JP7401334B2 - リリース剤、および、樹脂成形物の製造方法 - Google Patents
リリース剤、および、樹脂成形物の製造方法 Download PDFInfo
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- JP7401334B2 JP7401334B2 JP2020018482A JP2020018482A JP7401334B2 JP 7401334 B2 JP7401334 B2 JP 7401334B2 JP 2020018482 A JP2020018482 A JP 2020018482A JP 2020018482 A JP2020018482 A JP 2020018482A JP 7401334 B2 JP7401334 B2 JP 7401334B2
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- 239000011347 resin Substances 0.000 title claims description 78
- 229920005989 resin Polymers 0.000 title claims description 78
- 238000004519 manufacturing process Methods 0.000 title claims description 12
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 85
- 229920000642 polymer Polymers 0.000 claims description 82
- 239000003795 chemical substances by application Substances 0.000 claims description 79
- 239000002253 acid Substances 0.000 claims description 75
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 70
- 239000000178 monomer Substances 0.000 claims description 67
- 125000000217 alkyl group Chemical group 0.000 claims description 42
- 229910021529 ammonia Inorganic materials 0.000 claims description 34
- 238000006116 polymerization reaction Methods 0.000 claims description 33
- 229910052751 metal Inorganic materials 0.000 claims description 32
- 239000002184 metal Substances 0.000 claims description 32
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- 238000006386 neutralization reaction Methods 0.000 claims description 19
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical group OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 16
- 230000009477 glass transition Effects 0.000 claims description 16
- 125000004432 carbon atom Chemical group C* 0.000 claims description 15
- 238000000465 moulding Methods 0.000 claims description 11
- 125000003118 aryl group Chemical group 0.000 claims description 6
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- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims 1
- 125000002723 alicyclic group Chemical group 0.000 claims 1
- 125000001931 aliphatic group Chemical group 0.000 claims 1
- 125000002947 alkylene group Chemical group 0.000 claims 1
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- 125000004430 oxygen atom Chemical group O* 0.000 claims 1
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- 229910052717 sulfur Inorganic materials 0.000 claims 1
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- 238000000034 method Methods 0.000 description 32
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- WNAHIZMDSQCWRP-UHFFFAOYSA-N dodecane-1-thiol Chemical compound CCCCCCCCCCCCS WNAHIZMDSQCWRP-UHFFFAOYSA-N 0.000 description 10
- 125000000524 functional group Chemical group 0.000 description 10
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 9
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- IAXXETNIOYFMLW-GYSYKLTISA-N [(1r,3r,4r)-4,7,7-trimethyl-3-bicyclo[2.2.1]heptanyl] 2-methylprop-2-enoate Chemical compound C1C[C@@]2(C)[C@H](OC(=O)C(=C)C)C[C@@H]1C2(C)C IAXXETNIOYFMLW-GYSYKLTISA-N 0.000 description 9
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- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 8
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- HMZGPNHSPWNGEP-UHFFFAOYSA-N octadecyl 2-methylprop-2-enoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)C(C)=C HMZGPNHSPWNGEP-UHFFFAOYSA-N 0.000 description 8
- 238000010521 absorption reaction Methods 0.000 description 7
- ARXJGSRGQADJSQ-UHFFFAOYSA-N 1-methoxypropan-2-ol Chemical compound COCC(C)O ARXJGSRGQADJSQ-UHFFFAOYSA-N 0.000 description 6
