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 1
- WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 description 1
- RTTZISZSHSCFRH-UHFFFAOYSA-N 1,3-bis(isocyanatomethyl)benzene Chemical compound O=C=NCC1=CC=CC(CN=C=O)=C1 RTTZISZSHSCFRH-UHFFFAOYSA-N 0.000 description 1
- VGHSXKTVMPXHNG-UHFFFAOYSA-N 1,3-diisocyanatobenzene Chemical compound O=C=NC1=CC=CC(N=C=O)=C1 VGHSXKTVMPXHNG-UHFFFAOYSA-N 0.000 description 1
- WZCQRUWWHSTZEM-UHFFFAOYSA-N 1,3-phenylenediamine Chemical compound NC1=CC=CC(N)=C1 WZCQRUWWHSTZEM-UHFFFAOYSA-N 0.000 description 1
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
- OHLKMGYGBHFODF-UHFFFAOYSA-N 1,4-bis(isocyanatomethyl)benzene Chemical compound O=C=NCC1=CC=C(CN=C=O)C=C1 OHLKMGYGBHFODF-UHFFFAOYSA-N 0.000 description 1
- OCJBOOLMMGQPQU-UHFFFAOYSA-N 1,4-dichlorobenzene Chemical compound ClC1=CC=C(Cl)C=C1 OCJBOOLMMGQPQU-UHFFFAOYSA-N 0.000 description 1
- ALQLPWJFHRMHIU-UHFFFAOYSA-N 1,4-diisocyanatobenzene Chemical compound O=C=NC1=CC=C(N=C=O)C=C1 ALQLPWJFHRMHIU-UHFFFAOYSA-N 0.000 description 1
- OVBFMUAFNIIQAL-UHFFFAOYSA-N 1,4-diisocyanatobutane Chemical compound O=C=NCCCCN=C=O OVBFMUAFNIIQAL-UHFFFAOYSA-N 0.000 description 1
- CBCKQZAAMUWICA-UHFFFAOYSA-N 1,4-phenylenediamine Chemical compound NC1=CC=C(N)C=C1 CBCKQZAAMUWICA-UHFFFAOYSA-N 0.000 description 1
- SBJCUZQNHOLYMD-UHFFFAOYSA-N 1,5-Naphthalene diisocyanate Chemical compound C1=CC=C2C(N=C=O)=CC=CC2=C1N=C=O SBJCUZQNHOLYMD-UHFFFAOYSA-N 0.000 description 1
- ICLCCFKUSALICQ-UHFFFAOYSA-N 1-isocyanato-4-(4-isocyanato-3-methylphenyl)-2-methylbenzene Chemical compound C1=C(N=C=O)C(C)=CC(C=2C=C(C)C(N=C=O)=CC=2)=C1 ICLCCFKUSALICQ-UHFFFAOYSA-N 0.000 description 1
- SZIFAVKTNFCBPC-UHFFFAOYSA-N 2-chloroethanol Chemical compound OCCCl SZIFAVKTNFCBPC-UHFFFAOYSA-N 0.000 description 1
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 description 1
- QZWKEPYTBWZJJA-UHFFFAOYSA-N 3,3'-Dimethoxybenzidine-4,4'-diisocyanate Chemical compound C1=C(N=C=O)C(OC)=CC(C=2C=C(OC)C(N=C=O)=CC=2)=C1 QZWKEPYTBWZJJA-UHFFFAOYSA-N 0.000 description 1
- RNLHGQLZWXBQNY-UHFFFAOYSA-N 3-(aminomethyl)-3,5,5-trimethylcyclohexan-1-amine Chemical compound CC1(C)CC(N)CC(C)(CN)C1 RNLHGQLZWXBQNY-UHFFFAOYSA-N 0.000 description 1
- DBXBTMSZEOQQDU-UHFFFAOYSA-N 3-hydroxyisobutyric acid Chemical compound OCC(C)C(O)=O DBXBTMSZEOQQDU-UHFFFAOYSA-N 0.000 description 1
- DZIHTWJGPDVSGE-UHFFFAOYSA-N 4-[(4-aminocyclohexyl)methyl]cyclohexan-1-amine Chemical compound C1CC(N)CCC1CC1CCC(N)CC1 DZIHTWJGPDVSGE-UHFFFAOYSA-N 0.000 description 1
- VGVHNLRUAMRIEW-UHFFFAOYSA-N 4-methylcyclohexan-1-one Chemical compound CC1CCC(=O)CC1 VGVHNLRUAMRIEW-UHFFFAOYSA-N 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 1
- 229920008347 Cellulose acetate propionate Polymers 0.000 description 1
- 229920001747 Cellulose diacetate Polymers 0.000 description 1
- 229920002284 Cellulose triacetate Polymers 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- XTHFKEDIFFGKHM-UHFFFAOYSA-N Dimethoxyethane Chemical compound COCCOC XTHFKEDIFFGKHM-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical class C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- CTKINSOISVBQLD-UHFFFAOYSA-N Glycidol Chemical compound OCC1CO1 CTKINSOISVBQLD-UHFFFAOYSA-N 0.000 description 1
- 239000005057 Hexamethylene diisocyanate Substances 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 239000005058 Isophorone diisocyanate Substances 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 1
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 1
- CHJJGSNFBQVOTG-UHFFFAOYSA-N N-methyl-guanidine Natural products CNC(N)=N CHJJGSNFBQVOTG-UHFFFAOYSA-N 0.000 description 1
- 229920000459 Nitrile rubber Polymers 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 239000004962 Polyamide-imide Substances 0.000 description 1
- 239000005062 Polybutadiene Substances 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 239000004642 Polyimide Substances 0.000 description 1
- 229920001328 Polyvinylidene chloride Polymers 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 1
- 239000004433 Thermoplastic polyurethane Substances 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 229920002433 Vinyl chloride-vinyl acetate copolymer Polymers 0.000 description 1
- NNLVGZFZQQXQNW-ADJNRHBOSA-N [(2r,3r,4s,5r,6s)-4,5-diacetyloxy-3-[(2s,3r,4s,5r,6r)-3,4,5-triacetyloxy-6-(acetyloxymethyl)oxan-2-yl]oxy-6-[(2r,3r,4s,5r,6s)-4,5,6-triacetyloxy-2-(acetyloxymethyl)oxan-3-yl]oxyoxan-2-yl]methyl acetate Chemical compound O([C@@H]1O[C@@H]([C@H]([C@H](OC(C)=O)[C@H]1OC(C)=O)O[C@H]1[C@@H]([C@@H](OC(C)=O)[C@H](OC(C)=O)[C@@H](COC(C)=O)O1)OC(C)=O)COC(=O)C)[C@@H]1[C@@H](COC(C)=O)O[C@@H](OC(C)=O)[C@H](OC(C)=O)[C@H]1OC(C)=O NNLVGZFZQQXQNW-ADJNRHBOSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- KXKVLQRXCPHEJC-UHFFFAOYSA-N acetic acid trimethyl ester Natural products COC(C)=O KXKVLQRXCPHEJC-UHFFFAOYSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 125000003342 alkenyl group Chemical group 0.000 description 1
- 229920000180 alkyd Polymers 0.000 description 1
- 150000003973 alkyl amines Chemical class 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 150000001414 amino alcohols Chemical class 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 230000003321 amplification Effects 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 239000003849 aromatic solvent Substances 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 229910001566 austenite Inorganic materials 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- HFACYLZERDEVSX-UHFFFAOYSA-N benzidine Chemical compound C1=CC(N)=CC=C1C1=CC=C(N)C=C1 HFACYLZERDEVSX-UHFFFAOYSA-N 0.000 description 1
- NTXGQCSETZTARF-UHFFFAOYSA-N buta-1,3-diene;prop-2-enenitrile Chemical compound C=CC=C.C=CC#N NTXGQCSETZTARF-UHFFFAOYSA-N 0.000 description 1
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 1
- QHIWVLPBUQWDMQ-UHFFFAOYSA-N butyl prop-2-enoate;methyl 2-methylprop-2-enoate;prop-2-enoic acid Chemical compound OC(=O)C=C.COC(=O)C(C)=C.CCCCOC(=O)C=C QHIWVLPBUQWDMQ-UHFFFAOYSA-N 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- BCFSVSISUGYRMF-UHFFFAOYSA-N calcium;dioxido(dioxo)chromium;dihydrate Chemical compound O.O.[Ca+2].[O-][Cr]([O-])(=O)=O BCFSVSISUGYRMF-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 150000007942 carboxylates Chemical group 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 229920006217 cellulose acetate butyrate Polymers 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 150000008280 chlorinated hydrocarbons Chemical class 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- WVIIMZNLDWSIRH-UHFFFAOYSA-N cyclohexylcyclohexane Chemical compound C1CCCCC1C1CCCCC1 WVIIMZNLDWSIRH-UHFFFAOYSA-N 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- BYUPIIJMMRARRA-UHFFFAOYSA-N diamino(phenyl)methanesulfonic acid Chemical compound OS(=O)(=O)C(N)(N)C1=CC=CC=C1 BYUPIIJMMRARRA-UHFFFAOYSA-N 0.000 description 1
