JP7064272B2 - 光ガイドを使用して導電性バイアを形成する方法および構造体 - Google Patents
光ガイドを使用して導電性バイアを形成する方法および構造体 Download PDFInfo
- Publication number
- JP7064272B2 JP7064272B2 JP2019570506A JP2019570506A JP7064272B2 JP 7064272 B2 JP7064272 B2 JP 7064272B2 JP 2019570506 A JP2019570506 A JP 2019570506A JP 2019570506 A JP2019570506 A JP 2019570506A JP 7064272 B2 JP7064272 B2 JP 7064272B2
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- Prior art keywords
- photoresist
- photoresist layer
- metal
- optical guide
- light
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 230000003287 optical effect Effects 0.000 title claims description 92
- 238000000034 method Methods 0.000 title claims description 47
- 229920002120 photoresistant polymer Polymers 0.000 claims description 150
- 239000002184 metal Substances 0.000 claims description 72
- 229910052751 metal Inorganic materials 0.000 claims description 72
- 239000000758 substrate Substances 0.000 claims description 33
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 25
- 229910052802 copper Inorganic materials 0.000 claims description 25
- 239000010949 copper Substances 0.000 claims description 25
- 239000000463 material Substances 0.000 claims description 14
- 238000005406 washing Methods 0.000 claims description 4
- 239000010410 layer Substances 0.000 description 111
- 238000007747 plating Methods 0.000 description 15
- 239000011347 resin Substances 0.000 description 14
- 229920005989 resin Polymers 0.000 description 14
- 238000000576 coating method Methods 0.000 description 10
- 239000011248 coating agent Substances 0.000 description 9
- 238000004140 cleaning Methods 0.000 description 8
- 238000005553 drilling Methods 0.000 description 6
- 239000012212 insulator Substances 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 3
- 238000000151 deposition Methods 0.000 description 3
- 230000005540 biological transmission Effects 0.000 description 2
- 238000005520 cutting process Methods 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 230000008021 deposition Effects 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000005530 etching Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000003754 machining Methods 0.000 description 2
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 description 2
- 238000012795 verification Methods 0.000 description 2
- RKUAZJIXKHPFRK-UHFFFAOYSA-N 1,3,5-trichloro-2-(2,4-dichlorophenyl)benzene Chemical compound ClC1=CC(Cl)=CC=C1C1=C(Cl)C=C(Cl)C=C1Cl RKUAZJIXKHPFRK-UHFFFAOYSA-N 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- URQUNWYOBNUYJQ-UHFFFAOYSA-N diazonaphthoquinone Chemical compound C1=CC=C2C(=O)C(=[N]=[N])C=CC2=C1 URQUNWYOBNUYJQ-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 239000011810 insulating material Substances 0.000 description 1
- 238000000608 laser ablation Methods 0.000 description 1
- 230000005499 meniscus Effects 0.000 description 1
- 238000001465 metallisation Methods 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 238000004080 punching Methods 0.000 description 1
- 239000002094 self assembled monolayer Substances 0.000 description 1
- 239000013545 self-assembled monolayer Substances 0.000 description 1
- 239000002210 silicon-based material Substances 0.000 description 1
- 229910001961 silver nitrate Inorganic materials 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
Images
Classifications
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K3/00—Apparatus or processes for manufacturing printed circuits
- H05K3/40—Forming printed elements for providing electric connections to or between printed circuits
- H05K3/42—Plated through-holes or plated via connections
- H05K3/425—Plated through-holes or plated via connections characterised by the sequence of steps for plating the through-holes or via connections in relation to the conductive pattern
- H05K3/428—Plated through-holes or plated via connections characterised by the sequence of steps for plating the through-holes or via connections in relation to the conductive pattern initial plating of through-holes in substrates having a metal pattern
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/20—Exposure; Apparatus therefor
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F1/00—Originals for photomechanical production of textured or patterned surfaces, e.g., masks, photo-masks, reticles; Mask blanks or pellicles therefor; Containers specially adapted therefor; Preparation thereof
- G03F1/38—Masks having auxiliary features, e.g. special coatings or marks for alignment or testing; Preparation thereof
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/004—Photosensitive materials
