JP6719448B2 - 熱可塑性ポリウレタン組成物、物品、及びその方法 - Google Patents

熱可塑性ポリウレタン組成物、物品、及びその方法 Download PDF

Info

Publication number
JP6719448B2
JP6719448B2 JP2017505161A JP2017505161A JP6719448B2 JP 6719448 B2 JP6719448 B2 JP 6719448B2 JP 2017505161 A JP2017505161 A JP 2017505161A JP 2017505161 A JP2017505161 A JP 2017505161A JP 6719448 B2 JP6719448 B2 JP 6719448B2
Authority
JP
Japan
Prior art keywords
composite film
thermoplastic polyurethane
hardcoat
composition
layer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
JP2017505161A
Other languages
English (en)
Japanese (ja)
Other versions
JP2017525803A (ja
JP2017525803A5 (enExample
Inventor
チャーリー シー. ホー,
チャーリー シー. ホー,
ロバート ディー. ハマン,
ロバート ディー. ハマン,
ジェレミー ピー. ガンデール,
ジェレミー ピー. ガンデール,
ヴィジェイ ラジャマニ,
ヴィジェイ ラジャマニ,
憲 江頭
憲 江頭
チア フイ リン,
チア フイ リン,
シ ショウ クオ,
シ ショウ クオ,
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
3M Innovative Properties Co
Original Assignee
3M Innovative Properties Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 3M Innovative Properties Co filed Critical 3M Innovative Properties Co
Publication of JP2017525803A publication Critical patent/JP2017525803A/ja
Publication of JP2017525803A5 publication Critical patent/JP2017525803A5/ja
Application granted granted Critical
Publication of JP6719448B2 publication Critical patent/JP6719448B2/ja
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04Polyurethanes
    • C09D175/06Polyurethanes from polyesters
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C51/00Shaping by thermoforming, i.e. shaping sheets or sheet like preforms after heating, e.g. shaping sheets in matched moulds or by deep-drawing; Apparatus therefor
    • B29C51/14Shaping by thermoforming, i.e. shaping sheets or sheet like preforms after heating, e.g. shaping sheets in matched moulds or by deep-drawing; Apparatus therefor using multilayered preforms or sheets
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04Polyurethanes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/022Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the choice of material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/03Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
    • B29C48/07Flat, e.g. panels
    • B29C48/08Flat, e.g. panels flexible, e.g. films
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C51/00Shaping by thermoforming, i.e. shaping sheets or sheet like preforms after heating, e.g. shaping sheets in matched moulds or by deep-drawing; Apparatus therefor
    • B29C51/10Forming by pressure difference, e.g. vacuum
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/06Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/30Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B32B27/304Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising vinyl halide (co)polymers, e.g. PVC, PVDC, PVF, PVDF
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/30Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B32B27/308Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising acrylic (co)polymers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/36Layered products comprising a layer of synthetic resin comprising polyesters
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/40Layered products comprising a layer of synthetic resin comprising polyurethanes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04Interconnection of layers
    • B32B7/12Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40High-molecular-weight compounds
    • C08G18/42Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/4236Polycondensates having carboxylic or carbonic ester groups in the main chain containing only aliphatic groups
    • C08G18/4238Polycondensates having carboxylic or carbonic ester groups in the main chain containing only aliphatic groups derived from dicarboxylic acids and dialcohols
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40High-molecular-weight compounds
    • C08G18/42Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/4266Polycondensates having carboxylic or carbonic ester groups in the main chain prepared from hydroxycarboxylic acids and/or lactones
    • C08G18/4269Lactones
    • C08G18/4277Caprolactone and/or substituted caprolactone
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/65Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
    • C08G18/66Compounds of groups C08G18/42, C08G18/48, or C08G18/52
    • C08G18/6633Compounds of group C08G18/42
    • C08G18/6637Compounds of group C08G18/42 with compounds of group C08G18/32 or polyamines of C08G18/38
    • C08G18/664Compounds of group C08G18/42 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/3203
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72Polyisocyanates or polyisothiocyanates
    • C08G18/74Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/75Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic
    • C08G18/751Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring
    • C08G18/752Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group
