JP6741687B2 - メロナールの調製方法 - Google Patents
メロナールの調製方法 Download PDFInfo
- Publication number
- JP6741687B2 JP6741687B2 JP2017557332A JP2017557332A JP6741687B2 JP 6741687 B2 JP6741687 B2 JP 6741687B2 JP 2017557332 A JP2017557332 A JP 2017557332A JP 2017557332 A JP2017557332 A JP 2017557332A JP 6741687 B2 JP6741687 B2 JP 6741687B2
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/51—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition
- C07C45/54—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition of compounds containing doubly bound oxygen atoms, e.g. esters
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
- C07C45/64—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by introduction of functional groups containing oxygen only in singly bound form
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/78—Separation; Purification; Stabilisation; Use of additives
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/39—Preparation of carboxylic acid esters by oxidation of groups which are precursors for the acid moiety of the ester
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP15166260.8 | 2015-05-04 | ||
| EP15166260 | 2015-05-04 | ||
| PCT/EP2016/060062 WO2016177814A1 (en) | 2015-05-04 | 2016-05-04 | Process for the preparation of melonal |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2018518467A JP2018518467A (ja) | 2018-07-12 |
| JP2018518467A5 JP2018518467A5 (cg-RX-API-DMAC7.html) | 2019-06-06 |
| JP6741687B2 true JP6741687B2 (ja) | 2020-08-19 |
Family
ID=53040424
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2017557332A Active JP6741687B2 (ja) | 2015-05-04 | 2016-05-04 | メロナールの調製方法 |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US10202324B2 (cg-RX-API-DMAC7.html) |
| EP (1) | EP3292099B1 (cg-RX-API-DMAC7.html) |
| JP (1) | JP6741687B2 (cg-RX-API-DMAC7.html) |
| CN (1) | CN107735392B (cg-RX-API-DMAC7.html) |
| ES (1) | ES2821890T3 (cg-RX-API-DMAC7.html) |
| MX (1) | MX2017014148A (cg-RX-API-DMAC7.html) |
| WO (1) | WO2016177814A1 (cg-RX-API-DMAC7.html) |
Families Citing this family (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107735392B (zh) | 2015-05-04 | 2021-12-03 | 巴斯夫欧洲公司 | 制备甜瓜醛的方法 |
| EP3325457B1 (en) | 2015-07-22 | 2020-01-01 | Basf Se | Process for preparing furan-2,5-dicarboxylic acid |
| EP3170828A1 (de) * | 2015-11-23 | 2017-05-24 | Basf Se | Verfahren zur herstellung von verbindungen mit 16-oxabicyclo[10.3.1]pentadecengerüst und deren folgeprodukten |
| JP2018538284A (ja) | 2015-11-27 | 2018-12-27 | ビーエーエスエフ ソシエタス・ヨーロピアBasf Se | 金属−有機骨格体の超高速高空時収量合成 |
| BR112018011459A2 (pt) | 2015-12-08 | 2018-11-27 | Basf Se | processo, material zeolítico, e, uso de um material zeolítico. |
| EP3178788A1 (en) | 2015-12-08 | 2017-06-14 | Basf Se | A tin-containing zeolitic material having a bea framework structure |
| WO2017133995A1 (de) | 2016-02-01 | 2017-08-10 | Basf Se | Verfahren zur herstellung von c4-c15-lactamen |
| MY196447A (en) | 2016-02-19 | 2023-04-12 | Basf Se | Enzymatic Cyclization Of Homofarnesylic Acid |
| BR112018074538B1 (pt) | 2016-05-31 | 2022-09-13 | Basf Se | Composto, método para preparar compostos, uso de compostos, composição de substância aromatizante e/ou fragrância, produto perfumado ou aromatizado, e, método para perfumar um produto |
| CN109311789B (zh) | 2016-06-07 | 2023-04-04 | 巴斯夫欧洲公司 | 制备2,3-不饱和醇的方法 |
