JPH0116405B2 - - Google Patents
Info
- Publication number
- JPH0116405B2 JPH0116405B2 JP59263017A JP26301784A JPH0116405B2 JP H0116405 B2 JPH0116405 B2 JP H0116405B2 JP 59263017 A JP59263017 A JP 59263017A JP 26301784 A JP26301784 A JP 26301784A JP H0116405 B2 JPH0116405 B2 JP H0116405B2
- Authority
- JP
- Japan
- Prior art keywords
- group
- formula
- solvent
- structural unit
- derived
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229910052731 fluorine Inorganic materials 0.000 claims description 43
- 229920000642 polymer Polymers 0.000 claims description 29
- 239000003973 paint Substances 0.000 claims description 28
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims description 26
- 239000011737 fluorine Substances 0.000 claims description 26
- 229920002313 fluoropolymer Polymers 0.000 claims description 18
- 239000004811 fluoropolymer Substances 0.000 claims description 18
- 229920001577 copolymer Polymers 0.000 claims description 15
- 229910052739 hydrogen Inorganic materials 0.000 claims description 14
- 125000000217 alkyl group Chemical group 0.000 claims description 13
- 239000003960 organic solvent Substances 0.000 claims description 13
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical compound C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 claims description 12
- 150000003961 organosilicon compounds Chemical class 0.000 claims description 12
- 125000004432 carbon atom Chemical group C* 0.000 claims description 11
- 229910052801 chlorine Inorganic materials 0.000 claims description 9
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 8
- 229910052710 silicon Inorganic materials 0.000 claims description 8
- 239000010703 silicon Substances 0.000 claims description 8
- 238000005227 gel permeation chromatography Methods 0.000 claims description 6
- 125000004183 alkoxy alkyl group Chemical group 0.000 claims description 5
- 125000003118 aryl group Chemical group 0.000 claims description 5
- 125000003710 aryl alkyl group Chemical group 0.000 claims description 4
- 125000000753 cycloalkyl group Chemical group 0.000 claims description 4
- 125000000962 organic group Chemical group 0.000 claims description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 3
- 229910052799 carbon Inorganic materials 0.000 claims description 3
- 239000001301 oxygen Substances 0.000 claims description 3
- 229910052760 oxygen Inorganic materials 0.000 claims description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 2
- 150000001336 alkenes Chemical class 0.000 claims description 2
- 150000001875 compounds Chemical class 0.000 claims description 2
- 239000001257 hydrogen Substances 0.000 claims description 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 2
- 229920006395 saturated elastomer Polymers 0.000 claims 1
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 21
- -1 alkyl vinyl ether Chemical compound 0.000 description 20
- 239000002904 solvent Substances 0.000 description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 11
- UZKWTJUDCOPSNM-UHFFFAOYSA-N 1-ethenoxybutane Chemical compound CCCCOC=C UZKWTJUDCOPSNM-UHFFFAOYSA-N 0.000 description 10
- 229910000831 Steel Inorganic materials 0.000 description 10
- 239000010959 steel Substances 0.000 description 10
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 9
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 9
- 239000011248 coating agent Substances 0.000 description 9
- 238000006243 chemical reaction Methods 0.000 description 8
- KYKAJFCTULSVSH-UHFFFAOYSA-N chloro(fluoro)methane Chemical compound F[C]Cl KYKAJFCTULSVSH-UHFFFAOYSA-N 0.000 description 8
- 238000000576 coating method Methods 0.000 description 8
- 238000000034 method Methods 0.000 description 8
- HCDGVLDPFQMKDK-UHFFFAOYSA-N hexafluoropropylene Chemical compound FC(F)=C(F)C(F)(F)F HCDGVLDPFQMKDK-UHFFFAOYSA-N 0.000 description 7
- 239000000203 mixture Substances 0.000 description 7
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 description 6
- 239000002253 acid Substances 0.000 description 6
- 150000001735 carboxylic acids Chemical class 0.000 description 6
- 239000012975 dibutyltin dilaurate Substances 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- 239000003054 catalyst Substances 0.000 description 5
- 239000000178 monomer Substances 0.000 description 5
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 5
- 230000003068 static effect Effects 0.000 description 5
- 229920000298 Cellophane Polymers 0.000 description 4
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 4
- 238000007334 copolymerization reaction Methods 0.000 description 4
- 238000004132 cross linking Methods 0.000 description 4
- FJKIXWOMBXYWOQ-UHFFFAOYSA-N ethenoxyethane Chemical compound CCOC=C FJKIXWOMBXYWOQ-UHFFFAOYSA-N 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- 239000003999 initiator Substances 0.000 description 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 4
- 150000003254 radicals Chemical class 0.000 description 4
- 239000000758 substrate Substances 0.000 description 4
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 3
- 239000004593 Epoxy Substances 0.000 description 3
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 238000004458 analytical method Methods 0.000 description 3
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 125000001153 fluoro group Chemical group F* 0.000 description 3
- 230000009477 glass transition Effects 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 230000003287 optical effect Effects 0.000 description 3
- 230000000704 physical effect Effects 0.000 description 3
- 238000006116 polymerization reaction Methods 0.000 description 3
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 3
- 239000004810 polytetrafluoroethylene Substances 0.000 description 3
- SCPYDCQAZCOKTP-UHFFFAOYSA-N silanol Chemical compound [SiH3]O SCPYDCQAZCOKTP-UHFFFAOYSA-N 0.000 description 3
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 3
- 238000002834 transmittance Methods 0.000 description 3
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 3
- SKYXLDSRLNRAPS-UHFFFAOYSA-N 1,2,4-trifluoro-5-methoxybenzene Chemical compound COC1=CC(F)=C(F)C=C1F SKYXLDSRLNRAPS-UHFFFAOYSA-N 0.000 description 2
