JP6511754B2

JP6511754B2 - 樹脂組成物、及び樹脂成形体

樹脂組成物、及び樹脂成形体 Download PDF

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Publication number: JP6511754B2
Authority: JP; Japan
Prior art keywords: resin; resin composition; cellulose ester; less; group
Prior art date: 2014-09-26
Legal status : Expired - Fee Related

Application number

JP2014196845A

Other languages

English (en)

Japanese (ja)

Other versions

JP2016069395A5 (https=

JP2016069395A (ja

Inventor

八百　健二

健二八百

正洋森山

学川島

雅也生野

Current Assignee

Fujifilm Business Innovation Corp

Original Assignee

Fuji Xerox Co Ltd

Fujifilm Business Innovation Corp

Priority date

2014-09-26

Filing date

2014-09-26

Publication date

2019-05-15

2014-09-26 Application filed by Fuji Xerox Co Ltd, Fujifilm Business Innovation Corp filed Critical Fuji Xerox Co Ltd

2014-09-26 Priority to JP2014196845A priority Critical patent/JP6511754B2/ja

2015-02-02 Priority to US14/611,665 priority patent/US9441096B2/en

2015-03-13 Priority to CN201510111793.9A priority patent/CN106032414B/zh

2016-04-28 Priority to US15/140,601 priority patent/US9605136B2/en

2016-04-28 Priority to US15/140,966 priority patent/US9605139B2/en

2016-04-28 Priority to US15/140,873 priority patent/US9605138B2/en

2016-04-28 Priority to US15/140,810 priority patent/US9605137B2/en

2016-05-09 Publication of JP2016069395A publication Critical patent/JP2016069395A/ja

2017-11-02 Publication of JP2016069395A5 publication Critical patent/JP2016069395A5/ja