| ES2867052T3 (es) | 2016-06-29 | 2021-10-20 | Basf Se | Procedimiento de preparación de aldehídos alfa, beta insaturados por oxidación de alcoholes en presencia de una fase líquida |
| JP6986063B2 (ja) | 2016-07-08 | 2021-12-22 | ビーエーエスエフ ソシエタス・ヨーロピアBasf Se | 有機スルホンの製造方法 |
| US10544116B2 (en) | 2016-07-20 | 2020-01-28 | Basf Se | Process for purifying propylene oxide |
| CA3030687A1 (en) | 2016-07-29 | 2018-02-01 | Basf Corporation | Process for the preparation of a zeolitic material having a fau-type framework structure and use thereof in the selective catalytic reduction of nox |
| WO2018096171A1 (en) | 2016-11-28 | 2018-05-31 | Basf Se | Catalyst composite comprising an alkaline earth metal containing cha zeolite and use thereof in a process for the conversion of oxygenates to olefins |
| US11104637B2 (en) | 2016-11-30 | 2021-08-31 | Basf Se | Process for the conversion of monoethanolamine to ethylenediamine employing a copper-modified zeolite of the MOR framework structure |
| WO2018099967A1 (en) | 2016-11-30 | 2018-06-07 | Basf Se | Process for the conversion of ethylene glycol to ethylenediamine employing a zeolite catalyst |
| MY191036A (en) | 2016-12-13 | 2022-05-30 | Basf Se | Process for the preparation of a titanium-containing zeolite |
| WO2018172062A1 (de) | 2017-03-21 | 2018-09-27 | Basf Se | Verfahren zur herstellung einer korrosionsschutzkomponente für ein gefrierschutzmittel |
| US10774034B2 (en) | 2017-05-03 | 2020-09-15 | Basf Se | Process for the conversion of ethylene oxide to monoethanolamine and ethylenediamine employing a zeolite |
| MX2020006560A (es) * | 2017-12-21 | 2020-09-24 | Basf Se | Proceso para la preparacion de aldehidos alfa-beta insaturados mediante oxidacion de alcoholes en presencia de una fase liquida. |
| CN114292170B (zh) * | 2022-01-11 | 2023-01-13 | 万华化学集团股份有限公司 | 一种合成甜瓜醛的方法 |
Family Cites Families (89)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20140047837A1 (en) | 2012-08-17 | 2014-02-20 | Basf Se | Method of improving nitrite salt compositions for use as heat transfer medium or heat storage medium |
| EP2914584B1 (en) * | 2012-11-05 | 2017-07-05 | Basf Se | Process for the oxidation of organic carbonyl compounds |
| WO2014114538A1 (en) | 2013-01-25 | 2014-07-31 | Wintershall Holding GmbH | Method for recovering oil |
| WO2014180678A1 (de) | 2013-05-06 | 2014-11-13 | Basf Se | Verfahren zur herstellung von nitroalkanen in einem mikrostrukturierten reaktor |
| EP2999545A1 (en) | 2013-05-23 | 2016-03-30 | Wintershall Holding GmbH | A method of transporting oil |
| CN105492420B (zh) | 2013-05-29 | 2018-08-10 | 巴斯夫欧洲公司 | 亚砜的氧化方法 |
| US20140357718A1 (en) | 2013-06-03 | 2014-12-04 | Basf Se | Compositions for use in controlling intestinal microflora |
| WO2014199348A2 (en) | 2013-06-13 | 2014-12-18 | Basf Se | Metal doped silicate catalysts for the selective conversion of ethanol to butadiene |
| WO2014199349A2 (en) | 2013-06-13 | 2014-12-18 | Basf Se | Metal impregnated amorphous silicates for the selective conversion of ethanol to butadiene |
| BR112015031174B8 (pt) | 2013-06-13 | 2020-12-22 | Basf Se | processo em fase gasosa para a preparação de butadieno |
| RU2668962C2 (ru) | 2013-07-02 | 2018-10-05 | Басф Се | Способ получения 2,3,5-триметилбензохинона при помощи окисления 2,3,6-триметилфенола |
| EP3016925B1 (de) | 2013-07-02 | 2020-08-12 | Basf Se | Verfahren zur herstellung von 3-heptanol aus einer mischung enthaltend 2-ehthylhexanal und 3-heptylformiat |