- GWQOYRSARAWVTC-UHFFFAOYSA-N 1,4-bis(2-tert-butylperoxypropan-2-yl)benzene Chemical compound CC(C)(C)OOC(C)(C)C1=CC=C(C(C)(C)OOC(C)(C)C)C=C1 GWQOYRSARAWVTC-UHFFFAOYSA-N 0.000 description 2
- OVGRCEFMXPHEBL-UHFFFAOYSA-N 1-ethenoxypropane Chemical compound CCCOC=C OVGRCEFMXPHEBL-UHFFFAOYSA-N 0.000 description 2
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 description 2
- GVNVAWHJIKLAGL-UHFFFAOYSA-N 2-(cyclohexen-1-yl)cyclohexan-1-one Chemical compound O=C1CCCCC1C1=CCCCC1 GVNVAWHJIKLAGL-UHFFFAOYSA-N 0.000 description 2
- XDRAKJQFCQVBMP-UHFFFAOYSA-N 2-but-2-enyl-3-methylbutanedioic acid Chemical compound CC=CCC(C(O)=O)C(C)C(O)=O XDRAKJQFCQVBMP-UHFFFAOYSA-N 0.000 description 2
- JGZVUTYDEVUNMK-UHFFFAOYSA-N 5-carboxy-2',7'-dichlorofluorescein Chemical compound C12=CC(Cl)=C(O)C=C2OC2=CC(O)=C(Cl)C=C2C21OC(=O)C1=CC(C(=O)O)=CC=C21 JGZVUTYDEVUNMK-UHFFFAOYSA-N 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 2
- 101150065749 Churc1 gene Proteins 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- QUSNBJAOOMFDIB-UHFFFAOYSA-N Ethylamine Chemical compound CCN QUSNBJAOOMFDIB-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- 229910000760 Hardened steel Inorganic materials 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- YIVJZNGAASQVEM-UHFFFAOYSA-N Lauroyl peroxide Chemical compound CCCCCCCCCCCC(=O)OOC(=O)CCCCCCCCCCC YIVJZNGAASQVEM-UHFFFAOYSA-N 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- NQRYJNQNLNOLGT-UHFFFAOYSA-N Piperidine Chemical compound C1CCNCC1 NQRYJNQNLNOLGT-UHFFFAOYSA-N 0.000 description 2
- 102100038239 Protein Churchill Human genes 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 2
- 125000003545 alkoxy group Chemical group 0.000 description 2
- 125000005083 alkoxyalkoxy group Chemical group 0.000 description 2
- QARVLSVVCXYDNA-UHFFFAOYSA-N bromobenzene Chemical compound BrC1=CC=CC=C1 QARVLSVVCXYDNA-UHFFFAOYSA-N 0.000 description 2
- 239000000919 ceramic Substances 0.000 description 2
- UUAGAQFQZIEFAH-UHFFFAOYSA-N chlorotrifluoroethylene Chemical group FC(F)=C(F)Cl UUAGAQFQZIEFAH-UHFFFAOYSA-N 0.000 description 2
- 238000009833 condensation Methods 0.000 description 2
- 230000005494 condensation Effects 0.000 description 2
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 2
- JQVDAXLFBXTEQA-UHFFFAOYSA-N dibutylamine Chemical compound CCCCNCCCC JQVDAXLFBXTEQA-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- XUCNUKMRBVNAPB-UHFFFAOYSA-N fluoroethene Chemical group FC=C XUCNUKMRBVNAPB-UHFFFAOYSA-N 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 150000002430 hydrocarbons Chemical group 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000000123 paper Substances 0.000 description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 239000010453 quartz Substances 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
- 239000002023 wood Substances 0.000 description 2
- 239000008096 xylene Substances 0.000 description 2
- BOOBDAVNHSOIDB-UHFFFAOYSA-N (2,3-dichlorobenzoyl) 2,3-dichlorobenzenecarboperoxoate Chemical compound ClC1=CC=CC(C(=O)OOC(=O)C=2C(=C(Cl)C=CC=2)Cl)=C1Cl BOOBDAVNHSOIDB-UHFFFAOYSA-N 0.000 description 1
- SCYULBFZEHDVBN-UHFFFAOYSA-N 1,1-Dichloroethane Chemical compound CC(Cl)Cl SCYULBFZEHDVBN-UHFFFAOYSA-N 0.000 description 1
- QSSXJPIWXQTSIX-UHFFFAOYSA-N 1-bromo-2-methylbenzene Chemical compound CC1=CC=CC=C1Br QSSXJPIWXQTSIX-UHFFFAOYSA-N 0.000 description 1
- VFWCMGCRMGJXDK-UHFFFAOYSA-N 1-chlorobutane Chemical compound CCCCCl VFWCMGCRMGJXDK-UHFFFAOYSA-N 0.000 description 1
- TWWWGBSUPNNTMJ-UHFFFAOYSA-N 1-ethenoxy-2-methylbenzene Chemical compound CC1=CC=CC=C1OC=C TWWWGBSUPNNTMJ-UHFFFAOYSA-N 0.000 description 1
- ZBUCIAUZAGKZOS-UHFFFAOYSA-N 1-ethenoxy-3-methylbenzene Chemical compound CC1=CC=CC(OC=C)=C1 ZBUCIAUZAGKZOS-UHFFFAOYSA-N 0.000 description 1
- YXHRYLHTQVXZIK-UHFFFAOYSA-N 1-ethenoxy-4-methylbenzene Chemical compound CC1=CC=C(OC=C)C=C1 YXHRYLHTQVXZIK-UHFFFAOYSA-N 0.000 description 1
- XMJQCVMNFPEJLN-UHFFFAOYSA-N 1-ethenoxy-4-methylpentane Chemical compound CC(C)CCCOC=C XMJQCVMNFPEJLN-UHFFFAOYSA-N 0.000 description 1
- YAOJJEJGPZRYJF-UHFFFAOYSA-N 1-ethenoxyhexane Chemical compound CCCCCCOC=C YAOJJEJGPZRYJF-UHFFFAOYSA-N 0.000 description 1
- XXCVIFJHBFNFBO-UHFFFAOYSA-N 1-ethenoxyoctane Chemical compound CCCCCCCCOC=C XXCVIFJHBFNFBO-UHFFFAOYSA-N 0.000 description 1
- IOSXLUZXMXORMX-UHFFFAOYSA-N 1-ethenoxypentane Chemical compound CCCCCOC=C IOSXLUZXMXORMX-UHFFFAOYSA-N 0.000 description 1
- VJGCZWVJDRIHNC-UHFFFAOYSA-N 1-fluoroprop-1-ene Chemical compound CC=CF VJGCZWVJDRIHNC-UHFFFAOYSA-N 0.000 description 1
- BMVXCPBXGZKUPN-UHFFFAOYSA-N 1-hexanamine Chemical compound CCCCCCN BMVXCPBXGZKUPN-UHFFFAOYSA-N 0.000 description 1
- DMWVYCCGCQPJEA-UHFFFAOYSA-N 2,5-bis(tert-butylperoxy)-2,5-dimethylhexane Chemical compound CC(C)(C)OOC(C)(C)CCC(C)(C)OOC(C)(C)C DMWVYCCGCQPJEA-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 1
- PGYJSURPYAAOMM-UHFFFAOYSA-N 2-ethenoxy-2-methylpropane Chemical compound CC(C)(C)OC=C PGYJSURPYAAOMM-UHFFFAOYSA-N 0.000 description 1
- FCTZMFUKTFYQCC-UHFFFAOYSA-N 2-ethenoxyhexane Chemical compound CCCCC(C)OC=C FCTZMFUKTFYQCC-UHFFFAOYSA-N 0.000 description 1
- GNUGVECARVKIPH-UHFFFAOYSA-N 2-ethenoxypropane Chemical compound CC(C)OC=C GNUGVECARVKIPH-UHFFFAOYSA-N 0.000 description 1
- WROUWQQRXUBECT-UHFFFAOYSA-N 2-ethylacrylic acid Chemical compound CCC(=C)C(O)=O WROUWQQRXUBECT-UHFFFAOYSA-N 0.000 description 1
- SMSVUYQRWYTTLI-UHFFFAOYSA-L 2-ethylhexanoate;iron(2+) Chemical compound [Fe+2].CCCCC(CC)C([O-])=O.CCCCC(CC)C([O-])=O SMSVUYQRWYTTLI-UHFFFAOYSA-L 0.000 description 1
- ODGCZQFTJDEYNI-UHFFFAOYSA-N 2-methylcyclohex-3-ene-1,2-dicarboxylic acid Chemical compound OC(=O)C1(C)C=CCCC1C(O)=O ODGCZQFTJDEYNI-UHFFFAOYSA-N 0.000 description 1
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 1
- AYKYXWQEBUNJCN-UHFFFAOYSA-N 3-methylfuran-2,5-dione Chemical compound CC1=CC(=O)OC1=O AYKYXWQEBUNJCN-UHFFFAOYSA-N 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 239000004342 Benzoyl peroxide Substances 0.000 description 1
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
- WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical compound OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 description 1
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 1
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- 229910001209 Low-carbon steel Inorganic materials 0.000 description 1