    • C08G18/753Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group containing one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group having a primary carbon atom next to the isocyanate or isothiocyanate group
    • C08G18/755Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group containing one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group having a primary carbon atom next to the isocyanate or isothiocyanate group and at least one isocyanate or isothiocyanate group linked to a secondary carbon atom of the cycloaliphatic ring, e.g. isophorone diisocyanate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72Polyisocyanates or polyisothiocyanates
    • C08G18/74Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/75Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic
    • C08G18/758Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing two or more cycloaliphatic rings
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00Adhesives in the form of films or foils
    • C09J7/20Adhesives in the form of films or foils characterised by their carriers
    • C09J7/22Plastics; Metallised plastics
    • C09J7/25Plastics; Metallised plastics based on macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2075/00Use of PU, i.e. polyureas or polyurethanes or derivatives thereof, as moulding material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2995/00Properties of moulding materials, reinforcements, fillers, preformed parts or moulds
    • B29K2995/0037Other properties
    • B29K2995/007Hardness
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2995/00Properties of moulding materials, reinforcements, fillers, preformed parts or moulds
    • B29K2995/0037Other properties
    • B29K2995/0077Yield strength; Tensile strength
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29LINDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2009/00Layered products
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29LINDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2031/00Other particular articles
    • B29L2031/30Vehicles, e.g. ships or aircraft, or body parts thereof
    • B29L2031/3005Body finishings
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29LINDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2031/00Other particular articles
    • B29L2031/722Decorative or ornamental articles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2250/00Layers arrangement
    • B32B2250/24All layers being polymeric
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00Coating on the layer surface
    • B32B2255/10Coating on the layer surface on synthetic resin layer or on natural or synthetic rubber layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00Coating on the layer surface
    • B32B2255/26Polymeric coating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/30Properties of the layers or laminate having particular thermal properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/50Properties of the layers or laminate having particular mechanical properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/50Properties of the layers or laminate having particular mechanical properties
    • B32B2307/536Hardness
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/50Properties of the layers or laminate having particular mechanical properties
    • B32B2307/54Yield strength; Tensile strength
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/50Properties of the layers or laminate having particular mechanical properties
    • B32B2307/546Flexural strength; Flexion stiffness
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/50Properties of the layers or laminate having particular mechanical properties
    • B32B2307/554Wear resistance
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/50Properties of the layers or laminate having particular mechanical properties
    • B32B2307/558Impact strength, toughness
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/50Properties of the layers or laminate having particular mechanical properties
    • B32B2307/582Tearability
    • B32B2307/5825Tear resistant
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/712Weather resistant
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/714Inert, i.e. inert to chemical degradation, corrosion
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2451/00Decorative or ornamental articles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2605/00Vehicles
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00Additional features of adhesives in the form of films or foils
    • C09J2301/30Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier
    • C09J2301/302Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier the adhesive being pressure-sensitive, i.e. tacky at temperatures inferior to 30°C
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2475/00Presence of polyurethane
    • C09J2475/006Presence of polyurethane in the substrate

