JP6189325B2 - エチレン／アルファオレフィン／非共役ポリエン共重合体およびその形成方法 - Google Patents

エチレン／アルファオレフィン／非共役ポリエン共重合体およびその形成方法 Download PDF

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Publication number
JP6189325B2
JP6189325B2 JP2014548874A JP2014548874A JP6189325B2 JP 6189325 B2 JP6189325 B2 JP 6189325B2 JP 2014548874 A JP2014548874 A JP 2014548874A JP 2014548874 A JP2014548874 A JP 2014548874A JP 6189325 B2 JP6189325 B2 JP 6189325B2
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independently
atom
hydrocarbyl
heterohydrocarbyl
unsubstituted
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JP2015500920A (ja
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コリン・リピシャン
トーマス・ダブリュ・カージャラ
マイケル・エル・スミス
リアム・ピー・スペンサー
ジャージー・クロシン
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Dow Global Technologies LLC
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Dow Global Technologies LLC
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C08F210/18—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers with non-conjugated dienes, e.g. EPT rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
JP2014548874A 2011-12-20 2012-12-20 エチレン／アルファオレフィン／非共役ポリエン共重合体およびその形成方法 Active JP6189325B2 (ja)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US201161577720P 2011-12-20 2011-12-20
US61/577,720 2011-12-20
US201261731891P 2012-11-30 2012-11-30
US61/731,891 2012-11-30
PCT/US2012/070859 WO2013096573A1 (en) 2011-12-20 2012-12-20 Ethylene/alpha-olefin/nonconjugated polyene interpolymers and processes to form the same

Publications (2)

Publication Number Publication Date
JP2015500920A JP2015500920A (ja) 2015-01-08
JP6189325B2 true JP6189325B2 (ja) 2017-08-30

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JP2014548874A Active JP6189325B2 (ja) 2011-12-20 2012-12-20 エチレン／アルファオレフィン／非共役ポリエン共重合体およびその形成方法

Country Status (9)

Country Link
US (1) US9422383B2 (cg-RX-API-DMAC7.html)
EP (1) EP2794693B1 (cg-RX-API-DMAC7.html)
JP (1) JP6189325B2 (cg-RX-API-DMAC7.html)
KR (1) KR101989206B1 (cg-RX-API-DMAC7.html)
CN (1) CN104169313B (cg-RX-API-DMAC7.html)
BR (1) BR112014014855B1 (cg-RX-API-DMAC7.html)
ES (1) ES2835807T3 (cg-RX-API-DMAC7.html)
IN (1) IN2014CN04444A (cg-RX-API-DMAC7.html)
WO (1) WO2013096573A1 (cg-RX-API-DMAC7.html)