- 150000001991 dicarboxylic acids Chemical class 0.000 description 1
- 229940117389 dichlorobenzene Drugs 0.000 description 1
- QDOXWKRWXJOMAK-UHFFFAOYSA-N dichromium trioxide Chemical compound O=[Cr]O[Cr]=O QDOXWKRWXJOMAK-UHFFFAOYSA-N 0.000 description 1
- SWSQBOPZIKWTGO-UHFFFAOYSA-N dimethylaminoamidine Natural products CN(C)C(N)=N SWSQBOPZIKWTGO-UHFFFAOYSA-N 0.000 description 1
- FBNZWXVYNKUWIC-UHFFFAOYSA-L dipotassium;2-sulfobenzene-1,3-dicarboxylate Chemical compound [K+].[K+].OS(=O)(=O)C1=C(C([O-])=O)C=CC=C1C([O-])=O FBNZWXVYNKUWIC-UHFFFAOYSA-L 0.000 description 1
- KFMQPIHLHGRTFB-UHFFFAOYSA-L disodium;2,2-dimethyl-3-sulfobutanedioate Chemical compound [Na+].[Na+].[O-]C(=O)C(C)(C)C(C([O-])=O)S(O)(=O)=O KFMQPIHLHGRTFB-UHFFFAOYSA-L 0.000 description 1
- JMGZBMRVDHKMKB-UHFFFAOYSA-L disodium;2-sulfobutanedioate Chemical compound [Na+].[Na+].OS(=O)(=O)C(C([O-])=O)CC([O-])=O JMGZBMRVDHKMKB-UHFFFAOYSA-L 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 229910052571 earthenware Inorganic materials 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- 229910001651 emery Inorganic materials 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 239000003759 ester based solvent Substances 0.000 description 1
- 229940116333 ethyl lactate Drugs 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 230000005294 ferromagnetic effect Effects 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 230000004907 flux Effects 0.000 description 1
- 239000002223 garnet Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 230000009477 glass transition Effects 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 229920000578 graft copolymer Polymers 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 1
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-M hexanoate Chemical compound CCCCCC([O-])=O FUZZWVXGSFPDMH-UHFFFAOYSA-M 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 239000012442 inert solvent Substances 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 description 1
- 239000005453 ketone based solvent Substances 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 229940018564 m-phenylenediamine Drugs 0.000 description 1
- 229910001004 magnetic alloy Inorganic materials 0.000 description 1
- 239000002075 main ingredient Substances 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- GYNNXHKOJHMOHS-UHFFFAOYSA-N methyl-cycloheptane Natural products CC1CCCCCC1 GYNNXHKOJHMOHS-UHFFFAOYSA-N 0.000 description 1
- CWQXQMHSOZUFJS-UHFFFAOYSA-N molybdenum disulfide Chemical compound S=[Mo]=S CWQXQMHSOZUFJS-UHFFFAOYSA-N 0.000 description 1
- 229910052982 molybdenum disulfide Inorganic materials 0.000 description 1
- KQSABULTKYLFEV-UHFFFAOYSA-N naphthalene-1,5-diamine Chemical compound C1=CC=C2C(N)=CC=CC2=C1N KQSABULTKYLFEV-UHFFFAOYSA-N 0.000 description 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 238000003199 nucleic acid amplification method Methods 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 125000005496 phosphonium group Chemical group 0.000 description 1
- 125000002270 phosphoric acid ester group Chemical group 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920000233 poly(alkylene oxides) Polymers 0.000 description 1
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 description 1
- 229920002312 polyamide-imide Polymers 0.000 description 1
- 229920000768 polyamine Polymers 0.000 description 1
- 229920002857 polybutadiene Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920001721 polyimide Polymers 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- 239000004810 polytetrafluoroethylene Substances 0.000 description 1
- 229920000909 polytetrahydrofuran Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 229920002620 polyvinyl fluoride Polymers 0.000 description 1
- 239000005033 polyvinylidene chloride Substances 0.000 description 1
- 229910052573 porcelain Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 230000002250 progressing effect Effects 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 238000007151 ring opening polymerisation reaction Methods 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 1
- 229910010271 silicon carbide Inorganic materials 0.000 description 1
- 229920002050 silicone resin Polymers 0.000 description 1
- 235000011121 sodium hydroxide Nutrition 0.000 description 1
- NVKTUNLPFJHLCG-UHFFFAOYSA-N strontium chromate Chemical compound [Sr+2].[O-][Cr]([O-])(=O)=O NVKTUNLPFJHLCG-UHFFFAOYSA-N 0.000 description 1
- IIACRCGMVDHOTQ-UHFFFAOYSA-N sulfamic acid Chemical class NS(O)(=O)=O IIACRCGMVDHOTQ-UHFFFAOYSA-N 0.000 description 1
- NVBFHJWHLNUMCV-UHFFFAOYSA-N sulfamide Chemical compound NS(N)(=O)=O NVBFHJWHLNUMCV-UHFFFAOYSA-N 0.000 description 1
- 150000003457 sulfones Chemical group 0.000 description 1
- 229920003051 synthetic elastomer Polymers 0.000 description 1
- 239000005061 synthetic rubber Substances 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 description 1
- RUELTTOHQODFPA-UHFFFAOYSA-N toluene 2,6-diisocyanate Chemical compound CC1=C(N=C=O)C=CC=C1N=C=O RUELTTOHQODFPA-UHFFFAOYSA-N 0.000 description 1
- AAAQKTZKLRYKHR-UHFFFAOYSA-N triphenylmethane Chemical compound C1=CC=CC=C1C(C=1C=CC=CC=1)C1=CC=CC=C1 AAAQKTZKLRYKHR-UHFFFAOYSA-N 0.000 description 1
- ITRNXVSDJBHYNJ-UHFFFAOYSA-N tungsten disulfide Chemical compound S=[W]=S ITRNXVSDJBHYNJ-UHFFFAOYSA-N 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- NDKWCCLKSWNDBG-UHFFFAOYSA-N zinc;dioxido(dioxo)chromium Chemical compound [Zn+2].[O-][Cr]([O-])(=O)=O NDKWCCLKSWNDBG-UHFFFAOYSA-N 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
- PAPBSGBWRJIAAV-UHFFFAOYSA-N ε-Caprolactone Chemical compound O=C1CCCCCO1 PAPBSGBWRJIAAV-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
- Magnetic Record Carriers (AREA)
Description
æ¬çºæã¯éç£æ§æ¯æäœäžã«ç£æ§ç²ãšçµåå€ãäž»
äœãšããç£æ§å±€ã圢æãããŠãªãç£æ°èšé²åªäœã«
é¢ãããã®ã§ããã詳现ã«ã¯ã該ç£æ°èšé²åªäœã®
çµåå€ã®æ¹è¯ã«é¢ãããã®ã§ããã åŸæ¥ãçš®ã ã®æš¹èäŸãã°ãå¡©ãâé ¢ãâããã«
ã¢ã«ã³ãŒã«å ±éåäœããããã»ã«ããŒã¹ãããªãš
ã¹ãã«æš¹èåã³ããªãŠã¬ã¿ã³æš¹èçãåç¬åã¯æ··
åããçµåå€ãç£æ°èšé²åªäœãšããŠçšããããŠã
ãããè¿å¹Žãããç£æ°èšé²åªäœã®çšéã®æ¡å€§ã«äŒŽ
ãªã€ãŠãæŽã«é«æ§èœåãé«å¯åºŠåãèŠæ±ãããç£
æ§ç²åéã§ã¯ç£æ§ç²ã®åŸ®çŽ°åã«ããè¡šé¢ç©ã®å¢å€§
ãé žåéç³»ç£æ§ç²ããåéç£æ§ç²ãžã®ç§»åçç£æ§
ç²ã®æ¹è³ªãæ¥éã«é²ãã§ããã ä¹ãã®ããšã«ããè¡šé¢ç©å¢å€§ãæç£åã®å¢å€§ã«
ããç£æ§ç²çžäºäœçšã®å¢å¹ ãããåŸæ¥ã®çµåå€ã§
ã¯ç£æ§ç²ãå åã«åæ£ãããããšãå°é£ã«ãªãã€
ã€ããã è¿å¹Žãããã®åé¡ãæ¹åããããçµåå€ã«èŠªæ°Ž
æ§æ¥µæ§åºãå°å ¥ãç£æ§ç²ãšã®èŠªåæ§ãåäžããå
æ£æ©èœãé«ããçµåå€ãéçºããã€ã€ããããã
ã®ãããªçµåå€ãå«ããããŸã§å ¬ç¥ãšãããçµå
å€ã¯ç£æ§ç²åæ£æ§ã«åªããŠããŠããèä¹ æ§ãæºè¶³
ã§ããªãã€ãããèä¹ æ§ãåªããŠããŠãè¡šé¢å¹³æ»
æ§ãå£ãçãç£æ°èšé²åªäœã«èŠæ±ãããç£æ§ç²ã®
é«ãåæ£æ§ãç£æ§å±€ã®èä¹ æ§åã³ç£æ§å±€ã®è¡šé¢å¹³
æ»æ§ã®äžè ãåæã«æºè¶³ãããã®ã¯åŸãããŠããª
ãã åŸæ¥ããªãŠã¬ã¿ã³æš¹èã¯ãä»ã®æš¹èã§ã¯åŸãã
ãªãé«åŒŸæ§åã³æè»æ§ãæã匷床ã䌞ã³ã倧ãã
ãã€èæ©èæ§ã«åªããç¹åŸŽãæããããç£æ°èšé²
åªäœãšããŠçšããããŠããããç£æ§ç²åæ£æ§ã®ç¹
ã§ã¯ãå¡©ãâé ¢ãâããã«ã¢ã«ã³ãŒã«å ±éåäœã
ãããã»ã«ããŒã¹çã«æ¯èŒããŠå£ããšããæ¬ ç¹ã