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Laminated Bodies (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
JP2017505161A 2014-07-31 2015-07-24 熱可塑性ポリウレタン組成物、物品、及びその方法 Active JP6719448B2 (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201462031426P 2014-07-31 2014-07-31
US62/031,426 2014-07-31
PCT/US2015/041981 WO2016018749A1 (en) 2014-07-31 2015-07-24 Thermoplastic polyurethane compositions, articles, and methods thereof

Publications (3)

Publication Number Publication Date
JP2017525803A JP2017525803A (ja) 2017-09-07
JP2017525803A5 JP2017525803A5 (enExample) 2018-08-30
JP6719448B2 true JP6719448B2 (ja) 2020-07-08

Family

ID=53835500

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2017505161A Active JP6719448B2 (ja) 2014-07-31 2015-07-24 熱可塑性ポリウレタン組成物、物品、及びその方法

Country Status (8)

Country Link
US (1) US10590303B2 (enExample)
EP (1) EP3174911B1 (enExample)
JP (1) JP6719448B2 (enExample)
KR (1) KR102440987B1 (enExample)
CN (1) CN106661184B (enExample)
BR (1) BR112017002096A2 (enExample)
MX (1) MX2017001255A (enExample)
WO (1) WO2016018749A1 (enExample)

Families Citing this family (35)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10265932B2 (en) 2005-10-21 2019-04-23 Entrotech, Inc. Protective sheets, articles, and methods
EP2193024A4 (en) 2007-09-25 2013-11-06 Entrotech Inc PAINT SHEET FILMS, COMPOUNDS THEREOF AND RELATED METHODS
US10981371B2 (en) 2008-01-19 2021-04-20 Entrotech, Inc. Protected graphics and related methods
EP4624543A2 (en) * 2015-04-30 2025-10-01 Design Blue Limited Multilayer polyurethane protective films
JP6997074B2 (ja) 2015-07-07 2022-01-17 スリーエム イノベイティブ プロパティズ カンパニー 導光物品
US20170341699A1 (en) * 2016-05-24 2017-11-30 Kawasaki Jukogyo Kabushiki Kaisha Straddle-type vehicle and external members thereof
US11454741B2 (en) 2016-08-11 2022-09-27 Samsung Sdi Co., Ltd. Optical display device protecting film, optical member comprising same, and optical display device comprising same
US20190238171A1 (en) * 2016-09-01 2019-08-01 Entrotech, Inc. Multi-Layer Polymeric Protective Sheet, Related Articles and Methods
US20190136095A1 (en) 2016-09-20 2019-05-09 Aero Advanced Paint Technology, Inc. Paint Film Appliques with Reduced Defects, Articles, and Methods
PT3538578T (pt) * 2016-11-14 2025-03-21 Basf Se Partículas de poliuretano termoplástico expandido, processo para as produzir e processo para produzir um molde
JP2018146693A (ja) * 2017-03-03 2018-09-20 Smk株式会社 電子機器およびコネクタの防水構造
JP6853738B2 (ja) * 2017-06-13 2021-03-31 三菱瓦斯化学株式会社 ポリウレタン多層フィルム
CN109536074A (zh) * 2017-08-08 2019-03-29 3M创新有限公司 一种保护膜和使用该膜保护的物品
JP6999339B2 (ja) * 2017-09-19 2022-01-18 藤森工業株式会社 成形体の製造方法
WO2019060284A1 (en) * 2017-09-21 2019-03-28 3M Innovative Properties Company EXTRUDED POLYURETHANE SURFACE FILMS
JP7233840B2 (ja) * 2018-01-04 2023-03-07 スリーエム イノベイティブ プロパティズ カンパニー 粘着シート
US20190240963A1 (en) * 2018-02-02 2019-08-08 Ming-Je Tsai Waterproof decorative strip
EP3810672A1 (de) * 2018-06-19 2021-04-28 Basf Se Transparente harte thermoplastische polyurethane
US20210114361A1 (en) * 2018-08-14 2021-04-22 3M Innovative Properties Company Extruded polyurethane surface films
WO2020079518A1 (en) * 2018-10-16 2020-04-23 3M Innovative Properties Company Methods of making extensible barrier films
KR102725547B1 (ko) * 2018-11-21 2024-11-04 피피지 어드밴스드 서피스 테크놀로지스, 엘엘씨 물품의 요면 토포그래피에 적용하기에 유용한 중합체 시트 및 관련 방법
JP6738508B1 (ja) * 2018-12-05 2020-08-12 バンドー化学株式会社 フレキシブルディスプレイ用表面保護フィルム
EP3962735B1 (en) * 2019-04-30 2025-10-08 F&S B.V. Thermoplastic multilayer articles, methods of manufacture, and uses thereof
CN113263718B (zh) * 2020-02-17 2022-12-13 华为技术有限公司 保护膜及其制备方法、贴合方法和终端
KR102874252B1 (ko) * 2020-04-10 2025-10-22 (주)엘엑스하우시스 도장 보호 필름용 조성물 및 이를 이용하여 제조된 도장 보호 필름
US20230227698A1 (en) * 2020-06-29 2023-07-20 3M Innovative Properties Company Hard Coat Compositions and Composite Films Including a Thermoplastic Polyurethane
WO2022034398A1 (en) * 2020-08-10 2022-02-17 3M Innovative Properties Company Surfacing film
KR102530957B1 (ko) * 2020-08-19 2023-05-09 테사 소시에타스 유로파에아 폴리우레탄 캐리어를 갖는 접착 테이프
MX2023010056A (es) * 2021-03-03 2023-09-06 Seiren Co Ltd Cuero sintetico.
KR20240053614A (ko) * 2021-08-27 2024-04-24 이스트만 케미칼 컴파니 자동차 랩으로 유용한 열가소성 중합체를 포함하는 필름
NL2029176B1 (en) * 2021-09-13 2023-03-23 Champion Link Int Corp Panel and method for producing a panel
EP4402189A1 (en) * 2021-09-16 2024-07-24 3M Innovative Properties Company Thermoformable paint films
NL2029345B1 (en) 2021-10-07 2023-04-20 Champion Link Int Corp Decorative panel
EP4353269A1 (en) 2022-10-14 2024-04-17 Röhm GmbH Method for sterilization of formed articles made of thermoplastic polymers
CN120003017A (zh) * 2025-03-14 2025-05-16 奇瑞汽车股份有限公司 一种汽车内饰件的tom工艺及装置