2019-05-15 Application granted granted Critical

2019-05-15 Publication of JP6511754B2 publication Critical patent/JP6511754B2/ja

Status Expired - Fee Related legal-status Critical Current

2034-09-26 Anticipated expiration legal-status Critical

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229920005989 resin Polymers 0.000 title claims description 178
239000011347 resin Substances 0.000 title claims description 178
239000011342 resin composition Substances 0.000 title claims description 86
-1 ester compound Chemical class 0.000 claims description 77
229920002678 cellulose Polymers 0.000 claims description 73
239000004721 Polyphenylene oxide Substances 0.000 claims description 60
229920000570 polyether Polymers 0.000 claims description 60
239000005038 ethylene vinyl acetate Substances 0.000 claims description 30
229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 claims description 30
125000004432 carbon atom Chemical group C* 0.000 claims description 29
150000001875 compounds Chemical class 0.000 claims description 23
125000002947 alkylene group Chemical group 0.000 claims description 22
238000000465 moulding Methods 0.000 claims description 18
125000003710 aryl alkyl group Chemical group 0.000 claims description 14
125000003118 aryl group Chemical group 0.000 claims description 13
125000002252 acyl group Chemical group 0.000 claims description 12
238000006467 substitution reaction Methods 0.000 claims description 12
125000000217 alkyl group Chemical group 0.000 claims description 8
125000002777 acetyl group Chemical group [H]C([H])([H])C(*)=O 0.000 claims description 6
VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical group CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 claims description 4
125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 3
239000000047 product Substances 0.000 description 28
239000004014 plasticizer Substances 0.000 description 11
FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 10
239000000203 mixture Substances 0.000 description 10
238000001746 injection moulding Methods 0.000 description 9
238000000034 method Methods 0.000 description 8
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 8
229920002554 vinyl polymer Polymers 0.000 description 7
229920006026 co-polymeric resin Polymers 0.000 description 6
230000008018 melting Effects 0.000 description 5
238000002844 melting Methods 0.000 description 5
239000008188 pellet Substances 0.000 description 5
238000011156 evaluation Methods 0.000 description 4
125000002887 hydroxy group Chemical group [H]O* 0.000 description 4
239000000463 material Substances 0.000 description 4
239000000155 melt Substances 0.000 description 4
239000002244 precipitate Substances 0.000 description 4
238000012360 testing method Methods 0.000 description 4
230000000740 bleeding effect Effects 0.000 description 3
239000003795 chemical substances by application Substances 0.000 description 3
125000004122 cyclic group Chemical group 0.000 description 3
239000011521 glass Substances 0.000 description 3
238000004898 kneading Methods 0.000 description 3
239000007788 liquid Substances 0.000 description 3
239000000126 substance Substances 0.000 description 3
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 3
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
125000004429 atom Chemical group 0.000 description 2
125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 2
229910052799 carbon Inorganic materials 0.000 description 2
239000001913 cellulose Substances 0.000 description 2
230000000052 comparative effect Effects 0.000 description 2
238000002425 crystallisation Methods 0.000 description 2
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HDERJYVLTPVNRI-UHFFFAOYSA-N ethene;ethenyl acetate Chemical class C=C.CC(=O)OC=C HDERJYVLTPVNRI-UHFFFAOYSA-N 0.000 description 2
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UAOUIVVJBYDFKD-XKCDOFEDSA-N (1R,9R,10S,11R,12R,15S,18S,21R)-10,11,21-trihydroxy-8,8-dimethyl-14-methylidene-4-(prop-2-enylamino)-20-oxa-5-thia-3-azahexacyclo[9.7.2.112,15.01,9.02,6.012,18]henicosa-2(6),3-dien-13-one Chemical compound C([C@@H]1[C@@H](O)[C@@]23C(C1=C)=O)C[C@H]2[C@]12C(N=C(NCC=C)S4)=C4CC(C)(C)[C@H]1[C@H](O)[C@]3(O)OC2 UAOUIVVJBYDFKD-XKCDOFEDSA-N 0.000 description 1
DHKHKXVYLBGOIT-UHFFFAOYSA-N 1,1-Diethoxyethane Chemical compound CCOC(C)OCC DHKHKXVYLBGOIT-UHFFFAOYSA-N 0.000 description 1
HYZJCKYKOHLVJF-UHFFFAOYSA-N 1H-benzimidazole Chemical compound C1=CC=C2NC=NC2=C1 HYZJCKYKOHLVJF-UHFFFAOYSA-N 0.000 description 1
YSUIQYOGTINQIN-UZFYAQMZSA-N 2-amino-9-[(1S,6R,8R,9S,10R,15R,17R,18R)-8-(6-aminopurin-9-yl)-9,18-difluoro-3,12-dihydroxy-3,12-bis(sulfanylidene)-2,4,7,11,13,16-hexaoxa-3lambda5,12lambda5-diphosphatricyclo[13.2.1.06,10]octadecan-17-yl]-1H-purin-6-one Chemical compound NC1=NC2=C(N=CN2[C@@H]2O[C@@H]3COP(S)(=O)O[C@@H]4[C@@H](COP(S)(=O)O[C@@H]2[C@@H]3F)O[C@H]([C@H]4F)N2C=NC3=C2N=CN=C3N)C(=O)N1 YSUIQYOGTINQIN-UZFYAQMZSA-N 0.000 description 1
TVTJUIAKQFIXCE-HUKYDQBMSA-N 2-amino-9-[(2R,3S,4S,5R)-4-fluoro-3-hydroxy-5-(hydroxymethyl)oxolan-2-yl]-7-prop-2-ynyl-1H-purine-6,8-dione Chemical compound NC=1NC(C=2N(C(N(C=2N=1)[C@@H]1O[C@@H]([C@H]([C@H]1O)F)CO)=O)CC#C)=O TVTJUIAKQFIXCE-HUKYDQBMSA-N 0.000 description 1