ããããã®æ¹è¯ãšããŠæ°Žé žåºã第äžçŽçªçŽ ã
SO3Mâ²åºïŒMâ²ã¯ã¢ã«ã«ãªéå±ïŒçã®èŠªæ°Žæ§æ¥µæ§
åºãååå ã«å°å ¥ãç£æ§ç²ãšã®ãªãã¿ãè¯ããã
ããšã«ããç£æ§ç²åæ£æ§ãåäžãããçã®äºãè¡
ãããŠãããããããã®æ¹æ³ã«ãã€ãŠããæš¹èã®
溶å€ãžã®æº¶è§£æ§ãèç±æ§åã¯ç£æ§ç²åæ£æ§ãç£æ§
å±€ã®èä¹ æ§ãè¡šé¢å¹³æ»æ§çãåæã«æºè¶³ãããã
ã®ã¯èŠåºãããŠããªãã æ¬çºæã¯ããã®ãããªåé¡ç¹ã解決ããããã«
ãªããããã®ã§ãããç£æ§ç²ã®åæ£æ§ãç£æ§å±€ã®
èä¹ æ§åã³è¡šé¢å¹³æ»æ§çã®åªããç£æ°èšé²åªäœã
æäŸããããšãç®çãšãããã®ã§ããã æ¬çºæè ã¯ãéæç 究ã®çµæãããªãŠã¬ã¿ã³æš¹
èç³»çµåå€äžã«ããŠã¬ã¢çµåãå°å ¥ãããšãšã
ã«ã芪氎æ§æ¥µæ§åºãå°å ¥ããããšã«ããåŸæ¥ã®æ¬
ç¹ãæ¹åã§ããããšãèŠåºãæ¬çºæã«è³ã€ãã å³ã¡æ¬çºæã¯ãéç£æ§æ¯æäœäžã«ç£æ§ç²ãšçµå
å€ãäž»äœãšããç£æ§å±€ã圢æãããŠãªãç£æ°èšé²
åªäœã«ãããŠã äžèšç£æ§å±€ãååå ã«COOMåºïŒïŒã¯æ°ŽçŽ å
ã¯ã¢ã«ã«ãªéå±ïŒåã³ïŒåã¯SO3Mâ²åºïŒMâ²ã¯ã¢
ã«ã«ãªéå±ïŒãæããæ°Žãšã€ãœã·ã¢ããŒãåºãšã®
åå¿ãã圢æããããŠã¬ã¢çµåãæããããªãŠã¬
ã¿ã³âãŠã¬ã¢æš¹èãçµåå€ãšããŠå«æããããšã
ç¹åŸŽãšããç£æ°èšé²åªäœãåã³è©²ããªãŠã¬ã¿ã³â
ãŠã¬ã¢æš¹èãšããªã€ãœã·ã¢ããŒãååç©ãšã®åå¿
ç©ãçµåå€ãšããŠå«æããããšãç¹åŸŽãšããç£æ°
èšé²åªäœã«é¢ãããã®ã§ããã æŽã«è©³çŽ°ã«èª¬æãå ãããªãã°ãçµåå€ã«æ°Žã
掻æ§æ°ŽçŽ ååç©ã®äžéšãšããŠçšããããããšã€ãœ
ã·ã¢ããŒããšã®åå¿ã«ãããŠã¬ã¢çµåïŒâ
NHCONHâïŒãšèŠªæ°Žæ§æ¥µæ§åºå«æååç©ããå°
å ¥ãããCOOMåºïŒïŒã¯æ°ŽçŽ åã¯ã¢ã«ã«ãªéå±ïŒ
åã³ïŒåã¯SO3Mâ²åºïŒMâ²ã¯ã¢ã«ã«ãªéå±ïŒã®èŠª
æ°Žæ§æ¥µæ§åºãååå ã«åæã«å°å ¥ãããããšã«ã
ãé«ãç£æ§ç²åæ£æ§ãšåªãã匷床ãèä¹ æ§ãå¡å·¥
æ§çãåŸããããã®ã§ããã®å€§å·Ÿãªæ¹åã®åå
ã¯ããŠã¬ã¿ã³çµåã«èŒã¹ããŠã¬ã¢çµåã¯åéãšã
ã«ã®ãŒã倧ããããŠã¬ã¢çµåéã§æ°ŽçŽ çµåã«ãã
ç©çæ¶æ©ãçããŠã¬ã¢çµåã®åéã«ããéšåçãª
ååéã®ç±éåãåºå®åããæš¹èã®ãœããã»ã°ã¡
ã³ããšããŒãã»ã°ã¡ã³ãã®åé¢ãããããåªãã
ãŽã 匟æ§ã瀺ããã®ãšæãããæŽã«ãè»åç¹ããŠ
ã¬ã¿ã³çµåã®ã¿ã®æš¹èããé«ãã§ãããããçµå
å€ãšããŠçšããå Žåè¡šé¢ãå¹³æ»ã§æ©æŠä¿æ°ã®å°ã
ãã¹ã ãŒã¹ãªé¢ãåŸãããšãã§ãããã®ãšèãã
ããã ç¹ã«é©ãã¹ãããšã«æ°ŽããåŸããããŠã¬ã¢çµå
ã¯ãH2NRNH2ã§ç€ºãããææ©ãžã¢ãã³ãšææ©
ãžã€ãœã·ã¢ããŒãããå°å ¥ããããŠã¬ã¢çµåãã
ããè¿ãçµåééãçããã§ããçµæããŠã¬ã¢çµ
åãéäžçã«å°å ¥ããããšãå¯èœãªãããã匷å
ãªæ°ŽçŽ çµååãåŸãããããšã§ããã æ¬çºæã«æŒããããªãŠã¬ã¿ã³âãŠã¬ã¢æš¹èã®è£œ
é ã«äœ¿çšãããææ©ãžã€ãœã·ã¢ããŒããšããŠã¯ã
ïŒïŒïŒâããªã¬ã³ãžã€ãœã·ã¢ããŒããïŒïŒïŒâã
ãªã¬ã³ãžã€ãœã·ã¢ããŒããâããšãã¬ã³ãžã€ãœ
ã·ã¢ããŒãããžããšãã«ã¡ã¿ã³ãžã€ãœã·ã¢ããŒ
ããïœâããšãã¬ã³ãžã€ãœã·ã¢ããŒãããããµã¡
ãã¬ã³ãžã€ãœã·ã¢ããŒããããã©ã¡ãã¬ã³ãžã€ãœ
ã·ã¢ããŒããïŒïŒ3â²âãžã¡ããã·âïŒïŒ4â²âãã
ãšãã¬ã³ãžã€ãœã·ã¢ããŒããïŒïŒïŒâããã¿ã¬ã³
ãžã€ãœã·ã¢ããŒããïŒïŒ3â²âãžã¡ãã«âïŒïŒ4â²â
ãããšãã¬ã³ãžã€ãœã·ã¢ããŒããïŒïŒ4â²âãžããš
ãã¬ã³ãžã€ãœã·ã¢ããŒããïŒïŒ4â²âãžã€ãœã·ã¢ã
ãŒãâãžããšãã«ãšãŒãã«ãïŒïŒïŒâããã¿ã¬ã³
ãžã€ãœã·ã¢ããŒããâãã·ãªã¬ã³ãžã€ãœã·ã¢ã
ãŒããïœâãã·ãªã¬ã³ãžã€ãœã·ã¢ããŒããïŒïŒïŒ
âãžã€ãœã·ã¢ããŒãã¡ãã«ã·ã¯ããããµã³ãïŒïŒ
ïŒâãžã€ãœã·ã¢ããŒãã¡ãã«ã·ã¯ããããµã³ã
ïŒïŒ4â²âãžã€ãœã·ã¢ããŒããžã·ã¯ããããµã³ã
ïŒïŒ4â²âãžã€ãœã·ã¢ããŒãã·ã¯ãããã·ã«ã¡ã¿
ã³ãã€ãœããã³ãžã€ãœã·ã¢ããŒãçãæãããã
ãããã®åç¬åã¯ïŒçš®ä»¥äžã®æ··åç©ãšããŠäœ¿çšã§
ãããå該ã€ãœã·ã¢ããŒããããªãªãŒã«çã§å€æ§
ãããžã€ãœã·ã¢ããŒãé¡ãåæ§ã«äœ¿çšããããšã
ã§ããã æ¬çºæã«çšãããããžããããã·ååç©ãšããŠ
ã¯ãããªãšã¹ãã«ãžãªãŒã«ãããªãšãŒãã«ãžãªãŒ
ã«åã³çéã®ã°ãªã³ãŒã«é¡ãçšããããããªãšã¹
ãã«ãžãªãŒã«ãšããŠã¯ãå ·äœçã«ã¯äŸãã°ã³ãã¯
é žãã¢ãžãã³é žãã»ãã·ã³é žãã¢ãŒã©ã€ã³é žçã®
èèªæãžã«ã«ãã³é žããã¬ãã¿ã«é žãã€ãœãã¿ã«
é žçã®è³éŠæãžã«ã«ãã³é žåã¯ãããã®äœçŽã¢ã«
ã³ãŒã«ãšã¹ãã«ãšããšãã¬ã³ã°ãªã³ãŒã«ãïŒïŒïŒ
âãããã¬ã³ã°ãªã³ãŒã«ãïŒïŒïŒâããã¬ã³ã°ãª
ã³ãŒã«ãïŒïŒïŒâãããµã³ã°ãªã³ãŒã«ããžãšãã¬
ã³ã°ãªã³ãŒã«ãããªãã³ãã«ã°ãªã³ãŒã«ãããã¯
ãã¹ããšããŒã«ïŒ¡ã®ãšãã¬ã³ãªããµã€ãä»å ç©ç
åã¯ãããã®æ··åç©ãšãåå¿ããŠåŸãããããªãš
ã¹ãã«ãžãªãŒã«é¡åã¯Îµâã«ããã©ã¯ãã³çã®ã©
ã¯ãã³é¡ãéç°éåããŠåŸãããã©ã¯ãã³ç³»ã®ã
ãªãšã¹ãã«ãžãªãŒã«é¡çãæãããããããªãšãŒ
ãã«ãžãªãŒã«ãšããŠã¯ãäŸãã°ããªãšãã¬ã³ã°ãª
ã³ãŒã«ãããªãããã¬ã³ãšãŒãã«ã°ãªã³ãŒã«ãã
ãªããã©ã¡ãã¬ã³ãšãŒãã«ã°ãªã³ãŒã«çã®ããªã¢
ã«ãã¬ã³ãšãŒãã«ã°ãªã³ãŒã«é¡åã¯ãããã®å ±é
åããªãšãŒãã«ã°ãªã³ãŒã«é¡çãæããããã
åãããªãšãŒãã«ãšã¹ãã«ã°ãªã³ãŒã«ãšããŠã¯ã
äžèšããªã¢ã«ãã¬ã³ãšãŒãã«ã°ãªã³ãŒã«ãããªãª
ãŒã«æåãšããŠèèªæåã¯è³éŠæãžã«ã«ãã³é žãš
åå¿ãããŠåŸãããããªãšã¹ãã«ã°ãªã³ãŒã«é¡ã
æããããçéã°ãªã³ãŒã«é¡ãšããŠããªãšã¹ãã«
ãžãªãŒã«ã®åæãšããŠæããã°ãªã³ãŒã«é¡ã䜿çš
ã§ããã åãæ¬çºæã«æŒããææ©ãžã€ãœã·ã¢ããŒããšå
å¿ããŠãŠã¬ã¢çµåãçæãããååç©ãšããŠã¯ã
æ°Žã®ä»ã«ãææ©ãžã¢ãã³ã䜵çšããããšãã§ã
ããææ©ãžã¢ãã³ãšããŠã¯ãããã©ã¡ãã¬ã³ãžã¢
ãã³ããããµã¡ãã¬ã³ãžã¢ãã³ãªã©ã®èèªæãžã¢
ãã³ãïœâããšãã¬ã³ãžã¢ãã³ãâããšãã¬ã³
ãžã¢ãã³ãïŒïŒïŒâããªã¬ã³ãžã¢ãã³ãïŒïŒïŒâ
ããªã¬ã³ãžã¢ãã³ãïŒïŒ4â²âãããšãã¬ã³ãžã¢ã
ã³ãïŒïŒïŒâããã¿ã¬ã³ãžã¢ãã³çã®è³éŠæãžã¢
ãã³ãïŒïŒïŒâãžã¢ãã³ã¡ãã«ã·ã¯ããããµã
ã³ãïŒïŒïŒâãžã¢ããã»ã¡ãã«ã·ã¯ããããµã
ã³ãïŒïŒ4â²âãžã¢ãããžã·ã¯ãããã·ã«ã¡ã¿ã³ã
ã€ãœããã³ãžã¢ãã³çã®èç°æãžã¢ãã³çãæã
ãããã æ°Žã¯ãã€ãœã·ã¢ããŒãåºãšåå¿ããŠåŒ(1)ã«ç€ºã
ããšãã¢ããåºãçæããã âNCOïŒH2OââNH2ïŒCO2 (1) æŽã«ãæ¬çºæã«æŒããCOOMåºïŒïŒã¯æ°ŽçŽ å
ã¯ã¢ã«ã«ãªéå±ïŒåã³ïŒåã¯SO3Mâ²åºïŒMâ²ã¯ã¢
ã«ã«ãªéå±ïŒçã®èŠªæ°Žæ§æ¥µæ§åºãããªãŠã¬ã¿ã³â
ãŠã¬ã¢æš¹èã«å°å ¥ãã芪氎æ§æ¥µæ§åºå«æååç©ãš
ããŠã¯ããžããããã·ååç©ããžã¢ãã³ååç©ç
ã®ãããã§ãããããäŸãã°SO3Mâ²åºããžãã
ããã·ååç©ãšããŠå°å ¥ãããªãã°ãäŸãã°ã
äœãšããç£æ§å±€ã圢æãããŠãªãç£æ°èšé²åªäœã«
é¢ãããã®ã§ããã詳现ã«ã¯ã該ç£æ°èšé²åªäœã®
çµåå€ã®æ¹è¯ã«é¢ãããã®ã§ããã åŸæ¥ãçš®ã ã®æš¹èäŸãã°ãå¡©ãâé ¢ãâããã«
ã¢ã«ã³ãŒã«å ±éåäœããããã»ã«ããŒã¹ãããªãš
ã¹ãã«æš¹èåã³ããªãŠã¬ã¿ã³æš¹èçãåç¬åã¯æ··
åããçµåå€ãç£æ°èšé²åªäœãšããŠçšããããŠã
ãããè¿å¹Žãããç£æ°èšé²åªäœã®çšéã®æ¡å€§ã«äŒŽ
ãªã€ãŠãæŽã«é«æ§èœåãé«å¯åºŠåãèŠæ±ãããç£
æ§ç²åéã§ã¯ç£æ§ç²ã®åŸ®çŽ°åã«ããè¡šé¢ç©ã®å¢å€§
ãé žåéç³»ç£æ§ç²ããåéç£æ§ç²ãžã®ç§»åçç£æ§
ç²ã®æ¹è³ªãæ¥éã«é²ãã§ããã ä¹ãã®ããšã«ããè¡šé¢ç©å¢å€§ãæç£åã®å¢å€§ã«
ããç£æ§ç²çžäºäœçšã®å¢å¹ ãããåŸæ¥ã®çµåå€ã§
ã¯ç£æ§ç²ãå åã«åæ£ãããããšãå°é£ã«ãªãã€
ã€ããã è¿å¹Žãããã®åé¡ãæ¹åããããçµåå€ã«èŠªæ°Ž
æ§æ¥µæ§åºãå°å ¥ãç£æ§ç²ãšã®èŠªåæ§ãåäžããå
æ£æ©èœãé«ããçµåå€ãéçºããã€ã€ããããã
ã®ãããªçµåå€ãå«ããããŸã§å ¬ç¥ãšãããçµå
å€ã¯ç£æ§ç²åæ£æ§ã«åªããŠããŠããèä¹ æ§ãæºè¶³
ã§ããªãã€ãããèä¹ æ§ãåªããŠããŠãè¡šé¢å¹³æ»
æ§ãå£ãçãç£æ°èšé²åªäœã«èŠæ±ãããç£æ§ç²ã®
é«ãåæ£æ§ãç£æ§å±€ã®èä¹ æ§åã³ç£æ§å±€ã®è¡šé¢å¹³
æ»æ§ã®äžè ãåæã«æºè¶³ãããã®ã¯åŸãããŠããª
ãã åŸæ¥ããªãŠã¬ã¿ã³æš¹èã¯ãä»ã®æš¹èã§ã¯åŸãã
ãªãé«åŒŸæ§åã³æè»æ§ãæã匷床ã䌞ã³ã倧ãã
ãã€èæ©èæ§ã«åªããç¹åŸŽãæããããç£æ°èšé²
åªäœãšããŠçšããããŠããããç£æ§ç²åæ£æ§ã®ç¹
ã§ã¯ãå¡©ãâé ¢ãâããã«ã¢ã«ã³ãŒã«å ±éåäœã
ãããã»ã«ããŒã¹çã«æ¯èŒããŠå£ããšããæ¬ ç¹ã
ããããã®æ¹è¯ãšããŠæ°Žé žåºã第äžçŽçªçŽ ã
SO3Mâ²åºïŒMâ²ã¯ã¢ã«ã«ãªéå±ïŒçã®èŠªæ°Žæ§æ¥µæ§
åºãååå ã«å°å ¥ãç£æ§ç²ãšã®ãªãã¿ãè¯ããã
ããšã«ããç£æ§ç²åæ£æ§ãåäžãããçã®äºãè¡
ãããŠãããããããã®æ¹æ³ã«ãã€ãŠããæš¹èã®
溶å€ãžã®æº¶è§£æ§ãèç±æ§åã¯ç£æ§ç²åæ£æ§ãç£æ§
å±€ã®èä¹ æ§ãè¡šé¢å¹³æ»æ§çãåæã«æºè¶³ãããã
ã®ã¯èŠåºãããŠããªãã æ¬çºæã¯ããã®ãããªåé¡ç¹ã解決ããããã«
ãªããããã®ã§ãããç£æ§ç²ã®åæ£æ§ãç£æ§å±€ã®
èä¹ æ§åã³è¡šé¢å¹³æ»æ§çã®åªããç£æ°èšé²åªäœã
æäŸããããšãç®çãšãããã®ã§ããã æ¬çºæè ã¯ãéæç 究ã®çµæãããªãŠã¬ã¿ã³æš¹
èç³»çµåå€äžã«ããŠã¬ã¢çµåãå°å ¥ãããšãšã
ã«ã芪氎æ§æ¥µæ§åºãå°å ¥ããããšã«ããåŸæ¥ã®æ¬
ç¹ãæ¹åã§ããããšãèŠåºãæ¬çºæã«è³ã€ãã å³ã¡æ¬çºæã¯ãéç£æ§æ¯æäœäžã«ç£æ§ç²ãšçµå
å€ãäž»äœãšããç£æ§å±€ã圢æãããŠãªãç£æ°èšé²
åªäœã«ãããŠã äžèšç£æ§å±€ãååå ã«COOMåºïŒïŒã¯æ°ŽçŽ å
ã¯ã¢ã«ã«ãªéå±ïŒåã³ïŒåã¯SO3Mâ²åºïŒMâ²ã¯ã¢
ã«ã«ãªéå±ïŒãæããæ°Žãšã€ãœã·ã¢ããŒãåºãšã®
åå¿ãã圢æããããŠã¬ã¢çµåãæããããªãŠã¬
ã¿ã³âãŠã¬ã¢æš¹èãçµåå€ãšããŠå«æããããšã
ç¹åŸŽãšããç£æ°èšé²åªäœãåã³è©²ããªãŠã¬ã¿ã³â
ãŠã¬ã¢æš¹èãšããªã€ãœã·ã¢ããŒãååç©ãšã®åå¿
ç©ãçµåå€ãšããŠå«æããããšãç¹åŸŽãšããç£æ°
èšé²åªäœã«é¢ãããã®ã§ããã æŽã«è©³çŽ°ã«èª¬æãå ãããªãã°ãçµåå€ã«æ°Žã
掻æ§æ°ŽçŽ ååç©ã®äžéšãšããŠçšããããããšã€ãœ
ã·ã¢ããŒããšã®åå¿ã«ãããŠã¬ã¢çµåïŒâ
NHCONHâïŒãšèŠªæ°Žæ§æ¥µæ§åºå«æååç©ããå°
å ¥ãããCOOMåºïŒïŒã¯æ°ŽçŽ åã¯ã¢ã«ã«ãªéå±ïŒ
åã³ïŒåã¯SO3Mâ²åºïŒMâ²ã¯ã¢ã«ã«ãªéå±ïŒã®èŠª
æ°Žæ§æ¥µæ§åºãååå ã«åæã«å°å ¥ãããããšã«ã
ãé«ãç£æ§ç²åæ£æ§ãšåªãã匷床ãèä¹ æ§ãå¡å·¥