- PEEHTFAAVSWFBL-UHFFFAOYSA-N Maleimide Chemical compound O=C1NC(=O)C=C1 PEEHTFAAVSWFBL-UHFFFAOYSA-N 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- 239000002033 PVDF binder Substances 0.000 description 1
- CYTYCFOTNPOANT-UHFFFAOYSA-N Perchloroethylene Chemical group ClC(Cl)=C(Cl)Cl CYTYCFOTNPOANT-UHFFFAOYSA-N 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- 229910010413 TiO 2 Inorganic materials 0.000 description 1
- 229920001807 Urea-formaldehyde Polymers 0.000 description 1
- ISKQADXMHQSTHK-UHFFFAOYSA-N [4-(aminomethyl)phenyl]methanamine Chemical compound NCC1=CC=C(CN)C=C1 ISKQADXMHQSTHK-UHFFFAOYSA-N 0.000 description 1
- 230000005856 abnormality Effects 0.000 description 1
- 150000008065 acid anhydrides Chemical class 0.000 description 1
- 125000004423 acyloxy group Chemical group 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000002390 adhesive tape Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 125000003342 alkenyl group Chemical group 0.000 description 1
- 125000005370 alkoxysilyl group Chemical group 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 125000001769 aryl amino group Chemical group 0.000 description 1
- 125000003609 aryl vinyl group Chemical group 0.000 description 1
- YCOXTKKNXUZSKD-UHFFFAOYSA-N as-o-xylenol Natural products CC1=CC=C(O)C=C1C YCOXTKKNXUZSKD-UHFFFAOYSA-N 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 235000019400 benzoyl peroxide Nutrition 0.000 description 1
- 229960004217 benzyl alcohol Drugs 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- NIDNOXCRFUCAKQ-UHFFFAOYSA-N bicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic acid Chemical compound C1C2C=CC1C(C(=O)O)C2C(O)=O NIDNOXCRFUCAKQ-UHFFFAOYSA-N 0.000 description 1
- 125000004369 butenyl group Chemical group C(=CCC)* 0.000 description 1
- SXPLZNMUBFBFIA-UHFFFAOYSA-N butyl(trimethoxy)silane Chemical compound CCCC[Si](OC)(OC)OC SXPLZNMUBFBFIA-UHFFFAOYSA-N 0.000 description 1
- 150000001721 carbon Chemical group 0.000 description 1
- 235000011089 carbon dioxide Nutrition 0.000 description 1
- 229950005499 carbon tetrachloride Drugs 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 229960001701 chloroform Drugs 0.000 description 1
- HNEGQIOMVPPMNR-IHWYPQMZSA-N citraconic acid Chemical compound OC(=O)C(/C)=C\C(O)=O HNEGQIOMVPPMNR-IHWYPQMZSA-N 0.000 description 1
- 229940018557 citraconic acid Drugs 0.000 description 1
- 150000001925 cycloalkenes Chemical class 0.000 description 1
- IFDVQVHZEKPUSC-UHFFFAOYSA-N cyclohex-3-ene-1,2-dicarboxylic acid Chemical compound OC(=O)C1CCC=CC1C(O)=O IFDVQVHZEKPUSC-UHFFFAOYSA-N 0.000 description 1
- 125000000596 cyclohexenyl group Chemical group C1(=CCCCC1)* 0.000 description 1
- 125000000058 cyclopentadienyl group Chemical group C1(=CC=CC1)* 0.000 description 1
- PNOXNTGLSKTMQO-UHFFFAOYSA-L diacetyloxytin Chemical compound CC(=O)O[Sn]OC(C)=O PNOXNTGLSKTMQO-UHFFFAOYSA-L 0.000 description 1
- AYOHIQLKSOJJQH-UHFFFAOYSA-N dibutyltin Chemical compound CCCC[Sn]CCCC AYOHIQLKSOJJQH-UHFFFAOYSA-N 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- LDCRTTXIJACKKU-ARJAWSKDSA-N dimethyl maleate Chemical compound COC(=O)\C=C/C(=O)OC LDCRTTXIJACKKU-ARJAWSKDSA-N 0.000 description 1
- POLCUAVZOMRGSN-UHFFFAOYSA-N dipropyl ether Chemical compound CCCOCCC POLCUAVZOMRGSN-UHFFFAOYSA-N 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 238000000921 elemental analysis Methods 0.000 description 1
- ZSWFCLXCOIISFI-UHFFFAOYSA-N endo-cyclopentadiene Natural products C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- NHOGGUYTANYCGQ-UHFFFAOYSA-N ethenoxybenzene Chemical compound C=COC1=CC=CC=C1 NHOGGUYTANYCGQ-UHFFFAOYSA-N 0.000 description 1
- HJVKTYVDOZVQPA-UHFFFAOYSA-N ethenoxycyclopentane Chemical compound C=COC1CCCC1 HJVKTYVDOZVQPA-UHFFFAOYSA-N 0.000 description 1
- AZDCYKCDXXPQIK-UHFFFAOYSA-N ethenoxymethylbenzene Chemical compound C=COCC1=CC=CC=C1 AZDCYKCDXXPQIK-UHFFFAOYSA-N 0.000 description 1
- FWDBOZPQNFPOLF-UHFFFAOYSA-N ethenyl(triethoxy)silane Chemical compound CCO[Si](OCC)(OCC)C=C FWDBOZPQNFPOLF-UHFFFAOYSA-N 0.000 description 1
- NKSJNEHGWDZZQF-UHFFFAOYSA-N ethenyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C=C NKSJNEHGWDZZQF-UHFFFAOYSA-N 0.000 description 1
- MBGQQKKTDDNCSG-UHFFFAOYSA-N ethenyl-diethoxy-methylsilane Chemical compound CCO[Si](C)(C=C)OCC MBGQQKKTDDNCSG-UHFFFAOYSA-N 0.000 description 1
- IJNRGJJYCUCFHY-UHFFFAOYSA-N ethenyl-dimethoxy-phenylsilane Chemical compound CO[Si](OC)(C=C)C1=CC=CC=C1 IJNRGJJYCUCFHY-UHFFFAOYSA-N 0.000 description 1
- WOXXJEVNDJOOLV-UHFFFAOYSA-N ethenyl-tris(2-methoxyethoxy)silane Chemical compound COCCO[Si](OCCOC)(OCCOC)C=C WOXXJEVNDJOOLV-UHFFFAOYSA-N 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000007888 film coating Substances 0.000 description 1
- 238000009501 film coating Methods 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- NKHAVTQWNUWKEO-UHFFFAOYSA-N fumaric acid monomethyl ester Natural products COC(=O)C=CC(O)=O NKHAVTQWNUWKEO-UHFFFAOYSA-N 0.000 description 1
- 229940052308 general anesthetics halogenated hydrocarbons Drugs 0.000 description 1
- 238000012812 general test Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 150000008282 halocarbons Chemical class 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 150000002432 hydroperoxides Chemical class 0.000 description 1
- 150000003949 imides Chemical class 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- SNHMUERNLJLMHN-UHFFFAOYSA-N iodobenzene Chemical compound IC1=CC=CC=C1 SNHMUERNLJLMHN-UHFFFAOYSA-N 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 239000004973 liquid crystal related substance Substances 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- NKHAVTQWNUWKEO-IHWYPQMZSA-N methyl hydrogen fumarate Chemical compound COC(=O)\C=C/C(O)=O NKHAVTQWNUWKEO-IHWYPQMZSA-N 0.000 description 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 239000012046 mixed solvent Substances 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- GEMHFKXPOCTAIP-UHFFFAOYSA-N n,n-dimethyl-n'-phenylcarbamimidoyl chloride Chemical compound CN(C)C(Cl)=NC1=CC=CC=C1 GEMHFKXPOCTAIP-UHFFFAOYSA-N 0.000 description 1
- 239000013307 optical fiber Substances 0.000 description 1
- 150000007530 organic bases Chemical class 0.000 description 1
- 150000001451 organic peroxides Chemical class 0.000 description 1
