JP5855943B2 - ナノカルサイト複合材料 - Google Patents
ナノカルサイト複合材料 Download PDFInfo
- Publication number
- JP5855943B2 JP5855943B2 JP2011542415A JP2011542415A JP5855943B2 JP 5855943 B2 JP5855943 B2 JP 5855943B2 JP 2011542415 A JP2011542415 A JP 2011542415A JP 2011542415 A JP2011542415 A JP 2011542415A JP 5855943 B2 JP5855943 B2 JP 5855943B2
- Authority
- JP
- Japan
- Prior art keywords
- calcite
- composite material
- resin
- procedure
- fiber composite
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 229910021532 Calcite Inorganic materials 0.000 title claims description 81
- 239000002131 composite material Substances 0.000 title claims description 28
- 229920005989 resin Polymers 0.000 claims description 73
- 239000011347 resin Substances 0.000 claims description 73
- 239000000203 mixture Substances 0.000 claims description 44
- 239000003607 modifier Substances 0.000 claims description 34
- 239000000835 fiber Substances 0.000 claims description 28
- 125000005647 linker group Chemical group 0.000 claims description 27
- 239000002105 nanoparticle Substances 0.000 claims description 27
- 238000004364 calculation method Methods 0.000 claims description 11
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 7
- 239000011575 calcium Substances 0.000 claims description 7
- 229910052791 calcium Inorganic materials 0.000 claims description 7
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical compound OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 claims description 6
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 claims description 5
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 4
- 229920001451 polypropylene glycol Polymers 0.000 claims description 4
- 239000012783 reinforcing fiber Substances 0.000 claims description 4
- 239000000758 substrate Substances 0.000 claims description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims 1
- 229920000728 polyester Polymers 0.000 claims 1
- 238000000034 method Methods 0.000 description 69
- 239000002245 particle Substances 0.000 description 52
- 229920000647 polyepoxide Polymers 0.000 description 39
- 239000006185 dispersion Substances 0.000 description 38
- 239000003822 epoxy resin Substances 0.000 description 37
- 239000003446 ligand Substances 0.000 description 30
- 238000002156 mixing Methods 0.000 description 27
- 229920001971 elastomer Polymers 0.000 description 21
- KUBDPQJOLOUJRM-UHFFFAOYSA-N 2-(chloromethyl)oxirane;4-[2-(4-hydroxyphenyl)propan-2-yl]phenol Chemical compound ClCC1CO1.C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 KUBDPQJOLOUJRM-UHFFFAOYSA-N 0.000 description 19
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 18
- 239000000463 material Substances 0.000 description 17
- 239000002904 solvent Substances 0.000 description 17
- 239000011258 core-shell material Substances 0.000 description 14
- 230000008569 process Effects 0.000 description 13
- 239000003795 chemical substances by application Substances 0.000 description 12
- 230000000052 comparative effect Effects 0.000 description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 12
- 230000004048 modification Effects 0.000 description 10
- 238000012986 modification Methods 0.000 description 10
- 239000000243 solution Substances 0.000 description 10
- 239000004593 Epoxy Substances 0.000 description 9
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 8
- 238000010438 heat treatment Methods 0.000 description 8
- 239000007788 liquid Substances 0.000 description 8
- HGXVKAPCSIXGAK-UHFFFAOYSA-N 2,4-diethyl-6-methylbenzene-1,3-diamine;4,6-diethyl-2-methylbenzene-1,3-diamine Chemical compound CCC1=CC(CC)=C(N)C(C)=C1N.CCC1=CC(C)=C(N)C(CC)=C1N HGXVKAPCSIXGAK-UHFFFAOYSA-N 0.000 description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 6
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- 101001047645 Rhyparobia maderae Leucokinin-7 Proteins 0.000 description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 238000000576 coating method Methods 0.000 description 6
- 238000000746 purification Methods 0.000 description 6
- 229920000049 Carbon (fiber) Polymers 0.000 description 5
- 239000011164 primary particle Substances 0.000 description 5
- 239000007787 solid Substances 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- ARXJGSRGQADJSQ-UHFFFAOYSA-N 1-methoxypropan-2-ol Chemical compound COCC(C)O ARXJGSRGQADJSQ-UHFFFAOYSA-N 0.000 description 4