Family Cites Families (48)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE261098C (enExample)
IT610737A (enExample) 1955-11-18 1900-01-01
DE2447368A1 (de) 1974-10-04 1976-04-08 Basf Ag Verfahren zur kontinuierlichen herstellung von thermoplastischen polyurethan-elastomeren
DE3224324A1 (de) 1982-06-30 1984-01-05 Basf Ag, 6700 Ludwigshafen Zweistufenverfahren zur herstellung von thermoplastischen polyurethan-elastomeren
US4418120A (en) 1982-07-19 1983-11-29 Minnesota Mining And Manufacturing Co. Tackified crosslinked acrylic adhesives
US4648689A (en) * 1983-04-11 1987-03-10 Minnesota Mining And Manufacturing Company Pavement marking tape
US4619867A (en) 1983-06-14 1986-10-28 Minnesota Mining And Manufacturing Company Azlactone-containing pressure-sensitive adhesives
AU582876B2 (en) 1985-07-08 1989-04-13 Minnesota Mining And Manufacturing Company Crosslinked pressure-sensitive adhesive
US4835217A (en) 1985-10-17 1989-05-30 Minnesota Mining And Manufacturing Company Pressure-sensitive adhesive having broad useful temperature range
JPS62262777A (ja) * 1986-05-09 1987-11-14 Kansai Paint Co Ltd 防食塗膜形成法
US5059269A (en) 1988-03-07 1991-10-22 Becton, Dickinson And Company Method of making an article having a hemocompatible surface
US4948859A (en) 1988-10-28 1990-08-14 Minnesota Mining And Manufacturing Company Extruder polymerization of polyurethanes
EP0455585B1 (en) * 1990-04-26 1994-03-23 Ciba-Geigy Ag Unsaturated urea polysiloxanes
US5480946A (en) 1990-04-26 1996-01-02 Ciba Geigy Corporation Unsaturated urea polysiloxanes
DE4022741A1 (de) 1990-07-18 1992-01-23 Basf Ag Mehrschichtige polyurethanfolien und ihre verwendung zur herstellung von deckschichten
CA2079168A1 (en) 1991-10-18 1993-04-19 Ashok M. Sarpeshkar Thermoformable polyurethanes
US5458935A (en) 1991-12-24 1995-10-17 Abbott Laboratories Thermoplastic urethane elastomer
US5795948A (en) 1992-05-26 1998-08-18 Bayer Aktiengesellschaft Multistage process for production of thermoplastic polyurethane elastomers
US5405675A (en) 1992-12-10 1995-04-11 Minnesota Mining And Manufacturing Company Embossed multilayer film
US5468532A (en) 1992-12-10 1995-11-21 Minnesota Mining And Manufacturing Company Multilayer graphic article with color layer
DE4315173A1 (de) * 1992-12-23 1994-06-30 Bayer Ag Reine, insbesondere katalysatorfreie Polyurethane
DE4437586A1 (de) 1994-10-20 1996-04-25 Basf Schwarzheide Gmbh Verfahren zur Herstellung von thermoplastischen Polyurethanen
DE19625987A1 (de) 1996-06-28 1998-01-02 Bayer Ag Verfahren zur kontinuierlichen Herstellung von thermoplastisch verarbeitbaren Polyurethanen mit verbessertem Verarbeitungsverhalten