Families Citing this family (45)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2013096573A1 (en) 2011-12-20 2013-06-27 Dow Global Technologies Llc Ethylene/alpha-olefin/nonconjugated polyene interpolymers and processes to form the same
JP5946331B2 (ja) * 2012-06-01 2016-07-06 三井化学株式会社 エチレン・α−オレフィン非共役ポリエン共重合体ゴムペレット
KR102215306B1 (ko) * 2012-11-30 2021-02-16 다우 글로벌 테크놀로지스 엘엘씨 에틸렌/알파-올레핀/폴리엔 기재의 조성물
SG11201503581PA (en) * 2012-12-27 2015-06-29 Dow Global Technologies Llc Catalyst systems for olefin polymerization
BR112015013530B1 (pt) 2013-01-18 2021-10-13 Dow Global Technologies Llc Processo para formar um polímero à base de etileno e complexo metálico
RU2690373C2 (ru) * 2014-05-31 2019-06-03 Бриджстоун Корпорейшн Металлокомплексный катализатор, способы полимеризации с его использованием и полученные полимерные продукты
MY184826A (en) 2014-12-04 2021-04-24 Dow Technology Investments Llc Hydroformylation process
CN107041138B (zh) 2014-12-04 2020-11-27 陶氏环球技术有限责任公司 用于制备乙烯类聚合物的五配位双苯基苯氧基催化剂
JP6718453B2 (ja) * 2014-12-29 2020-07-08 ダウ グローバル テクノロジーズ エルエルシー 油含有エチレン系ポリマーを形成する方法
EP3240808B1 (en) 2014-12-29 2020-05-13 Dow Global Technologies LLC Process to form ethylene/alpha-olefin interpolymers
EP3277737B1 (en) 2015-03-31 2019-01-30 Dow Global Technologies LLC Processes for the production of high molecular weight ethylene/alpha-olefin/non-conjugated interpolymers with low levels of long chain branching
WO2016191076A1 (en) * 2015-05-28 2016-12-01 Dow Global Technologies Llc Process to form ethylene/alpha-olefin interpolymers
KR102587539B1 (ko) * 2015-09-02 2023-10-12 다우 글로벌 테크놀로지스 엘엘씨 가요성 가교결합된 케이블 절연체 및 가요성 가교결합된 케이블 절연체를 제조하는 방법
EP3345193B1 (en) 2015-09-02 2021-04-21 Dow Global Technologies LLC Flexible crosslinked cable insulation and methods for making flexible crosslinked cable insulation
US10487200B2 (en) 2015-10-29 2019-11-26 Dow Global Technologies Llc Crosslinkable polymeric compositions for flexible crosslinked cable insulation and methods for making flexible crosslinked cable insulation
WO2017206008A1 (en) * 2016-05-30 2017-12-07 Dow Global Technologies Llc Ethylene/alpha-olefin/diene interpolymer
WO2017206009A1 (en) 2016-05-30 2017-12-07 Dow Global Technologies Llc Ethylene/alpha-olefin/diene interpolymers compositions
BR112018077391B1 (pt) * 2016-06-30 2023-01-03 Dow Global Technologies Llc. Composição, composição reticulada e artigo
EP3478762A1 (en) * 2016-06-30 2019-05-08 Dow Global Technologies, LLC Ethylene/alpha-olefin/polyene based compositions
WO2018013283A2 (en) 2016-07-13 2018-01-18 Exxonmobil Chemical Patents Inc. Dual metallocene catalyst copolymer compositions
CN109641990B (zh) 2016-07-13 2022-08-19 埃克森美孚化学专利公司 双金属茂催化剂共聚物组合物
WO2018013286A1 (en) 2016-07-14 2018-01-18 Exxonmobil Chemical Patents Inc. Lubricating oil compositions comprising dual metallocene-catalyzed bimodal copolymer compositions useful as viscosity modifiers
US10221260B2 (en) 2016-07-29 2019-03-05 Exxonmobil Chemical Patents Inc. Phenolate transition metal complexes, production and use thereof
WO2018022279A1 (en) 2016-07-29 2018-02-01 Exxonmobil Chemical Patents Inc. Phenolate transition metal complexes, production and use thereof
CN109601003A (zh) * 2016-07-29 2019-04-09 陶氏环球技术有限责任公司 用于产生多峰弹性体的混合催化剂系统
US11261319B2 (en) * 2016-12-26 2022-03-01 Dow Global Technologies Llc Ethylene/α-olefin/nonconjugated polyene interpolymer compositions and articles prepared from the same
ES2988640T3 (es) * 2017-03-31 2024-11-21 Dow Global Technologies Llc Catalizadores de bis-bifenil-fenoxilo para la polimerización de olefinas
EP3638730B1 (en) * 2017-06-14 2024-05-01 ExxonMobil Chemical Patents Inc. Ethylene copolymer blends for cross-linking applications
WO2019040845A1 (en) 2017-08-24 2019-02-28 Dow Global Technologies Llc ETHYLENE / ALPHA-OLEFIN C5-C10 / POLYENE INTERPOLYMERS
WO2019157687A1 (en) 2018-02-14 2019-08-22 Dow Global Technologies Llc Ethylene/alpha-olefin interpolymer compositions with improved long term heat aging performance
US12006423B2 (en) 2018-08-29 2024-06-11 ExxonMobil Engineering & Technology Company Methods of making polymer compositions with enhanced elasticity by employing VTP and HMP catalyst systems in parallel processes
KR102538844B1 (ko) * 2018-12-21 2023-06-01 주식회사 엘지화학 방향족 비닐 화합물-비닐시안 화합물 공중합체의 제조방법 및 이를 포함하는 열가소성 수지 조성물의 제조방법
JP7186856B2 (ja) 2019-03-12 2022-12-09 三井化学株式会社 オレフィン系樹脂、その架橋物およびそれらの製造方法
KR102715918B1 (ko) * 2019-03-29 2024-10-15 다우 글로벌 테크놀로지스 엘엘씨 열가소성 가황물을 위한 오일-증량된 펠릿 형태 에틸렌 알파-올레핀 디엔 인터폴리머
US12098268B2 (en) 2019-04-30 2024-09-24 Dow Global Technologies Llc Ethylene/propylene/nonconjugated diene interpolymer composition
BR112022005357A2 (pt) * 2019-09-24 2022-06-14 Dow Global Technologies Llc Composição, e, artigo
CN114466891B (zh) 2019-09-24 2024-06-18 陶氏环球技术有限责任公司 乙烯/α-烯烃/多烯互聚物组合物
BR112022005584A2 (pt) 2019-09-24 2022-06-21 Dow Global Technologies Llc Composição, e, artigo
WO2021133925A1 (en) * 2019-12-27 2021-07-01 Dow Global Technologies Llc Ethylene/butene multi-block copolymer and process for producing same
JP2021147420A (ja) * 2020-03-16 2021-09-27 三井化学株式会社 オレフィン・環状オレフィン共重合体の製造方法
EP4127001A1 (en) * 2020-03-27 2023-02-08 Dow Global Technologies LLC A process for producing long-chain branched ethylene-based polymers
EP4127061A1 (en) 2020-03-30 2023-02-08 ExxonMobil Chemical Patents Inc. Comb-block copolymers and methods thereof
JP2024500603A (ja) * 2020-12-28 2024-01-10 サビック エスケー ネクスレン カンパニー プライヴェート リミテッド 金属－リガンド錯体、これを含むエチレン系重合体製造用の触媒組成物およびこれを用いたエチレン系重合体の製造方法
KR20240074467A (ko) * 2022-11-21 2024-05-28 롯데케미칼 주식회사 에틸렌-알파-올레핀 공중합체 제조방법
WO2025117273A1 (en) 2023-12-01 2025-06-05 ExxonMobil Technology and Engineering Company Support-bound activators, supported catalyst systems, and processes for use thereof

