JP6719448B2 - 熱可塑性ポリウレタン組成物、物品、及びその方法 - Google Patents
熱可塑性ポリウレタン組成物、物品、及びその方法 Download PDFInfo
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- JP6719448B2 JP6719448B2 JP2017505161A JP2017505161A JP6719448B2 JP 6719448 B2 JP6719448 B2 JP 6719448B2 JP 2017505161 A JP2017505161 A JP 2017505161A JP 2017505161 A JP2017505161 A JP 2017505161A JP 6719448 B2 JP6719448 B2 JP 6719448B2
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- thermoplastic polyurethane
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
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- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Laminated Bodies (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Polyurethanes Or Polyureas (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201462031426P | 2014-07-31 | 2014-07-31 | |
| US62/031,426 | 2014-07-31 | ||
| PCT/US2015/041981 WO2016018749A1 (en) | 2014-07-31 | 2015-07-24 | Thermoplastic polyurethane compositions, articles, and methods thereof |
Publications (3)
| Publication Number | Publication Date |
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Families Citing this family (35)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US10265932B2 (en) | 2005-10-21 | 2019-04-23 | Entrotech, Inc. | Protective sheets, articles, and methods |
| EP2193024A4 (en) | 2007-09-25 | 2013-11-06 | Entrotech Inc | PAINT SHEET FILMS, COMPOUNDS THEREOF AND RELATED METHODS |
| US10981371B2 (en) | 2008-01-19 | 2021-04-20 | Entrotech, Inc. | Protected graphics and related methods |
| EP4624543A2 (en) * | 2015-04-30 | 2025-10-01 | Design Blue Limited | Multilayer polyurethane protective films |
| JP6997074B2 (ja) | 2015-07-07 | 2022-01-17 | スリーエム イノベイティブ プロパティズ カンパニー | 導光物品 |
| US20170341699A1 (en) * | 2016-05-24 | 2017-11-30 | Kawasaki Jukogyo Kabushiki Kaisha | Straddle-type vehicle and external members thereof |
| US11454741B2 (en) | 2016-08-11 | 2022-09-27 | Samsung Sdi Co., Ltd. | Optical display device protecting film, optical member comprising same, and optical display device comprising same |
| US20190238171A1 (en) * | 2016-09-01 | 2019-08-01 | Entrotech, Inc. | Multi-Layer Polymeric Protective Sheet, Related Articles and Methods |
| US20190136095A1 (en) | 2016-09-20 | 2019-05-09 | Aero Advanced Paint Technology, Inc. | Paint Film Appliques with Reduced Defects, Articles, and Methods |
| PT3538578T (pt) * | 2016-11-14 | 2025-03-21 | Basf Se | Partículas de poliuretano termoplástico expandido, processo para as produzir e processo para produzir um molde |
| JP2018146693A (ja) * | 2017-03-03 | 2018-09-20 | Smk株式会社 | 電子機器およびコネクタの防水構造 |
| JP6853738B2 (ja) * | 2017-06-13 | 2021-03-31 | 三菱瓦斯化学株式会社 | ポリウレタン多層フィルム |
| CN109536074A (zh) * | 2017-08-08 | 2019-03-29 | 3M创新有限公司 | 一种保护膜和使用该膜保护的物品 |
| JP6999339B2 (ja) * | 2017-09-19 | 2022-01-18 | 藤森工業株式会社 | 成形体の製造方法 |
| WO2019060284A1 (en) * | 2017-09-21 | 2019-03-28 | 3M Innovative Properties Company | EXTRUDED POLYURETHANE SURFACE FILMS |
| JP7233840B2 (ja) * | 2018-01-04 | 2023-03-07 | スリーエム イノベイティブ プロパティズ カンパニー | 粘着シート |