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 6
- 239000012986 chain transfer agent Substances 0.000 description 6
- 238000011109 contamination Methods 0.000 description 6
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- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 6
- 229940119545 isobornyl methacrylate Drugs 0.000 description 6
- 239000007787 solid Substances 0.000 description 6
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical class OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 5
- 239000011203 carbon fibre reinforced carbon Substances 0.000 description 5
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- 239000004816 latex Substances 0.000 description 5
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- 238000002156 mixing Methods 0.000 description 5
- 239000010935 stainless steel Substances 0.000 description 5
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- 125000000542 sulfonic acid group Chemical group 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 4
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- 150000005215 alkyl ethers Chemical class 0.000 description 4
- 125000003277 amino group Chemical group 0.000 description 4
- 239000002270 dispersing agent Substances 0.000 description 4
- GMSCBRSQMRDRCD-UHFFFAOYSA-N dodecyl 2-methylprop-2-enoate Chemical compound CCCCCCCCCCCCOC(=O)C(C)=C GMSCBRSQMRDRCD-UHFFFAOYSA-N 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 4
- 239000010452 phosphate Substances 0.000 description 4
- 229910001415 sodium ion Inorganic materials 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- 125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- 239000004793 Polystyrene Substances 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 125000005037 alkyl phenyl group Chemical group 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
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- 238000000071 blow moulding Methods 0.000 description 3
- 238000005266 casting Methods 0.000 description 3
- 125000004122 cyclic group Chemical group 0.000 description 3
- 239000008367 deionised water Substances 0.000 description 3
- 229910021641 deionized water Inorganic materials 0.000 description 3
- UAOMVDZJSHZZME-UHFFFAOYSA-N diisopropylamine Chemical compound CC(C)NC(C)C UAOMVDZJSHZZME-UHFFFAOYSA-N 0.000 description 3
- 239000012153 distilled water Substances 0.000 description 3
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 description 3
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
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- 229910052708 sodium Inorganic materials 0.000 description 3
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- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 3
- DTGKSKDOIYIVQL-WEDXCCLWSA-N (+)-borneol Chemical group C1C[C@@]2(C)[C@@H](O)C[C@@H]1C2(C)C DTGKSKDOIYIVQL-WEDXCCLWSA-N 0.000 description 2
- AVTLBBWTUPQRAY-UHFFFAOYSA-N 2-(2-cyanobutan-2-yldiazenyl)-2-methylbutanenitrile Chemical compound CCC(C)(C#N)N=NC(C)(CC)C#N AVTLBBWTUPQRAY-UHFFFAOYSA-N 0.000 description 2
- UXFQFBNBSPQBJW-UHFFFAOYSA-N 2-amino-2-methylpropane-1,3-diol Chemical compound OCC(N)(C)CO UXFQFBNBSPQBJW-UHFFFAOYSA-N 0.000 description 2
- KDSNLYIMUZNERS-UHFFFAOYSA-N 2-methylpropanamine Chemical compound CC(C)CN KDSNLYIMUZNERS-UHFFFAOYSA-N 0.000 description 2
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- ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical compound CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 description 2
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- QUSNBJAOOMFDIB-UHFFFAOYSA-N Ethylamine Chemical compound CCN QUSNBJAOOMFDIB-UHFFFAOYSA-N 0.000 description 2