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6545088B1 (en) 1991-12-30 2003-04-08 Dow Global Technologies Inc. Metallocene-catalyzed process for the manufacture of EP and EPDM polymers
US5977251A (en) 1996-04-01 1999-11-02 The Dow Chemical Company Non-adiabatic olefin solution polymerization
US6680361B1 (en) * 1998-11-02 2004-01-20 Dupont Dow Elastomers Llc Shear thinning ethylene/α-olefin interpolymers and their preparation
AU2003225156A1 (en) * 2002-04-24 2003-11-10 Symyx Technologies, Inc. Bridged bi-aromatic ligands, complexes, catalysts and processes for polymerizing and poymers therefrom
JP2008509277A (ja) 2004-08-09 2008-03-27 ダウ グローバル テクノロジーズ インコーポレイティド ポリマーの製造のための担持ビス（ヒドロキシアリールアリールオキシ）触媒
BRPI0711029A2 (pt) 2006-05-17 2011-05-31 Dow Global Technologies Inc processo para polimerização de etileno e uma ou mais a-olefinas ou diolefinas de c3-30
CN101918463B (zh) 2007-11-19 2012-09-05 陶氏环球技术有限责任公司 长链支化丙烯-α-烯烃共聚物
US8772414B2 (en) * 2008-09-16 2014-07-08 Dow Global Technologies Llc Polymeric compositions and foams, methods of making the same, and articles prepared from the same
CN102471403A (zh) 2009-07-01 2012-05-23 陶氏环球技术有限责任公司 烯属聚合物和它的用途
KR101742832B1 (ko) 2009-07-01 2017-06-01 다우 글로벌 테크놀로지스 엘엘씨 에틸렌계 중합체 및 그의 용도
CN102471551B (zh) 2009-07-15 2013-09-04 陶氏环球技术有限责任公司 聚合物组合物、其制备方法、以及由该组合物制备的制品
CN105294905A (zh) * 2010-08-25 2016-02-03 陶氏环球技术有限责任公司 聚合可聚合烯烃的方法以及用于该方法的催化剂
KR101938440B1 (ko) * 2011-12-13 2019-01-14 다우 글로벌 테크놀로지스 엘엘씨 에틸렌-프로필렌-디엔 혼성중합체 조성물
WO2013096573A1 (en) 2011-12-20 2013-06-27 Dow Global Technologies Llc Ethylene/alpha-olefin/nonconjugated polyene interpolymers and processes to form the same

Also Published As

Publication number Publication date
US20150322185A1 (en) 2015-11-12
IN2014CN04444A (cg-RX-API-DMAC7.html) 2015-09-04
US9422383B2 (en) 2016-08-23
CN104169313A (zh) 2014-11-26
EP2794693B1 (en) 2020-09-23
JP2015500920A (ja) 2015-01-08
BR112014014855A2 (pt) 2017-06-13
WO2013096573A1 (en) 2013-06-27
CN104169313B (zh) 2016-09-21
EP2794693A1 (en) 2014-10-29
KR101989206B1 (ko) 2019-09-24
BR112014014855B1 (pt) 2022-01-11
KR20140107263A (ko) 2014-09-04
ES2835807T3 (es) 2021-06-23

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