| US20190240963A1 (en) * | 2018-02-02 | 2019-08-08 | Ming-Je Tsai | Waterproof decorative strip |
| EP3810672A1 (de) * | 2018-06-19 | 2021-04-28 | Basf Se | Transparente harte thermoplastische polyurethane |
| US20210114361A1 (en) * | 2018-08-14 | 2021-04-22 | 3M Innovative Properties Company | Extruded polyurethane surface films |
| WO2020079518A1 (en) * | 2018-10-16 | 2020-04-23 | 3M Innovative Properties Company | Methods of making extensible barrier films |
| KR102725547B1 (ko) * | 2018-11-21 | 2024-11-04 | 피피지 어드밴스드 서피스 테크놀로지스, 엘엘씨 | 물품의 요면 토포그래피에 적용하기에 유용한 중합체 시트 및 관련 방법 |
| JP6738508B1 (ja) * | 2018-12-05 | 2020-08-12 | バンドー化学株式会社 | フレキシブルディスプレイ用表面保護フィルム |
| EP3962735B1 (en) * | 2019-04-30 | 2025-10-08 | F&S B.V. | Thermoplastic multilayer articles, methods of manufacture, and uses thereof |
| CN113263718B (zh) * | 2020-02-17 | 2022-12-13 | 华为技术有限公司 | 保护膜及其制备方法、贴合方法和终端 |
| KR102874252B1 (ko) * | 2020-04-10 | 2025-10-22 | (주)엘엑스하우시스 | 도장 보호 필름용 조성물 및 이를 이용하여 제조된 도장 보호 필름 |
| US20230227698A1 (en) * | 2020-06-29 | 2023-07-20 | 3M Innovative Properties Company | Hard Coat Compositions and Composite Films Including a Thermoplastic Polyurethane |
| WO2022034398A1 (en) * | 2020-08-10 | 2022-02-17 | 3M Innovative Properties Company | Surfacing film |
| KR102530957B1 (ko) * | 2020-08-19 | 2023-05-09 | 테사 소시에타스 유로파에아 | 폴리우레탄 캐리어를 갖는 접착 테이프 |
| MX2023010056A (es) * | 2021-03-03 | 2023-09-06 | Seiren Co Ltd | Cuero sintetico. |
| KR20240053614A (ko) * | 2021-08-27 | 2024-04-24 | 이스트만 케미칼 컴파니 | 자동차 랩으로 유용한 열가소성 중합체를 포함하는 필름 |
| NL2029176B1 (en) * | 2021-09-13 | 2023-03-23 | Champion Link Int Corp | Panel and method for producing a panel |
| EP4402189A1 (en) * | 2021-09-16 | 2024-07-24 | 3M Innovative Properties Company | Thermoformable paint films |
| NL2029345B1 (en) | 2021-10-07 | 2023-04-20 | Champion Link Int Corp | Decorative panel |
| EP4353269A1 (en) | 2022-10-14 | 2024-04-17 | Röhm GmbH | Method for sterilization of formed articles made of thermoplastic polymers |
| CN120003017A (zh) * | 2025-03-14 | 2025-05-16 | 奇瑞汽车股份有限公司 | 一种汽车内饰件的tom工艺及装置 |
Family Cites Families (48)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE261098C (enExample) | ||||
| IT610737A (enExample) | 1955-11-18 | 1900-01-01 | ||
| DE2447368A1 (de) | 1974-10-04 | 1976-04-08 | Basf Ag | Verfahren zur kontinuierlichen herstellung von thermoplastischen polyurethan-elastomeren |
| DE3224324A1 (de) | 1982-06-30 | 1984-01-05 | Basf Ag, 6700 Ludwigshafen | Zweistufenverfahren zur herstellung von thermoplastischen polyurethan-elastomeren |
| US4418120A (en) | 1982-07-19 | 1983-11-29 | Minnesota Mining And Manufacturing Co. | Tackified crosslinked acrylic adhesives |
| US4648689A (en) * | 1983-04-11 | 1987-03-10 | Minnesota Mining And Manufacturing Company | Pavement marking tape |
| US4619867A (en) | 1983-06-14 | 1986-10-28 | Minnesota Mining And Manufacturing Company | Azlactone-containing pressure-sensitive adhesives |
| AU582876B2 (en) | 1985-07-08 | 1989-04-13 | Minnesota Mining And Manufacturing Company | Crosslinked pressure-sensitive adhesive |