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- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
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- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 2
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- 238000000926 separation method Methods 0.000 description 2
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 2
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- PSGCQDPCAWOCSH-UHFFFAOYSA-N (4,7,7-trimethyl-3-bicyclo[2.2.1]heptanyl) prop-2-enoate Chemical compound C1CC2(C)C(OC(=O)C=C)CC1C2(C)C PSGCQDPCAWOCSH-UHFFFAOYSA-N 0.000 description 1
- XVOUMQNXTGKGMA-OWOJBTEDSA-N (E)-glutaconic acid Chemical compound OC(=O)C\C=C\C(O)=O XVOUMQNXTGKGMA-OWOJBTEDSA-N 0.000 description 1
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- CWKVFRNCODQPDB-UHFFFAOYSA-N 1-(2-aminoethylamino)propan-2-ol Chemical compound CC(O)CNCCN CWKVFRNCODQPDB-UHFFFAOYSA-N 0.000 description 1
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- YAJYJWXEWKRTPO-UHFFFAOYSA-N 2,3,3,4,4,5-hexamethylhexane-2-thiol Chemical compound CC(C)C(C)(C)C(C)(C)C(C)(C)S YAJYJWXEWKRTPO-UHFFFAOYSA-N 0.000 description 1
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- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 1
- 229920000536 2-Acrylamido-2-methylpropane sulfonic acid Polymers 0.000 description 1
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- PTTPXKJBFFKCEK-UHFFFAOYSA-N 2-Methyl-4-heptanone Chemical compound CC(C)CC(=O)CC(C)C PTTPXKJBFFKCEK-UHFFFAOYSA-N 0.000 description 1
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- WDQMWEYDKDCEHT-UHFFFAOYSA-N 2-ethylhexyl 2-methylprop-2-enoate Chemical compound CCCCC(CC)COC(=O)C(C)=C WDQMWEYDKDCEHT-UHFFFAOYSA-N 0.000 description 1
- 125000006020 2-methyl-1-propenyl group Chemical group 0.000 description 1
- RUMACXVDVNRZJZ-UHFFFAOYSA-N 2-methylpropyl 2-methylprop-2-enoate Chemical compound CC(C)COC(=O)C(C)=C RUMACXVDVNRZJZ-UHFFFAOYSA-N 0.000 description 1
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 1
- QOXOZONBQWIKDA-UHFFFAOYSA-N 3-hydroxypropyl Chemical group [CH2]CCO QOXOZONBQWIKDA-UHFFFAOYSA-N 0.000 description 1
- AYKYXWQEBUNJCN-UHFFFAOYSA-N 3-methylfuran-2,5-dione Chemical compound CC1=CC(=O)OC1=O AYKYXWQEBUNJCN-UHFFFAOYSA-N 0.000 description 1
- OFNISBHGPNMTMS-UHFFFAOYSA-N 3-methylideneoxolane-2,5-dione Chemical compound C=C1CC(=O)OC1=O OFNISBHGPNMTMS-UHFFFAOYSA-N 0.000 description 1
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- 125000002889 tridecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- GKODZWOPPOTFGA-UHFFFAOYSA-N tris(hydroxyethyl)aminomethane Chemical compound OCCC(N)(CCO)CCO GKODZWOPPOTFGA-UHFFFAOYSA-N 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N urethane group Chemical group NC(=O)OCC JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- NLVXSWCKKBEXTG-UHFFFAOYSA-N vinylsulfonic acid Chemical compound OS(=O)(=O)C=C NLVXSWCKKBEXTG-UHFFFAOYSA-N 0.000 description 1
- 230000037303 wrinkles Effects 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- DGVVWUTYPXICAM-UHFFFAOYSA-N β‐Mercaptoethanol Chemical compound OCCS DGVVWUTYPXICAM-UHFFFAOYSA-N 0.000 description 1
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- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
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Description
次いで、この方法では、得られた重合体を、アンモニアおよび/またはアミン類からなる中和剤により中和する。
(実施例1)
撹拌装置、温度計および還流冷却器を備えた4つ口フラスコに、ラウリルメタクリレート(LMA)25質量部、ステアリルメタクリレート(SMA)20質量部、nブチルメタクリレート(nBMA)40質量部、アクリル酸(AA)15質量部、連鎖移動剤としてのn-ドデシルメルカプタン(NDM)4質量部、および、溶剤としてのプロピレングリコールモノメチルエーテル(PGME)35質量部を入れて撹拌した。