DE19738498A1 (de) 1997-09-03 1999-03-04 Bayer Ag Verfahren zur kontinuierlichen Herstellung von thermoplastisch verarbeitbaren Polyurethanen in einem Zweiwellenextruder mit spezieller Temperaturführung
JP2000052374A (ja) * 1998-08-06 2000-02-22 Kansai Paint Co Ltd プラスチック成型用化粧フィルム、その製造方法及びそのフィルムを使用して得られる射出成型物品
CA2279737C (en) 1998-08-06 2004-04-27 Naoya Haruta Decorative film for use in platics molding, process for preparing the same and injection-molded part by use of the same
DE69827142T2 (de) 1998-11-11 2006-03-09 Minnesota Mining And Manufacturing Co., St. Paul Mehrschichtige Folie enthaltend eine Polyurethanschutzschicht
JP2001225414A (ja) 2000-02-18 2001-08-21 Sekisui Chem Co Ltd 積層シート
US6607831B2 (en) 2000-12-28 2003-08-19 3M Innovative Properties Company Multi-layer article
JP4365215B2 (ja) * 2001-10-31 2009-11-18 スリーエム イノベイティブ プロパティズ カンパニー 熱成形性フィルム及びその製造方法
US7264858B2 (en) 2002-10-29 2007-09-04 Lubrizol Advanced Materials, Inc. Multilayered articles having biocompatibility and biostability characteristics
US20040087754A1 (en) 2002-10-31 2004-05-06 Paul Foley Polyurethane compounds and articles prepared therefrom
DE10254600B4 (de) 2002-11-22 2007-12-27 Bayer Materialscience Ag Verfahren zur Herstellung von thermoplastischen, nicht klebenden Polyurethanen
KR101442280B1 (ko) 2006-10-04 2014-09-22 쓰리엠 이노베이티브 프로퍼티즈 컴파니 다층 폴리우레탄 보호 필름의 제조 방법
WO2009120548A2 (en) * 2008-03-25 2009-10-01 3M Innovative Properties Company Multilayer articles and methods of making and using the same
JP5694641B2 (ja) 2008-09-12 2015-04-01 スリーエム イノベイティブ プロパティズ カンパニー ラッピング立体成形体及びその製造方法
US20100222524A1 (en) * 2009-02-27 2010-09-02 Bayer Materialscience Llc High modulus transparent thermoplastic polyurethanes characterized by high heat and chemical resistance
CN102361900B (zh) * 2009-03-24 2014-07-30 Ppg工业俄亥俄公司 聚氨酯、由其制成的制品和涂料及其制造方法
US9163108B2 (en) 2009-04-17 2015-10-20 Insight Equity A.P.X., L.P. Photochromic polyurethane laminate
WO2011125540A1 (ja) 2010-03-31 2011-10-13 三井化学株式会社 熱可塑性ポリウレタン樹脂および成形品
WO2012160894A1 (ja) 2011-05-26 2012-11-29 株式会社ダイセル ディスプレイ用透明積層フィルム及びその使用方法並びにタッチパネル
CA2844368A1 (en) 2011-08-02 2013-02-07 3M Innovative Properties Company Graphic article
KR20140041903A (ko) * 2011-08-02 2014-04-04 쓰리엠 이노베이티브 프로퍼티즈 캄파니 그래픽 용품
TWI583401B (zh) 2011-10-24 2017-05-21 布雷本製藥股份有限公司 可植入替紮尼定組合物及其治療方法
DE102012218848A1 (de) * 2012-10-16 2014-04-17 Bayer Materialscience Ag Herstellung und Verwendung neuer thermoplastischer Polyurethan-Elastomere auf Basis von Polyethercarbonatpolyolen
US10406845B2 (en) 2013-03-15 2019-09-10 Gemalto Sa Flexible hinge material comprising cross-linked polyurethane material
JP6285729B2 (ja) * 2014-01-22 2018-02-28 株式会社ダイセル 耐擦傷性ハードコートフィルム及びその製造方法
US20170100923A1 (en) 2014-03-26 2017-04-13 Covestro Llc Method of producing a surface protection composite