| US4835217A (en) | 1985-10-17 | 1989-05-30 | Minnesota Mining And Manufacturing Company | Pressure-sensitive adhesive having broad useful temperature range |
| JPS62262777A (ja) * | 1986-05-09 | 1987-11-14 | Kansai Paint Co Ltd | 防食塗膜形成法 |
| US5059269A (en) | 1988-03-07 | 1991-10-22 | Becton, Dickinson And Company | Method of making an article having a hemocompatible surface |
| US4948859A (en) | 1988-10-28 | 1990-08-14 | Minnesota Mining And Manufacturing Company | Extruder polymerization of polyurethanes |
| EP0455585B1 (en) * | 1990-04-26 | 1994-03-23 | Ciba-Geigy Ag | Unsaturated urea polysiloxanes |
| US5480946A (en) | 1990-04-26 | 1996-01-02 | Ciba Geigy Corporation | Unsaturated urea polysiloxanes |
| DE4022741A1 (de) | 1990-07-18 | 1992-01-23 | Basf Ag | Mehrschichtige polyurethanfolien und ihre verwendung zur herstellung von deckschichten |
| CA2079168A1 (en) | 1991-10-18 | 1993-04-19 | Ashok M. Sarpeshkar | Thermoformable polyurethanes |
| US5458935A (en) | 1991-12-24 | 1995-10-17 | Abbott Laboratories | Thermoplastic urethane elastomer |
| US5795948A (en) | 1992-05-26 | 1998-08-18 | Bayer Aktiengesellschaft | Multistage process for production of thermoplastic polyurethane elastomers |
| US5405675A (en) | 1992-12-10 | 1995-04-11 | Minnesota Mining And Manufacturing Company | Embossed multilayer film |
| US5468532A (en) | 1992-12-10 | 1995-11-21 | Minnesota Mining And Manufacturing Company | Multilayer graphic article with color layer |
| DE4315173A1 (de) * | 1992-12-23 | 1994-06-30 | Bayer Ag | Reine, insbesondere katalysatorfreie Polyurethane |
| DE4437586A1 (de) | 1994-10-20 | 1996-04-25 | Basf Schwarzheide Gmbh | Verfahren zur Herstellung von thermoplastischen Polyurethanen |
| DE19625987A1 (de) | 1996-06-28 | 1998-01-02 | Bayer Ag | Verfahren zur kontinuierlichen Herstellung von thermoplastisch verarbeitbaren Polyurethanen mit verbessertem Verarbeitungsverhalten |
| DE19738498A1 (de) | 1997-09-03 | 1999-03-04 | Bayer Ag | Verfahren zur kontinuierlichen Herstellung von thermoplastisch verarbeitbaren Polyurethanen in einem Zweiwellenextruder mit spezieller Temperaturführung |
| JP2000052374A (ja) * | 1998-08-06 | 2000-02-22 | Kansai Paint Co Ltd | プラスチック成型用化粧フィルム、その製造方法及びそのフィルムを使用して得られる射出成型物品 |
| CA2279737C (en) | 1998-08-06 | 2004-04-27 | Naoya Haruta | Decorative film for use in platics molding, process for preparing the same and injection-molded part by use of the same |
| DE69827142T2 (de) | 1998-11-11 | 2006-03-09 | Minnesota Mining And Manufacturing Co., St. Paul | Mehrschichtige Folie enthaltend eine Polyurethanschutzschicht |
| JP2001225414A (ja) | 2000-02-18 | 2001-08-21 | Sekisui Chem Co Ltd | 積層シート |
| US6607831B2 (en) | 2000-12-28 | 2003-08-19 | 3M Innovative Properties Company | Multi-layer article |
| JP4365215B2 (ja) * | 2001-10-31 | 2009-11-18 | スリーエム イノベイティブ プロパティズ カンパニー | 熱成形性フィルム及びその製造方法 |
| US7264858B2 (en) | 2002-10-29 | 2007-09-04 | Lubrizol Advanced Materials, Inc. | Multilayered articles having biocompatibility and biostability characteristics |