- 238000003775 Density Functional Theory Methods 0.000 description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- 239000004917 carbon fiber Substances 0.000 description 4
- 238000001460 carbon-13 nuclear magnetic resonance spectrum Methods 0.000 description 4
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- 230000000737 periodic effect Effects 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 238000000425 proton nuclear magnetic resonance spectrum Methods 0.000 description 4
- 239000002002 slurry Substances 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 4
- FALRKNHUBBKYCC-UHFFFAOYSA-N 2-(chloromethyl)pyridine-3-carbonitrile Chemical compound ClCC1=NC=CC=C1C#N FALRKNHUBBKYCC-UHFFFAOYSA-N 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 3
- BJSKBZUMYQBSOQ-UHFFFAOYSA-N Jeffamine M-600 Chemical compound COCCOCC(C)OCC(C)OCC(C)OCC(C)OCC(C)OCC(C)OCC(C)OCC(C)OCC(C)N BJSKBZUMYQBSOQ-UHFFFAOYSA-N 0.000 description 3
- 239000004721 Polyphenylene oxide Substances 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 150000001412 amines Chemical class 0.000 description 3
- 229910000019 calcium carbonate Inorganic materials 0.000 description 3
- 238000001704 evaporation Methods 0.000 description 3
- 230000008020 evaporation Effects 0.000 description 3
- 239000004744 fabric Substances 0.000 description 3
- 230000009477 glass transition Effects 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 238000003801 milling Methods 0.000 description 3
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 3
- 239000008188 pellet Substances 0.000 description 3
- 229920000570 polyether Polymers 0.000 description 3
- 230000005855 radiation Effects 0.000 description 3
- 239000011541 reaction mixture Substances 0.000 description 3
- 229940014800 succinic anhydride Drugs 0.000 description 3
- 230000008961 swelling Effects 0.000 description 3
- 238000010998 test method Methods 0.000 description 3
- 238000001721 transfer moulding Methods 0.000 description 3
- BDZBKCUKTQZUTL-UHFFFAOYSA-N triethyl phosphite Chemical compound CCOP(OCC)OCC BDZBKCUKTQZUTL-UHFFFAOYSA-N 0.000 description 3
- FSSPGSAQUIYDCN-UHFFFAOYSA-N 1,3-Propane sultone Chemical compound O=S1(=O)CCCO1 FSSPGSAQUIYDCN-UHFFFAOYSA-N 0.000 description 2
- 238000005160 1H NMR spectroscopy Methods 0.000 description 2
- NEAQRZUHTPSBBM-UHFFFAOYSA-N 2-hydroxy-3,3-dimethyl-7-nitro-4h-isoquinolin-1-one Chemical compound C1=C([N+]([O-])=O)C=C2C(=O)N(O)C(C)(C)CC2=C1 NEAQRZUHTPSBBM-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 235000021355 Stearic acid Nutrition 0.000 description 2
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000004590 computer program Methods 0.000 description 2
- 239000012141 concentrate Substances 0.000 description 2
- -1 curing accelerators Substances 0.000 description 2
- WYACBZDAHNBPPB-UHFFFAOYSA-N diethyl oxalate Chemical compound CCOC(=O)C(=O)OCC WYACBZDAHNBPPB-UHFFFAOYSA-N 0.000 description 2
- MJUJXFBTEFXVKU-UHFFFAOYSA-N diethyl phosphonate Chemical compound CCOP(=O)OCC MJUJXFBTEFXVKU-UHFFFAOYSA-N 0.000 description 2
- 238000007865 diluting Methods 0.000 description 2
- 239000002270 dispersing agent Substances 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000010894 electron beam technology Methods 0.000 description 2
- 230000003628 erosive effect Effects 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 125000000524 functional group Chemical group 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 239000003365 glass fiber Substances 0.000 description 2
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 2
- 239000004850 liquid epoxy resins (LERs) Substances 0.000 description 2
- 229920001427 mPEG Polymers 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 230000002787 reinforcement Effects 0.000 description 2
- 239000012744 reinforcing agent Substances 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 239000008117 stearic acid Substances 0.000 description 2
- KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid Chemical compound OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 2
- FYSNRJHAOHDILO-UHFFFAOYSA-N thionyl chloride Chemical compound ClS(Cl)=O FYSNRJHAOHDILO-UHFFFAOYSA-N 0.000 description 2
- 239000012745 toughening agent Substances 0.000 description 2
- 238000009849 vacuum degassing Methods 0.000 description 2
- 239000003039 volatile agent Substances 0.000 description 2
- WTFAGPBUAGFMQX-UHFFFAOYSA-N 1-[2-[2-(2-aminopropoxy)propoxy]propoxy]propan-2-amine Chemical compound CC(N)COCC(C)OCC(C)OCC(C)N WTFAGPBUAGFMQX-UHFFFAOYSA-N 0.000 description 1