- 239000012860 organic pigment Substances 0.000 description 1
- 150000002923 oximes Chemical group 0.000 description 1
- 150000002976 peresters Chemical class 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000012429 reaction media Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- JIYNFFGKZCOPKN-UHFFFAOYSA-N sbb061129 Chemical compound O=C1OC(=O)C2C1C1C=C(C)C2C1 JIYNFFGKZCOPKN-UHFFFAOYSA-N 0.000 description 1
- 125000005372 silanol group Chemical group 0.000 description 1
- 150000003377 silicon compounds Chemical class 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000012756 surface treatment agent Substances 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- OPQYOFWUFGEMRZ-UHFFFAOYSA-N tert-butyl 2,2-dimethylpropaneperoxoate Chemical compound CC(C)(C)OOC(=O)C(C)(C)C OPQYOFWUFGEMRZ-UHFFFAOYSA-N 0.000 description 1
- GJBRNHKUVLOCEB-UHFFFAOYSA-N tert-butyl benzenecarboperoxoate Chemical compound CC(C)(C)OOC(=O)C1=CC=CC=C1 GJBRNHKUVLOCEB-UHFFFAOYSA-N 0.000 description 1
- SWAXTRYEYUTSAP-UHFFFAOYSA-N tert-butyl ethaneperoxoate Chemical compound CC(=O)OOC(C)(C)C SWAXTRYEYUTSAP-UHFFFAOYSA-N 0.000 description 1
- 229950011008 tetrachloroethylene Drugs 0.000 description 1
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- UFDHBDMSHIXOKF-UHFFFAOYSA-N tetrahydrophthalic acid Natural products OC(=O)C1=C(C(O)=O)CCCC1 UFDHBDMSHIXOKF-UHFFFAOYSA-N 0.000 description 1
- KSBAEPSJVUENNK-UHFFFAOYSA-L tin(ii) 2-ethylhexanoate Chemical compound [Sn+2].CCCCC(CC)C([O-])=O.CCCCC(CC)C([O-])=O KSBAEPSJVUENNK-UHFFFAOYSA-L 0.000 description 1
- 125000003944 tolyl group Chemical group 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Description
çºæã®æè¡åé
æ¬çºæã¯ãææ©æº¶å€ã«æº¶è§£ããåžžæž©ã§éããã«
硬åãããããšã®ã§ããããçŽ ç³»éåäœããã³ã
ã®çšéã«é¢ããã çºæã®æè¡çèæ¯ãªãã³ã«ãã®åé¡ç¹ 建ç¯ç©ãè»èŒãè¹è¶ãèªç©ºæ©çã®å€è£ åéã«ã¯
èåæ§ãèä¹ æ§ã®åªããå¡æãèŠæ±ãããããªãš
ã¹ãã«ç³»ãŸãã¯ã¢ã¯ãªã«ç³»ã®é«çŽå€è£ å¡æãå©çš
ãããŠãããããããæ¢åå¡æã®å±å€èçšå¹Žæ°ã¯
çããäžè¿°ã®é«çŽå¡æã§ããæ°å¹Žã®çŸèŠ³ãšåºæä¿
è·äœçšã倱ãã äžæ¹ãããçŽ ç³»éåäœã¯ç±çã«ãååŠçã«ã極
ããŠå®å®ã§ãããèåæ§ãèæ°Žæ§ãèè¬åæ§ãè
溶å€æ§ãããã¯é¢åæ§ãäœæ©æŠæ§ãæ¥æ°Žæ§ã«åªã
ãŠããã®ã§ãåçš®åºæã®è¡šé¢åŠçå€ãšããŠå¥œé©ã§
ãããããããåŸæ¥ç¥ãããŠããããçŽ ç³»éåäœ
ã¯ãåè¿°ã®ãããªæ§è³ªãçœãããŠãææ©æº¶åªã«æº¶
ãé£ãå¡èã®åœ¢æãå°é£ã§ãã€ãŠãå¡æãšããŠé
åžžã«äœ¿çšãé£ããããšãã°ãçŸåšç¥ãããŠããã
ãçŽ ç³»éåäœã®å¡æã¯ç²äœå¡æãå€ããå ãã«
PVdFïŒããªãããªãã³ãã«ãªã©ã€ãïŒãé«æž©äž
ã«ç¹å®ã®æº¶åªã«æº¶è§£ããæ§è³ªãå©çšããŠææ©æº¶åª
åæ£åå¡æãšããŠçšããããŠããã«éããªããã
ãããããã®ããçŽ ç³»éåäœã®å¡æã¯ãç®è圢æ
ã®éã«é«æž©ã®çŒä»ããå¿ èŠã§ããã®ã§ããã®å©çš
åéãå ç±èšåã®ã§ããå Žæã«å¶éãããããŸã
å ç±èšåã®ååšããã³çŒä»å·¥çšã®ååšã¯ãäœæ¥ã«
åŸäºãã人ã®å®å šé¢ãäœæ¥å Žã®ç°å¢é¢ããã奜ãŸ
ãããã®ã§ã¯ãªããããã§ãè¿å¹Žã«ãªã溶å€å¯æº¶
æ§ãããã¯é«æž©ã§ã®çŒä»å·¥çšã®å¿ èŠã®ãªãããçŽ
ç³»éåäœã®éçºãè©Šã¿ãããŠããã ããšãã°ç¹éæ57â34107å·å ¬å ±ã«ã¯ããã«ãª
ããªã¬ãã€ã³ãã·ã¯ãããã·ã«ããã«ãšãŒãã«ã
ã¢ã«ãã«ããã«ãšãŒãã«ããã³ããããã·ã¢ã«ã
ã«ããã«ãšãŒãã«ãããªãïŒå å ±éåäœãé瀺ã
ãŠããããã®å ±éåäœã¯ææ©æº¶å€ã«å¯æº¶ã§ãã€
ãŠãåžžæž©ã§ç¡¬åãããããšãå¯èœã§ããããšãèš
èŒãããŠããããããããã®å ±éåäœã垞枩硬å
ãããã«ã¯ãã¡ã©ãã³ç³»ç¡¬åå€ãå°¿çŽ æš¹è系硬å
å€ãå¿ èŠã§ãã€ãŠãåœç¶ãªãããã®äœ¿çšåœ¢æ ã¯ïŒ
液åã§ããäœæ¥æ§ã«å£ãããŸãããã®å ±éåäœã®
ã¬ã©ã¹è»¢ç§»æž©åºŠã¯ã垞枩以äžããªãã¡25â以äžãš
æ¯èŒçé«ããç¹å ¬æ46â39472å·å ¬å ±ã«ã¯ãå®é
ã®äŸã¯èšèŒãããŠããªãããPTFEïŒããªããã©
ãã«ãªããšãã¬ã³ïŒã«ãªã¬ãã€ã³æ§äžé£œåçµåã
ãã³å æ°Žå解å¯èœãªåºããã€ææ©çªçŽ ååç©ãã
ææ©ããããã«ãªãã·ãçã®ã©ãžã«ã«éå§å€ã®å
åšäžã§æ©æ¢°çã«åŠçãããã®ã¯ãåžžæž©ã§æ°Žã«ãã€
ãŠæ¶æ©ã硬åããããšã瀺åãããŠããããã
ãããã®æ¹æ³ã§è£œé ããããã®ã¯ãææ©çªçŽ åå
ç©ãPTFEã«ã°ã©ããããéåäœã§ãããææ©æº¶
å€ã«ã¯å®è³ªçã«äžæº¶ã§ããã çºæã®ç®ç æ¬çºæã¯ã ææ©æº¶å€ã«äœæž©ã§æº¶è§£ããã 硬åã«éããŠç¹æ®ãªç¡¬åå€ãå¿ èŠãšããªãã åžžæž©ã§ç¡¬åããã ïŒæ¶²åã®å¡æãšããŠäœ¿çšã§ããã 硬ååŸã¯èåæ§ãèæ°Žæ§ãèè¬åæ§ãè溶å€
æ§ãäœæ©æŠæ§ã«åªããã ã¢ãããŒæåããçŽæ¥éåã§ããã ãšãã€ãç¹åŸŽããã€ããçŽ ç³»éåäœãæäŸããã
ãšãç®çãšããŠããã ãŸãæ¬çºæã¯ãäžèšã®ãããªããçŽ ç³»éåäœã
å«ãããçŽ ç³»å¡æãæäŸããããšãç®çãšããŠã
ãã çºæã®æŠèŠ æ¬çºæã«ä¿ãããçŽ ç³»éåäœã¯ã [A] åŒäžR1ã¯ïŒŠã§ãããR2ãR3ããã³R4ã®å°ãª
ããšãïŒã€ã¯ïŒŠããClããéžã°ããåºã§ã
ããæ®ãã®ïŒã€ã¯ïŒŠããClããéžã°ããåºãŸ
ãã¯âCX1X2X3ïŒãã ããX1ãX3ã¯ïŒŠãã
Clããéžã°ããåºã§ãããïŒã§ãã ã§è¡šãããããã«ãªããªã¬ãã€ã³ããå°ããã
æ§æåäœ(a)ã ïŒåŒäžR5ã¯ãã¢ã«ãã«åºãã·ã¯ãã¢ã«ãã«åºã
ã¢ãªãŒã«åºãã¢ãªãŒã«ã¢ã«ãã«åºãŸãã¯ã¢ã«ã³
ãã·ã«ã¢ã«ãã«åºã§ããïŒ ã§è¡šããããããã«ãšãŒãã«ããå°ãããæ§æ
åäœ(b)ã ïŒåŒäžR6ããã³R7ã¯ããŸãã¯ççŽ æ°ïŒãïŒ
ã®äœçŽã¢ã«ãã«åºã§ãããR8ã¯å æ°Žå解å¯èœ
ãªåºãæããçªçŽ å«æåºã§ããïŒãŸã㯠ïŒåŒäžR9ã¯å æ°Žå解å¯èœãªåºãæããçªçŽ å«
æåºã§ããïŒ ã§è¡šããããããªã¬ãã€ã³æ§äžé£œåçµåããã³
å æ°Žå解å¯èœãªåºãæããææ©çªçŽ ååç©ãã
å°ãããæ§æåäœ(c)ãããªãã [B] å ±éåäœäžã®(a)ã(c)ã®åèšã¢ã«æ°ã«å¯ŸããŠã
(a)ã¯30ã70ã¢ã«ïŒ ã(b)ã¯20ã60ã¢ã«ïŒ ã(c)ã¯ïŒ
ã25ã¢ã«ïŒ ã®éã§ååšããŠããã [C] ã²ã«ã»ããŒããšãŒã·ãšã³ã¯ãããã°ã©ãæ³
ã«ãã€ãŠæž¬å®ããæ°å¹³åååéïŒïœïŒã3000
ã200000ã§ãã ã«ãã€ãŠå®çŸ©ã¥ãããã溶å€å¯æº¶æ§ã§ããã ãŸãæ¬çºæã«ä¿ãããçŽ ç³»å¡æã¯ãäžèšã®ãã
ãªããçŽ ç³»éåäœãææ©æº¶å€ã«æº¶è§£ãããŠãªãã
ãšãç¹åŸŽãšããŠããã çºæã®å ·äœç説æ 以äžæ¬çºæã«ä¿ãããçŽ ç³»éåäœããã³ããçŽ
ç³»å¡æã«ã€ããŠå ·äœçã«èª¬æããã æ¬çºæã«ä¿ãããçŽ ç³»éåäœã¯ãå°ãªããšãã
ãã«ãªããªã¬ãã€ã³ããå°ãããæ§æåäœ(a)ãšã
ããã«ãšãŒãã«ããå°ãããæ§æåäœ(b)ãšãææ©
çªçŽ ååç©ããå°ãããæ§æåäœ(c)ãšããæ§æã
ããŠãããåæ§æåäœ(a)ã(c)ã¯ã©ã³ãã ã«é åã
ããŠããããããæ¬çºæã®ç®çãæããªãç¯å²
ã§ãå°éã®ä»ã®å ±éåå¯èœãªã¢ãããŒæåãããš
ãã°Î±âãªã¬ãã€ã³é¡ãã·ã¯ããªã¬ãã€ã³é¡ãäž
飜åã«ã«ãã³é žé¡ãªã©ãå ±éåãããŠããŠãããŸ
ããªãã æ§æåäœ(a) æ¬çºæã«ä¿ãããçŽ ç³»éåäœã¯ããã«ãªããªã¬
ãã€ã³ããå°ãããæ§æåäœ(a)ãæããŠãããã
ã®æ§æåäœ(a)ã¯ãåŒ ïŒ»åŒäžR1ã¯ïŒŠã§ãããR2ãR3ããã³R4ã®å°ãªã
ãšãïŒã€ã¯ïŒŠããClããéžã°ããåºã§ãããæ®
ãã®ïŒã€ã¯ïŒŠããClããéžã°ããåºãŸãã¯â
CX1X2X3ïŒãã ããX1ãX3ã¯ïŒŠããClããéž
ã°ããåºã§ããïŒã§ããã§è¡šããããã ãã®ãããªæ§æåäœ(a)ã¯ããã«ãªããªã¬ãã€ã³
ããå°ããããããã®ãããªãã«ãªããªã¬ãã€ã³
ã¯ãäžé£œåçµåã圢æããççŽ ååã®ãã¡å°ãªã
ãšãïŒã€ã®ççŽ ååãå°ãªããšãïŒå以äžã®ãã
çŽ ååãšçµåããŠããã奜ãŸããã¯ãªã¬ãã€ã³ã®
æ°ŽçŽ ååãå šãŠããçŽ ååããã³ä»ã®ããã²ã³å
åãšã§çœ®æãããŠãããã«ãããªã¬ãã€ã³ãã
ãããšãã«ãã«ãã«ãªããªã¬ãã€ã³ã奜é©ã§ã
ããããã«éåæ§ããã³è£œé ãããéåäœã®æ§è³ª
ã®èŠ³ç¹ããã¯ãççŽ ååæ°ïŒãŸãã¯ïŒã®ãã«ãªã
ãªã¬ãã€ã³ãšãã«ãã«ãã«ãªããªã¬ãã€ã³ã奜ãŸ
ããã ãã®ãããªãã«ãªããªã¬ãã€ã³ãšããŠã¯ãå ·äœ
çã«ã¯ãCF2ïŒCF2ãCHFïŒCF2ãCH2ïŒCF2ã
CH2ïŒCHFãCClFïŒCF2ãCHClïŒCF2ãCCl2ïŒ
CF2ãCClFïŒCClFãCHFïŒCCl2ãCH2ïŒCClFã
CCl2ïŒCClFçã®ãã«ãªããšãã¬ã³ãCF3CFïŒ
CF2ãCF3CFïŒCHFãCF3CHïŒCF2ãCF3CFïŒ
CH2ãCF3FïŒCHFãCHF2CFïŒCHFãCF3CH
ïŒCH2ãCH3CFïŒCF2ãCH3CHïŒCF2ãCH3CF
ïŒCH2ãCF2ClCFïŒCF2ãCF3CClïŒCF2ã
CF3CFïŒCFClãCF2ClCClïŒCF2ãCF2ClCFïŒ
CFClãCFCl2CFïŒCF2ãCF3CClïŒCClFã
CF3CClïŒCCl2ãCClF2CFïŒCCl2ãCCl3CFïŒ
CF2ãCF2ClCClïŒCCl2ãCFCl2CClïŒCCl2ã
CF3CFïŒCHClãCClF2CFïŒCHClãCF3CClïŒ
CHClãCHF2CClïŒCCl2ãCF2ClCHïŒCCl2ã