125000000094 2-phenylethyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])C([H])([H])* 0.000 description 1
229910052582 BN Inorganic materials 0.000 description 1
PZNSFCLAULLKQX-UHFFFAOYSA-N Boron nitride Chemical compound N#B PZNSFCLAULLKQX-UHFFFAOYSA-N 0.000 description 1
229920000049 Carbon (fiber) Polymers 0.000 description 1
BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
125000003535 D-glucopyranosyl group Chemical group [H]OC([H])([H])[C@@]1([H])OC([H])(*)[C@]([H])(O[H])[C@@]([H])(O[H])[C@]1([H])O[H] 0.000 description 1
229920002943 EPDM rubber Polymers 0.000 description 1
238000006124 Pilkington process Methods 0.000 description 1
239000004696 Poly ether ether ketone Substances 0.000 description 1
229930182556 Polyacetal Natural products 0.000 description 1
239000004695 Polyether sulfone Substances 0.000 description 1
239000004697 Polyetherimide Substances 0.000 description 1
239000004734 Polyphenylene sulfide Substances 0.000 description 1
239000004743 Polypropylene Substances 0.000 description 1
239000004793 Polystyrene Substances 0.000 description 1
229910052581 Si3N4 Inorganic materials 0.000 description 1
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical class ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
239000011354 acetal resin Substances 0.000 description 1
239000002253 acid Substances 0.000 description 1
125000005396 acrylic acid ester group Chemical group 0.000 description 1
150000008360 acrylonitriles Chemical class 0.000 description 1
230000010933 acylation Effects 0.000 description 1
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239000011324 bead Substances 0.000 description 1
235000013361 beverage Nutrition 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
238000000071 blow moulding Methods 0.000 description 1
125000004063 butyryl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
238000011088 calibration curve Methods 0.000 description 1
239000004917 carbon fiber Substances 0.000 description 1
238000006243 chemical reaction Methods 0.000 description 1
239000004927 clay Substances 0.000 description 1
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239000011248 coating agent Substances 0.000 description 1
238000000576 coating method Methods 0.000 description 1
239000003086 colorant Substances 0.000 description 1
229940125851 compound 27 Drugs 0.000 description 1
229910002026 crystalline silica Inorganic materials 0.000 description 1
230000003247 decreasing effect Effects 0.000 description 1
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125000006182 dimethyl benzyl group Chemical group 0.000 description 1
238000007598 dipping method Methods 0.000 description 1
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239000003365 glass fiber Substances 0.000 description 1
238000004128 high performance liquid chromatography Methods 0.000 description 1
239000003112 inhibitor Substances 0.000 description 1
239000003999 initiator Substances 0.000 description 1
125000005397 methacrylic acid ester group Chemical group 0.000 description 1
VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
125000006178 methyl benzyl group Chemical group 0.000 description 1
239000010445 mica Substances 0.000 description 1
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125000001624 naphthyl group Chemical group 0.000 description 1
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150000001451 organic peroxides Chemical class 0.000 description 1
125000004344 phenylpropyl group Chemical group 0.000 description 1
229910052698 phosphorus Inorganic materials 0.000 description 1
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239000000049 pigment Substances 0.000 description 1
229920001643 poly(ether ketone) Polymers 0.000 description 1
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229920000412 polyarylene Polymers 0.000 description 1
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230000000379 polymerizing effect Effects 0.000 description 1
229920005672 polyolefin resin Polymers 0.000 description 1
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238000001556 precipitation Methods 0.000 description 1
125000001501 propionyl group Chemical group O=C([*])C([H])([H])C([H])([H])[H] 0.000 description 1
150000003254 radicals Chemical class 0.000 description 1
230000009257 reactivity Effects 0.000 description 1
239000012744 reinforcing agent Substances 0.000 description 1
235000012239 silicon dioxide Nutrition 0.000 description 1
HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 1
239000000454 talc Substances 0.000 description 1
229910052623 talc Inorganic materials 0.000 description 1
125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
238000005979 thermal decomposition reaction Methods 0.000 description 1
AYEKOFBPNLCAJY-UHFFFAOYSA-O thiamine pyrophosphate Chemical compound CC1=C(CCOP(O)(=O)OP(O)(O)=O)SC=[N+]1CC1=CN=C(C)N=C1N AYEKOFBPNLCAJY-UHFFFAOYSA-O 0.000 description 1
125000003944 tolyl group Chemical group 0.000 description 1
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XZZNDPSIHUTMOC-UHFFFAOYSA-N triphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)OC1=CC=CC=C1 XZZNDPSIHUTMOC-UHFFFAOYSA-N 0.000 description 1