| EP3025389B1 (en) | 2013-07-23 | 2017-06-14 | Basf Se | Oxiranyl derivatives as additives for electrolytes in lithium-ion batteries |
| US9793577B2 (en) | 2013-07-23 | 2017-10-17 | Basf Se | Oxiranyl-acyl derivatives as additives for electrolytes in lithium ion batteries |
| WO2015010994A1 (en) | 2013-07-24 | 2015-01-29 | Basf Se | Regeneration of a titanium containing zeolite |
| SG10201803770YA (en) | 2013-07-24 | 2018-06-28 | Basf Se | A process for preparing propylene oxide |
| ES2687470T3 (es) | 2013-07-24 | 2018-10-25 | Basf Se | Un proceso para la preparación de óxido de propileno |
| US9725428B2 (en) | 2013-07-24 | 2017-08-08 | Basf Se | Process for preparing propylene oxide |
| WO2015018676A1 (de) | 2013-08-06 | 2015-02-12 | Basf Se | Verfahren zur herstellung von trisaziridinomethan |
| WO2015018807A2 (en) | 2013-08-09 | 2015-02-12 | Basf Se | Process for the oxygen free conversion of methane to ethylene on zeolite catalysts |
| WO2015018815A1 (en) | 2013-08-09 | 2015-02-12 | Basf Se | Process for the oxygen free conversion of methane to ethylene on zeolite catalysts |
| US20160201855A1 (en) | 2013-08-15 | 2016-07-14 | Basf Se | Sorption store with improved heat transfer |
| CN105636669A (zh) | 2013-08-15 | 2016-06-01 | 巴斯夫欧洲公司 | 指示吸着储存器的填充水平的装置和方法 |
| US20160201853A1 (en) | 2013-08-15 | 2016-07-14 | Basf Se | Filling device for a sorption store and sorption store |
| KR20160043063A (ko) | 2013-08-15 | 2016-04-20 | 바스프 에스이 | 흡착 저장소의 가스 충전 방법 |
| WO2015025268A1 (en) | 2013-08-22 | 2015-02-26 | Basf Se | Method for purifying a mixture comprising liquid hydrocarbons, especially btx, and water |
| WO2015032851A2 (en) | 2013-09-06 | 2015-03-12 | Basf Se | Silicon-bridged pillared silicate compounds and process for their production |
| EP3049185B1 (en) | 2013-09-23 | 2019-12-11 | Basf Se | Process for the recovery of components forming a metal-organic framework material |
| US20150090344A1 (en) | 2013-09-27 | 2015-04-02 | Basf Corporation | Gas filtering in adsorbed gas systems |
| EP4249115A3 (en) | 2013-10-23 | 2023-12-20 | Basf Se | Molding for a hydrophobic zeolitic material |
| WO2015059175A1 (en) | 2013-10-23 | 2015-04-30 | Basf Se | Powder or granulate for a zeolitic material and process for its production |
| CN105899459B (zh) | 2013-11-05 | 2018-11-09 | 巴斯夫欧洲公司 | 具有bea骨架结构的含锡沸石材料 |
| DK3066086T3 (en) | 2013-11-05 | 2018-11-19 | Basf Se | PROCEDURE FOR OXIDATION OF ORGANIC CARBONYL COMPOUNDS |
| ES2907275T3 (es) | 2013-11-05 | 2022-04-22 | Basf Se | Un material zeolítico que contiene estaño y que tiene una estructura de marco de tipo mww |
| WO2015083113A1 (en) | 2013-12-05 | 2015-06-11 | Basf Se | Method and use for the tertiary mineral oil production by means of metal-organic framework materials |
| JP6526005B2 (ja) | 2013-12-11 | 2019-06-05 | ビーエーエスエフ ソシエタス・ヨーロピアBasf Se | 2−メルカプトエタノールの酸化 |
| WO2015091924A1 (en) | 2013-12-20 | 2015-06-25 | Basf Se | Novel aroma chemicals |
| WO2015101930A1 (en) | 2014-01-03 | 2015-07-09 | Basf Se | Bimetal-exchanged zeolite beta from organotemplate-free synthesis and use thereof in the selective catalytic reduction of nox |
| EP3094614B1 (de) | 2014-01-17 | 2018-05-02 | Basf Se | Verfahren zur herstellung von arylpropenen |
| WO2015123531A1 (en) | 2014-02-14 | 2015-08-20 | Basf Corporation | Methods and systems for heating adsorbed gas systems |
| WO2015123530A1 (en) | 2014-02-14 | 2015-08-20 | Basf Corporation | Methods and systems for improving capacity of adsorbed gas systems |