CF2ClCClïŒCHClãCCl3CFïŒCHClãCF2ICFïŒ
CF2ãCF2BrCHïŒCF2ãCF3CBrïŒCHBrã
CF2ClCBrïŒCH2ãCH2BrCFïŒCCl2ãCF3CBrïŒ
CH2ãCF2CHïŒCHBrãCF2BrCHïŒCHFã
CF2BrCFïŒCF2çã®ãã«ãªããããã³ãçšãã
ããã ãŸããäžèšã®ãããªãã«ãªããšãã¬ã³ããã³ã
ã«ãªãã«å ããŠãCF3CF2CFïŒCF2ãCF3CFïŒ
CFCF3ãCF3CHïŒCFCF3ãCF2ïŒCFCF2CHF2ã
CF3CF2CFïŒCH2ãCF3CHïŒCHCF3ãCF2ïŒ
CFCF2CH3ãCF2ïŒCFCH2CH3ãCF3CH2CHïŒ
CH2ãCF3CHïŒCHCH3ãCF2ïŒCHCH2CH3ã
CH3CF2CHïŒCH2ãCFH2CHïŒCHCFH2ã
CH3CF2CHïŒCH3ãCH2ïŒCFCH2CH3ãCF3
ïŒCF2ïŒ2CFïŒCF2ãCF3ïŒCF2ïŒ3CFïŒCF2çã®ççŽ
ååæ°ïŒä»¥äžã®ãã«ãªããªã¬ãã€ã³ãå°éçšãã
ããšãã§ããã ãããã®äžã§ã¯ããšãã«ããã©ãã«ãªããšãã¬
ã³ïŒCF2ïŒCF2ïŒããã³ãããµãã«ãªããããã³
ïŒCF2ïŒCFCF3ïŒã奜é©ã§ãããããã«ã¯å®å šæ§ã
åæ±ãæ§ã®é¢ãããããµãã«ãªããããã³ã奜é©
ã§ããã ãŸãæ¬çºæã«ãããŠãã«ãªããªã¬ãã€ã³ã¯ãå
ç¬ã§çšããã»ãã«è€æ°ãæ··åããŠçšããããšãã§
ããã æ§æåäœ(b) æ¬çºæã«ä¿ãããçŽ ç³»éåäœã¯ãããã«ãšãŒã
ã«ããå°ãããæ§æåäœ(b)ãæããŠããããã®æ§
æåäœ(b)ã¯ã ïŒåŒäžR5ã¯ãã¢ã«ãã«åºãã·ã¯ãã¢ã«ãã«åºã
ã¢ãªãŒã«åºãã¢ãªãŒã«ã¢ã«ãã«åºãŸãã¯ã¢ã«ã³ã
ã·ã«ã¢ã«ãã«åºã§ããïŒ ã§è¡šããããã ãã®ãããªæ§æåäœ(b)ã«ãããŠãR5åºã¯ãç
çŽ ååæ°ãïŒä»¥äžå¥œãŸããã¯ççŽ ååæ°ïŒãïŒã®
ã¢ã«ãã«åºã§ããããšãæãŸãããããã«ã¢ã«ã
ã«åºã¯éç¶ã§ããããšãæãŸããã ãã®ãããªæ§æåäœ(b)ã¯ãããã«ãšãŒãã«ãã
å°ãããããããã«ãšãŒãã«ãšããŠã¯ããšãã«ã
ãã«ãšãŒãã«ããããã«ããã«ãšãŒãã«ãã€ãœã
ããã«ããã«ãšãŒãã«ãããã«ããã«ãšãŒãã«ã
tertâããã«ããã«ãšãŒãã«ããã³ãã«ããã«ãš
ãŒãã«ãããã·ã«ããã«ãšãŒãã«ãã€ãœããã·ã«
ããã«ãšãŒãã«ããªã¯ãã«ããã«ãšãŒãã«ãïŒâ
ã¡ãã«âïŒâãã³ãã«ããã«ãšãŒãã«çã®éç¶ã¢
ã«ãã«ããã«ãšãŒãã«é¡ãã·ã¯ããã³ãã«ããã«
ãšãŒãã«ãã·ã¯ãããã·ã«ããã«ãšãŒãã«çã®ã·
ã¯ãã¢ã«ãã«ããã«ãšãŒãã«é¡ãããšãã«ããã«
ãšãŒãã«ãïœâãïœâãïœâããªã«ããã«ãšãŒã
ã«çã®ã¢ãªãŒã«ããã«ãšãŒãã«é¡ããã³ãžã«ãã
ã«ãšãŒãã«ãããšããã«ããã«ãšãŒãã«çã®ã¢ã©
ã«ãã«ããã«ãšãŒãã«é¡ãæããããšãã§ããã ãããã®äžã§ã¯ãšãã«éç¶ã¢ã«ãã«ããã«ãšãŒ
ãã«ããã³ã·ã¯ãã¢ã«ãã«ããã«ãšãŒãã«ã奜ãŸ
ãããããã«ã¯ãšãã«ããã«ãšãŒãã«ããããã«
ããã«ãšãŒãã«ãããã«ããã«ãšãŒãã«ã奜é©ã§
ããã ãŸãæ¬çºæã«ãããŠããã«ãšãŒãã«ã¯ãåç¬ã§
çšããã»ãã«è€æ°æ··åããŠçšããããšãã§ããã æ§æåäœ(c) æ¬çºæã«ä¿ãããçŽ ç³»éåäœã¯ããªã¬ãã€ã³æ§
äžé£œåçµåããã³å æ°Žå解å¯èœãªåºãæããææ©
çªçŽ ååç©ããå°ãããæ§æåäœ(c)ãæããŠã
ãããã®æ§æåäœ(c)ã¯ã ïŒåŒäžR6ããã³R7ã¯ããŸãã¯ççŽ æ°ïŒãïŒã®
äœçŽã¢ã«ãã«åºã§ãããR8ã¯å æ°Žå解å¯èœãªåº
ãæããçªçŽ å«æåºã§ããïŒãŸã㯠ïŒåŒäžR9ã¯å æ°Žå解å¯èœãªåºãæããçªçŽ å«æ
åºã§ããïŒ ã§è¡šããããã äžèšã®ãããªæ§æåäœïœâ(i)ã¯ãããå ·äœçã«
ã¯ã奜ãŸããã¯ã åŒäžR6ããã³R7ã¯ããŸãã¯ççŽ æ°ïŒãïŒã®
äœçŽã¢ã«ãã«åºã§ãããR10ã¯âïŒCH2ïŒâïœïŒãã
ããïœã¯ïŒãïŒã§ããïŒãŸã㯠âïŒCH2ïŒïœïŒãã ããïœâ§ïŒïŒã§ãããY1ã
Y2ã¯âOR11ãâïŒïŒ®âR12ã
硬åãããããšã®ã§ããããçŽ ç³»éåäœããã³ã
ã®çšéã«é¢ããã çºæã®æè¡çèæ¯ãªãã³ã«ãã®åé¡ç¹ 建ç¯ç©ãè»èŒãè¹è¶ãèªç©ºæ©çã®å€è£ åéã«ã¯
èåæ§ãèä¹ æ§ã®åªããå¡æãèŠæ±ãããããªãš
ã¹ãã«ç³»ãŸãã¯ã¢ã¯ãªã«ç³»ã®é«çŽå€è£ å¡æãå©çš
ãããŠãããããããæ¢åå¡æã®å±å€èçšå¹Žæ°ã¯
çããäžè¿°ã®é«çŽå¡æã§ããæ°å¹Žã®çŸèŠ³ãšåºæä¿
è·äœçšã倱ãã äžæ¹ãããçŽ ç³»éåäœã¯ç±çã«ãååŠçã«ã極
ããŠå®å®ã§ãããèåæ§ãèæ°Žæ§ãèè¬åæ§ãè
溶å€æ§ãããã¯é¢åæ§ãäœæ©æŠæ§ãæ¥æ°Žæ§ã«åªã
ãŠããã®ã§ãåçš®åºæã®è¡šé¢åŠçå€ãšããŠå¥œé©ã§
ãããããããåŸæ¥ç¥ãããŠããããçŽ ç³»éåäœ
ã¯ãåè¿°ã®ãããªæ§è³ªãçœãããŠãææ©æº¶åªã«æº¶
ãé£ãå¡èã®åœ¢æãå°é£ã§ãã€ãŠãå¡æãšããŠé
åžžã«äœ¿çšãé£ããããšãã°ãçŸåšç¥ãããŠããã
ãçŽ ç³»éåäœã®å¡æã¯ç²äœå¡æãå€ããå ãã«
PVdFïŒããªãããªãã³ãã«ãªã©ã€ãïŒãé«æž©äž
ã«ç¹å®ã®æº¶åªã«æº¶è§£ããæ§è³ªãå©çšããŠææ©æº¶åª
åæ£åå¡æãšããŠçšããããŠããã«éããªããã
ãããããã®ããçŽ ç³»éåäœã®å¡æã¯ãç®è圢æ
ã®éã«é«æž©ã®çŒä»ããå¿ èŠã§ããã®ã§ããã®å©çš
åéãå ç±èšåã®ã§ããå Žæã«å¶éãããããŸã
å ç±èšåã®ååšããã³çŒä»å·¥çšã®ååšã¯ãäœæ¥ã«
åŸäºãã人ã®å®å šé¢ãäœæ¥å Žã®ç°å¢é¢ããã奜ãŸ
ãããã®ã§ã¯ãªããããã§ãè¿å¹Žã«ãªã溶å€å¯æº¶
æ§ãããã¯é«æž©ã§ã®çŒä»å·¥çšã®å¿ èŠã®ãªãããçŽ
ç³»éåäœã®éçºãè©Šã¿ãããŠããã ããšãã°ç¹éæ57â34107å·å ¬å ±ã«ã¯ããã«ãª
ããªã¬ãã€ã³ãã·ã¯ãããã·ã«ããã«ãšãŒãã«ã
ã¢ã«ãã«ããã«ãšãŒãã«ããã³ããããã·ã¢ã«ã
ã«ããã«ãšãŒãã«ãããªãïŒå å ±éåäœãé瀺ã
ãŠããããã®å ±éåäœã¯ææ©æº¶å€ã«å¯æº¶ã§ãã€
ãŠãåžžæž©ã§ç¡¬åãããããšãå¯èœã§ããããšãèš
èŒãããŠããããããããã®å ±éåäœã垞枩硬å
ãããã«ã¯ãã¡ã©ãã³ç³»ç¡¬åå€ãå°¿çŽ æš¹è系硬å
å€ãå¿ èŠã§ãã€ãŠãåœç¶ãªãããã®äœ¿çšåœ¢æ ã¯ïŒ
液åã§ããäœæ¥æ§ã«å£ãããŸãããã®å ±éåäœã®
ã¬ã©ã¹è»¢ç§»æž©åºŠã¯ã垞枩以äžããªãã¡25â以äžãš
æ¯èŒçé«ããç¹å ¬æ46â39472å·å ¬å ±ã«ã¯ãå®é
ã®äŸã¯èšèŒãããŠããªãããPTFEïŒããªããã©
ãã«ãªããšãã¬ã³ïŒã«ãªã¬ãã€ã³æ§äžé£œåçµåã
ãã³å æ°Žå解å¯èœãªåºããã€ææ©çªçŽ ååç©ãã
ææ©ããããã«ãªãã·ãçã®ã©ãžã«ã«éå§å€ã®å
åšäžã§æ©æ¢°çã«åŠçãããã®ã¯ãåžžæž©ã§æ°Žã«ãã€
ãŠæ¶æ©ã硬åããããšã瀺åãããŠããããã
ãããã®æ¹æ³ã§è£œé ããããã®ã¯ãææ©çªçŽ åå
ç©ãPTFEã«ã°ã©ããããéåäœã§ãããææ©æº¶
å€ã«ã¯å®è³ªçã«äžæº¶ã§ããã çºæã®ç®ç æ¬çºæã¯ã ææ©æº¶å€ã«äœæž©ã§æº¶è§£ããã 硬åã«éããŠç¹æ®ãªç¡¬åå€ãå¿ èŠãšããªãã åžžæž©ã§ç¡¬åããã ïŒæ¶²åã®å¡æãšããŠäœ¿çšã§ããã 硬ååŸã¯èåæ§ãèæ°Žæ§ãèè¬åæ§ãè溶å€
æ§ãäœæ©æŠæ§ã«åªããã ã¢ãããŒæåããçŽæ¥éåã§ããã ãšãã€ãç¹åŸŽããã€ããçŽ ç³»éåäœãæäŸããã
ãšãç®çãšããŠããã ãŸãæ¬çºæã¯ãäžèšã®ãããªããçŽ ç³»éåäœã
å«ãããçŽ ç³»å¡æãæäŸããããšãç®çãšããŠã
ãã çºæã®æŠèŠ æ¬çºæã«ä¿ãããçŽ ç³»éåäœã¯ã [A] åŒäžR1ã¯ïŒŠã§ãããR2ãR3ããã³R4ã®å°ãª
ããšãïŒã€ã¯ïŒŠããClããéžã°ããåºã§ã
ããæ®ãã®ïŒã€ã¯ïŒŠããClããéžã°ããåºãŸ
ãã¯âCX1X2X3ïŒãã ããX1ãX3ã¯ïŒŠãã
Clããéžã°ããåºã§ãããïŒã§ãã ã§è¡šãããããã«ãªããªã¬ãã€ã³ããå°ããã
æ§æåäœ(a)ã ïŒåŒäžR5ã¯ãã¢ã«ãã«åºãã·ã¯ãã¢ã«ãã«åºã
ã¢ãªãŒã«åºãã¢ãªãŒã«ã¢ã«ãã«åºãŸãã¯ã¢ã«ã³
ãã·ã«ã¢ã«ãã«åºã§ããïŒ ã§è¡šããããããã«ãšãŒãã«ããå°ãããæ§æ
åäœ(b)ã ïŒåŒäžR6ããã³R7ã¯ããŸãã¯ççŽ æ°ïŒãïŒ
ã®äœçŽã¢ã«ãã«åºã§ãããR8ã¯å æ°Žå解å¯èœ
ãªåºãæããçªçŽ å«æåºã§ããïŒãŸã㯠ïŒåŒäžR9ã¯å æ°Žå解å¯èœãªåºãæããçªçŽ å«
æåºã§ããïŒ ã§è¡šããããããªã¬ãã€ã³æ§äžé£œåçµåããã³
å æ°Žå解å¯èœãªåºãæããææ©çªçŽ ååç©ãã
å°ãããæ§æåäœ(c)ãããªãã [B] å ±éåäœäžã®(a)ã(c)ã®åèšã¢ã«æ°ã«å¯ŸããŠã
(a)ã¯30ã70ã¢ã«ïŒ ã(b)ã¯20ã60ã¢ã«ïŒ ã(c)ã¯ïŒ
ã25ã¢ã«ïŒ ã®éã§ååšããŠããã [C] ã²ã«ã»ããŒããšãŒã·ãšã³ã¯ãããã°ã©ãæ³
ã«ãã€ãŠæž¬å®ããæ°å¹³åååéïŒïœïŒã3000
ã200000ã§ãã ã«ãã€ãŠå®çŸ©ã¥ãããã溶å€å¯æº¶æ§ã§ããã ãŸãæ¬çºæã«ä¿ãããçŽ ç³»å¡æã¯ãäžèšã®ãã
ãªããçŽ ç³»éåäœãææ©æº¶å€ã«æº¶è§£ãããŠãªãã
ãšãç¹åŸŽãšããŠããã çºæã®å ·äœç説æ 以äžæ¬çºæã«ä¿ãããçŽ ç³»éåäœããã³ããçŽ
ç³»å¡æã«ã€ããŠå ·äœçã«èª¬æããã æ¬çºæã«ä¿ãããçŽ ç³»éåäœã¯ãå°ãªããšãã
ãã«ãªããªã¬ãã€ã³ããå°ãããæ§æåäœ(a)ãšã
ããã«ãšãŒãã«ããå°ãããæ§æåäœ(b)ãšãææ©
çªçŽ ååç©ããå°ãããæ§æåäœ(c)ãšããæ§æã
ããŠãããåæ§æåäœ(a)ã(c)ã¯ã©ã³ãã ã«é åã
ããŠããããããæ¬çºæã®ç®çãæããªãç¯å²
ã§ãå°éã®ä»ã®å ±éåå¯èœãªã¢ãããŒæåãããš
ãã°Î±âãªã¬ãã€ã³é¡ãã·ã¯ããªã¬ãã€ã³é¡ãäž
飜åã«ã«ãã³é žé¡ãªã©ãå ±éåãããŠããŠãããŸ
ããªãã æ§æåäœ(a) æ¬çºæã«ä¿ãããçŽ ç³»éåäœã¯ããã«ãªããªã¬
ãã€ã³ããå°ãããæ§æåäœ(a)ãæããŠãããã
ã®æ§æåäœ(a)ã¯ãåŒ ïŒ»åŒäžR1ã¯ïŒŠã§ãããR2ãR3ããã³R4ã®å°ãªã
ãšãïŒã€ã¯ïŒŠããClããéžã°ããåºã§ãããæ®
ãã®ïŒã€ã¯ïŒŠããClããéžã°ããåºãŸãã¯â
CX1X2X3ïŒãã ããX1ãX3ã¯ïŒŠããClããéž
ã°ããåºã§ããïŒã§ããã§è¡šããããã ãã®ãããªæ§æåäœ(a)ã¯ããã«ãªããªã¬ãã€ã³
ããå°ããããããã®ãããªãã«ãªããªã¬ãã€ã³
ã¯ãäžé£œåçµåã圢æããççŽ ååã®ãã¡å°ãªã
ãšãïŒã€ã®ççŽ ååãå°ãªããšãïŒå以äžã®ãã
çŽ ååãšçµåããŠããã奜ãŸããã¯ãªã¬ãã€ã³ã®
æ°ŽçŽ ååãå šãŠããçŽ ååããã³ä»ã®ããã²ã³å
åãšã§çœ®æãããŠãããã«ãããªã¬ãã€ã³ãã
ãããšãã«ãã«ãã«ãªããªã¬ãã€ã³ã奜é©ã§ã
ããããã«éåæ§ããã³è£œé ãããéåäœã®æ§è³ª
ã®èŠ³ç¹ããã¯ãççŽ ååæ°ïŒãŸãã¯ïŒã®ãã«ãªã
ãªã¬ãã€ã³ãšãã«ãã«ãã«ãªããªã¬ãã€ã³ã奜ãŸ