表1~表3に示す処方に変更した以外は、実施例1と同じ方法で、重合体中和物を含むリリース剤を得た。
撹拌装置、温度計および還流冷却器を備えた4つ口フラスコに、脱イオン水385質量部と、非反応性乳化剤としてのドデシルベンゼンスルホン酸ナトリウム10質量部とを入れて、撹拌した。
撹拌装置、温度計および還流冷却器を備えた4つ口フラスコに、脱イオン水385質量部と、反応性乳化剤としてのソジウムアルキルアリルスルホサクシネート10質量部とを入れて、撹拌した。
アンモニアに代えて水酸化ナトリウムにより重合体中の酸基(カルボキシ基)を中和した以外は、実施例1と同じ方法で、重合体中和物を含むリリース剤を得た。
(1)重量平均分子量
以下の条件で、酸基中和前の重合体の重量平均分子量を測定した。その結果を、表中に示す。
・装置:GPC-101(昭和電工製)
・流量:1.0mL/min
・展開溶媒:テトラヒドロフラン(THF)
・カラム種類:GPC KF-806L(昭和電工製)、KF-802(昭和電工製)
・カラム温度:40℃
・試料濃度:0.2質量%
・検出器:RI
・標準試料:単分散ポリスチレン(昭和電工製)
(2)酸価
各実施例および各比較例における配合処方に基づいて、酸基中和前の重合体の酸価を算出した。
各実施例および各比較例における配合処方、および、FOX式(下記式(1))に基づいて、酸基中和前の重合体のガラス転移温度を算出した。
上記式(1)において、Tgは酸基中和前の重合体のガラス転移温度(単位:K)を示し、Tgi(i=1、2、・・・n)は、重合成分に含まれる各モノマーiがホモポリマーを形成した際のガラス転移温度(単位:K)を示し、Wi(i=1、2、・・・n)は、各モノマーiの全重合成分中の質量分率を示す。
各実施例および各比較例における配合処方、および、以下の方法により、酸基中和前の重合体のClogP(poly)値を算出した。
<評価>
(1)耐水性
各実施例および各比較例で得られたリリース剤を、固形分濃度5質量%となるように蒸留水で希釈した後、ステンレス(SUS 304)製のテストピースに、バーコーター(No3)にて塗布し、80℃の乾燥機で5分間乾燥させた。これにより、テストピースにリリース膜を形成した。
各実施例および各比較例で得られたリリース剤を、固形分濃度5質量%となるように蒸留水で希釈した後、ステンレス(SUS 304)製のテストピースに、バーコーター(No3)にて塗布し、80℃の乾燥機で5分間乾燥させた。これにより、テストピースに塗布量(乾燥後の量)0.5g/m2のリリース膜を形成した。
A+: 10mN/cm未満
A : 10mN/cm以上 40mN/cm未満
B+: 40mN/cm以上 70mN/cm未満
B : 70mN/cm以上100mN/cm未満
C :100mN/cm以上
(3)耐成形物汚染性
上記(2)の剥離試験の後において、ポリビニルアルコールのフィルムにおけるリリース膜と接触していた面を、フーリエ交換赤外分光光度計(FTIR-4600 日本分光製)にて分析した。
C:リリース膜に由来する赤外吸収強度 ≧ ポリビニルアルコールフィルムに由来する赤外吸収強度
A評価~C評価のIRチャートの具体例を、図1に示す。
SMA:ステアリルメタクリレート
SA:ステアリルアクリレート
VA:ベヘニルアクリレート
2EHA:2-エチルヘキシルアクリレート
2EHMA:2-エチルヘキシルメタクリレート
nBMA:n-ブチルメタクリレート
iBMA:イソブチルメタクリレート
IBXMA:イソボルニルメタクリレート
AA:アクリル酸
リン酸系A:2-アクリロイルオキシエチルアシッドフォスフェート
PGME:プロピレングリコールモノメチルエーテル
ABN-E:2,2’-アゾビス(2-メチルブチロニトリル)、日本ファインケム社製
NDM:n-ドデシルメルカプタン
KPS:過硫酸カリウム
非反応性乳化剤A:ドデシルベンゼンスルホン酸ナトリウム
反応性乳化剤B:ソジウムアルキルアリルスルホサクシネート
NH3:アンモニア
NaOH:水酸化ナトリウム
Claims (10)
- 炭素数12~22の長鎖アルキル基を有する(メタ)アクリレートと、酸基含有エチレン性不飽和結合含有モノマーとを含む重合成分の重合体であって、
酸基がアンモニアおよび/またはアミン類により中和されている重合体を含み、
前記重合成分は、下記一般式(1)で表される含フッ素モノマーを含有しない
ことを特徴とする、リリース剤。
一般式(1) CH2=C(-X)C(=O)-Y-Z-Rf
(式中、Xは、水素原子、1価の有機基、ハロゲン原子、炭素数1~21の直鎖状または分岐鎖状パーフルオロアルキル基、または、シアノ基を示す。Yは、酸素原子、硫黄原子、または、第2級アミンを示す。Zは、直鎖アルキレン基、2価有機基、炭素数6~18の芳香族基または脂環族基、または、炭素数1~10の脂肪族基を示す。Rfは、炭素数1~21の直鎖状または分岐鎖状パーフルオロアルキルを示す。) - 前記重合体のガラス転移温度が、25℃以上であることを特徴とする、請求項1に記載のリリース剤。
- 酸基中和前の前記重合体の酸価が、80mgKOH/g以上200mgKOH/g以下である
ことを特徴とする、請求項1または2に記載のリリース剤。 - 前記重合体の重量平均分子量が、3,000以上220,000以下である
ことを特徴とする、請求項1~3のいずれか一項に記載のリリース剤。 - 前記酸基がアンモニアにより中和されている
ことを特徴とする、請求項1~4のいずれか一項に記載のリリース剤。 - 前記酸基の中和率が、60モル%以上である
ことを特徴とする、請求項1~5のいずれか一項に記載のリリース剤。 - 前記酸基含有エチレン性不飽和結合含有モノマーが、リン酸基含有(メタ)アクリレートを含有する
ことを特徴とする、請求項1~6のいずれか一項に記載のリリース剤。 - 前記酸基含有エチレン性不飽和結合含有モノマーの割合が、前記重合成分の総量に対して、5質量%以上25質量%以下である
ことを特徴とする、請求項1~7のいずれか一項に記載のリリース剤。 - 極性基含有樹脂の成形に用いられる
ことを特徴とする、請求項1~8のいずれか一項に記載のリリース剤。 - 金属基体の表面に、請求項1~9のいずれか一項に記載のリリース剤からリリース膜を形成する工程と、
前記リリース膜に極性基含有樹脂を接触させた状態で、前記極性基含有樹脂を成形する工程と、
前記極性基含有樹脂の成形物を、前記金属基体から離す工程と
を備えることを特徴とする、樹脂成形物の製造方法。
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CN103613717B (zh) * | 2013-12-06 | 2015-10-07 | 中科院广州化学有限公司 | 一种自乳化型丙烯酸有机硅蜡防护材料及制备方法与应用 |
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JP2014129517A (ja) | 2012-11-29 | 2014-07-10 | Daikin Ind Ltd | 離型剤、離型剤組成物及び離型剤の製造方法 |
US20160002377A1 (en) | 2014-07-01 | 2016-01-07 | Taiwan Fluoro Technology Co., Ltd. | Mold releasing agent |
JP2018103579A (ja) | 2016-12-28 | 2018-07-05 | 日華化学株式会社 | 加硫ゴム用離型剤 |
JP2019026836A (ja) | 2017-07-25 | 2019-02-21 | ダイキン工業株式会社 | 含フッ素重合体、離型剤組成物および離型方法 |
JP2019084803A (ja) | 2017-11-10 | 2019-06-06 | 東洋紡株式会社 | 離型フィルム |
JP2018095888A (ja) | 2018-02-06 | 2018-06-21 | 株式会社ネオス | フッ素系重合体及びこれを含有する表面処理剤 |
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