| EP2915797A1 (de) | 2014-03-07 | 2015-09-09 | Basf Se | Verfahren zur Herstellung von Menthonen aus Isopulegol in der Gasphase |
| JP6510027B2 (ja) | 2014-03-27 | 2019-05-08 | ビーエーエスエフ ソシエタス・ヨーロピアBasf Se | 有機金属骨格材料を含む多孔質膜 |
| JP6549611B2 (ja) | 2014-04-14 | 2019-07-24 | ビーエーエスエフ ソシエタス・ヨーロピアBasf Se | 匂いの品質が安定した2−置換4−ヒドロキシ−4−メチルテトラヒドロピランの製造 |
| EA201692123A1 (ru) | 2014-04-22 | 2017-04-28 | Винтерсхол Хольдинг Гмбх | Стабилизированная твердыми веществами эмульсия |
| WO2015162083A1 (en) | 2014-04-22 | 2015-10-29 | Wintershall Holding Ag | Process for recovery of oil |
| MX2016014508A (es) | 2014-05-05 | 2017-02-23 | Basf Se | Proceso para producir 2,6-dimetil-5-hepten-1-al. |
| WO2015169939A1 (en) | 2014-05-09 | 2015-11-12 | Basf Se | Method and device for filling a storage tank by recirculation of gas |
| MX2016015210A (es) | 2014-05-20 | 2017-03-23 | Basf Se | Proceso para la dimerizacion de olefinas activadas. |
| DE102014008081A1 (de) | 2014-05-30 | 2015-11-19 | Basf Se | Verfahren zur Herstellung von Acrylsäure unter Verwendung eines alkali- und erdalkalifreien zeolithischen Materials |
| KR102481159B1 (ko) | 2014-05-30 | 2022-12-23 | 바스프 에스이 | 2,6- 및 2,7-이중 치환된 안트라퀴논 유도체의 제조 |
| DE102014008080A1 (de) | 2014-05-30 | 2015-11-12 | Basf Se | Verfahren zur Herstellung von Acrylsäure unter Verwendung eines aluminiumfreien zeolithischen Materials |
| KR102381010B1 (ko) | 2014-05-30 | 2022-04-01 | 바스프 에스이 | 2,6- 및 2,7-이치환 안트라퀴논 유도체의 제조 |
| EP3152162B1 (en) | 2014-06-05 | 2018-12-12 | Basf Se | Cha type zeolitic materials and methods for their preparation using combinations of cyclohexyl- and tetramethylammonium compounds |
| JP6629304B2 (ja) | 2014-06-06 | 2020-01-15 | ビーエーエスエフ ソシエタス・ヨーロピアBasf Se | Mww骨格構造を有するホウ素含有ゼオライトの合成 |
| WO2015197699A1 (en) | 2014-06-25 | 2015-12-30 | Basf Se | Process for preparing furan-2,5-dicarboxylic acid |
| US9171568B1 (en) | 2014-06-25 | 2015-10-27 | Western Digital Technologies, Inc. | Data storage device periodically re-initializing spindle motor commutation sequence based on timing data |
| EP2985364A1 (en) | 2014-08-14 | 2016-02-17 | Basf Se | Process for preparing alcohols by electrochemical reductive coupling |
| EP2985075A1 (en) | 2014-08-15 | 2016-02-17 | Basf Se | Shaped body made of a porous material |
| US20170275076A1 (en) | 2014-09-05 | 2017-09-28 | Basf Corporation | Adsorbent materials for extending produce shelf life |
| CN106687433A (zh) | 2014-09-09 | 2017-05-17 | 巴斯夫欧洲公司 | 制备2‑烷氧基环己醇的方法 |
| ES2727604T3 (es) | 2014-09-09 | 2019-10-17 | Basf Se | Un proceso para la preparación de un material zeolítico MWW que contiene boro y titanio |
| EP3191440A1 (de) | 2014-09-09 | 2017-07-19 | Basf Se | Verfahren zur herstellung eines aromastoffs |
| EP3191498B1 (en) | 2014-09-12 | 2020-09-30 | Basf Se | Method for preparing 2'-o-fucosyllactose |
| ES2721530T3 (es) | 2014-09-26 | 2019-08-01 | Basf Se | Uso de acetato de cis- o trans-(2-isobutil-4-metil-tetrahidropiran-4-ilo) isoméricamente puro o altamente enriquecido con isómeros |
| WO2016050690A1 (de) | 2014-09-29 | 2016-04-07 | Basf Se | Verfahren zur biokatalytischen cyclisierung von geranyllinalool und dabei erhaltene cyclisierungsprodukte |
| EP3002003A1 (de) | 2014-09-30 | 2016-04-06 | Basf Se | Verwendung neuartiger cyclischer Carbaldehyde als Aromastoff |
| WO2016059042A1 (de) | 2014-10-14 | 2016-04-21 | Basf Se | Verwendung von hexadeca-8,15-dienal als aromachemikalie |