æ§çãåŸããããã®ã§ããã®å€§å·Ÿãªæ¹åã®åå
ã¯ããŠã¬ã¿ã³çµåã«èŒã¹ããŠã¬ã¢çµåã¯åéãšã
ã«ã®ãŒã倧ããããŠã¬ã¢çµåéã§æ°ŽçŽ çµåã«ãã
ç©çæ¶æ©ãçããŠã¬ã¢çµåã®åéã«ããéšåçãª
ååéã®ç±éåãåºå®åããæš¹èã®ãœããã»ã°ã¡
ã³ããšããŒãã»ã°ã¡ã³ãã®åé¢ãããããåªãã
ãŽã 匟æ§ã瀺ããã®ãšæãããæŽã«ãè»åç¹ããŠ
ã¬ã¿ã³çµåã®ã¿ã®æš¹èããé«ãã§ãããããçµå
å€ãšããŠçšããå Žåè¡šé¢ãå¹³æ»ã§æ©æŠä¿æ°ã®å°ã
ãã¹ã ãŒã¹ãªé¢ãåŸãããšãã§ãããã®ãšèãã
ããã ç¹ã«é©ãã¹ãããšã«æ°ŽããåŸããããŠã¬ã¢çµå
ã¯ãH2NRNH2ã§ç€ºãããææ©ãžã¢ãã³ãšææ©
ãžã€ãœã·ã¢ããŒãããå°å ¥ããããŠã¬ã¢çµåãã
ããè¿ãçµåééãçããã§ããçµæããŠã¬ã¢çµ
åãéäžçã«å°å ¥ããããšãå¯èœãªãããã匷å
ãªæ°ŽçŽ çµååãåŸãããããšã§ããã æ¬çºæã«æŒããããªãŠã¬ã¿ã³âãŠã¬ã¢æš¹èã®è£œ
é ã«äœ¿çšãããææ©ãžã€ãœã·ã¢ããŒããšããŠã¯ã
ïŒïŒïŒâããªã¬ã³ãžã€ãœã·ã¢ããŒããïŒïŒïŒâã
ãªã¬ã³ãžã€ãœã·ã¢ããŒããâããšãã¬ã³ãžã€ãœ
ã·ã¢ããŒãããžããšãã«ã¡ã¿ã³ãžã€ãœã·ã¢ããŒ
ããïœâããšãã¬ã³ãžã€ãœã·ã¢ããŒãããããµã¡
ãã¬ã³ãžã€ãœã·ã¢ããŒããããã©ã¡ãã¬ã³ãžã€ãœ
ã·ã¢ããŒããïŒïŒ3â²âãžã¡ããã·âïŒïŒ4â²âãã
ãšãã¬ã³ãžã€ãœã·ã¢ããŒããïŒïŒïŒâããã¿ã¬ã³
ãžã€ãœã·ã¢ããŒããïŒïŒ3â²âãžã¡ãã«âïŒïŒ4â²â
ãããšãã¬ã³ãžã€ãœã·ã¢ããŒããïŒïŒ4â²âãžããš
ãã¬ã³ãžã€ãœã·ã¢ããŒããïŒïŒ4â²âãžã€ãœã·ã¢ã
ãŒãâãžããšãã«ãšãŒãã«ãïŒïŒïŒâããã¿ã¬ã³
ãžã€ãœã·ã¢ããŒããâãã·ãªã¬ã³ãžã€ãœã·ã¢ã
ãŒããïœâãã·ãªã¬ã³ãžã€ãœã·ã¢ããŒããïŒïŒïŒ
âãžã€ãœã·ã¢ããŒãã¡ãã«ã·ã¯ããããµã³ãïŒïŒ
ïŒâãžã€ãœã·ã¢ããŒãã¡ãã«ã·ã¯ããããµã³ã
ïŒïŒ4â²âãžã€ãœã·ã¢ããŒããžã·ã¯ããããµã³ã
ïŒïŒ4â²âãžã€ãœã·ã¢ããŒãã·ã¯ãããã·ã«ã¡ã¿
ã³ãã€ãœããã³ãžã€ãœã·ã¢ããŒãçãæãããã
ãããã®åç¬åã¯ïŒçš®ä»¥äžã®æ··åç©ãšããŠäœ¿çšã§
ãããå該ã€ãœã·ã¢ããŒããããªãªãŒã«çã§å€æ§
ãããžã€ãœã·ã¢ããŒãé¡ãåæ§ã«äœ¿çšããããšã
ã§ããã æ¬çºæã«çšãããããžããããã·ååç©ãšããŠ
ã¯ãããªãšã¹ãã«ãžãªãŒã«ãããªãšãŒãã«ãžãªãŒ
ã«åã³çéã®ã°ãªã³ãŒã«é¡ãçšããããããªãšã¹
ãã«ãžãªãŒã«ãšããŠã¯ãå ·äœçã«ã¯äŸãã°ã³ãã¯
é žãã¢ãžãã³é žãã»ãã·ã³é žãã¢ãŒã©ã€ã³é žçã®
èèªæãžã«ã«ãã³é žããã¬ãã¿ã«é žãã€ãœãã¿ã«
é žçã®è³éŠæãžã«ã«ãã³é žåã¯ãããã®äœçŽã¢ã«
ã³ãŒã«ãšã¹ãã«ãšããšãã¬ã³ã°ãªã³ãŒã«ãïŒïŒïŒ
âãããã¬ã³ã°ãªã³ãŒã«ãïŒïŒïŒâããã¬ã³ã°ãª
ã³ãŒã«ãïŒïŒïŒâãããµã³ã°ãªã³ãŒã«ããžãšãã¬
ã³ã°ãªã³ãŒã«ãããªãã³ãã«ã°ãªã³ãŒã«ãããã¯
ãã¹ããšããŒã«ïŒ¡ã®ãšãã¬ã³ãªããµã€ãä»å ç©ç
åã¯ãããã®æ··åç©ãšãåå¿ããŠåŸãããããªãš
ã¹ãã«ãžãªãŒã«é¡åã¯Îµâã«ããã©ã¯ãã³çã®ã©
ã¯ãã³é¡ãéç°éåããŠåŸãããã©ã¯ãã³ç³»ã®ã
ãªãšã¹ãã«ãžãªãŒã«é¡çãæãããããããªãšãŒ
ãã«ãžãªãŒã«ãšããŠã¯ãäŸãã°ããªãšãã¬ã³ã°ãª
ã³ãŒã«ãããªãããã¬ã³ãšãŒãã«ã°ãªã³ãŒã«ãã
ãªããã©ã¡ãã¬ã³ãšãŒãã«ã°ãªã³ãŒã«çã®ããªã¢
ã«ãã¬ã³ãšãŒãã«ã°ãªã³ãŒã«é¡åã¯ãããã®å ±é
åããªãšãŒãã«ã°ãªã³ãŒã«é¡çãæããããã
åãããªãšãŒãã«ãšã¹ãã«ã°ãªã³ãŒã«ãšããŠã¯ã
äžèšããªã¢ã«ãã¬ã³ãšãŒãã«ã°ãªã³ãŒã«ãããªãª
ãŒã«æåãšããŠèèªæåã¯è³éŠæãžã«ã«ãã³é žãš
åå¿ãããŠåŸãããããªãšã¹ãã«ã°ãªã³ãŒã«é¡ã
æããããçéã°ãªã³ãŒã«é¡ãšããŠããªãšã¹ãã«
ãžãªãŒã«ã®åæãšããŠæããã°ãªã³ãŒã«é¡ã䜿çš
ã§ããã åãæ¬çºæã«æŒããææ©ãžã€ãœã·ã¢ããŒããšå
å¿ããŠãŠã¬ã¢çµåãçæãããååç©ãšããŠã¯ã
æ°Žã®ä»ã«ãææ©ãžã¢ãã³ã䜵çšããããšãã§ã
ããææ©ãžã¢ãã³ãšããŠã¯ãããã©ã¡ãã¬ã³ãžã¢
ãã³ããããµã¡ãã¬ã³ãžã¢ãã³ãªã©ã®èèªæãžã¢
ãã³ãïœâããšãã¬ã³ãžã¢ãã³ãâããšãã¬ã³
ãžã¢ãã³ãïŒïŒïŒâããªã¬ã³ãžã¢ãã³ãïŒïŒïŒâ
ããªã¬ã³ãžã¢ãã³ãïŒïŒ4â²âãããšãã¬ã³ãžã¢ã
ã³ãïŒïŒïŒâããã¿ã¬ã³ãžã¢ãã³çã®è³éŠæãžã¢
ãã³ãïŒïŒïŒâãžã¢ãã³ã¡ãã«ã·ã¯ããããµã
ã³ãïŒïŒïŒâãžã¢ããã»ã¡ãã«ã·ã¯ããããµã
ã³ãïŒïŒ4â²âãžã¢ãããžã·ã¯ãããã·ã«ã¡ã¿ã³ã
ã€ãœããã³ãžã¢ãã³çã®èç°æãžã¢ãã³çãæã
ãããã æ°Žã¯ãã€ãœã·ã¢ããŒãåºãšåå¿ããŠåŒ(1)ã«ç€ºã
ããšãã¢ããåºãçæããã âNCOïŒH2OââNH2ïŒCO2 (1) æŽã«ãæ¬çºæã«æŒããCOOMåºïŒïŒã¯æ°ŽçŽ å
ã¯ã¢ã«ã«ãªéå±ïŒåã³ïŒåã¯SO3Mâ²åºïŒMâ²ã¯ã¢
ã«ã«ãªéå±ïŒçã®èŠªæ°Žæ§æ¥µæ§åºãããªãŠã¬ã¿ã³â
ãŠã¬ã¢æš¹èã«å°å ¥ãã芪氎æ§æ¥µæ§åºå«æååç©ãš
ããŠã¯ããžããããã·ååç©ããžã¢ãã³ååç©ç
ã®ãããã§ãããããäŸãã°SO3Mâ²åºããžãã
ããã·ååç©ãšããŠå°å ¥ãããªãã°ãäŸãã°ã
ãåŒããã
Râ²ã¯CoH2oïŒïœïŒïŒãïŒïŒãåã¯
ãåŒãïŒïœãïœã¯ïŒã
20ïŒãMâ²ã¯ã¢ã«ã«ãªéå±ãã§ç€ºãããSO3Mâ²åºå«
æã°ãªã³ãŒã«ãçéãžãªãŒã«ãšããŠçšããããã
ãªãšã¹ãã«ãžãªãŒã«ã®åæã°ãªã³ãŒã«åã¯ããªãš
ãŒãã«ãžãªãŒã«åã¯ããªã«ããã©ã¯ãã³ãžãªãŒã«
ã®éå§å€ãšããŠçšããããšã«ããããªãšã¹ãã«ãž
ãªãŒã«åã¯ããªãšãŒãã«ãžãªãŒã«åã¯ããªã«ãã
ã©ã¯ãã³ãžãªãŒã«ã«èŠªæ°Žæ§æ¥µæ§åºãå°å ¥ãããã
ãšãå¯èœã§ããã åä»ã®å°å ¥æ³ãšããŠããªãšã¹ãã«ãžãªãŒã«ã®é ž
æåãšããŠSO3Mâ²åºãæããïŒâãããªãŠã ã¹
ã«ãã€ãœãã¿ã«é žãïŒâã«ãªãŠã ã¹ã«ãã€ãœãã¿
ã«é žãïŒâãããªãŠã ã¹ã«ãã€ãœãã¿ã«é žãïŒâ
ã«ãªãŠã ã¹ã«ãã€ãœãã¿ã«é žããããªãŠã ã¹ã«ã
ã³ãã¯é žçãçšããããšãå¯èœã§ããã åãSO3Mâ²åºïŒMâ²ã¯ã¢ã«ã«ãªéå±ïŒãæãã
ãžã¢ãã³ååç©ãšããŠã¯ããžã¢ãããã«ãšã³ã¹ã«
ãã³é žéå±å¡©ããããã¬ã³ãžã¢ãã³ã¹ã«ãã³é žé
å±å¡©çããããé延é·å€ãšããŠäœ¿çšããããšã«ã
ãSO3Mâ²åºãå°å ¥ããããšãã§ããã åæ§ã«COOMã¯ãäŸãã°ãžã¡ãããŒã«ããã
ãªã³é ž
æã°ãªã³ãŒã«ãçéãžãªãŒã«ãšããŠçšããããã
ãªãšã¹ãã«ãžãªãŒã«ã®åæã°ãªã³ãŒã«åã¯ããªãš
ãŒãã«ãžãªãŒã«åã¯ããªã«ããã©ã¯ãã³ãžãªãŒã«
ã®éå§å€ãšããŠçšããããšã«ããããªãšã¹ãã«ãž
ãªãŒã«åã¯ããªãšãŒãã«ãžãªãŒã«åã¯ããªã«ãã
ã©ã¯ãã³ãžãªãŒã«ã«èŠªæ°Žæ§æ¥µæ§åºãå°å ¥ãããã
ãšãå¯èœã§ããã åä»ã®å°å ¥æ³ãšããŠããªãšã¹ãã«ãžãªãŒã«ã®é ž
æåãšããŠSO3Mâ²åºãæããïŒâãããªãŠã ã¹
ã«ãã€ãœãã¿ã«é žãïŒâã«ãªãŠã ã¹ã«ãã€ãœãã¿
ã«é žãïŒâãããªãŠã ã¹ã«ãã€ãœãã¿ã«é žãïŒâ
ã«ãªãŠã ã¹ã«ãã€ãœãã¿ã«é žããããªãŠã ã¹ã«ã
ã³ãã¯é žçãçšããããšãå¯èœã§ããã åãSO3Mâ²åºïŒMâ²ã¯ã¢ã«ã«ãªéå±ïŒãæãã
ãžã¢ãã³ååç©ãšããŠã¯ããžã¢ãããã«ãšã³ã¹ã«
ãã³é žéå±å¡©ããããã¬ã³ãžã¢ãã³ã¹ã«ãã³é žé
å±å¡©çããããé延é·å€ãšããŠäœ¿çšããããšã«ã
ãSO3Mâ²åºãå°å ¥ããããšãã§ããã åæ§ã«COOMã¯ãäŸãã°ãžã¡ãããŒã«ããã
ãªã³é ž
ãåŒããçéãžãªãŒã«ãš
ããŠçšãããåã¯SO3Mâ²åºå°å
¥ãšåæ§ã®åœ¢ã§ã
ãªãšã¹ãã«ãžãªãŒã«ãããªãšãŒãã«ãžãªãŒã«ãã
ãªã«ããã©ã¯ãã³ãžãªãŒã«ã®æ§é äžã«COOMåº
ãå°å ¥ãããããšãå¯èœã§ããã ãããã®ååç©ã«æŒããã¢ã«ã«ãªéå±ãšããŠ
ã¯ãã«ãªãŠã ããããªãŠã çã奜ãŸããã ãããããªãŠã¬ã¿ã³âãŠã¬ã¢æš¹èã®è£œé ã¯ã溶
èç¶æ ã§åå¿ããã溶èéåãã¡ãã«ãšãã«ã±ã
ã³ããã«ãšã³ãã·ã¯ããããµãã³ããžã¡ãã«ãã«
ã ã¢ãããããã©ããããã©ã³çã®åç¬åã¯æ··å
溶å€çã®äžæŽ»æ§æº¶å€ã«åèšèšèŒã®ååæã溶解ã
ãããŠè¡ã溶液éåçãããã åå¿ã«éãã觊åªãšããŠææ©éå±ååç©ãäŸã
ã°ããžããã«é«ãžã©ãŠã¬ãŒãããããã¯äžçŽã¢ã
ã³äŸãã°ïŒ®âã¡ãã«ã¢ã«ããªãªã³ãããªãšãã«ã¢
ãã³çãæ·»å ããŠãè¯ããåæš¹èã®å®å®æ§çãå¢
ãããã«ãé žåé²æ¢å€ã玫å€ç·åžåå€ãå æ°Žå解
é²æ¢å€çãæ·»å ããŠãããã ãã®ããã«ããŠåŸãããããªãŠã¬ã¿ã³âãŠã¬ã¢
æš¹èã«æŒãããŠã¬ã¿ã³åºæ¿åºŠã¯æº¶è§£æ§ã«å¯ŸããŠå€§
ãã圱é¿ããææ©ãžã€ãœã·ã¢ããŒãã®çš®é¡ããžã
ãããã·ååç©ã®çš®é¡ãååéãçã«ãã€ãŠç°ãª
ãã®ã§äžæŠã«ã¯äºããªãããŠã¬ã¿ã³åºæ¿åºŠçŽ2.0
ïœmolïŒïœä»¥äžã§ã¯ã±ãã³ç³»ããšã¹ãã«ç³»ãè³éŠ
æ系溶å€çã«ã¯æº¶è§£ãå°é£ãšãªãåŸåã瀺ããã
ãã®ç³»ã§äŸãã°ãŠã¬ã¿ã³çµåæ¿åºŠ2.0ïœmolïŒïœ
ã«åºå®ãããŠã¬ã¢çµåæ¿åºŠãå¢å ãããŠãé©ãã¹
ãããšã«æº¶è§£æ§ã¯äœäžããããšãªããæŽã«ã€ã³ã°
çãè»åç¹çã®ç©çç¹æ§ãåäžãããããšãã§ã
ãã ç¹ã«æ°Žãé延é·å€ãšããŠçšããå Žåãã®å¹æã
èããã åããŠã¬ã¿ã³çµåããåéãšãã«ã®ãŒã®å€§ãã
ãŠã¬ã¢çµåå°å ¥ã«ãããŠã¬ã¢çµåãå«ãŸãªãåŸæ¥
ã®ãŠã¬ã¿ã³ç³»ãã硬ã匷éãªãã€ã«ã ãåŸãããš
ãã§ãããåãŠã¬ã¢çµåã¯åŒ±ã芪氎æ§åºã§ããã
ã®ã§ãåæ£æ§åäžã«ãå¯äžããCOOMåºã
SO3Mâ²åºç芪氎æ§æ¥µæ§åºãšã®åæååšã¯åæ£æ§
ã«æŒãŠæŽã«å¥œãŸããå¹æã瀺ããŠããããšãèªã
ãããããã®æé©ãªãŠã¬ã¢çµåæ¿åºŠã¯ãããªãªãŒ
ã«ã®ååéã«ãã€ãŠç°ãªãäžæŠã«ã¯èŠå®ã§ããªã
ãããŠã¬ã¢åºçµåãå€ããããšçæããããªãŠã¬
ã¿ã³âãŠã¬ã¢æš¹èã¯ãçµåå€ãšããŠèŠæ±ãããæ
è»æ§ã«æ¬ ããããã«ãªããããã®äžéã¯2.0ïœ
molïŒïœã«èšå®ããããšã奜ãŸãããéã«ãŠã¬ã¢
çµåãå°ãªãå ŽåãåŸæ¥ã®ãŠã¬ã¿ã³æš¹èåæ§è»å
ç¹ãäœããªãããã€è¡šé¢å¹³æ»æ§ãæªãèãããã
ã³ã°æ§ã®æ¹è¯ãã§ãããã®äžéãšããŠ0.1ïœ
molïŒïœã«èšå®ããããšã奜ãŸããã åããªãŠã¬ã¿ã³âãŠã¬ã¢æš¹èã®ååéã¯èä¹
æ§ãæäœæ§ã®é¢ãã5000ã100000奜ãŸããã¯8000
ã50000ãè¯ã5000以äžã§ã¯å¡æç²åºŠãäœãã®ã§
é«åºåœ¢ååã§ããå©ç¹ãããããç©çç¹æ§ãæªã
èä¹ æ§ãæªããªããéã«100000以äžã§ã¯èä¹ æ§ã¯
è¯ãããå¡æåæã«é«ç²åºŠãšãªãåæ£ã«é·æéã
èŠãããã€å¡å·¥æå å·¥æ§ãæªãè¡šé¢å¹³æ»æ§ãåäž
ã§ããªãã æŽã«ãæ¬çºæã®çµåå€ã«å°å ¥ãã芪氎æ§æ¥µæ§åº
ã§ããCOOMåºåã³ïŒåã¯SO3Mâ²åºã®å«æéã¯ã
çŽ0.01ãªãã1.0ïœmolïŒïœãé©åœã§ããããã奜
ãŸããã¯0.02ãªãã0.5ïœmolïŒïœã®ç¯å²ã§ããã
芪氎æ§æ¥µæ§åºæ¿åºŠã0.01ïœmolïŒïœæªæºã§ãããš
åæ£æ§ã«å åãªå¹æãèªããããªããªãã åäžèšèŠªæ°Žæ§æ¥µæ§åºæ¿åºŠã1.0ïœmolïŒïœãè¶