Also Published As

Publication number Publication date
EP3174911B1 (en) 2023-04-19
JP2017525803A (ja) 2017-09-07
BR112017002096A2 (pt) 2017-11-21
EP3174911A1 (en) 2017-06-07
KR102440987B1 (ko) 2022-09-06
KR20170038005A (ko) 2017-04-05
WO2016018749A1 (en) 2016-02-04
CN106661184B (zh) 2021-10-15
US20170218226A1 (en) 2017-08-03
US10590303B2 (en) 2020-03-17
MX2017001255A (es) 2017-05-01
CN106661184A (zh) 2017-05-10

Similar Documents

Publication Publication Date Title
JP6719448B2 (ja) 熱可塑性ポリウレタン組成物、物品、及びその方法
US8128779B2 (en) Method of making multilayer polyurethane protective film
EP2818488B1 (en) Paint Replacement Film with polymer layer containing polyurethane
CN108367553A (zh) 保护性显示器膜
JP2004002825A (ja) ポリオレフィン系樹脂製積層フィルム
EP3991965A1 (en) Polyisocyanate composition, composition for film formation, film, film laminated body, adhesive resin composition, adhesive resin cured product, composition for coating materials, and coating material cured product
JP2003313330A (ja) ポリオレフィン系樹脂製積層フィルム
JP2003176373A (ja) ポリオレフィン樹脂製積層フィルム
CN115768629A (zh) 包含热塑性聚氨酯的硬涂层组合物和复合膜
JP2012172094A (ja) 成形用樹脂組成物、シート、粘着シート、シートの製造方法及び成型体
JP2006142668A (ja) ポリオレフィン系積層フィルム及び粘着フィルム
US10550297B2 (en) Paint protection films
JP4003232B2 (ja) マーキングシート用ベースフィルム
EP4074506A1 (en) Resin composition, resin film comprising said resin composition, and glass laminate including said resin film
KR102846099B1 (ko) 자동차 도막 보호용 시트 및 이의 제조방법
CN114746464A (zh) 装饰膜和使用该装饰膜的装饰制品以及表面保护组合物

Legal Events

Date Code Title Description
A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20170629

RD03 Notification of appointment of power of attorney

Free format text: JAPANESE INTERMEDIATE CODE: A7423

Effective date: 20180416

RD04 Notification of resignation of power of attorney

Free format text: JAPANESE INTERMEDIATE CODE: A7424

Effective date: 20180418

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20180720

A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20180720

A977 Report on retrieval

Free format text: JAPANESE INTERMEDIATE CODE: A971007

Effective date: 20190628

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20190709

A601 Written request for extension of time

Free format text: JAPANESE INTERMEDIATE CODE: A601

Effective date: 20191009

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20191209

TRDD Decision of grant or rejection written
A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

Effective date: 20200519

A61 First payment of annual fees (during grant procedure)

Free format text: JAPANESE INTERMEDIATE CODE: A61

Effective date: 20200616

R150 Certificate of patent or registration of utility model

Ref document number: 6719448

Country of ref document: JP

Free format text: JAPANESE INTERMEDIATE CODE: R150

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250