ããã ãã®ãããªãã«ãªããªã¬ãã€ã³ãšããŠã¯ãå ·äœ
çã«ã¯ãCF2ïŒCF2ãCHFïŒCF2ãCH2ïŒCF2ã
CH2ïŒCHFãCClFïŒCF2ãCHClïŒCF2ãCCl2ïŒ
CF2ãCClFïŒCClFãCHFïŒCCl2ãCH2ïŒCClFã
CCl2ïŒCClFçã®ãã«ãªããšãã¬ã³ãCF3CFïŒ
CF2ãCF3CFïŒCHFãCF3CHïŒCF2ãCF3CFïŒ
CH2ãCF3FïŒCHFãCHF2CFïŒCHFãCF3CH
ïŒCH2ãCH3CFïŒCF2ãCH3CHïŒCF2ãCH3CF
ïŒCH2ãCF2ClCFïŒCF2ãCF3CClïŒCF2ã
CF3CFïŒCFClãCF2ClCClïŒCF2ãCF2ClCFïŒ
CFClãCFCl2CFïŒCF2ãCF3CClïŒCClFã
CF3CClïŒCCl2ãCClF2CFïŒCCl2ãCCl3CFïŒ
CF2ãCF2ClCClïŒCCl2ãCFCl2CClïŒCCl2ã
CF3CFïŒCHClãCClF2CFïŒCHClãCF3CClïŒ
CHClãCHF2CClïŒCCl2ãCF2ClCHïŒCCl2ã
CF2ClCClïŒCHClãCCl3CFïŒCHClãCF2ICFïŒ
CF2ãCF2BrCHïŒCF2ãCF3CBrïŒCHBrã
CF2ClCBrïŒCH2ãCH2BrCFïŒCCl2ãCF3CBrïŒ
CH2ãCF2CHïŒCHBrãCF2BrCHïŒCHFã
CF2BrCFïŒCF2çã®ãã«ãªããããã³ãçšãã
ããã ãŸããäžèšã®ãããªãã«ãªããšãã¬ã³ããã³ã
ã«ãªãã«å ããŠãCF3CF2CFïŒCF2ãCF3CFïŒ
CFCF3ãCF3CHïŒCFCF3ãCF2ïŒCFCF2CHF2ã
CF3CF2CFïŒCH2ãCF3CHïŒCHCF3ãCF2ïŒ
CFCF2CH3ãCF2ïŒCFCH2CH3ãCF3CH2CHïŒ
CH2ãCF3CHïŒCHCH3ãCF2ïŒCHCH2CH3ã
CH3CF2CHïŒCH2ãCFH2CHïŒCHCFH2ã
CH3CF2CHïŒCH3ãCH2ïŒCFCH2CH3ãCF3
ïŒCF2ïŒ2CFïŒCF2ãCF3ïŒCF2ïŒ3CFïŒCF2çã®ççŽ
ååæ°ïŒä»¥äžã®ãã«ãªããªã¬ãã€ã³ãå°éçšãã
ããšãã§ããã ãããã®äžã§ã¯ããšãã«ããã©ãã«ãªããšãã¬
ã³ïŒCF2ïŒCF2ïŒããã³ãããµãã«ãªããããã³
ïŒCF2ïŒCFCF3ïŒã奜é©ã§ãããããã«ã¯å®å šæ§ã
åæ±ãæ§ã®é¢ãããããµãã«ãªããããã³ã奜é©
ã§ããã ãŸãæ¬çºæã«ãããŠãã«ãªããªã¬ãã€ã³ã¯ãå
ç¬ã§çšããã»ãã«è€æ°ãæ··åããŠçšããããšãã§
ããã æ§æåäœ(b) æ¬çºæã«ä¿ãããçŽ ç³»éåäœã¯ãããã«ãšãŒã
ã«ããå°ãããæ§æåäœ(b)ãæããŠããããã®æ§
æåäœ(b)ã¯ã ïŒåŒäžR5ã¯ãã¢ã«ãã«åºãã·ã¯ãã¢ã«ãã«åºã
ã¢ãªãŒã«åºãã¢ãªãŒã«ã¢ã«ãã«åºãŸãã¯ã¢ã«ã³ã
ã·ã«ã¢ã«ãã«åºã§ããïŒ ã§è¡šããããã ãã®ãããªæ§æåäœ(b)ã«ãããŠãR5åºã¯ãç
çŽ ååæ°ãïŒä»¥äžå¥œãŸããã¯ççŽ ååæ°ïŒãïŒã®
ã¢ã«ãã«åºã§ããããšãæãŸãããããã«ã¢ã«ã
ã«åºã¯éç¶ã§ããããšãæãŸããã ãã®ãããªæ§æåäœ(b)ã¯ãããã«ãšãŒãã«ãã
å°ãããããããã«ãšãŒãã«ãšããŠã¯ããšãã«ã
ãã«ãšãŒãã«ããããã«ããã«ãšãŒãã«ãã€ãœã
ããã«ããã«ãšãŒãã«ãããã«ããã«ãšãŒãã«ã
tertâããã«ããã«ãšãŒãã«ããã³ãã«ããã«ãš
ãŒãã«ãããã·ã«ããã«ãšãŒãã«ãã€ãœããã·ã«
ããã«ãšãŒãã«ããªã¯ãã«ããã«ãšãŒãã«ãïŒâ
ã¡ãã«âïŒâãã³ãã«ããã«ãšãŒãã«çã®éç¶ã¢
ã«ãã«ããã«ãšãŒãã«é¡ãã·ã¯ããã³ãã«ããã«
ãšãŒãã«ãã·ã¯ãããã·ã«ããã«ãšãŒãã«çã®ã·
ã¯ãã¢ã«ãã«ããã«ãšãŒãã«é¡ãããšãã«ããã«
ãšãŒãã«ãïœâãïœâãïœâããªã«ããã«ãšãŒã
ã«çã®ã¢ãªãŒã«ããã«ãšãŒãã«é¡ããã³ãžã«ãã
ã«ãšãŒãã«ãããšããã«ããã«ãšãŒãã«çã®ã¢ã©
ã«ãã«ããã«ãšãŒãã«é¡ãæããããšãã§ããã ãããã®äžã§ã¯ãšãã«éç¶ã¢ã«ãã«ããã«ãšãŒ
ãã«ããã³ã·ã¯ãã¢ã«ãã«ããã«ãšãŒãã«ã奜ãŸ
ãããããã«ã¯ãšãã«ããã«ãšãŒãã«ããããã«
ããã«ãšãŒãã«ãããã«ããã«ãšãŒãã«ã奜é©ã§
ããã ãŸãæ¬çºæã«ãããŠããã«ãšãŒãã«ã¯ãåç¬ã§
çšããã»ãã«è€æ°æ··åããŠçšããããšãã§ããã æ§æåäœ(c) æ¬çºæã«ä¿ãããçŽ ç³»éåäœã¯ããªã¬ãã€ã³æ§
äžé£œåçµåããã³å æ°Žå解å¯èœãªåºãæããææ©
çªçŽ ååç©ããå°ãããæ§æåäœ(c)ãæããŠã
ãããã®æ§æåäœ(c)ã¯ã ïŒåŒäžR6ããã³R7ã¯ããŸãã¯ççŽ æ°ïŒãïŒã®
äœçŽã¢ã«ãã«åºã§ãããR8ã¯å æ°Žå解å¯èœãªåº
ãæããçªçŽ å«æåºã§ããïŒãŸã㯠ïŒåŒäžR9ã¯å æ°Žå解å¯èœãªåºãæããçªçŽ å«æ
åºã§ããïŒ ã§è¡šããããã äžèšã®ãããªæ§æåäœïœâ(i)ã¯ãããå ·äœçã«
ã¯ã奜ãŸããã¯ã åŒäžR6ããã³R7ã¯ããŸãã¯ççŽ æ°ïŒãïŒã®
äœçŽã¢ã«ãã«åºã§ãããR10ã¯âïŒCH2ïŒâïœïŒãã
ããïœã¯ïŒãïŒã§ããïŒãŸã㯠âïŒCH2ïŒïœïŒãã ããïœâ§ïŒïŒã§ãããY1ã
Y2ã¯âOR11ãâïŒïŒ®âR12ã
ãåŒã
ïŒãã ãåŒäžR11ãR14ã¯ã¢ã«ãã«åºãã¢ã«ã³ã
ã·ã¢ã«ãã«åºãã¢ã«ã±ãã«åºãã¢ãªãŒã«åºããéž
ã°ããåºã§ããïŒã§ãããã¯ãåèšâOR11ãâ
ïŒNR12ã
ã·ã¢ã«ãã«åºãã¢ã«ã±ãã«åºãã¢ãªãŒã«åºããéž
ã°ããåºã§ããïŒã§ãããã¯ãåèšâOR11ãâ
ïŒNR12ã
以äžæ¬çºæã®å
容ã奜é©ãªäŸã§ãã€ãŠèª¬æãã
ãããšãã«æããã®ãªãéãæ¬çºæã¯ãããã®äŸ
ã«å¶éããããã®ã§ã¯ãªããæ¬çºæã®ç®çãæã
ãªãç¯å²ã§ãããªãæ æ§ãå¯èœã§ããã å®æœäŸ ïŒ å 容ç©300c.c.ã®ã¹ãã³ã¬ã¹è£œæ¹ææ©ä»ãªãŒãã¯
ã¬ãŒãã«ãã³ãŒã³80ïœãããã«ããã«ãšãŒãã«
ïŒBVEïŒ25.2ïœãããªã¡ããã·ããã«ã·ã©ã³
ïŒTMVSïŒ7.1ïœãéé žåãžã©ãŠãã€ã«ïŒïœãä»
蟌ã¿ãã¢ã»ãã³ããã©ã€ã¢ã€ã¹ã«ããåºåãè±æ°
ãè¡ããç³»å ã®é žçŽ ãé€å»ããããã®ã®ã¡ããã
ãµãã«ãªããããã³ïŒHFPïŒ45ïœããªãŒãã¯ã¬
ãŒãäžã«å°å ¥ããææž©ããããªãŒãã¯ã¬ãŒãå ã®
枩床ã65âã«éããæç¹ã§ã®å§åã¯8.1KgïŒcm2ã§
ãã€ããæ¹æäžã«ïŒæéåå¿ãç¶ããå§åã4.6
KgïŒcm2ã«éããæç¹ã§ãªãŒãã¯ã¬ãŒããæ°Žå·ãå
å¿ãåæ¢ãããå·åŽåŸãæªåå¿ã¢ãããŒãè¿œãåº
ãããªãŒãã¯ã¬ãŒããéæŸããåå¿æ¶²ããšãåºã
ããæ¿çž®åŸããã³ãŒã³ã¡ã¿ããŒã«æ··å溶åªã§æŽæµ
ããåã³æ¿çž®ã也ç¥ãè¡ã€ããããªããŒåéã¯60
ïœã§ãã€ãã åŸãããããªããŒã®GPCã«ããæ°å¹³åååé
ã¯1.0Ã104ã§ãããã¬ã©ã¹è»¢ç§»ç¹ã¯â14âã§ãã€
ãã ãã®å ±éåäœã®çµæåæãå çŽ åæããã³
NMRãçšããŠè¡ã€ããšãããHFPïŒBVEïŒ
TMVSïŒ48ïŒ40ïŒ12ïŒã¢ã«æ¯ïŒã§ãã€ãã æ¬éåäœïŒïœããã«ãšã³ïŒïœã«æº¶è§£ãããžãã
ã«é«ãžã©ãŠã¬ãŒãïŒDBTDLïŒ3.2Ã10âïŒïœã
å ãããã®ãè»éŒæ¿ã«ãšããã·ç³»ãã©ã€ããŒãå¡
åžããäžã«ã¢ããªã±ãŒã¿ãŒãçšããŠå¡åžããã宀
æž©é€çã§æå·14æ¥ã«ãããå¡èã®æ§ç¶ã調ã¹ããš
ããè¡šïŒã«ç€ºãçµæãåŸãã ãŸããåæ§ã«ã¬ã©ã¹æ¿ã«å¡åžïŒãšããã·ãã©ã€
ããŒããïŒãããã®ã10ïŒ ç¡«é žã10ïŒ å¡©é žã10ïŒ
é ¢é žã10ïŒ æ°Žé žåãããªãŠã ã®å液ã«æµžæŒ¬ããã
ã®ã¯ïŒé±éã§ãç°åžžã¯ã¿ãããªãã€ãã äžæ¹ã45ÎŒïœåã®ç¡¬åãã€ã«ã ã®å ç·ééçã¯
99.6ïŒ ã§ãã€ãããŸãéŒæ¿å¡åžç©ã§ã®60ãâ60ãé¡
é¢åå°çã¯86.8ïŒ ã§ãã€ãã æ¬éåäœ100éééšãTiO250éééšããã«ãšã³
100éééšãããã³ãžããã«é«ãžã©ãŠã¬ãŒã0.16
éééšãããªãçµæç©ããšããã·ç³»ãã©ã€ããŒã
å¡åžããéŒæ¿ã«å¡ãã宀枩ã§10æ¥éé€çãããã
ã®éŒæ¿å¡åžç©ããµã³ã·ã€ã€ã³ãŠãšã¶ã¡ãŒã¿ãŒïŒã
ã©ãã¯ããã«æž©åºŠ63âïŒã«800æéããããšãã®
60ãâ60ãé¡é¢ä¿æçã¯99.6ïŒ ãè²å·®ïŒÎEïŒã¯0.51
ã§ãã€ãã
ãããšãã«æããã®ãªãéãæ¬çºæã¯ãããã®äŸ
ã«å¶éããããã®ã§ã¯ãªããæ¬çºæã®ç®çãæã
ãªãç¯å²ã§ãããªãæ æ§ãå¯èœã§ããã å®æœäŸ ïŒ å 容ç©300c.c.ã®ã¹ãã³ã¬ã¹è£œæ¹ææ©ä»ãªãŒãã¯
ã¬ãŒãã«ãã³ãŒã³80ïœãããã«ããã«ãšãŒãã«
ïŒBVEïŒ25.2ïœãããªã¡ããã·ããã«ã·ã©ã³
ïŒTMVSïŒ7.1ïœãéé žåãžã©ãŠãã€ã«ïŒïœãä»
蟌ã¿ãã¢ã»ãã³ããã©ã€ã¢ã€ã¹ã«ããåºåãè±æ°
ãè¡ããç³»å ã®é žçŽ ãé€å»ããããã®ã®ã¡ããã
ãµãã«ãªããããã³ïŒHFPïŒ45ïœããªãŒãã¯ã¬
ãŒãäžã«å°å ¥ããææž©ããããªãŒãã¯ã¬ãŒãå ã®
枩床ã65âã«éããæç¹ã§ã®å§åã¯8.1KgïŒcm2ã§
ãã€ããæ¹æäžã«ïŒæéåå¿ãç¶ããå§åã4.6
KgïŒcm2ã«éããæç¹ã§ãªãŒãã¯ã¬ãŒããæ°Žå·ãå
å¿ãåæ¢ãããå·åŽåŸãæªåå¿ã¢ãããŒãè¿œãåº
ãããªãŒãã¯ã¬ãŒããéæŸããåå¿æ¶²ããšãåºã
ããæ¿çž®åŸããã³ãŒã³ã¡ã¿ããŒã«æ··å溶åªã§æŽæµ
ããåã³æ¿çž®ã也ç¥ãè¡ã€ããããªããŒåéã¯60
ïœã§ãã€ãã åŸãããããªããŒã®GPCã«ããæ°å¹³åååé
ã¯1.0Ã104ã§ãããã¬ã©ã¹è»¢ç§»ç¹ã¯â14âã§ãã€
ãã ãã®å ±éåäœã®çµæåæãå çŽ åæããã³
NMRãçšããŠè¡ã€ããšãããHFPïŒBVEïŒ
TMVSïŒ48ïŒ40ïŒ12ïŒã¢ã«æ¯ïŒã§ãã€ãã æ¬éåäœïŒïœããã«ãšã³ïŒïœã«æº¶è§£ãããžãã
ã«é«ãžã©ãŠã¬ãŒãïŒDBTDLïŒ3.2Ã10âïŒïœã
å ãããã®ãè»éŒæ¿ã«ãšããã·ç³»ãã©ã€ããŒãå¡
åžããäžã«ã¢ããªã±ãŒã¿ãŒãçšããŠå¡åžããã宀
æž©é€çã§æå·14æ¥ã«ãããå¡èã®æ§ç¶ã調ã¹ããš
ããè¡šïŒã«ç€ºãçµæãåŸãã ãŸããåæ§ã«ã¬ã©ã¹æ¿ã«å¡åžïŒãšããã·ãã©ã€
ããŒããïŒãããã®ã10ïŒ ç¡«é žã10ïŒ å¡©é žã10ïŒ
é ¢é žã10ïŒ æ°Žé žåãããªãŠã ã®å液ã«æµžæŒ¬ããã
ã®ã¯ïŒé±éã§ãç°åžžã¯ã¿ãããªãã€ãã äžæ¹ã45ÎŒïœåã®ç¡¬åãã€ã«ã ã®å ç·ééçã¯
99.6ïŒ ã§ãã€ãããŸãéŒæ¿å¡åžç©ã§ã®60ãâ60ãé¡
é¢åå°çã¯86.8ïŒ ã§ãã€ãã æ¬éåäœ100éééšãTiO250éééšããã«ãšã³
100éééšãããã³ãžããã«é«ãžã©ãŠã¬ãŒã0.16
éééšãããªãçµæç©ããšããã·ç³»ãã©ã€ããŒã
å¡åžããéŒæ¿ã«å¡ãã宀枩ã§10æ¥éé€çãããã
ã®éŒæ¿å¡åžç©ããµã³ã·ã€ã€ã³ãŠãšã¶ã¡ãŒã¿ãŒïŒã
ã©ãã¯ããã«æž©åºŠ63âïŒã«800æéããããšãã®
60ãâ60ãé¡é¢ä¿æçã¯99.6ïŒ ãè²å·®ïŒÎEïŒã¯0.51
ã§ãã€ãã
ãè¡šã
ãè¡šã
ãŽãã³ç®ã»ã»ãããŒãè©ŠéšïŒéŒæ¿ã«å¡åžããå¡ã
æ¿ã®å¡èè¡šé¢ã«ãJIS  5400 1979å¡æäžè¬
è©Šéšæ¹æ³6.15ç¢ç€ç®è©Šéšãã«æºããŠåãå·ãå ¥
ãããã€ãã«ç¢ç€ç®éšåã®å¡èè¡šé¢ã«å¹ 20mmã®