ãããšååéãããã¯ååå ã§åéãèµ·ãæãç£
æ§å¡æã®ç²åºŠãé«ããªã€ããããããã¯åéãã
éã«åæ£ã«æªåœ±é¿ãåãŒãã°ãããã溶å€ãžã®æº¶
解æ§ãäœäžããŠéåžžçšãããã溶å€ã«æº¶è§£ããªã
ãªãçµåå€ãšããŠã®çšéã§ã¯äœ¿ããªããªã€ããã
ããåã¯ã芪氎æ§æ¥µæ§åºæ¿åºŠãåè¿°ã®äžéããã
ãçµåå€ã§ç£æ§å±€ã圢æãããå Žåäœãã«èŠªæ°Žæ§
ã匷ãããè湿æ§ãäœäžãé·æä¿ååã¯é«æž©é«æ¹¿
äžã§ã®å£åãæ¿ããç£æ°èšé²åªäœãšããŠäžé©åœã§
ããã åäžèšããªãŠã¬ã¿ã³âãŠã¬ã¢æš¹èã¯ä»ã®ç±å¯å¡
æ§æš¹èãç±ç¡¬åæ§æš¹èãããã¯åå¿æ§æš¹èãšçµã¿
åããŠäœ¿çšããããšãã§ããããã®å Žåç£æ§å±€ã®
å šçµåå€ã«å¯ŸãããªãŠã¬ã¿ã³âãŠã¬ã¢æš¹èã®é å
å²åã¯ïŒééïŒ ä»¥äžã§ããã®ã奜ãŸãããå šçµå
å€ã«å¯ŸããããªãŠã¬ã¿ã³âãŠã¬ã¢æš¹èã®é åå²å
ãïŒééïŒ æªæºã§ãããšç£æ°èšé²åªäœã®èããã
ãã³ã°æ§ã®æ¹åã¯æ®ãã©æåŸ ã§ããªããäžè¿°ãã
ç±å¯å¡æ§æš¹èãšããŠã¯ãå¡©åããã«âé ¢é žããã«
ç³»å ±éåäœãå¡©åããã«âå¡©åãããªãã³å ±éå
äœãå¡©åããã«âã¢ã¯ãªããããªã«å ±éåäœãã¢
ã¯ãªã«é žãšã¹ãã«âã¢ã¯ãªããããªã«å ±éåäœã
ç±å¯å¡æ§ããªãŠã¬ã¿ã³ãšã©ã¹ãããŒãããªããå
ããã«ãå¡©åãããªãã³âã¢ã¯ãªããããªã«å ±é
åäœããã¿ãžãšã³âã¢ã¯ãªããããªã«å ±éåäœã
ããªã¢ããæš¹èãããªããã«ããã©ãŒã«ãã»ã«ã
ãŒã¹èªå°äœãããªãšã¹ãã«æš¹èãããªãã¿ãžãšã³
çã®åæãŽã ç³»ã®ç±å¯å¡æ§æš¹èçãæããããã
åãç±ç¡¬åæ§æš¹èãããã¯åå¿æ§æš¹èãšããŠã¯äŸ
ãã°ãããšããŒã«æš¹èããšããã·æš¹èãããªãŠã¬
ã¿ã³ç¡¬ååæš¹èãã¡ã©ãã³æš¹èãã¢ã«ãããæš¹
èãã·ãªã³ã³æš¹èãã¢ã¯ãªã«ç³»åå¿æš¹èããšãã
ã·âããªã¢ããæš¹èããããã»ã«ããŒã¹âã¡ã©ã
ã³æš¹èãé«ååéããªãšã¹ãã«æš¹èãšã€ãœã·ã¢ã
ãŒããã¬ããªããŒã®æ··åç©ãã¡ã¿ã¯ãªã«é žå¡©å ±é
åäœãšãžã€ãœã·ã¢ããŒããã¬ããªããŒã®æ··åç©ã
ããªãšã¹ãã«ããªãªãŒã«ãšããªã€ãœã·ã¢ããŒãã®
æ··åç©ãå°¿çŽ ãã«ã ã¢ã«ãããæš¹èãäœååéã°
ãªã³ãŒã«ïŒé«ååéãžãªãŒã«ïŒããªããšãã«ã¡ã¿
ã³ããªã€ãœã·ã¢ããŒãã®æ··åç©ãããªã¢ãã³æš¹è
åã³ãããã®æ··åç©çãæããããã äžè¿°ã®çµåå€ã«åŒ·ç£æ§ç²æ«ãåæ£ãææ©æº¶å€ã«
溶解ããŠéç£æ§æ¯æäœäžã«å¡åžããããšã«ããç£
æ§å±€ã圢æãããã ããã«äžèšç£æ§å±€ã«ã¯ãåèšã®çµåå€ãç£æ§ç²
ã®ä»ã«æ·»å å€ãšããŠåæ£å€ã最æ»å€ãç 磚å€ã垯
é»é²æ¢å€ãé²éå€çãå ããããŠãããã äžèšåæ£å€ïŒé¡æ湿最å€ïŒãšããŠã¯ãã«ããªã«
æ®ãã«ããªã³é žãã©ãŠãªã³é žãããªã¹ãã³é žãã
ã«ããã³é žãã¹ãã¢ãªã³é žããªã¬ã€ã³é žããªããŒ
ã«é žããªãã¬ã³é žãçã®ççŽ æ°12ã18åã®èèªé ž
ïŒR1COOHãR1ã¯ççŽ æ°11ã17åã®ã¢ã«ãã«ãŸã
ã¯ã¢ã«ã±ãã«åºïŒãåèšã®èèªé žã®ã¢ã«ã«ãªéå±
ïŒLiãNaãçïŒãŸãã¯ã¢ã«ã«ãªåé¡éå±ïŒMgã
CaãBaïŒããæãéå±ç³é¹žãåèšã®èèªé žãšã¹
ãã«ã®åŒçŽ ãå«æããååç©ãåèšã®èèªé žã®ã¢
ãããããªã¢ã«ãã¬ã³ãªããµã€ãã¢ã«ãã«ãªã³é ž
ãšã¹ãã«ãããªã¢ã«ãã«ããªãªã¬ãã€ã³ãªãã·ç¬¬
åã¢ã³ã¢ããŠã å¡©ïŒã¢ã«ãã«ã¯ççŽ æ°ïŒãïŒåã
ãªã¬ãã€ã³ã¯ãšãã¬ã³ããããã¬ã³ãªã©ïŒãçã
䜿çšãããããã®ä»ã«ççŽ æ°12以äžã®é«çŽã¢ã«ã³
ãŒã«ãåã³ãããã®ä»ã«ç¡«é žãšã¹ãã«çã䜿çšå¯
èœã§ããããããã®åæ£å€ã¯ç£æ§ç²100éééšã«
察ããŠ0.5ã10éééšã®ç¯å²ã§æ·»å ãããã äžèšæœ€æ»å€ãšããŠã¯ããžã¢ã«ãã«ããªã·ãããµ
ã³ïŒã¢ã«ãã«ã¯ççŽ æ°ïŒãïŒåïŒããžã¢ã«ã³ãã·
ããªã·ãããµã³ïŒã¢ã«ã³ãã·ã¯ççŽ æ°ïŒãïŒåïŒã
ã¢ãã¢ã«ãã«ã¢ãã¢ã«ã³ãã·ããªã·ãããµã³ïŒã¢
ã«ãã«ã¯ççŽ æ°ïŒãïŒåãã¢ã«ã³ãã·ã¯ççŽ æ°ïŒ
ãïŒåïŒãããšãã«ããªã·ãããµã³ããããã¢ã«
ãã«ããªã·ãããµã³ïŒã¢ã«ãã«ã¯ççŽ æ°ïŒãïŒ
åïŒãªã©ã®ã·ãªã³ã³ãªã€ã«ãã°ã©ãã¢ã€ããªã©ã®
å°é»æ§åŸ®ç²æ«ãäºç¡«åã¢ãªããã³ãäºç¡«åã¿ã³ã°
ã¹ãã³çã®ç¡æ©åŸ®ç²æ«ãããªããã©ãã«ãªããšã
ã¬ã³çã®ãã©ã¹ããã¯åŸ®ç²æ«ãαâãªã¬ãã€ã³é
åç©ãåžžæž©ã§æ¶²ç¶ã®äžé£œåèèªæçåæ°ŽçŽ ãççŽ
æ°12ã20åã®äžå¡©åºæ§èèªé žãšççŽ æ°ïŒã12åã®
äžäŸ¡ã®ã¢ã«ã³ãŒã«ããæãèèªé žãšã¹ãã«é¡ãã
ã«ãªãã«ãŒãã³ã³é¡çã䜿çšã§ããã ãããã®æœ€æ»å€ã¯ãç£æ§ç²100éééšã«å¯ŸããŠ
0.2ã10éééšã®æå²ã§æ·»å ããããäžèšç 磚å€
ãšããŠã¯ãäžè¬ã«äœ¿çšãããææã§æº¶èã¢ã«ã
ããçåã±ã€çŽ ãé žåã¯ãã ïŒCr2O3ïŒãã³ã©ã³
ãã ã人é ã³ã©ã³ãã ããã€ã€ã¢ã³ãã人é ãã€
ã€ã¢ã³ããã¶ã¯ãç³ããšã¡ãªãŒïŒäž»æåïŒã³ã©ã³
ãã ãšéé±ç²ïŒçã䜿çšãããããããã®ç 磚å€
ã¯ç£æ§ç²100éééšã«å¯ŸããŠ0.5ã20éééšã®ç¯å²
ã§æ·»å ãããã äžèšåž¯é»é²æ¢å€ãšããŠã¯ãã«ãŒãã³ãã©ãã¯ã
ã«ãŒãã³ãã©ãã¯ã°ã©ããããªããŒçã®å°é»æ§åŸ®
ç²æ«ããµããã³ãªã©ã®å€©ç¶çé¢æŽ»æ§å€ãã¢ã«ãã¬
ã³ãªããµã€ãç³»ãã°ãªã»ãªã³ç³»ãã°ãªã·ããŒã«ç³»
ãªã©ã®ãããªã³çé¢æŽ»æ§å€ãé«çŽã¢ã«ãã«ã¢ãã³
é¡ã第åçŽã¢ã³ã¢ããŠã å¡©é¡ãããªãžã³ãã®ä»ã®
è€çŽ ç°é¡ããã¹ãããŠã é¡ãªã©ã®ã«ããªã³çé¢æŽ»
æ§å€ãã«ã«ãã³é¡ãã¹ã«ãã³é¡ããªã³é žãç¡«é žãš
ã¹ãã«åºããªã³é žãšã¹ãã«åºçã®é žæ§åºãå«ãã¢
ããªã³çé¢æŽ»æ§å€ãã¢ããé žé¡ãã¢ããã¹ã«ãã³
é žé¡ãã¢ããã¢ã«ã³ãŒã«ã®ç¡«é žãŸãã¯ãªã³é žãšã¹
ãã«é¡çã®äž¡æ§æŽ»æ§å€ãªã©ã䜿çšããããäžèšã®
å°é»ç¶åŸ®ç²æ«ã¯ç£æ§ç²100éééšã«å¯ŸããŠ0.2ã20
éééšããçé¢æŽ»æ§å€ã¯0.1ã20éééšã®ç¯å²ã§
æ·»å ãããããããã®çé¢æŽ»æ§å€ã¯åç¬ãŸãã¯æ··
åããŠæ·»å ããŠãããããããã¯åž¯é»é²æ¢å€ãšã
ãŠçšãããããã®ã§ããããæãšããŠãã®ä»ã®ç®
çãäŸãã°åæ£ãç£æ°ç¹æ§ã®æ¹è¯ã最æ»æ§ã®æ¹
è¯ãå¡åžå©å€ãšããŠé©çšãããå Žåãããã äžèšé²éå€ãšããŠã¯ããªã³é žãã¹ã«ãã¢ããã
ã°ã¢ããžã³ãããªãžã³ãã¢ãã³ãå°¿çŽ ããžã³ã¯ã¯
ãã¡ãŒããã«ã«ã·ãŠã ã¯ãã¡ãŒããã¹ããã³ããŠ
ã ã¯ãã¡ãŒãçã䜿çšã§ããã ãããã®é²éå€ã¯ç£æ§ç²100éééšã«å¯ŸããŠ
0.01ã2.0éééšã®ç¯å²ã§äœ¿çšãããã åãç£æ§å±€ã®æ§æææã¯ææ©æº¶å€ã«æº¶ãããŠç£
æ§å¡æã調補ãããããéç£æ§æ¯æäœäžã«å¡åžã
ããããã®ç£æ§å¡æã®æº¶å€ãšããŠã¯ã¢ã»ãã³ãã¡
ãã«ãšãã«ã±ãã³ãã¡ãã«ã€ãœããã«ã±ãã³ãã·
ã¯ããããµãã³çã®ã±ãã³ç³»ãé ¢é žã¡ãã«ãé ¢é ž
ãšãã«ãé ¢é žããã«ãä¹³é žãšãã«ãé ¢é žã°ãªã³ãŒ
ã«ã¢ããšãã«ãšãŒãã«çã®ãšã¹ãã«ç³»ãã°ãªã³ãŒ
ã«ãžã¡ãã«ãšãŒãã«ãã°ãªã³ãŒã«ã¢ããšãã«ãšãŒ
ãã«ããžãªããµã³çã®ã°ãªã³ãŒã«ãšãŒãã«ç³»ãã
ã³ãŒã³ããã«ãšã³ããã·ã¬ã³çã®è³éŠæçåæ°Ž
çŽ ããããµã³ãããã¿ã³çã®èèªæçåæ°ŽçŽ ãã¡
ãã¬ã³ã¯ãã©ã€ãããšãã¬ã³ã¯ãã©ã€ããåå¡©å
ççŽ ãã¯ãããã«ã ããšãã¬ã³ã¯ãã«ãããªã³ã
ãžã¯ãã«ãã³ãŒã³çã®å¡©çŽ åçåæ°ŽçŽ çãæãã
ããã åãäžè¿°ããããªãŠã¬ã¿ã³âãŠã¬ã¢æš¹èã«ããª
ã€ãœã·ã¢ããŒãååç©ã硬åå€ãšããŠäœµçšããå Ž
åã«æŒãŠã¯ãèæ©èæ§ã®åªããç£æ°èšé²åªäœãåŸ
ãããšãã§ããã å°ã硬åå€ãšããŠçšããããããªã€ãœã·ã¢ããŒ
ãååç©ãšããŠã¯ãäŸãã°ã³ãããŒããã³ãã
ãŒãHLãã³ãããŒãEHãã³ãããŒã2030ãã³
ãããŒã3030ãã³ãããŒã4048ãã³ãããŒã
4190ãã³ãããŒã4192ïŒããããæ¥æ¬ããªãŠã¬ã¿
ã³å·¥æ¥è£œïŒçã§ããã°ãããã䜿çšã§ããã åããã®ããªã€ãœã·ã¢ããŒãååç©ã®éã«ããŠ
ãé垞䜿çšãããŠããéã§ããã°ãããããªãŠã¬
ã¿ã³âãŠã¬ã¢æš¹èãšä»æš¹èãšã®ç·é100éééšã«
察ããŠïŒã30éééšïŒåã åºåœ¢åæç®ïŒã®ç¯å²å
ã§ããã åãéç£æ§æ¯æäœã®çŽ æãšããŠã¯ããªãšãã¬ã³
ãã¬ãã¿ã¬ãŒããããªãšãã¬ã³âïŒïŒïŒâããã¿
ã¬ãŒãçã®ããªãšã¹ãã«é¡ãããªãšãã¬ã³ãããª
ãããã¬ã³çã®ããªãªã¬ãã€ã³é¡ãã»ã«ããŒã¹ã
ãªã¢ã»ããŒããã»ã«ããŒã¹ãã€ã¢ã»ããŒããã»ã«
ããŒã¹ã¢ã»ããŒãããã¬ãŒããã»ã«ããŒã¹ã¢ã»ã
ãŒãããããªããŒãçã®ã»ã«ããŒã¹èªå°äœãããª
å¡©åããã«ãããªå¡©åãããªãã³çã®ããã«ç³»æš¹
èãããªã«ãŒãããŒããããªã€ãããããªã¢ãã
ã€ããçã®ãã©ã¹ããã¯ã®ä»ã«çšéã«å¿ããŠã¢ã«
ãããŠã ãé ãã¹ãºãæªéãŸãã¯ããããå«ãé
ç£æ§åéãªã©ã®éç£æ§éå±é¡ãã¬ã©ã¹ãé¶åšãç£
åšãªã©ã®ã»ã©ããã¯é¡ãçŽããã©ã€ã¿åã¯ããªãš
ãã¬ã³ãããªãããã¬ã³ããšãã¬ã³âããã³å ±é
åäœãªã©ã®ççŽ æ°ïŒã10ã®Î±âããªãªã¬ãã€ã³é¡
ãå¡åžãŸãã¯ã©ãããŒãããçŽãªã©ã®çŽé¡ã䜿çš
ã§ãããåéç£æ§æ¯æäœã®åœ¢æ ã¯ãã€ã«ã ãããŒ
ããã·ãŒãããã€ã¹ã¯ãã«ãŒãããã©ã çããã
ã§ãè¯ãã æ¬çºæã«ããçµåå€ãçšããããšã«ãããç£æ§
ç²ã®åæ£æ§ãåäžããè§åæ¯Rsã飜åç£æå¯åºŠ
Bmçã®ç£æ°ç¹æ§ãåªãããã®ãšãªããåç£æ§å±€
ã®èä¹ æ§ãåäžããããšãã§ããã¹ãã«æéãç²
èœã¡ã«èµ·å ããã¬ãã«å€ååºåæžè¡°çã®ç¹æ§ãæ¹
åãããæŽã«ç£æ§å±€ã®è¡šé¢å¹³æ»æ§ãåäžã§ããã®
ã§é»ç£å€æç¹æ§ãäŸãã°åšæ³¢æ°ç¹æ§ãïŒïŒ®æ¯ç
ã®ç¹æ§ãæ¹åããããšãã§ããã 以äžå®æœäŸã«ããæŽã«è©³çŽ°ã«èª¬æããã å®æœäŸã«æŒãããéšãåã³ãïŒ ãã¯ããšããã®
ãªãéããéééšãåã³ãééïŒ ãã§ããã 芪氎æ§æ¥µæ§åºå«æããªãšã¹ãã«ããªãªãŒã«ã®è£œé å®æœäŸ ïŒ æž©åºŠèšãæ¹ææ©åã³ã³ã³ãã³ãµãŒãåããåå¿
åšã«ã¢ãžãã³é ž484éšãïŒïŒïŒâãããµã³ã°ãªã³
ãŒã«459éšãSO3Naåºå«æååç©1)176éšã觊åªãš
ããŠé ¢é žäºé0.3éšãé ¢é žãããªãŠã 0.04éšãå
ã140âã220âã§åžžå§ãšã¹ãã«ååå¿ãé²ããæ
å®åå¿çã«éãããåå¿ç³»ã100mmHgïŒ30åã®é
床ã§æžå§ããïŒæéåŸ20mmHgãŸã§æžå§ãããã®
ç空床ã§ïŒæéä¿æããšã¹ãã«ååå¿ãé²ã
SO3Mâ²åºãå«æããããªãšã¹ãã«ããªãªãŒã«ã
åŸããåŸãããããªãªãŒã«ã¯äžèšã®éãã æ°Žé žåºäŸ¡ 102ãé žäŸ¡ 0.6ã SO3Naåºæ¿åºŠ 0.42ïœmolïŒïœ å®æœäŸ ïŒ å®æœäŸïŒãšåæ§ã®åå¿åšã«ãããªãã³ãã«ã°ãª
ã³ãŒã«216éšãïŒïŒïŒâããã¬ã³ã°ãªã³ãŒã«78éšã
ïŒïŒïŒâãããµã³ã°ãªã³ãŒã«245éšããããªãŠã
ã¹ã«ãã³ãã¯é žãžã¡ãã«165éšåã³è§ŠåªãšããŠé ¢
é žäºé0.3éšãé ¢é žãããªãŠã 0.04éšãå ã140ã
180âã§è±ã¡ã¿ããŒã«ãšã¹ãã«äº€æåå¿ãè¡ãªã€
ãåŸãã¢ãžãã³é ž489éšãå ããŠ210ã240âã«æ