- G03F7/038—Macromolecular compounds which are rendered insoluble or differentially wettable
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/004—Photosensitive materials
- G03F7/039—Macromolecular compounds which are photodegradable, e.g. positive electron resists
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/16—Coating processes; Apparatus therefor
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/26—Processing photosensitive materials; Apparatus therefor
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/26—Processing photosensitive materials; Apparatus therefor
- G03F7/40—Treatment after imagewise removal, e.g. baking
- G03F7/405—Treatment with inorganic or organometallic reagents after imagewise removal
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K3/00—Apparatus or processes for manufacturing printed circuits
- H05K3/40—Forming printed elements for providing electric connections to or between printed circuits
- H05K3/4038—Through-connections; Vertical interconnect access [VIA] connections
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K2201/00—Indexing scheme relating to printed circuits covered by H05K1/00
- H05K2201/09—Shape and layout
- H05K2201/09209—Shape and layout details of conductors
- H05K2201/095—Conductive through-holes or vias
- H05K2201/09645—Patterning on via walls; Plural lands around one hole
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K2203/00—Indexing scheme relating to apparatus or processes for manufacturing printed circuits covered by H05K3/00
- H05K2203/05—Patterning and lithography; Masks; Details of resist
- H05K2203/0502—Patterning and lithography
- H05K2203/0514—Photodevelopable thick film, e.g. conductive or insulating paste
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K2203/00—Indexing scheme relating to apparatus or processes for manufacturing printed circuits covered by H05K3/00
- H05K2203/05—Patterning and lithography; Masks; Details of resist
- H05K2203/0562—Details of resist
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K2203/00—Indexing scheme relating to apparatus or processes for manufacturing printed circuits covered by H05K3/00
- H05K2203/13—Moulding and encapsulation; Deposition techniques; Protective layers
- H05K2203/1377—Protective layers
- H05K2203/1383—Temporary protective insulating layer
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K3/00—Apparatus or processes for manufacturing printed circuits
- H05K3/40—Forming printed elements for providing electric connections to or between printed circuits
- H05K3/42—Plated through-holes or plated via connections
- H05K3/423—Plated through-holes or plated via connections characterised by electroplating method
- H05K3/424—Plated through-holes or plated via connections characterised by electroplating method by direct electroplating
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K3/00—Apparatus or processes for manufacturing printed circuits
- H05K3/40—Forming printed elements for providing electric connections to or between printed circuits
- H05K3/42—Plated through-holes or plated via connections
- H05K3/429—Plated through-holes specially for multilayer circuits, e.g. having connections to inner circuit layers
Landscapes
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Organic Chemistry (AREA)
- Printing Elements For Providing Electric Connections Between Printed Circuits (AREA)
- Optical Couplings Of Light Guides (AREA)
- Production Of Multi-Layered Print Wiring Board (AREA)
- Photosensitive Polymer And Photoresist Processing (AREA)
- Exposure And Positioning Against Photoresist Photosensitive Materials (AREA)
- Manufacturing Of Printed Wiring (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US15/635,374 US10481496B2 (en) | 2017-06-28 | 2017-06-28 | Forming conductive vias using a light guide |
| US15/635,374 | 2017-06-28 | ||
| PCT/IB2018/054316 WO2019003016A1 (en) | 2017-06-28 | 2018-06-13 | FORMING CONDUCTIVE INTERCONNECTION HOLES USING AN OPTICAL WAVEGUIDE |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2020526011A JP2020526011A (ja) | 2020-08-27 |
| JP2020526011A5 JP2020526011A5 (enExample) | 2020-10-08 |
| JP7064272B2 true JP7064272B2 (ja) | 2022-05-10 |
Family
ID=64738653
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2019570506A Active JP7064272B2 (ja) | 2017-06-28 | 2018-06-13 | 光ガイドを使用して導電性バイアを形成する方法および構造体 |
Country Status (6)
| Country | Link |
|---|---|
| US (2) | US10481496B2 (enExample) |
| JP (1) | JP7064272B2 (enExample) |
| CN (1) | CN110710339B (enExample) |
| DE (1) | DE112018003324T5 (enExample) |