ã»ããã³ç²çããŒããããŠããã®äžããå¹ ïŒmm
ã®ã¹ãããŠã©ã§åŒ·ãããããªããããŒããå¡è
é¢ã«å¯çãããããšãæ¥éã«ã»ããã³ããŒãã
éçŽäžæ¹ã«åŒãäžããŠã¯ãããããã®ã»ããã³
ããŒãã®å¯çãšã¯ãããç¢ç€ç®ã®ïŒèŸºã®åæ¹å
ããèšïŒåè¡ããé€ãããã«æ®ã€ãç¢ç€ç®ã®æ°
ã調ã¹ããã®æ°ã§è©Šéšæç©ã衚瀺ããã ã¢ã»ãã³ããã«ãšã³æµžæŒ¬ïŒã¢ã»ãã³ãŸãã¯ãã«ãš
ã³æº¶æ¶²äžã«å®€æž©äžã§24æéæŸçœ®ããå¡èã«ã¯ã
ãããµãããçºçããªãããç®èŠã§å€æããã éç硬床ïŒJIS  5400ïŒ1979ïŒ6.14ã«æºæ ããŠ
枬å®ããã å±æ²æ§ïŒJIS  5400ïŒ1979ïŒ6.16ã«æºæ ããŠæž¬
å®ããã éæ©æŠä¿æ°ïŒéŒæ¿ã«ããçŽ ç³»å¡æãå¡åžãã硬å
ãããéŒæ¿ããïŒcmÃïŒcmã®å°çãåãåºãã
åäžéåäœå¡åžç¡¬åããéŒæ¿äžã«å¡èé¢ãæ¥è§Š
ããããã«çœ®ããå°çäžã«145ïœã®ããããèŒ
ããŠéŒæ¿ã®äžç«¯ãæã¡äžããŠãå°çããã¹ãèœ
ã¡ã¯ãããæã®åŸæè§ïŒÎžïŒãæ±ããtanΞãé
æ©æŠä¿æ°ãšããã æ°Žãšã®æ¥è§Šè§ïŒæ¥è§Šè§æž¬å®æ©ïŒååçé¢ç§åŠ(æ ª)補
ã³ã³ã¿ã¯ã¿ã³ã°ã«ã¡ãŒã¿ãŒïŒã«å¡è£ æ¿ãæ°Žå¹³ã«
ãšãã€ããããã€ã¯ãã·ãªã³ãžãçšããŠãéå
ã«èžçæ°Žã®æ¶²æ»Žã圢æããããå¡è£ æ¿è¡šé¢ãé
å ã«è¿ã¥ã液滎ã«éãã«è§ŠããããåŸãéå ã
ãéãã«é¢ããŠã液滎ãéå ããå¡è£ æ¿è¡šé¢ã«
移è¡ããããæ°Žãšç©ºæ°ãšã®çé¢ãšå¡è£ æ¿ãšã®ãª
ãè§ãã枬å®æ©ä»å±ã®å åŠé¡ãçšããŠèªã¿ãšã€
ãã å®æœäŸ ïŒ å®æœäŸïŒãšåæ§ã®æ¡ä»¶ã§ãããµãã«ãªãããã
ã³ãã¯ããããªãã«ãªããšãã¬ã³ïŒCTFEïŒã«å€
ããå ±éåäœã®åæãè¡ã€ãã çµæåæã®çµæTMVSå«éã¯ïŒã¢ã«ïŒ ã§ãã€
ãããŸããååéã¯ïŒÃ104ãTgã¯ïŒâã§ãã€
ãã ãã®å ±éåäœãå®æœäŸïŒãšåæ§ã®åŠæ¹ã§å¡åžã
ããã®ã®æ§ç¶ãè¡šïŒã«ç€ºãã
æ¿ã®å¡èè¡šé¢ã«ãJIS  5400 1979å¡æäžè¬
è©Šéšæ¹æ³6.15ç¢ç€ç®è©Šéšãã«æºããŠåãå·ãå ¥
ãããã€ãã«ç¢ç€ç®éšåã®å¡èè¡šé¢ã«å¹ 20mmã®
ã»ããã³ç²çããŒããããŠããã®äžããå¹ ïŒmm
ã®ã¹ãããŠã©ã§åŒ·ãããããªããããŒããå¡è
é¢ã«å¯çãããããšãæ¥éã«ã»ããã³ããŒãã
éçŽäžæ¹ã«åŒãäžããŠã¯ãããããã®ã»ããã³
ããŒãã®å¯çãšã¯ãããç¢ç€ç®ã®ïŒèŸºã®åæ¹å
ããèšïŒåè¡ããé€ãããã«æ®ã€ãç¢ç€ç®ã®æ°
ã調ã¹ããã®æ°ã§è©Šéšæç©ã衚瀺ããã ã¢ã»ãã³ããã«ãšã³æµžæŒ¬ïŒã¢ã»ãã³ãŸãã¯ãã«ãš
ã³æº¶æ¶²äžã«å®€æž©äžã§24æéæŸçœ®ããå¡èã«ã¯ã
ãããµãããçºçããªãããç®èŠã§å€æããã éç硬床ïŒJIS  5400ïŒ1979ïŒ6.14ã«æºæ ããŠ
枬å®ããã å±æ²æ§ïŒJIS  5400ïŒ1979ïŒ6.16ã«æºæ ããŠæž¬
å®ããã éæ©æŠä¿æ°ïŒéŒæ¿ã«ããçŽ ç³»å¡æãå¡åžãã硬å
ãããéŒæ¿ããïŒcmÃïŒcmã®å°çãåãåºãã
åäžéåäœå¡åžç¡¬åããéŒæ¿äžã«å¡èé¢ãæ¥è§Š
ããããã«çœ®ããå°çäžã«145ïœã®ããããèŒ
ããŠéŒæ¿ã®äžç«¯ãæã¡äžããŠãå°çããã¹ãèœ
ã¡ã¯ãããæã®åŸæè§ïŒÎžïŒãæ±ããtanΞãé
æ©æŠä¿æ°ãšããã æ°Žãšã®æ¥è§Šè§ïŒæ¥è§Šè§æž¬å®æ©ïŒååçé¢ç§åŠ(æ ª)補
ã³ã³ã¿ã¯ã¿ã³ã°ã«ã¡ãŒã¿ãŒïŒã«å¡è£ æ¿ãæ°Žå¹³ã«
ãšãã€ããããã€ã¯ãã·ãªã³ãžãçšããŠãéå
ã«èžçæ°Žã®æ¶²æ»Žã圢æããããå¡è£ æ¿è¡šé¢ãé
å ã«è¿ã¥ã液滎ã«éãã«è§ŠããããåŸãéå ã
ãéãã«é¢ããŠã液滎ãéå ããå¡è£ æ¿è¡šé¢ã«
移è¡ããããæ°Žãšç©ºæ°ãšã®çé¢ãšå¡è£ æ¿ãšã®ãª
ãè§ãã枬å®æ©ä»å±ã®å åŠé¡ãçšããŠèªã¿ãšã€
ãã å®æœäŸ ïŒ å®æœäŸïŒãšåæ§ã®æ¡ä»¶ã§ãããµãã«ãªãããã
ã³ãã¯ããããªãã«ãªããšãã¬ã³ïŒCTFEïŒã«å€
ããå ±éåäœã®åæãè¡ã€ãã çµæåæã®çµæTMVSå«éã¯ïŒã¢ã«ïŒ ã§ãã€
ãããŸããååéã¯ïŒÃ104ãTgã¯ïŒâã§ãã€
ãã ãã®å ±éåäœãå®æœäŸïŒãšåæ§ã®åŠæ¹ã§å¡åžã
ããã®ã®æ§ç¶ãè¡šïŒã«ç€ºãã
ãè¡šã
å®æœäŸ ïŒã13
å®æœäŸïŒãšåæ§ã«éåãè¡ããåŸãããå
±éå
äœã®ç©æ§ãè¡šïŒã«ç€ºãã ãŸããéŒæ¿ã«ãšããã·ç³»ãã©ã€ããŒãå¡åžãã
äžã«ãåå ±éåäœã®ãã«ãšã³æº¶æ¶²ã«é©å®DBTDL
ãå ãããã®ãå¡åžãã宀枩ã§ïŒé±éé€çããã
ã®ã®ç©æ§ãè¡šïŒã«ç€ºãããªããè¡šïŒã«ã¯å®æœäŸ
ïŒãïŒã®çµæãããããŠç€ºããã ãªããå®æœäŸïŒã§åŸãããå ±éåäœã®NMRã
ã€ãŒãã第ïŒå³ã«ç€ºãã
äœã®ç©æ§ãè¡šïŒã«ç€ºãã ãŸããéŒæ¿ã«ãšããã·ç³»ãã©ã€ããŒãå¡åžãã
äžã«ãåå ±éåäœã®ãã«ãšã³æº¶æ¶²ã«é©å®DBTDL
ãå ãããã®ãå¡åžãã宀枩ã§ïŒé±éé€çããã
ã®ã®ç©æ§ãè¡šïŒã«ç€ºãããªããè¡šïŒã«ã¯å®æœäŸ
ïŒãïŒã®çµæãããããŠç€ºããã ãªããå®æœäŸïŒã§åŸãããå ±éåäœã®NMRã
ã€ãŒãã第ïŒå³ã«ç€ºãã
ãè¡šã
ãè¡šã
å®æœäŸ 14
å®æœäŸïŒãšåæ§ã®æ¡ä»¶ã§ãããµãã«ãªãããã
ã³ãããã©ãã«ãªããšãã¬ã³ïŒTFEïŒã«å€ãã
å ±éåäœã®åæãè¡ã€ãã çµæåæã®çµæTMVSå«æã¯ïŒã¢ã«ïŒ ã§ãã€
ãããŸããååéã¯ïŒÃ104ãTgã¯ïŒâã§ãã€
ãã ãã®å ±éåäœãå®æœäŸïŒãšåæ§ã®åŠæ¹ã§å¡åžã
ããã®ã®æ§ç¶ãè¡šïŒã«ç€ºãã
ã³ãããã©ãã«ãªããšãã¬ã³ïŒTFEïŒã«å€ãã
å ±éåäœã®åæãè¡ã€ãã çµæåæã®çµæTMVSå«æã¯ïŒã¢ã«ïŒ ã§ãã€
ãããŸããååéã¯ïŒÃ104ãTgã¯ïŒâã§ãã€
ãã ãã®å ±éåäœãå®æœäŸïŒãšåæ§ã®åŠæ¹ã§å¡åžã
ããã®ã®æ§ç¶ãè¡šïŒã«ç€ºãã
ãè¡šã
çºæã®å¹æ
æ¬çºæã®ããçŽ ç³»éåäœã¯ã
(i) ææ©æº¶å€ã«åžžæž©ã§æº¶è§£ããã
(ii) æ°Žåãååšããã°åžžæž©ã§ç¡¬ååå¿ãé²ãã
(iii) éææ§ã«åªãã硬ååŸã¯èåæ§ãèè¬åæ§ã
æ©æ¢°çæ§è³ªãå®æ©æŠæ§çã®æ§è³ªã«åªããã ãšãã€ãç¹é·ã瀺ãããããã€ãŠå¡æãšããŠçšã
ãå Žåã«ã¯ã (iv) ïŒæ¶²åå¡æãšããŠäœ¿çšã§ãã (v) ããçŽ ç³»å¡æã§ãããªããçŒä»å·¥çšãäžèŠã§
ããã ãšãã€ãç¹é·ã瀺ããæ ã«éå±ãæšæããã©ã¹ã
ãã¯ãã»ã©ããã¯ãçŽçã®ã³ãŒãã€ã³ã°å€ãå ã
ã¢ã€ããŒãå ãã€ã¹ã¯ã液æ¶è¡šç€ºåºæ¿ã®è¡šé¢ã³ãŒ
ãã«å©çšã§ããã
æ©æ¢°çæ§è³ªãå®æ©æŠæ§çã®æ§è³ªã«åªããã ãšãã€ãç¹é·ã瀺ãããããã€ãŠå¡æãšããŠçšã
ãå Žåã«ã¯ã (iv) ïŒæ¶²åå¡æãšããŠäœ¿çšã§ãã (v) ããçŽ ç³»å¡æã§ãããªããçŒä»å·¥çšãäžèŠã§
ããã ãšãã€ãç¹é·ã瀺ããæ ã«éå±ãæšæããã©ã¹ã
ãã¯ãã»ã©ããã¯ãçŽçã®ã³ãŒãã€ã³ã°å€ãå ã
ã¢ã€ããŒãå ãã€ã¹ã¯ã液æ¶è¡šç€ºåºæ¿ã®è¡šé¢ã³ãŒ
ãã«å©çšã§ããã
第ïŒå³ã¯ãæ¬çºæã«ä¿ã溶å€å¯æº¶æ§ããçŽ ç³»é
åäœã®NMRãã€ãŒãã§ããã
åäœã®NMRãã€ãŒãã§ããã
Claims (1)
- ãç¹èš±è«æ±ã®ç¯å²ã ïŒ [A] åŒäžR1ã¯ïŒŠã§ãããR2ãR3ããã³R4ã®å°ãª
ããšãïŒã€ã¯ïŒŠããClããéžã°ããåºã§ã
ããæ®ãã®ïŒã€ã¯ïŒŠããClããéžã°ããåºãŸ
ãã¯âCX1X2X3ïŒãã ããX1ãX3ã¯ïŒŠãã
Clããéžã°ããåºã§ããïŒã§ãã ã§è¡šãããããã«ãªããªã¬ãã€ã³ããå°ããã
æ§æåäœ(a)ã ïŒåŒäžR5ã¯ãã¢ã«ãã«åºãã·ã¯ãã¢ã«ãã«åºã
ã¢ãªãŒã«åºãã¢ãªãŒã«ã¢ã«ãã«åºãŸãã¯ã¢ã«ã³
ãã·ã«ã¢ã«ãã«åºã§ããïŒ ã§è¡šããããããã«ãšãŒãã«ããå°ãããæ§æ
åäœ(b)ã ïŒåŒäžR6ããã³R7ã¯ããŸãã¯ççŽ æ°ïŒãïŒ
ã®äœçŽã¢ã«ãã«åºã§ãããR8ã¯å æ°Žå解å¯èœ
ãªåºãæããçªçŽ å«æåºã§ããïŒãŸã㯠ïŒåŒäžR9ã¯å æ°Žå解å¯èœãªåºãæããçªçŽ å«
æåºã§ããïŒ ã§è¡šããããããªã¬ãã€ã³æ§äžé£œåçµåããã³
å æ°Žå解å¯èœãªåºãæããææ©çªçŽ ååç©ãã
å°ãããæ§æåäœ(c)ãããªãã [B] å ±éåäœäžã®(a)ã(c)ã®åèšã¢ã«æ°ã«å¯ŸããŠã
(a)ã¯30ã70ã¢ã«ïŒ ã(b)ã¯20ã60ã¢ã«ïŒ ã(c)ã¯ïŒ
ã25ã¢ã«ïŒ ã®éã§ååšããŠããã [C] ã²ã«ã»ããŒããšãŒã·ãšã³ã¯ãããã°ã©ãæ³
ã«ãã€ãŠæž¬å®ããæ°å¹³åååéïŒïœïŒã3000
ã200000ã§ãã ã«ãã€ãŠå®çŸ©ã¥ãããã溶å€å¯æº¶æ§ããçŽ ç³»éå
äœã ïŒ ããã«ãšãŒãã«ããå°ãããæ§æåäœ(b)ã«ã
ããŠãR5ãã¢ã«ãã«åºã§ããç¹èš±è«æ±ã®ç¯å²ç¬¬
ïŒé ã«èšèŒã®æº¶å€å¯æº¶æ§ããçŽ ç³»éåäœã ïŒ R5ã®ççŽ ååæ°ãïŒä»¥äžã§ããç¹èš±è«æ±ã®
ç¯å²ç¬¬ïŒé ã«èšèŒã®æº¶å€å¯æº¶æ§ããçŽ ç³»éåäœã ïŒ ãªã¬ãã€ã³æ§äžé£œåçµåããã³å æ°Žå解å¯èœ
ãªåºãæããææ©çªçŽ ååç©ããäžèšåŒ(1)ã(3)ã§
瀺ãããããããã§ããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé ã«
èšèŒã®æº¶å€å¯æº¶æ§ããçŽ ç³»éåäœã R21R22SiY1Y2 âŠâŠ(1) R21XSiY1Y2 âŠâŠ(2) R21SiY1Y2Y3 âŠâŠ(3) ïŒåŒäžãR21ãR22ã¯ãªã¬ãã€ã³æ§äžé£œåçµåã
æããççŽ ãæ°ŽçŽ ããã³ä»»æã«é žçŽ ãããªããå
åäžãŸãã¯çžç°ãªãåºã§ãããã¯ãªã¬ãã€ã³æ§
äžé£œåçµåãæããªãææ©åºã§ãããY1ãY2ã
ãã³Y3ã¯ååäžãŸãã¯çžç°ãªãå æ°Žå解å¯èœãª
åºã§ãããïŒ ïŒ äžèšæº¶å€å¯æº¶æ§ããçŽ ç³»éåäœããããã«ã
ãªã¹ã¢ã«ã³ãã·ã·ã©ã³ãŸãã¯ããªã¢ã«ã³ãã·ãã
ããã·ã¢ã«ãã«ã·ã©ã³ã§ããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒ
é ã«èšèŒã®æº¶å€å¯æº¶æ§ããçŽ ç³»éåäœã ïŒ [A] åŒäžR1ã¯ïŒŠã§ãããR2ãR3ããã³R4ã®å°ãª
ããšãïŒã€ã¯ïŒŠããClããéžã°ããåºã§ã
ããæ®ãã®ïŒã€ã¯ïŒŠããClããéžã°ããåºãŸ
ãã¯âCX1X2X3ïŒãã ããX1ãX3ã¯ïŒŠãã
Clããéžã°ããåºã§ããïŒã§ãã ã§è¡šãããããã«ãªããªã¬ãã€ã³ããå°ããã
æ§æåäœ(a)ã ïŒåŒäžR5ã¯ãã¢ã«ãã«åºãã·ã¯ãã¢ã«ãã«åºã
ã¢ãªãŒã«åºãã¢ãªãŒã«ã¢ã«ãã«åºãŸãã¯ã¢ã«ã³
ãã·ã«ã¢ã«ãã«åºã§ããïŒ ã§è¡šããããããã«ãšãŒãã«ããå°ãããæ§æ
åäœ(b)ã ïŒåŒäžR6ããã³R7ã¯ããŸãã¯ççŽ æ°ïŒãïŒ