æž©ããŠè±æ°Žåå¿ã§ã®ããªãšã¹ãã«åããå®æœäŸïŒ
ãšåæ§ã®æžå§åå¿ãçµãŠSO3Naåºãå«æããã
ãªãšã¹ãã«ããªãªãŒã«ãåŸããåŸãããããªãªãŒ
ã«ã¯äžèšã®éãã æ°Žé žåºäŸ¡ 110ãé žäŸ¡ 0.8 SO3Naåºæ¿åºŠ 0.64ïœmolïŒïœ å®æœäŸ ïŒ å®æœäŸïŒãšåæ§ã®åå¿åšã«ãããªããã¬ã³ã¢ãž
ããŒãïŒååé2000ïŒïŒ2000éšãšãžã¡ãããŒã«ã
ãããªã³é ž134éšåã³ãšã¹ãã«äº€æ觊åªãšããŠã
ã¿ããŠã ã¢ã»ãã«ã¢ã»ããŒã0.3éšå ã140ã180
âã§ïŒæéå ç±æ¹æãåŽéã«COOHåºãå«æã
ãããªãšã¹ãã«ããªãªãŒã«ãåŸããåŸãããããª
ãªãŒã«ã¯äžèšã®éãã æ°Žé žåºäŸ¡ 106ãCOOHåºæ¿åºŠ 0.469ïœmolïŒïœ å®æœäŸ ïŒ å®æœäŸïŒã§åŸãCOOHåºå«æããªãšã¹ãã«ã
ãªãªãŒã«1000éšã«ãCOOHã®95ïŒ ãäžåããã«
å¿ èŠãªèæ§ãœãŒã10ïŒ æ°Žæº¶æ¶²ãå ããCOOHã
äžåããåŸ150âã20mmHgãïŒæéã®æ¡ä»¶ã§æžå§
è±æ°ŽãCOONaåºå«æããªãšã¹ãã«ããªãªãŒã«ã
åŸããåŸãããããªãªãŒã«ã¯äžèšã®éãã æ°Žé žäŸ¡åº 106 é žäŸ¡ 0.2 COONaåºæ¿åºŠ 0.445ïœmolïŒïœ å®æœäŸ ïŒãïŒ å®æœäŸïŒãšåæ§ã®åå¿åšã«ãè¡šïŒã«ç€ºãå²åã®
åæãçšãã觊åªãšããŠé ¢é žäºé0.05éšãé ¢é žã
ããªãŠã 0.007éšã䜿çšãå®æœäŸïŒãšåæ§ã®æ¹æ³
ã§ãšã¹ãã«ååå¿ãè¡ãè¡šïŒã«ç€ºãããªãšã¹ãã«
ããªãªãŒã«ãåŸãã
ãªãšã¹ãã«ãžãªãŒã«ãããªãšãŒãã«ãžãªãŒã«ãã
ãªã«ããã©ã¯ãã³ãžãªãŒã«ã®æ§é äžã«COOMåº
ãå°å ¥ãããããšãå¯èœã§ããã ãããã®ååç©ã«æŒããã¢ã«ã«ãªéå±ãšããŠ
ã¯ãã«ãªãŠã ããããªãŠã çã奜ãŸããã ãããããªãŠã¬ã¿ã³âãŠã¬ã¢æš¹èã®è£œé ã¯ã溶
èç¶æ ã§åå¿ããã溶èéåãã¡ãã«ãšãã«ã±ã
ã³ããã«ãšã³ãã·ã¯ããããµãã³ããžã¡ãã«ãã«
ã ã¢ãããããã©ããããã©ã³çã®åç¬åã¯æ··å
溶å€çã®äžæŽ»æ§æº¶å€ã«åèšèšèŒã®ååæã溶解ã
ãããŠè¡ã溶液éåçãããã åå¿ã«éãã觊åªãšããŠææ©éå±ååç©ãäŸã
ã°ããžããã«é«ãžã©ãŠã¬ãŒãããããã¯äžçŽã¢ã
ã³äŸãã°ïŒ®âã¡ãã«ã¢ã«ããªãªã³ãããªãšãã«ã¢
ãã³çãæ·»å ããŠãè¯ããåæš¹èã®å®å®æ§çãå¢
ãããã«ãé žåé²æ¢å€ã玫å€ç·åžåå€ãå æ°Žå解
é²æ¢å€çãæ·»å ããŠãããã ãã®ããã«ããŠåŸãããããªãŠã¬ã¿ã³âãŠã¬ã¢
æš¹èã«æŒãããŠã¬ã¿ã³åºæ¿åºŠã¯æº¶è§£æ§ã«å¯ŸããŠå€§
ãã圱é¿ããææ©ãžã€ãœã·ã¢ããŒãã®çš®é¡ããžã
ãããã·ååç©ã®çš®é¡ãååéãçã«ãã€ãŠç°ãª
ãã®ã§äžæŠã«ã¯äºããªãããŠã¬ã¿ã³åºæ¿åºŠçŽ2.0
ïœmolïŒïœä»¥äžã§ã¯ã±ãã³ç³»ããšã¹ãã«ç³»ãè³éŠ
æ系溶å€çã«ã¯æº¶è§£ãå°é£ãšãªãåŸåã瀺ããã
ãã®ç³»ã§äŸãã°ãŠã¬ã¿ã³çµåæ¿åºŠ2.0ïœmolïŒïœ
ã«åºå®ãããŠã¬ã¢çµåæ¿åºŠãå¢å ãããŠãé©ãã¹
ãããšã«æº¶è§£æ§ã¯äœäžããããšãªããæŽã«ã€ã³ã°
çãè»åç¹çã®ç©çç¹æ§ãåäžãããããšãã§ã
ãã ç¹ã«æ°Žãé延é·å€ãšããŠçšããå Žåãã®å¹æã
èããã åããŠã¬ã¿ã³çµåããåéãšãã«ã®ãŒã®å€§ãã
ãŠã¬ã¢çµåå°å ¥ã«ãããŠã¬ã¢çµåãå«ãŸãªãåŸæ¥
ã®ãŠã¬ã¿ã³ç³»ãã硬ã匷éãªãã€ã«ã ãåŸãããš
ãã§ãããåãŠã¬ã¢çµåã¯åŒ±ã芪氎æ§åºã§ããã
ã®ã§ãåæ£æ§åäžã«ãå¯äžããCOOMåºã
SO3Mâ²åºç芪氎æ§æ¥µæ§åºãšã®åæååšã¯åæ£æ§
ã«æŒãŠæŽã«å¥œãŸããå¹æã瀺ããŠããããšãèªã
ãããããã®æé©ãªãŠã¬ã¢çµåæ¿åºŠã¯ãããªãªãŒ
ã«ã®ååéã«ãã€ãŠç°ãªãäžæŠã«ã¯èŠå®ã§ããªã
ãããŠã¬ã¢åºçµåãå€ããããšçæããããªãŠã¬
ã¿ã³âãŠã¬ã¢æš¹èã¯ãçµåå€ãšããŠèŠæ±ãããæ
è»æ§ã«æ¬ ããããã«ãªããããã®äžéã¯2.0ïœ
molïŒïœã«èšå®ããããšã奜ãŸãããéã«ãŠã¬ã¢
çµåãå°ãªãå ŽåãåŸæ¥ã®ãŠã¬ã¿ã³æš¹èåæ§è»å
ç¹ãäœããªãããã€è¡šé¢å¹³æ»æ§ãæªãèãããã
ã³ã°æ§ã®æ¹è¯ãã§ãããã®äžéãšããŠ0.1ïœ
molïŒïœã«èšå®ããããšã奜ãŸããã åããªãŠã¬ã¿ã³âãŠã¬ã¢æš¹èã®ååéã¯èä¹
æ§ãæäœæ§ã®é¢ãã5000ã100000奜ãŸããã¯8000
ã50000ãè¯ã5000以äžã§ã¯å¡æç²åºŠãäœãã®ã§
é«åºåœ¢ååã§ããå©ç¹ãããããç©çç¹æ§ãæªã
èä¹ æ§ãæªããªããéã«100000以äžã§ã¯èä¹ æ§ã¯
è¯ãããå¡æåæã«é«ç²åºŠãšãªãåæ£ã«é·æéã
èŠãããã€å¡å·¥æå å·¥æ§ãæªãè¡šé¢å¹³æ»æ§ãåäž
ã§ããªãã æŽã«ãæ¬çºæã®çµåå€ã«å°å ¥ãã芪氎æ§æ¥µæ§åº
ã§ããCOOMåºåã³ïŒåã¯SO3Mâ²åºã®å«æéã¯ã
çŽ0.01ãªãã1.0ïœmolïŒïœãé©åœã§ããããã奜
ãŸããã¯0.02ãªãã0.5ïœmolïŒïœã®ç¯å²ã§ããã
芪氎æ§æ¥µæ§åºæ¿åºŠã0.01ïœmolïŒïœæªæºã§ãããš
åæ£æ§ã«å åãªå¹æãèªããããªããªãã åäžèšèŠªæ°Žæ§æ¥µæ§åºæ¿åºŠã1.0ïœmolïŒïœãè¶
ãããšååéãããã¯ååå ã§åéãèµ·ãæãç£
æ§å¡æã®ç²åºŠãé«ããªã€ããããããã¯åéãã
éã«åæ£ã«æªåœ±é¿ãåãŒãã°ãããã溶å€ãžã®æº¶
解æ§ãäœäžããŠéåžžçšãããã溶å€ã«æº¶è§£ããªã
ãªãçµåå€ãšããŠã®çšéã§ã¯äœ¿ããªããªã€ããã
ããåã¯ã芪氎æ§æ¥µæ§åºæ¿åºŠãåè¿°ã®äžéããã
ãçµåå€ã§ç£æ§å±€ã圢æãããå Žåäœãã«èŠªæ°Žæ§
ã匷ãããè湿æ§ãäœäžãé·æä¿ååã¯é«æž©é«æ¹¿
äžã§ã®å£åãæ¿ããç£æ°èšé²åªäœãšããŠäžé©åœã§
ããã åäžèšããªãŠã¬ã¿ã³âãŠã¬ã¢æš¹èã¯ä»ã®ç±å¯å¡
æ§æš¹èãç±ç¡¬åæ§æš¹èãããã¯åå¿æ§æš¹èãšçµã¿
åããŠäœ¿çšããããšãã§ããããã®å Žåç£æ§å±€ã®
å šçµåå€ã«å¯ŸãããªãŠã¬ã¿ã³âãŠã¬ã¢æš¹èã®é å
å²åã¯ïŒééïŒ ä»¥äžã§ããã®ã奜ãŸãããå šçµå
å€ã«å¯ŸããããªãŠã¬ã¿ã³âãŠã¬ã¢æš¹èã®é åå²å
ãïŒééïŒ æªæºã§ãããšç£æ°èšé²åªäœã®èããã
ãã³ã°æ§ã®æ¹åã¯æ®ãã©æåŸ ã§ããªããäžè¿°ãã
ç±å¯å¡æ§æš¹èãšããŠã¯ãå¡©åããã«âé ¢é žããã«
ç³»å ±éåäœãå¡©åããã«âå¡©åãããªãã³å ±éå
äœãå¡©åããã«âã¢ã¯ãªããããªã«å ±éåäœãã¢
ã¯ãªã«é žãšã¹ãã«âã¢ã¯ãªããããªã«å ±éåäœã
ç±å¯å¡æ§ããªãŠã¬ã¿ã³ãšã©ã¹ãããŒãããªããå
ããã«ãå¡©åãããªãã³âã¢ã¯ãªããããªã«å ±é
åäœããã¿ãžãšã³âã¢ã¯ãªããããªã«å ±éåäœã
ããªã¢ããæš¹èãããªããã«ããã©ãŒã«ãã»ã«ã
ãŒã¹èªå°äœãããªãšã¹ãã«æš¹èãããªãã¿ãžãšã³
çã®åæãŽã ç³»ã®ç±å¯å¡æ§æš¹èçãæããããã
åãç±ç¡¬åæ§æš¹èãããã¯åå¿æ§æš¹èãšããŠã¯äŸ
ãã°ãããšããŒã«æš¹èããšããã·æš¹èãããªãŠã¬
ã¿ã³ç¡¬ååæš¹èãã¡ã©ãã³æš¹èãã¢ã«ãããæš¹
èãã·ãªã³ã³æš¹èãã¢ã¯ãªã«ç³»åå¿æš¹èããšãã
ã·âããªã¢ããæš¹èããããã»ã«ããŒã¹âã¡ã©ã
ã³æš¹èãé«ååéããªãšã¹ãã«æš¹èãšã€ãœã·ã¢ã
ãŒããã¬ããªããŒã®æ··åç©ãã¡ã¿ã¯ãªã«é žå¡©å ±é
åäœãšãžã€ãœã·ã¢ããŒããã¬ããªããŒã®æ··åç©ã
ããªãšã¹ãã«ããªãªãŒã«ãšããªã€ãœã·ã¢ããŒãã®
æ··åç©ãå°¿çŽ ãã«ã ã¢ã«ãããæš¹èãäœååéã°
ãªã³ãŒã«ïŒé«ååéãžãªãŒã«ïŒããªããšãã«ã¡ã¿
ã³ããªã€ãœã·ã¢ããŒãã®æ··åç©ãããªã¢ãã³æš¹è
åã³ãããã®æ··åç©çãæããããã äžè¿°ã®çµåå€ã«åŒ·ç£æ§ç²æ«ãåæ£ãææ©æº¶å€ã«
溶解ããŠéç£æ§æ¯æäœäžã«å¡åžããããšã«ããç£
æ§å±€ã圢æãããã ããã«äžèšç£æ§å±€ã«ã¯ãåèšã®çµåå€ãç£æ§ç²
ã®ä»ã«æ·»å å€ãšããŠåæ£å€ã最æ»å€ãç 磚å€ã垯
é»é²æ¢å€ãé²éå€çãå ããããŠãããã äžèšåæ£å€ïŒé¡æ湿最å€ïŒãšããŠã¯ãã«ããªã«
æ®ãã«ããªã³é žãã©ãŠãªã³é žãããªã¹ãã³é žãã
ã«ããã³é žãã¹ãã¢ãªã³é žããªã¬ã€ã³é žããªããŒ
ã«é žããªãã¬ã³é žãçã®ççŽ æ°12ã18åã®èèªé ž
ïŒR1COOHãR1ã¯ççŽ æ°11ã17åã®ã¢ã«ãã«ãŸã
ã¯ã¢ã«ã±ãã«åºïŒãåèšã®èèªé žã®ã¢ã«ã«ãªéå±
ïŒLiãNaãçïŒãŸãã¯ã¢ã«ã«ãªåé¡éå±ïŒMgã
CaãBaïŒããæãéå±ç³é¹žãåèšã®èèªé žãšã¹
ãã«ã®åŒçŽ ãå«æããååç©ãåèšã®èèªé žã®ã¢
ãããããªã¢ã«ãã¬ã³ãªããµã€ãã¢ã«ãã«ãªã³é ž
ãšã¹ãã«ãããªã¢ã«ãã«ããªãªã¬ãã€ã³ãªãã·ç¬¬
åã¢ã³ã¢ããŠã å¡©ïŒã¢ã«ãã«ã¯ççŽ æ°ïŒãïŒåã
ãªã¬ãã€ã³ã¯ãšãã¬ã³ããããã¬ã³ãªã©ïŒãçã
䜿çšãããããã®ä»ã«ççŽ æ°12以äžã®é«çŽã¢ã«ã³
ãŒã«ãåã³ãããã®ä»ã«ç¡«é žãšã¹ãã«çã䜿çšå¯
èœã§ããããããã®åæ£å€ã¯ç£æ§ç²100éééšã«
察ããŠ0.5ã10éééšã®ç¯å²ã§æ·»å ãããã äžèšæœ€æ»å€ãšããŠã¯ããžã¢ã«ãã«ããªã·ãããµ
ã³ïŒã¢ã«ãã«ã¯ççŽ æ°ïŒãïŒåïŒããžã¢ã«ã³ãã·
ããªã·ãããµã³ïŒã¢ã«ã³ãã·ã¯ççŽ æ°ïŒãïŒåïŒã
ã¢ãã¢ã«ãã«ã¢ãã¢ã«ã³ãã·ããªã·ãããµã³ïŒã¢
ã«ãã«ã¯ççŽ æ°ïŒãïŒåãã¢ã«ã³ãã·ã¯ççŽ æ°ïŒ
ãïŒåïŒãããšãã«ããªã·ãããµã³ããããã¢ã«
ãã«ããªã·ãããµã³ïŒã¢ã«ãã«ã¯ççŽ æ°ïŒãïŒ
åïŒãªã©ã®ã·ãªã³ã³ãªã€ã«ãã°ã©ãã¢ã€ããªã©ã®
å°é»æ§åŸ®ç²æ«ãäºç¡«åã¢ãªããã³ãäºç¡«åã¿ã³ã°
ã¹ãã³çã®ç¡æ©åŸ®ç²æ«ãããªããã©ãã«ãªããšã
ã¬ã³çã®ãã©ã¹ããã¯åŸ®ç²æ«ãαâãªã¬ãã€ã³é
åç©ãåžžæž©ã§æ¶²ç¶ã®äžé£œåèèªæçåæ°ŽçŽ ãççŽ
æ°12ã20åã®äžå¡©åºæ§èèªé žãšççŽ æ°ïŒã12åã®
äžäŸ¡ã®ã¢ã«ã³ãŒã«ããæãèèªé žãšã¹ãã«é¡ãã
ã«ãªãã«ãŒãã³ã³é¡çã䜿çšã§ããã ãããã®æœ€æ»å€ã¯ãç£æ§ç²100éééšã«å¯ŸããŠ
0.2ã10éééšã®æå²ã§æ·»å ããããäžèšç 磚å€
ãšããŠã¯ãäžè¬ã«äœ¿çšãããææã§æº¶èã¢ã«ã
ããçåã±ã€çŽ ãé žåã¯ãã ïŒCr2O3ïŒãã³ã©ã³
ãã ã人é ã³ã©ã³ãã ããã€ã€ã¢ã³ãã人é ãã€
ã€ã¢ã³ããã¶ã¯ãç³ããšã¡ãªãŒïŒäž»æåïŒã³ã©ã³
ãã ãšéé±ç²ïŒçã䜿çšãããããããã®ç 磚å€
ã¯ç£æ§ç²100éééšã«å¯ŸããŠ0.5ã20éééšã®ç¯å²
ã§æ·»å ãããã äžèšåž¯é»é²æ¢å€ãšããŠã¯ãã«ãŒãã³ãã©ãã¯ã
ã«ãŒãã³ãã©ãã¯ã°ã©ããããªããŒçã®å°é»æ§åŸ®
ç²æ«ããµããã³ãªã©ã®å€©ç¶çé¢æŽ»æ§å€ãã¢ã«ãã¬
ã³ãªããµã€ãç³»ãã°ãªã»ãªã³ç³»ãã°ãªã·ããŒã«ç³»
ãªã©ã®ãããªã³çé¢æŽ»æ§å€ãé«çŽã¢ã«ãã«ã¢ãã³
é¡ã第åçŽã¢ã³ã¢ããŠã å¡©é¡ãããªãžã³ãã®ä»ã®
è€çŽ ç°é¡ããã¹ãããŠã é¡ãªã©ã®ã«ããªã³çé¢æŽ»
æ§å€ãã«ã«ãã³é¡ãã¹ã«ãã³é¡ããªã³é žãç¡«é žãš
ã¹ãã«åºããªã³é žãšã¹ãã«åºçã®é žæ§åºãå«ãã¢
ããªã³çé¢æŽ»æ§å€ãã¢ããé žé¡ãã¢ããã¹ã«ãã³
é žé¡ãã¢ããã¢ã«ã³ãŒã«ã®ç¡«é žãŸãã¯ãªã³é žãšã¹
ãã«é¡çã®äž¡æ§æŽ»æ§å€ãªã©ã䜿çšããããäžèšã®
å°é»ç¶åŸ®ç²æ«ã¯ç£æ§ç²100éééšã«å¯ŸããŠ0.2ã20
éééšããçé¢æŽ»æ§å€ã¯0.1ã20éééšã®ç¯å²ã§
æ·»å ãããããããã®çé¢æŽ»æ§å€ã¯åç¬ãŸãã¯æ··
åããŠæ·»å ããŠãããããããã¯åž¯é»é²æ¢å€ãšã