| US20040087754A1 (en) | 2002-10-31 | 2004-05-06 | Paul Foley | Polyurethane compounds and articles prepared therefrom |
| DE10254600B4 (de) | 2002-11-22 | 2007-12-27 | Bayer Materialscience Ag | Verfahren zur Herstellung von thermoplastischen, nicht klebenden Polyurethanen |
| KR101442280B1 (ko) | 2006-10-04 | 2014-09-22 | 쓰리엠 이노베이티브 프로퍼티즈 컴파니 | 다층 폴리우레탄 보호 필름의 제조 방법 |
| WO2009120548A2 (en) * | 2008-03-25 | 2009-10-01 | 3M Innovative Properties Company | Multilayer articles and methods of making and using the same |
| JP5694641B2 (ja) | 2008-09-12 | 2015-04-01 | スリーエム イノベイティブ プロパティズ カンパニー | ラッピング立体成形体及びその製造方法 |
| US20100222524A1 (en) * | 2009-02-27 | 2010-09-02 | Bayer Materialscience Llc | High modulus transparent thermoplastic polyurethanes characterized by high heat and chemical resistance |
| CN102361900B (zh) * | 2009-03-24 | 2014-07-30 | Ppg工业俄亥俄公司 | 聚氨酯、由其制成的制品和涂料及其制造方法 |
| US9163108B2 (en) | 2009-04-17 | 2015-10-20 | Insight Equity A.P.X., L.P. | Photochromic polyurethane laminate |
| WO2011125540A1 (ja) | 2010-03-31 | 2011-10-13 | 三井化学株式会社 | 熱可塑性ポリウレタン樹脂および成形品 |
| WO2012160894A1 (ja) | 2011-05-26 | 2012-11-29 | 株式会社ダイセル | ディスプレイ用透明積層フィルム及びその使用方法並びにタッチパネル |
| CA2844368A1 (en) | 2011-08-02 | 2013-02-07 | 3M Innovative Properties Company | Graphic article |
| KR20140041903A (ko) * | 2011-08-02 | 2014-04-04 | 쓰리엠 이노베이티브 프로퍼티즈 캄파니 | 그래픽 용품 |
| TWI583401B (zh) | 2011-10-24 | 2017-05-21 | 布雷本製藥股份有限公司 | 可植入替紮尼定組合物及其治療方法 |
| DE102012218848A1 (de) * | 2012-10-16 | 2014-04-17 | Bayer Materialscience Ag | Herstellung und Verwendung neuer thermoplastischer Polyurethan-Elastomere auf Basis von Polyethercarbonatpolyolen |
| US10406845B2 (en) | 2013-03-15 | 2019-09-10 | Gemalto Sa | Flexible hinge material comprising cross-linked polyurethane material |
| JP6285729B2 (ja) * | 2014-01-22 | 2018-02-28 | 株式会社ダイセル | 耐擦傷性ハードコートフィルム及びその製造方法 |
| US20170100923A1 (en) | 2014-03-26 | 2017-04-13 | Covestro Llc | Method of producing a surface protection composite |
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2015
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- 2015-07-24 EP EP15749904.7A patent/EP3174911B1/en active Active
- 2015-07-24 BR BR112017002096A patent/BR112017002096A2/pt not_active Application Discontinuation
- 2015-07-24 JP JP2017505161A patent/JP6719448B2/ja active Active
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- 2015-07-24 CN CN201580040791.3A patent/CN106661184B/zh active Active
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Also Published As
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|---|---|
| EP3174911B1 (en) | 2023-04-19 |
| JP2017525803A (ja) | 2017-09-07 |
| BR112017002096A2 (pt) | 2017-11-21 |
| EP3174911A1 (en) | 2017-06-07 |
| KR102440987B1 (ko) | 2022-09-06 |
| KR20170038005A (ko) | 2017-04-05 |
| WO2016018749A1 (en) | 2016-02-04 |
| CN106661184B (zh) | 2021-10-15 |
| US20170218226A1 (en) | 2017-08-03 |
| US10590303B2 (en) | 2020-03-17 |
| MX2017001255A (es) | 2017-05-01 |
| CN106661184A (zh) | 2017-05-10 |
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