ã®äœçŽã¢ã«ãã«åºã§ãããR8ã¯å æ°Žå解å¯èœ
ãªåºãæããçªçŽ å«æåºã§ããïŒãŸã㯠ïŒåŒäžR9ã¯å æ°Žå解å¯èœãªåºãæããçªçŽ å«
æåºã§ããïŒ ã§è¡šããããããªã¬ãã€ã³æ§äžé£œåçµåããã³
å æ°Žå解å¯èœãªåºãæããææ©çªçŽ ååç©ãã
å°ãããæ§æåäœ(c)ãããªãã [B] å ±éåäœäžã®(a)ã(c)ã®åèšã¢ã«æ°ã«å¯ŸããŠã
(a)ã¯30ã70ã¢ã«ïŒ ã(b)ã¯20ã60ã¢ã«ïŒ ã(c)ã¯ïŒ
ã25ã¢ã«ïŒ ã®éã§ååšããŠããã [C] ã²ã«ã»ããŒããšãŒã·ãšã³ã¯ãããã°ã©ãæ³
ã«ãã€ãŠæž¬å®ããæ°å¹³åååéïŒïœïŒã3000
ã200000ã§ãã ã«ãã€ãŠå®çŸ©ã¥ãããã溶å€å¯æº¶æ§ããçŽ ç³»éå
äœããææ©æº¶å€äžã«æº¶è§£ããããšãç¹åŸŽãšããã
ãçŽ ç³»å¡æã
Priority Applications (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP26301784A JPS61141713A (ja) | 1984-12-14 | 1984-12-14 | 溶å€å¯æº¶æ§ããçŽ ç³»éåäœåã³ãã®çšé |
US06/808,241 US4701508A (en) | 1984-12-14 | 1985-12-12 | Solvent soluble fluorine-containing polymer, coating composition containing the same and coating process thereof |
DE8585309108T DE3582129D1 (de) | 1984-12-14 | 1985-12-13 | Loesliches fluorhaltiges polymer, dieses enthaltende beschichtungsmasse und beschichtungsverfahren. |
CA000497688A CA1257737A (en) | 1984-12-14 | 1985-12-13 | Solvent soluble fluorine-containing polymer, coating composition containing the same and coating process thereof |
EP85309108A EP0185526B1 (en) | 1984-12-14 | 1985-12-13 | Solvent soluble fluorine-containing polymer, coating composition containing the same and coating process thereof |
US07/082,197 US4751114A (en) | 1984-12-14 | 1987-08-06 | Solvent soluble fluorine-containing polymer, coating composition containing the same and coating process thereof |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP26301784A JPS61141713A (ja) | 1984-12-14 | 1984-12-14 | 溶å€å¯æº¶æ§ããçŽ ç³»éåäœåã³ãã®çšé |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS61141713A JPS61141713A (ja) | 1986-06-28 |
JPH0116405B2 true JPH0116405B2 (ja) | 1989-03-24 |
Family
ID=17383724
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP26301784A Granted JPS61141713A (ja) | 1984-12-14 | 1984-12-14 | 溶å€å¯æº¶æ§ããçŽ ç³»éåäœåã³ãã®çšé |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS61141713A (ja) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2007010706A1 (ja) * | 2005-07-22 | 2007-01-25 | Daikin Industries, Ltd. | 倪éœé»æ± ã®ããã¯ã·ãŒã |
Families Citing this family (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2509088B2 (ja) * | 1985-03-25 | 1996-06-19 | äžæŽåæå·¥æ¥ æ ªåŒäŒç€Ÿ | 被èŠçµæç© |
JPH0649358B2 (ja) * | 1985-03-25 | 1994-06-29 | ãã€ãã³å·¥æ¥æ ªåŒäŒç€Ÿ | äžè¬å€è£ æ |
JPH0819194B2 (ja) * | 1987-03-27 | 1996-02-28 | æç¡åæ ªåŒäŒç€Ÿ | ãã«ãªããªã¬ãã€ã³ïŒã·ãããµã³å«æããã«ãšãŒãã«å ±éåäœ |
JPH02151607A (ja) * | 1988-12-02 | 1990-06-11 | Mitsui Petrochem Ind Ltd | å«ããçŽ å ±éåäœããã³ãã®çšé |
JP2725726B2 (ja) * | 1988-12-02 | 1998-03-11 | äžäºååŠæ ªåŒäŒç€Ÿ | å«ããçŽ å ±éåäœã®è£œé æ¹æ³ |
JPH02151608A (ja) * | 1988-12-02 | 1990-06-11 | Mitsui Petrochem Ind Ltd | å«ããçŽ å ±éåäœããã³ãã®çšé |
JPH02252714A (ja) * | 1989-03-28 | 1990-10-11 | Shin Etsu Chem Co Ltd | ããåãããªãã³ç³»å ±éåäœã®è£œé æ¹æ³ |
JP2008274306A (ja) * | 1998-05-26 | 2008-11-13 | Jsr Corp | çµæç© |
JP5561407B2 (ja) * | 2012-05-24 | 2014-07-30 | ãã€ãã³å·¥æ¥æ ªåŒäŒç€Ÿ | å«ããçŽ éåäœåã³ãã®è£œé æ¹æ³ |
KR20180105154A (ko) * | 2016-02-05 | 2018-09-27 | ë ìŒë¬ŽìŽì€ 컎íŒë ìíìš, ìììš | í룚ì€ë¡ì€í©ì²Ž ìœí íì±ì© í룚ì€ë¡ì€í©ì²Ž ì©ì¡ |
KR102542925B1 (ko) * | 2017-07-21 | 2023-06-16 | ë ìŒë¬ŽìŽì€ 컎íŒë ìíìš, ìììš | êŽê°êµê²°í©ì± í룚ì€ë¡ì€í©ì²Ž ìœí ì¡°ì±ë¬Œ ë° ê·žë¡ë¶í° íì±ëë íšìë² ìŽì ìžµ |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5436395A (en) * | 1977-08-25 | 1979-03-17 | Kanegafuchi Chem Ind Co Ltd | Novel vinyl type resins, their preparation, and coatings containing the same |
JPS5734107A (en) * | 1980-08-08 | 1982-02-24 | Asahi Glass Co Ltd | Room temperature-curable fluorine-containing copolymer |
JPS60202156A (ja) * | 1984-03-28 | 1985-10-12 | Du Pont Mitsui Fluorochem Co Ltd | ã»ã©ããã¯ã¹åºæçšããã©ãã«ãªããšãã¬ã³ã³ããªãâç²äœå¡æãã©ã€ãâ |
-
1984
- 1984-12-14 JP JP26301784A patent/JPS61141713A/ja active Granted
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5436395A (en) * | 1977-08-25 | 1979-03-17 | Kanegafuchi Chem Ind Co Ltd | Novel vinyl type resins, their preparation, and coatings containing the same |
JPS5734107A (en) * | 1980-08-08 | 1982-02-24 | Asahi Glass Co Ltd | Room temperature-curable fluorine-containing copolymer |
JPS60202156A (ja) * | 1984-03-28 | 1985-10-12 | Du Pont Mitsui Fluorochem Co Ltd | ã»ã©ããã¯ã¹åºæçšããã©ãã«ãªããšãã¬ã³ã³ããªãâç²äœå¡æãã©ã€ãâ |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2007010706A1 (ja) * | 2005-07-22 | 2007-01-25 | Daikin Industries, Ltd. | 倪éœé»æ± ã®ããã¯ã·ãŒã |
JP2007035694A (ja) * | 2005-07-22 | 2007-02-08 | Daikin Ind Ltd | 倪éœé»æ± ã®ããã¯ã·ãŒã |
EP2418082A1 (en) * | 2005-07-22 | 2012-02-15 | Daikin Industries, Limited | Back sheet of solar cell |
EP2730406A1 (en) * | 2005-07-22 | 2014-05-14 | Daikin Industries, Limited | Back sheet of solar cell |
Also Published As
Publication number | Publication date |
---|---|
JPS61141713A (ja) | 1986-06-28 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US4701508A (en) | Solvent soluble fluorine-containing polymer, coating composition containing the same and coating process thereof | |
JPH0116405B2 (ja) | ||
JPH0588845B2 (ja) | ||
KR940008034B1 (ko) | ë¶ìíšì ê³µì€í©ì²Ž ì¡°ì±ë¬Œ | |
US5043393A (en) | Process for producing fluorine-containing copolymer and fluorine-containing copolymer composition | |
JPH02151608A (ja) | å«ããçŽ å ±éåäœããã³ãã®çšé | |
US5179181A (en) | Process for producing fluorine-containing copolymer and fluorine-containing copolymer composition | |
JPH0239948B2 (ja) | Futsusokeitoryonotosohoho | |
JPS6332826B2 (ja) | ||
JP2725726B2 (ja) | å«ããçŽ å ±éåäœã®è£œé æ¹æ³ | |
JP2697906B2 (ja) | å«ããçŽ å ±éåäœããã³ãã®çšé | |
JPS62265605A (ja) | ããçŽ éåäœãäž»æåãšããã¯ã©ããéšãæããå ãã¡ã€ã | |
JP2725725B2 (ja) | å«ããçŽ å ±éåäœããã³ãã®çšé | |
JPH02151607A (ja) | å«ããçŽ å ±éåäœããã³ãã®çšé | |
JPH02265979A (ja) | å¡æçšå«ããçŽ æš¹è | |
JPH03281612A (ja) | å«ããçŽ å ±éåäœããã³ãã®çšé | |
JPH0136869B2 (ja) | ||
JPH07286126A (ja) | ç¡æ©ã»ææ©è€å被èŠå€çšãã€ã³ã㌠| |
JPH03281611A (ja) | å«ããçŽ å ±éåäœããã³ãã®çšé | |
JPS63170478A (ja) | åå°å¡æ | |
JPS62187739A (ja) | ããçŽ ç³»éåäœã®è¢«èŠå±€ãæããæ圢å | |
JP2685255B2 (ja) | å«ããçŽ å ±éåäœçµæç© | |
JPH03281610A (ja) | å«ããçŽ å ±éåäœããã³ãã®çšé | |
JPH0243847Y2 (ja) | ||
JP2698261B2 (ja) | å¡æçšæš¹è |