| GB (1) | GB2579456B (enExample) |
| WO (1) | WO2019003016A1 (enExample) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US10481496B2 (en) * | 2017-06-28 | 2019-11-19 | International Business Machines Corporation | Forming conductive vias using a light guide |
| JP2021076590A (ja) * | 2019-10-03 | 2021-05-20 | テクトロニクス・インコーポレイテッドTektronix,Inc. | 封止された試験ポイントから信号を取得する方法及び試験測定装置を試験ポイントに電気的に接続するシステム |
| JP7567182B2 (ja) * | 2020-03-17 | 2024-10-16 | 日本電気株式会社 | 回路基板の製造方法 |
| CN115776769A (zh) * | 2021-09-06 | 2023-03-10 | 先丰通讯股份有限公司 | 具有多网络通孔的线路板及其制作方法 |
| TWI782696B (zh) * | 2021-09-06 | 2022-11-01 | 先豐通訊股份有限公司 | 具有多網路通孔的線路板及其製作方法 |
| CN114980537A (zh) * | 2022-06-28 | 2022-08-30 | 生益电子股份有限公司 | 一种pcb的制作方法 |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002516386A (ja) | 1998-05-22 | 2002-06-04 | ビーエムシー インダストリーズ,インコーポレイティド | 筒状物品を製造する方法及び装置 |
| WO2003072967A1 (en) | 2002-02-28 | 2003-09-04 | Fujitsu Limited | Dynamic pressure bearing manufacturing method, dynamic pressure bearing, and dynamic pressure bearing manufacturing device |
| US20100044095A1 (en) | 2008-08-19 | 2010-02-25 | International Business Machines Corporation | Via Stub Elimination |
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|---|---|---|---|---|
| JPS56132326A (en) | 1980-03-19 | 1981-10-16 | Matsushita Electric Ind Co Ltd | Exposure method and exposure device |
| US4357205A (en) * | 1980-09-23 | 1982-11-02 | Siemens Aktiengesellschaft | Method for etched and/or galvanic production of ring zones in small diameter holes |
| US4888450A (en) * | 1981-12-11 | 1989-12-19 | At&T Bell Laboratories | Circuit board fabrication leading to increased capacity |
| JPS6254433A (ja) | 1985-09-03 | 1987-03-10 | Fujitsu Ltd | 半導体基板の検査方法 |
| JPS63182888A (ja) * | 1987-01-26 | 1988-07-28 | 関西ペイント株式会社 | プリント配線板の製造方法 |
| US5246813A (en) | 1989-07-21 | 1993-09-21 | Mitsubishi Denki Kabushiki Kaisha | Method of exposing printed wiring boards having through holes |
| US5147760A (en) | 1989-07-21 | 1992-09-15 | Mitsubishi Denki Kabushiki Kaisha | Method of exposing printed wiring boards having through holes |
| US5082755A (en) | 1989-10-02 | 1992-01-21 | General Electric Company | Liquid crystal programmable photoresist exposure method for making a set of masks |
| JPH04326717A (ja) * | 1991-04-26 | 1992-11-16 | Yokogawa Electric Corp | 3次元露光方法 |
| JPH05206644A (ja) * | 1992-01-08 | 1993-08-13 | Nec Corp | 印刷配線板の製造方法 |
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| TW312079B (enExample) * | 1994-06-06 | 1997-08-01 | Ibm | |
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| US6312876B1 (en) | 1999-07-08 | 2001-11-06 | Taiwan Semiconductor Manufacturing Company | Method for placing identifying mark on semiconductor wafer |
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| JP2003204157A (ja) * | 2001-12-28 | 2003-07-18 | Toshiba Corp | 多層プリント配線板、多層プリント配線板を搭載した電子機器および多層プリント配線板の製造方法 |
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| US10481496B2 (en) * | 2017-06-28 | 2019-11-19 | International Business Machines Corporation | Forming conductive vias using a light guide |
-
2017
- 2017-06-28 US US15/635,374 patent/US10481496B2/en active Active
-
2018
- 2018-06-13 CN CN201880035594.6A patent/CN110710339B/zh active Active
- 2018-06-13 WO PCT/IB2018/054316 patent/WO2019003016A1/en not_active Ceased
- 2018-06-13 JP JP2019570506A patent/JP7064272B2/ja active Active
- 2018-06-13 GB GB2000790.2A patent/GB2579456B/en active Active
- 2018-06-13 DE DE112018003324.4T patent/DE112018003324T5/de active Pending
-
2019
- 2019-09-13 US US16/569,903 patent/US10712664B2/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002516386A (ja) | 1998-05-22 | 2002-06-04 | ビーエムシー インダストリーズ,インコーポレイティド | 筒状物品を製造する方法及び装置 |
| WO2003072967A1 (en) | 2002-02-28 | 2003-09-04 | Fujitsu Limited | Dynamic pressure bearing manufacturing method, dynamic pressure bearing, and dynamic pressure bearing manufacturing device |
| US20100044095A1 (en) | 2008-08-19 | 2010-02-25 | International Business Machines Corporation | Via Stub Elimination |
Also Published As
| Publication number | Publication date |
|---|---|
| US10712664B2 (en) | 2020-07-14 |
| WO2019003016A1 (en) | 2019-01-03 |
| GB2579456A (en) | 2020-06-24 |
| US10481496B2 (en) | 2019-11-19 |
| CN110710339A (zh) | 2020-01-17 |
| GB2579456B (en) | 2022-01-26 |
| CN110710339B (zh) | 2022-08-30 |
| US20200004154A1 (en) | 2020-01-02 |
| GB202000790D0 (en) | 2020-03-04 |
| DE112018003324T5 (de) | 2020-03-12 |
| JP2020526011A (ja) | 2020-08-27 |
| US20190004428A1 (en) | 2019-01-03 |
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