ãŠçšãããããã®ã§ããããæãšããŠãã®ä»ã®ç®
çãäŸãã°åæ£ãç£æ°ç¹æ§ã®æ¹è¯ã最æ»æ§ã®æ¹
è¯ãå¡åžå©å€ãšããŠé©çšãããå Žåãããã äžèšé²éå€ãšããŠã¯ããªã³é žãã¹ã«ãã¢ããã
ã°ã¢ããžã³ãããªãžã³ãã¢ãã³ãå°¿çŽ ããžã³ã¯ã¯
ãã¡ãŒããã«ã«ã·ãŠã ã¯ãã¡ãŒããã¹ããã³ããŠ
ã ã¯ãã¡ãŒãçã䜿çšã§ããã ãããã®é²éå€ã¯ç£æ§ç²100éééšã«å¯ŸããŠ
0.01ã2.0éééšã®ç¯å²ã§äœ¿çšãããã åãç£æ§å±€ã®æ§æææã¯ææ©æº¶å€ã«æº¶ãããŠç£
æ§å¡æã調補ãããããéç£æ§æ¯æäœäžã«å¡åžã
ããããã®ç£æ§å¡æã®æº¶å€ãšããŠã¯ã¢ã»ãã³ãã¡
ãã«ãšãã«ã±ãã³ãã¡ãã«ã€ãœããã«ã±ãã³ãã·
ã¯ããããµãã³çã®ã±ãã³ç³»ãé ¢é žã¡ãã«ãé ¢é ž
ãšãã«ãé ¢é žããã«ãä¹³é žãšãã«ãé ¢é žã°ãªã³ãŒ
ã«ã¢ããšãã«ãšãŒãã«çã®ãšã¹ãã«ç³»ãã°ãªã³ãŒ
ã«ãžã¡ãã«ãšãŒãã«ãã°ãªã³ãŒã«ã¢ããšãã«ãšãŒ
ãã«ããžãªããµã³çã®ã°ãªã³ãŒã«ãšãŒãã«ç³»ãã
ã³ãŒã³ããã«ãšã³ããã·ã¬ã³çã®è³éŠæçåæ°Ž
çŽ ããããµã³ãããã¿ã³çã®èèªæçåæ°ŽçŽ ãã¡
ãã¬ã³ã¯ãã©ã€ãããšãã¬ã³ã¯ãã©ã€ããåå¡©å
ççŽ ãã¯ãããã«ã ããšãã¬ã³ã¯ãã«ãããªã³ã
ãžã¯ãã«ãã³ãŒã³çã®å¡©çŽ åçåæ°ŽçŽ çãæãã
ããã åãäžè¿°ããããªãŠã¬ã¿ã³âãŠã¬ã¢æš¹èã«ããª
ã€ãœã·ã¢ããŒãååç©ã硬åå€ãšããŠäœµçšããå Ž
åã«æŒãŠã¯ãèæ©èæ§ã®åªããç£æ°èšé²åªäœãåŸ
ãããšãã§ããã å°ã硬åå€ãšããŠçšããããããªã€ãœã·ã¢ããŒ
ãååç©ãšããŠã¯ãäŸãã°ã³ãããŒããã³ãã
ãŒãHLãã³ãããŒãEHãã³ãããŒã2030ãã³
ãããŒã3030ãã³ãããŒã4048ãã³ãããŒã
4190ãã³ãããŒã4192ïŒããããæ¥æ¬ããªãŠã¬ã¿
ã³å·¥æ¥è£œïŒçã§ããã°ãããã䜿çšã§ããã åããã®ããªã€ãœã·ã¢ããŒãååç©ã®éã«ããŠ
ãé垞䜿çšãããŠããéã§ããã°ãããããªãŠã¬
ã¿ã³âãŠã¬ã¢æš¹èãšä»æš¹èãšã®ç·é100éééšã«
察ããŠïŒã30éééšïŒåã åºåœ¢åæç®ïŒã®ç¯å²å
ã§ããã åãéç£æ§æ¯æäœã®çŽ æãšããŠã¯ããªãšãã¬ã³
ãã¬ãã¿ã¬ãŒããããªãšãã¬ã³âïŒïŒïŒâããã¿
ã¬ãŒãçã®ããªãšã¹ãã«é¡ãããªãšãã¬ã³ãããª
ãããã¬ã³çã®ããªãªã¬ãã€ã³é¡ãã»ã«ããŒã¹ã
ãªã¢ã»ããŒããã»ã«ããŒã¹ãã€ã¢ã»ããŒããã»ã«
ããŒã¹ã¢ã»ããŒãããã¬ãŒããã»ã«ããŒã¹ã¢ã»ã
ãŒãããããªããŒãçã®ã»ã«ããŒã¹èªå°äœãããª
å¡©åããã«ãããªå¡©åãããªãã³çã®ããã«ç³»æš¹
èãããªã«ãŒãããŒããããªã€ãããããªã¢ãã
ã€ããçã®ãã©ã¹ããã¯ã®ä»ã«çšéã«å¿ããŠã¢ã«
ãããŠã ãé ãã¹ãºãæªéãŸãã¯ããããå«ãé
ç£æ§åéãªã©ã®éç£æ§éå±é¡ãã¬ã©ã¹ãé¶åšãç£
åšãªã©ã®ã»ã©ããã¯é¡ãçŽããã©ã€ã¿åã¯ããªãš
ãã¬ã³ãããªãããã¬ã³ããšãã¬ã³âããã³å ±é
åäœãªã©ã®ççŽ æ°ïŒã10ã®Î±âããªãªã¬ãã€ã³é¡
ãå¡åžãŸãã¯ã©ãããŒãããçŽãªã©ã®çŽé¡ã䜿çš
ã§ãããåéç£æ§æ¯æäœã®åœ¢æ ã¯ãã€ã«ã ãããŒ
ããã·ãŒãããã€ã¹ã¯ãã«ãŒãããã©ã çããã
ã§ãè¯ãã æ¬çºæã«ããçµåå€ãçšããããšã«ãããç£æ§
ç²ã®åæ£æ§ãåäžããè§åæ¯Rsã飜åç£æå¯åºŠ
Bmçã®ç£æ°ç¹æ§ãåªãããã®ãšãªããåç£æ§å±€
ã®èä¹ æ§ãåäžããããšãã§ããã¹ãã«æéãç²
èœã¡ã«èµ·å ããã¬ãã«å€ååºåæžè¡°çã®ç¹æ§ãæ¹
åãããæŽã«ç£æ§å±€ã®è¡šé¢å¹³æ»æ§ãåäžã§ããã®
ã§é»ç£å€æç¹æ§ãäŸãã°åšæ³¢æ°ç¹æ§ãïŒïŒ®æ¯ç
ã®ç¹æ§ãæ¹åããããšãã§ããã 以äžå®æœäŸã«ããæŽã«è©³çŽ°ã«èª¬æããã å®æœäŸã«æŒãããéšãåã³ãïŒ ãã¯ããšããã®
ãªãéããéééšãåã³ãééïŒ ãã§ããã 芪氎æ§æ¥µæ§åºå«æããªãšã¹ãã«ããªãªãŒã«ã®è£œé å®æœäŸ ïŒ æž©åºŠèšãæ¹ææ©åã³ã³ã³ãã³ãµãŒãåããåå¿
åšã«ã¢ãžãã³é ž484éšãïŒïŒïŒâãããµã³ã°ãªã³
ãŒã«459éšãSO3Naåºå«æååç©1)176éšã觊åªãš
ããŠé ¢é žäºé0.3éšãé ¢é žãããªãŠã 0.04éšãå
ã140âã220âã§åžžå§ãšã¹ãã«ååå¿ãé²ããæ
å®åå¿çã«éãããåå¿ç³»ã100mmHgïŒ30åã®é
床ã§æžå§ããïŒæéåŸ20mmHgãŸã§æžå§ãããã®
ç空床ã§ïŒæéä¿æããšã¹ãã«ååå¿ãé²ã
SO3Mâ²åºãå«æããããªãšã¹ãã«ããªãªãŒã«ã
åŸããåŸãããããªãªãŒã«ã¯äžèšã®éãã æ°Žé žåºäŸ¡ 102ãé žäŸ¡ 0.6ã SO3Naåºæ¿åºŠ 0.42ïœmolïŒïœ å®æœäŸ ïŒ å®æœäŸïŒãšåæ§ã®åå¿åšã«ãããªãã³ãã«ã°ãª
ã³ãŒã«216éšãïŒïŒïŒâããã¬ã³ã°ãªã³ãŒã«78éšã
ïŒïŒïŒâãããµã³ã°ãªã³ãŒã«245éšããããªãŠã
ã¹ã«ãã³ãã¯é žãžã¡ãã«165éšåã³è§ŠåªãšããŠé ¢
é žäºé0.3éšãé ¢é žãããªãŠã 0.04éšãå ã140ã
180âã§è±ã¡ã¿ããŒã«ãšã¹ãã«äº€æåå¿ãè¡ãªã€
ãåŸãã¢ãžãã³é ž489éšãå ããŠ210ã240âã«æ
æž©ããŠè±æ°Žåå¿ã§ã®ããªãšã¹ãã«åããå®æœäŸïŒ
ãšåæ§ã®æžå§åå¿ãçµãŠSO3Naåºãå«æããã
ãªãšã¹ãã«ããªãªãŒã«ãåŸããåŸãããããªãªãŒ
ã«ã¯äžèšã®éãã æ°Žé žåºäŸ¡ 110ãé žäŸ¡ 0.8 SO3Naåºæ¿åºŠ 0.64ïœmolïŒïœ å®æœäŸ ïŒ å®æœäŸïŒãšåæ§ã®åå¿åšã«ãããªããã¬ã³ã¢ãž
ããŒãïŒååé2000ïŒïŒ2000éšãšãžã¡ãããŒã«ã
ãããªã³é ž134éšåã³ãšã¹ãã«äº€æ觊åªãšããŠã
ã¿ããŠã ã¢ã»ãã«ã¢ã»ããŒã0.3éšå ã140ã180
âã§ïŒæéå ç±æ¹æãåŽéã«COOHåºãå«æã
ãããªãšã¹ãã«ããªãªãŒã«ãåŸããåŸãããããª
ãªãŒã«ã¯äžèšã®éãã æ°Žé žåºäŸ¡ 106ãCOOHåºæ¿åºŠ 0.469ïœmolïŒïœ å®æœäŸ ïŒ å®æœäŸïŒã§åŸãCOOHåºå«æããªãšã¹ãã«ã
ãªãªãŒã«1000éšã«ãCOOHã®95ïŒ ãäžåããã«
å¿ èŠãªèæ§ãœãŒã10ïŒ æ°Žæº¶æ¶²ãå ããCOOHã
äžåããåŸ150âã20mmHgãïŒæéã®æ¡ä»¶ã§æžå§
è±æ°ŽãCOONaåºå«æããªãšã¹ãã«ããªãªãŒã«ã
åŸããåŸãããããªãªãŒã«ã¯äžèšã®éãã æ°Žé žäŸ¡åº 106 é žäŸ¡ 0.2 COONaåºæ¿åºŠ 0.445ïœmolïŒïœ å®æœäŸ ïŒãïŒ å®æœäŸïŒãšåæ§ã®åå¿åšã«ãè¡šïŒã«ç€ºãå²åã®
åæãçšãã觊åªãšããŠé ¢é žäºé0.05éšãé ¢é žã
ããªãŠã 0.007éšã䜿çšãå®æœäŸïŒãšåæ§ã®æ¹æ³
ã§ãšã¹ãã«ååå¿ãè¡ãè¡šïŒã«ç€ºãããªãšã¹ãã«
ããªãªãŒã«ãåŸãã
ãè¡šã
ãè¡šã
ããªãŠã¬ã¿ã³âãŠã¬ã¢æš¹èã®è£œé
å®æœäŸ ïŒ
枩床èšãæ¹ææ©ãã³ã³ãã³ãµãŒãåããåå¿åš
ã«å®æœäŸïŒã§åŸãSO3Naåºå«æããªãšã¹ãã«ã
ãªãªãŒã«36.0éšãããªãããµã¡ãã¬ã³ã¢ãžããŒã
ïŒååé1000ïŒ2000.0éšãšïŒïŒ4â²âãžããšãã«ã¡
ã¿ã³ãžã€ãœã·ã¢ããŒãïŒä»¥äžMDIãšç¥ãïŒ69.9éš
åã³ã¡ãã«ãšãã«ã±ãã³ïŒä»¥äžMEKãšç¥ãïŒ306
éšãå ã70ã80âã§ïŒæéåå¿ãNCOæªç«¯ããª
ããªããŒãåŸãã 次ãã§ãŠã¬ã¢ååå¿ãé²ãããããæ°Ž0.84éšã
ãŠã¬ã¢å觊åªãšããŠããªãšãã«ã¢ãã³1.0éšå ã
æŽã«75ã80âã§åå¿ãé²ããç²åºŠçŽ50äžcpsïŒ25
âã«éãããMEKã§åºåœ¢å30ïŒ ãŸã§åžéããã®
ã¡æ®åNCOæ¿åºŠã«çžåœããã¢ããšã¿ããŒã«ã¢ã
ã³ãå ãOHæ«ç«¯åãåå¿ãåæ¢ãããåŸããã
æš¹èã¯ä»¥äžã®éãã å€èŠ³ æ·¡é»è²éæãåºåœ¢å 30ïŒ ç²åºŠ 5000cpsïŒ25â å®æœäŸ ïŒã13 å®æœäŸïŒãšåæ§ã®åå¿åšã«ãå®æœäŸïŒã§åŸã
SO3Naåºå«æããªãšã¹ãã«ããªãªãŒã«ãšããªã
ããµã¡ãã¬ã³ã¢ãžããŒãïŒååé1000ïŒã®æ¯çã
å€åããä»ã¯ãå®æœäŸïŒãšåæ§ã®æ¡ä»¶ã§ããªãŠã¬
ã¿ã³âãŠã¬ã¢æš¹èã®SO3Naåºæ¿åºŠãå€åããã
æš¹èã補é ãããåŸãããæš¹èã¯è¡šïŒã«ç€ºãã
ã«å®æœäŸïŒã§åŸãSO3Naåºå«æããªãšã¹ãã«ã
ãªãªãŒã«36.0éšãããªãããµã¡ãã¬ã³ã¢ãžããŒã
ïŒååé1000ïŒ2000.0éšãšïŒïŒ4â²âãžããšãã«ã¡
ã¿ã³ãžã€ãœã·ã¢ããŒãïŒä»¥äžMDIãšç¥ãïŒ69.9éš
åã³ã¡ãã«ãšãã«ã±ãã³ïŒä»¥äžMEKãšç¥ãïŒ306
éšãå ã70ã80âã§ïŒæéåå¿ãNCOæªç«¯ããª
ããªããŒãåŸãã 次ãã§ãŠã¬ã¢ååå¿ãé²ãããããæ°Ž0.84éšã
ãŠã¬ã¢å觊åªãšããŠããªãšãã«ã¢ãã³1.0éšå ã
æŽã«75ã80âã§åå¿ãé²ããç²åºŠçŽ50äžcpsïŒ25
âã«éãããMEKã§åºåœ¢å30ïŒ ãŸã§åžéããã®
ã¡æ®åNCOæ¿åºŠã«çžåœããã¢ããšã¿ããŒã«ã¢ã
ã³ãå ãOHæ«ç«¯åãåå¿ãåæ¢ãããåŸããã
æš¹èã¯ä»¥äžã®éãã å€èŠ³ æ·¡é»è²éæãåºåœ¢å 30ïŒ ç²åºŠ 5000cpsïŒ25â å®æœäŸ ïŒã13 å®æœäŸïŒãšåæ§ã®åå¿åšã«ãå®æœäŸïŒã§åŸã
SO3Naåºå«æããªãšã¹ãã«ããªãªãŒã«ãšããªã
ããµã¡ãã¬ã³ã¢ãžããŒãïŒååé1000ïŒã®æ¯çã
å€åããä»ã¯ãå®æœäŸïŒãšåæ§ã®æ¡ä»¶ã§ããªãŠã¬
ã¿ã³âãŠã¬ã¢æš¹èã®SO3Naåºæ¿åºŠãå€åããã
æš¹èã補é ãããåŸãããæš¹èã¯è¡šïŒã«ç€ºãã
ãè¡šã
ãè¡šã
å®æœäŸ 14
å®æœäŸïŒãšåæ§ã®åå¿åšã«ãå®æœäŸïŒã§åŸã
COOHåºå«æããªãšã¹ãã«ããªãªãŒã«ïŒæ°Žé žåº
䟡106ãCOOHåºæ¿åºŠ0.469ïœmolïŒïœïŒ533éšã
ããªãã³ãã«ã°ãªã³ãŒã«52éšãMDI375éšåã³
MEK640éšã觊åªãšããŠãžããã«é«ãžã©ãŠã¬ãŒã
0.2éšå ã70ã80âã§ïŒæéåå¿ããã®ã¡æ°Ž9.0éš
ãå ããŠã¬ã¢ååå¿ãé²ãããç²åºŠçŽ50äžcpsïŒ
25âã«éããMEKïŒã·ã¯ããããµãã³ïŒïŒïŒïŒ
1600éšã§åºåœ¢å30ïŒ ã«åžéãããæ®åNCOæ¿
床ã¯0.010ïœmolïŒïœæã€ãããã®NCOã«çžåœã
ãNH2åºãæããã¢ããšã¿ããŒã«ã¢ãã³2.0ïœã
å ãæ«ç«¯OHåºãšãåå¿ãåæ¢ãããåŸãããæš¹
èã¯äžèšã®éãã å€èŠ³ æ·¡é»è²éæãåºåœ¢å 30ïŒ ç²åºŠ 10000cpsïŒ25â å®æœäŸ 15ïŒæ¯èŒäŸïŒ å®æœäŸ14ã«ããããæ°Žã®ä»£ãã«åã¢ã«ã®ïŒïŒïŒ
âããã¬ã³ã°ãªã³ãŒã«45éšå ããŠã¬ã¿ã³ååå¿ã§
延é·ãCOOHåºå«æãŠã¬ã¿ã³æš¹èãšãããã
ã®æš¹è溶液ã¯æ¶²æ§ãæªãæ¿åºŠã®ãã液äœã§ãã€ã
ãæ°æ¥åŸå¯å€©ç¶ãšãªãä¿åæ§ã®ç¹ã§å£ãã å€èŠ³ ä¹³çœè²äžéæ åºåœ¢å 30ïŒ ç²åºŠ 15000cpsïŒ25âïŒè£œé çŽåŸïŒ å®æœäŸ 16 å®æœäŸïŒãšåæ§ã®åå¿åšã«ãTDIïŒïŒŽâ80ïŒ261
éšããžã¡ãããŒã«ããããªã³é žïŒéšåã³MEK268
éšå ã80âã§ïŒæéåå¿ãããCOOHåºæ¿åºŠ0.09
ïœmolïŒïœå«æããå€æ§TDI溶液ãåŸãã次ãã§
MEK1250éšãšããªããã¬ã³ã¢ãžããŒãïŒååé
1000ïŒ1250éšãå ãé«ååååå¿ããããæŽã«æ°Ž
3.6éšãããªãšã¿ããŒã«ã¢ãã³ïŒéšãå ããŠã¬ã¢
ååå¿ããããŠMEK1300éšãå ãã¢ããšã¿ããŒ
ã«ã¢ãã³ã§æ«ç«¯OHåºãšãCOOHåºå«æããªãŠã¬
ã¿ã³âãŠã¬ã¢æš¹èãåŸããåŸãããæš¹èã¯äž
èšã®éãã å€èŠ³ æ·¡é»è²éæ åºåœ¢å 35ïŒ ç²åºŠ 8000cpsïŒ25â ã¯ãªã¢ãã¢ã€ã«ã®äœæ å®æœäŸåã³æ¯èŒäŸã§åŸãæš¹è溶液ãã®ãŸãŸãšã
該暹è溶液ã«ããªã€ãœã·ã¢ããŒãååç©ïŒã³ãã
ãŒãïŒãæš¹è100éšã«å¯ŸããŠ10éšïŒåã åºåœ¢å