| CN107074566A (zh) | 2014-10-15 | 2017-08-18 | 巴斯夫欧洲公司 | 沸石材料的固热合成以及由此得到的沸石 |
| JP6664388B2 (ja) | 2014-10-23 | 2020-03-13 | コンストラクション リサーチ アンド テクノロジー ゲーエムベーハーConstruction Research & Technology GmbH | グリセリン酸カーボネートの製造方法 |
| MY182496A (en) | 2014-10-27 | 2021-01-25 | Dow Global Technologies Llc | Part-stream distillation |
| EP3215593A1 (de) | 2014-11-07 | 2017-09-13 | Basf Se | Verwendung von 3,3'-dimethoxy-4,4'-dihydroxystilben als aromastoff |
| MX2017005876A (es) | 2014-11-07 | 2017-06-26 | Basf Se | Metodo para extraer productos aromaticos de valor de composiciones que contienen lignina. |
| WO2016075129A1 (en) | 2014-11-11 | 2016-05-19 | Basf Se | Storage vessel comprising at least one shaped body of a porous solid with spacers |
| WO2016074918A1 (en) | 2014-11-11 | 2016-05-19 | Basf Se | Thermoelectric device |
| WO2016075100A1 (en) | 2014-11-11 | 2016-05-19 | Basf Se | Storage vessel comprising layers of a shaped body of a porous solid separated by a seal |
| JP6668344B2 (ja) | 2014-11-11 | 2020-03-18 | ビーエーエスエフ ソシエタス・ヨーロピアBasf Se | 多孔質体の成形体を含む貯蔵容器 |
| ES2730024T3 (es) | 2014-11-18 | 2019-11-07 | Basf Se | Procedimiento de preparación de 1-(2,6,6-trimetilciclohexil)-alcan-3-oles |
| DE102014017804A1 (de) | 2014-12-02 | 2016-04-21 | Basf Se | Verfahren zur Herstellung von Acrylsäure |
| CN107223120B (zh) | 2014-12-19 | 2020-10-13 | 巴斯夫欧洲公司 | 作为新型芳香化学品的1-(7,10,10-三甲基-4-双环[6.2.0]癸基)乙酮 |
| MX2017008171A (es) | 2014-12-19 | 2017-09-18 | Basf Se | Proceso para preparar 1-[(1r,4r/s,8s)-10,10-dimetil-7-metilen-4-bi ciclo [6.2.0] decanilo] etanona. |
| EP3489213B1 (de) | 2014-12-19 | 2021-04-28 | Basf Se | Zusammensetzung zur verwendung in einem verfahren zur herstellung optisch aktiver carbonylverbindungen |
| WO2016116406A1 (de) | 2015-01-21 | 2016-07-28 | Basf Se | Gasdruckbehälter enthaltend ein gas, ein latentwärmespeichermaterial und einen porösen feststoff |
| CN107848822B (zh) | 2015-02-12 | 2021-03-02 | 巴斯夫欧洲公司 | 用于制备具有bea骨架结构的脱铝沸石材料的方法 |
| KR102512661B1 (ko) | 2015-02-13 | 2023-03-21 | 바스프 에스이 | 프로필렌 에폭시화용 티타늄 제올라이트 촉매의 재생 방법 |
| WO2016135133A1 (en) | 2015-02-27 | 2016-09-01 | Basf Se | A vehicle comprising a storage system and a combustion engine, the storage system comprising a container and at least one storage vessel |
| EP3483151B1 (de) | 2015-03-05 | 2025-06-25 | Basf Se | Tetrahydropyranylester als riechstoffe |
| DE102015103608A1 (de) | 2015-03-11 | 2016-09-15 | Basf Se | Verfahren zur mikrobiellen de novo Synthese von Terpenen |
| CN107735392B (zh) | 2015-05-04 | 2021-12-03 | 巴斯夫欧洲公司 | 制备甜瓜醛的方法 |
-
2016
- 2016-05-04 CN CN201680039475.9A patent/CN107735392B/zh active Active
- 2016-05-04 ES ES16722841T patent/ES2821890T3/es active Active
- 2016-05-04 MX MX2017014148A patent/MX2017014148A/es unknown
- 2016-05-04 WO PCT/EP2016/060062 patent/WO2016177814A1/en not_active Ceased
- 2016-05-04 US US15/571,107 patent/US10202324B2/en active Active
- 2016-05-04 JP JP2017557332A patent/JP6741687B2/ja active Active
- 2016-05-04 EP EP16722841.0A patent/EP3292099B1/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| JP2018518467A (ja) | 2018-07-12 |
| US10202324B2 (en) | 2019-02-12 |
| CN107735392B (zh) | 2021-12-03 |
| EP3292099A1 (en) | 2018-03-14 |
| MX2017014148A (es) | 2018-03-15 |
| US20180170850A1 (en) | 2018-06-21 |
| CN107735392A (zh) | 2018-02-23 |
| WO2016177814A1 (en) | 2016-11-10 |
| ES2821890T3 (es) | 2021-04-28 |
| EP3292099B1 (en) | 2020-07-22 |
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