æç®ïŒã®å²åã§å ããïŒçš®ã«ã€ããŠãé¢åçŽäžã«
ãã€ãã³ãŒã¿ãŒãçšããŠä¹Ÿç¥èå100ÎŒãšãªãã
ãã«å¡åžãã宀枩ã§30åã80âã§15åã120âã§
15å硬å也ç¥ãããã€ã«ã ãåŸãã ã¯ãªã¢ãã€ã«ã ã®ç©æ§ ã¬ã©ã¹è»¢ç§»ç¹ïŒTgïŒ ã¯ãªã¢ãã€ã«ã ãåçç²åŒŸæ§æž¬å®è£ 眮ïŒDDV
ââEAãæ±æŽããŒã«ããŠã€ã³è£œïŒã«ãŠ110Hzã
ïŒâïŒminæ¡ä»¶ã§æž¬å®ãEâ³å€æé«æž©åºŠããã€ãŠ
Tgãšããã è»ç¹åïŒSPïŒ ã¯ãªã¢ãã€ã«ã ãJIS2å·ãã³ãã«ã§ã«ãããè·
éïŒïœïŒ100ÎŒã®ããããä»ããææž©é床10âïŒ
minæ¡ä»¶äžã§ã®ãã€ã«ã ã®äŒžã³ãã枩床ããã€ãŠ
SPãšããã èä¹ æ§ é«æž©é«æ¹¿ïŒ70âÃ95ïŒ RHïŒæ¡ä»¶ã§ã®ïŒé±éåŸ
ã®åææåŒåŒµã匷ãïŒTBïŒã®ä¿æçããã€ãŠè
ä¹ æ§ã®ææšãšããã TBä¿æçïŒïŒ ïŒ â 90ä»¥äž ã 70ã89 â³ 50ã69 à 50ä»¥äž ç£æ§å¡æå å®æœäŸåæ¯èŒäŸã§åŸãããªãŠã¬ã¿ã³âãŠã¬ã¢æš¹è
100 COâγâFe2O3ïŒHc650OešãBET32m2ïŒïœïŒ 400 ãã«ãšã³ïŒMEKïŒã·ã¯ããããµãã³ïŒïŒïŒïŒïŒ
ïŒ 930 ãããŒã«ãã«ã§48æéåæ£ããŠåŸãããç£æ§å¡æ
ãåã15ÎŒã®ããªãšãã¬ã³ãã¬ãã¿ã¬ãŒããã€ã«
ã äžã«ä¹Ÿç¥èåã§5ÎŒãšãªãããã«å¡åžãè«žç¹æ§
ã枬å®ããã å 沢床 å æ²¢èšïŒã°ãã¹ã¡ãŒã¿ãUGVâ5Gã¹ã¬è©Šéšæ©
補ïŒã§60ãã60ãåå°å æ²¢çã枬å®ããã ã¿ã㯠æ觊å€å® è¡šé¢å¹³æ»æ§ è¡šé¢æ§æž¬å®æ©ïŒHEIDON æ°æ±ç§åŠè£œïŒã§è¡š
é¢åžå¹åã³åæ©æŠä¿æ°ã枬å®ãå€å®ããã èä¹ æ§ èæ©èè©Šéšæ©ïŒããŒããŒæ©èè©Šéšæ©ïŒã§æ©èé
ããå€å®ããã 枬å®çµæã®è¡šç€º â åª ã è¯ â³ å¯ Ã äžå¯ è¡šïŒã«å皮暹èã®ç©æ§æž¬å®çµæã瀺ãã
COOHåºå«æããªãšã¹ãã«ããªãªãŒã«ïŒæ°Žé žåº
䟡106ãCOOHåºæ¿åºŠ0.469ïœmolïŒïœïŒ533éšã
ããªãã³ãã«ã°ãªã³ãŒã«52éšãMDI375éšåã³
MEK640éšã觊åªãšããŠãžããã«é«ãžã©ãŠã¬ãŒã
0.2éšå ã70ã80âã§ïŒæéåå¿ããã®ã¡æ°Ž9.0éš
ãå ããŠã¬ã¢ååå¿ãé²ãããç²åºŠçŽ50äžcpsïŒ
25âã«éããMEKïŒã·ã¯ããããµãã³ïŒïŒïŒïŒ
1600éšã§åºåœ¢å30ïŒ ã«åžéãããæ®åNCOæ¿
床ã¯0.010ïœmolïŒïœæã€ãããã®NCOã«çžåœã
ãNH2åºãæããã¢ããšã¿ããŒã«ã¢ãã³2.0ïœã
å ãæ«ç«¯OHåºãšãåå¿ãåæ¢ãããåŸãããæš¹
èã¯äžèšã®éãã å€èŠ³ æ·¡é»è²éæãåºåœ¢å 30ïŒ ç²åºŠ 10000cpsïŒ25â å®æœäŸ 15ïŒæ¯èŒäŸïŒ å®æœäŸ14ã«ããããæ°Žã®ä»£ãã«åã¢ã«ã®ïŒïŒïŒ
âããã¬ã³ã°ãªã³ãŒã«45éšå ããŠã¬ã¿ã³ååå¿ã§
延é·ãCOOHåºå«æãŠã¬ã¿ã³æš¹èãšãããã
ã®æš¹è溶液ã¯æ¶²æ§ãæªãæ¿åºŠã®ãã液äœã§ãã€ã
ãæ°æ¥åŸå¯å€©ç¶ãšãªãä¿åæ§ã®ç¹ã§å£ãã å€èŠ³ ä¹³çœè²äžéæ åºåœ¢å 30ïŒ ç²åºŠ 15000cpsïŒ25âïŒè£œé çŽåŸïŒ å®æœäŸ 16 å®æœäŸïŒãšåæ§ã®åå¿åšã«ãTDIïŒïŒŽâ80ïŒ261
éšããžã¡ãããŒã«ããããªã³é žïŒéšåã³MEK268
éšå ã80âã§ïŒæéåå¿ãããCOOHåºæ¿åºŠ0.09
ïœmolïŒïœå«æããå€æ§TDI溶液ãåŸãã次ãã§
MEK1250éšãšããªããã¬ã³ã¢ãžããŒãïŒååé
1000ïŒ1250éšãå ãé«ååååå¿ããããæŽã«æ°Ž
3.6éšãããªãšã¿ããŒã«ã¢ãã³ïŒéšãå ããŠã¬ã¢
ååå¿ããããŠMEK1300éšãå ãã¢ããšã¿ããŒ
ã«ã¢ãã³ã§æ«ç«¯OHåºãšãCOOHåºå«æããªãŠã¬
ã¿ã³âãŠã¬ã¢æš¹èãåŸããåŸãããæš¹èã¯äž
èšã®éãã å€èŠ³ æ·¡é»è²éæ åºåœ¢å 35ïŒ ç²åºŠ 8000cpsïŒ25â ã¯ãªã¢ãã¢ã€ã«ã®äœæ å®æœäŸåã³æ¯èŒäŸã§åŸãæš¹è溶液ãã®ãŸãŸãšã
該暹è溶液ã«ããªã€ãœã·ã¢ããŒãååç©ïŒã³ãã
ãŒãïŒãæš¹è100éšã«å¯ŸããŠ10éšïŒåã åºåœ¢å
æç®ïŒã®å²åã§å ããïŒçš®ã«ã€ããŠãé¢åçŽäžã«
ãã€ãã³ãŒã¿ãŒãçšããŠä¹Ÿç¥èå100ÎŒãšãªãã
ãã«å¡åžãã宀枩ã§30åã80âã§15åã120âã§
15å硬å也ç¥ãããã€ã«ã ãåŸãã ã¯ãªã¢ãã€ã«ã ã®ç©æ§ ã¬ã©ã¹è»¢ç§»ç¹ïŒTgïŒ ã¯ãªã¢ãã€ã«ã ãåçç²åŒŸæ§æž¬å®è£ 眮ïŒDDV
ââEAãæ±æŽããŒã«ããŠã€ã³è£œïŒã«ãŠ110Hzã
ïŒâïŒminæ¡ä»¶ã§æž¬å®ãEâ³å€æé«æž©åºŠããã€ãŠ
Tgãšããã è»ç¹åïŒSPïŒ ã¯ãªã¢ãã€ã«ã ãJIS2å·ãã³ãã«ã§ã«ãããè·
éïŒïœïŒ100ÎŒã®ããããä»ããææž©é床10âïŒ
minæ¡ä»¶äžã§ã®ãã€ã«ã ã®äŒžã³ãã枩床ããã€ãŠ
SPãšããã èä¹ æ§ é«æž©é«æ¹¿ïŒ70âÃ95ïŒ RHïŒæ¡ä»¶ã§ã®ïŒé±éåŸ
ã®åææåŒåŒµã匷ãïŒTBïŒã®ä¿æçããã€ãŠè
ä¹ æ§ã®ææšãšããã TBä¿æçïŒïŒ ïŒ â 90ä»¥äž ã 70ã89 â³ 50ã69 à 50ä»¥äž ç£æ§å¡æå å®æœäŸåæ¯èŒäŸã§åŸãããªãŠã¬ã¿ã³âãŠã¬ã¢æš¹è
100 COâγâFe2O3ïŒHc650OešãBET32m2ïŒïœïŒ 400 ãã«ãšã³ïŒMEKïŒã·ã¯ããããµãã³ïŒïŒïŒïŒïŒ
ïŒ 930 ãããŒã«ãã«ã§48æéåæ£ããŠåŸãããç£æ§å¡æ
ãåã15ÎŒã®ããªãšãã¬ã³ãã¬ãã¿ã¬ãŒããã€ã«
ã äžã«ä¹Ÿç¥èåã§5ÎŒãšãªãããã«å¡åžãè«žç¹æ§
ã枬å®ããã å 沢床 å æ²¢èšïŒã°ãã¹ã¡ãŒã¿ãUGVâ5Gã¹ã¬è©Šéšæ©
補ïŒã§60ãã60ãåå°å æ²¢çã枬å®ããã ã¿ã㯠æ觊å€å® è¡šé¢å¹³æ»æ§ è¡šé¢æ§æž¬å®æ©ïŒHEIDON æ°æ±ç§åŠè£œïŒã§è¡š
é¢åžå¹åã³åæ©æŠä¿æ°ã枬å®ãå€å®ããã èä¹ æ§ èæ©èè©Šéšæ©ïŒããŒããŒæ©èè©Šéšæ©ïŒã§æ©èé
ããå€å®ããã 枬å®çµæã®è¡šç€º â åª ã è¯ â³ å¯ Ã äžå¯ è¡šïŒã«å皮暹èã®ç©æ§æž¬å®çµæã瀺ãã
ãè¡šã
ãè¡šã
ãè¡šã
Claims (1)
- ãç¹èš±è«æ±ã®ç¯å²ã ïŒ éç£æ§æ¯æäœäžã«ç£æ§ç²ãšçµåå€ãäž»äœãšã
ãç£æ§å±€ã圢æãããŠãªãç£æ°èšé²åªäœã«ãã
ãŠã äžèšç£æ§å±€ãååå ã«COOMåºïŒïŒã¯æ°ŽçŽ å
ã¯ã¢ã«ã«ãªéå±ïŒåã³ïŒåã¯SO3Mâ²åºïŒMâ²ã¯ã¢
ã«ã«ãªéå±ïŒãæããæ°Žãšã€ãœã·ã¢ããŒãåºãšã®
åå¿ãã圢æããããŠã¬ã¢çµåãæããããªãŠã¬
ã¿ã³âãŠã¬ã¢æš¹èãçµåå€ãšããŠå«æããããšã
ç¹åŸŽãšããç£æ°èšé²åªäœã ïŒ éç£æ§æ¯æäœäžã«ç£æ§ç²ãšçµåå€ãäž»äœãšã
ãç£æ§å±€ã圢æãããŠãªãç£æ°èšé²åªäœã«ãã
ãŠã äžèšç£æ§å±€ãååå ã«COOMåºïŒïŒã¯æ°ŽçŽ å
ã¯ã¢ã«ã«ãªéå±ïŒåã³ïŒåã¯SO3Mâ²åºïŒMâ²ã¯ã¢
ã«ã«ãªéå±ïŒãæããæ°Žãšã€ãœã·ã¢ããŒããšã®å
å¿ãã圢æããããŠã¬ã¢çµåãæããããªãŠã¬ã¿
ã³âãŠã¬ã¢æš¹èãšããªã€ãœã·ã¢ããŒãååç©ãšã®
åå¿ç©ãçµåå€ãšããŠå«æããããšãç¹åŸŽãšãã
ç£æ°èšé²åªäœã
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP22793484A JPS61107531A (ja) | 1984-10-31 | 1984-10-31 | ç£æ°èšé²åªäœ |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP22793484A JPS61107531A (ja) | 1984-10-31 | 1984-10-31 | ç£æ°èšé²åªäœ |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS61107531A JPS61107531A (ja) | 1986-05-26 |
JPH044650B2 true JPH044650B2 (ja) | 1992-01-29 |
Family
ID=16868570
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP22793484A Granted JPS61107531A (ja) | 1984-10-31 | 1984-10-31 | ç£æ°èšé²åªäœ |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS61107531A (ja) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2576103B2 (ja) * | 1986-12-05 | 1997-01-29 | ãœããŒæ ªåŒäŒç€Ÿ | ç£æ°èšé²åªäœ |
JPS63142517A (ja) * | 1986-12-05 | 1988-06-14 | Sony Corp | ç£æ°èšé²åªäœ |
JPS63142518A (ja) * | 1986-12-05 | 1988-06-14 | Sony Corp | ç£æ°èšé²åªäœ |
JPS63142519A (ja) * | 1986-12-05 | 1988-06-14 | Sony Corp | ç£æ°èšé²åªäœ |
US5148562A (en) * | 1991-10-21 | 1992-09-22 | Hill-Rom Company, Inc. | Birthing bed adjustable to Trendelenburg position |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6076017A (ja) * | 1983-09-30 | 1985-04-30 | Sony Corp | ç£æ°èšé²åªäœ |
-
1984
- 1984-10-31 JP JP22793484A patent/JPS61107531A/ja active Granted
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6076017A (ja) * | 1983-09-30 | 1985-04-30 | Sony Corp | ç£æ°èšé²åªäœ |
Also Published As
Publication number | Publication date |
---|---|
JPS61107531A (ja) | 1986-05-26 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US4568611A (en) | Polyester-polyurethane composition and use thereof | |
JP3083311B2 (ja) | ç£æ°èšé²æ äœ | |
JPH02306427A (ja) | ç£æ°èšé²åªäœçšããªãŠã¬ã¿ã³æš¹èãã€ã³ã㌠| |
JPH044650B2 (ja) | ||
JPH08127632A (ja) | ããªãŠã¬ã¿ã³æš¹èã®è£œé æ¹æ³ | |
JP2950951B2 (ja) | ç£æ°èšé²æ äœ | |
JPH04298818A (ja) | ç£æ°èšé²åªäœ | |
JP2615574B2 (ja) | ç£æ°èšé²åªäœ | |
JP3031377B1 (ja) | ç£æ°èšé²åªäœçšãã€ã³ãâåã³ãããçšããç£æ°èšé²åªäœ | |
JPS58145722A (ja) | ç£æ§æš¹èçµæç© | |
JPH048856B2 (ja) | ||
KR100352695B1 (ko) | ê°êµì±ê²°í©ì ì±ë¶ìŒë¡ìì í©íì¬ë£ | |
JP2882500B2 (ja) | ç£æ°èšé²åªäœ | |
JPH03152116A (ja) | ç£æ°èšé²æ äœ | |
JP2576103B2 (ja) | ç£æ°èšé²åªäœ | |
JPH10320749A (ja) | ç£æ°èšé²åªäœ | |
JP2016085768A (ja) | ç£æ°èšé²çšãã€ã³ããŒããã³ç£æ°èšé²åªäœ | |
JPH11217539A (ja) | ç£æ°èšé²åªäœçšçµåææš¹èããã³ç£æ°èšé²åªäœçšå¡æçµæç©ããã³ç£æ°èšé²åªäœ | |
KR20010033551A (ko) | íëë¡ìêž° ë° ìë¯žë žêž°ë¥Œ íšì í íŽëŠ¬ì°ë í ìë¹ì€í©ì²Žêž°ì¬ì ìêž° êž°ë¡ ë§€ì²Ž | |
JPH0363124B2 (ja) | ||
JPS6288134A (ja) | ç£æ°èšé²åªäœ | |
JPH06101114B2 (ja) | ç£æ°èšé²åªäœ | |
JPH02173927A (ja) | ç£æ°èšé²åªäœ | |
JPH08165372A (ja) | ãã€ã³ããŒããã³ç£æ°èšé²åªäœ | |
JPS63142518A (ja) | ç£æ°èšé²åªäœ |