- XQUPVDVFXZDTLT-UHFFFAOYSA-N 1-[4-[[4-(2,5-dioxopyrrol-1-yl)phenyl]methyl]phenyl]pyrrole-2,5-dione Chemical compound O=C1C=CC(=O)N1C(C=C1)=CC=C1CC1=CC=C(N2C(C=CC2=O)=O)C=C1 XQUPVDVFXZDTLT-UHFFFAOYSA-N 0.000 description 1
- AATNZNJRDOVKDD-UHFFFAOYSA-N 1-[ethoxy(ethyl)phosphoryl]oxyethane Chemical compound CCOP(=O)(CC)OCC AATNZNJRDOVKDD-UHFFFAOYSA-N 0.000 description 1
- 238000001644 13C nuclear magnetic resonance spectroscopy Methods 0.000 description 1
- VHYFNPMBLIVWCW-UHFFFAOYSA-N 4-Dimethylaminopyridine Chemical compound CN(C)C1=CC=NC=C1 VHYFNPMBLIVWCW-UHFFFAOYSA-N 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 241000288673 Chiroptera Species 0.000 description 1
- PJWWRFATQTVXHA-UHFFFAOYSA-N Cyclohexylaminopropanesulfonic acid Chemical compound OS(=O)(=O)CCCNC1CCCCC1 PJWWRFATQTVXHA-UHFFFAOYSA-N 0.000 description 1
- 206010012335 Dependence Diseases 0.000 description 1
- AVXURJPOCDRRFD-UHFFFAOYSA-N Hydroxylamine Chemical compound ON AVXURJPOCDRRFD-UHFFFAOYSA-N 0.000 description 1
- 239000004609 Impact Modifier Substances 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004642 Polyimide Substances 0.000 description 1
- 101001047650 Rhyparobia maderae Leucokinin-3 Proteins 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000011157 advanced composite material Substances 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 238000003491 array Methods 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 239000004841 bisphenol A epoxy resin Substances 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- IYYIVELXUANFED-UHFFFAOYSA-N bromo(trimethyl)silane Chemical compound C[Si](C)(C)Br IYYIVELXUANFED-UHFFFAOYSA-N 0.000 description 1
- 230000005587 bubbling Effects 0.000 description 1
- QHIWVLPBUQWDMQ-UHFFFAOYSA-N butyl prop-2-enoate;methyl 2-methylprop-2-enoate;prop-2-enoic acid Chemical compound OC(=O)C=C.COC(=O)C(C)=C.CCCCOC(=O)C=C QHIWVLPBUQWDMQ-UHFFFAOYSA-N 0.000 description 1
- 229910001424 calcium ion Inorganic materials 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 239000004643 cyanate ester Substances 0.000 description 1
- 238000007872 degassing Methods 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- QGBSISYHAICWAH-UHFFFAOYSA-N dicyandiamide Chemical compound NC(N)=NC#N QGBSISYHAICWAH-UHFFFAOYSA-N 0.000 description 1
- GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical compound C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- UHESRSKEBRADOO-UHFFFAOYSA-N ethyl carbamate;prop-2-enoic acid Chemical compound OC(=O)C=C.CCOC(N)=O UHESRSKEBRADOO-UHFFFAOYSA-N 0.000 description 1
- 238000009730 filament winding Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 238000009499 grossing Methods 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 1
- 235000019341 magnesium sulphate Nutrition 0.000 description 1
- 230000003278 mimic effect Effects 0.000 description 1
- 239000002114 nanocomposite Substances 0.000 description 1
- 238000009828 non-uniform distribution Methods 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920000233 poly(alkylene oxides) Polymers 0.000 description 1
- 229920003192 poly(bis maleimide) Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 239000004645 polyester resin Substances 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 239000004848 polyfunctional curative Substances 0.000 description 1
- 229920001721 polyimide Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- XTUSEBKMEQERQV-UHFFFAOYSA-N propan-2-ol;hydrate Chemical compound O.CC(C)O XTUSEBKMEQERQV-UHFFFAOYSA-N 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 1
- 229910010271 silicon carbide Inorganic materials 0.000 description 1
- SIFIMQMTABTXMD-UHFFFAOYSA-N silylphosphonic acid Chemical compound OP(O)([SiH3])=O SIFIMQMTABTXMD-UHFFFAOYSA-N 0.000 description 1
- 238000004088 simulation Methods 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 238000007655 standard test method Methods 0.000 description 1
- 239000001384 succinic acid Substances 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 238000002411 thermogravimetry Methods 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 230000009974 thixotropic effect Effects 0.000 description 1
- 238000011282 treatment Methods 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Reinforced Plastic Materials (AREA)
- Paints Or Removers (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US13914508P | 2008-12-19 | 2008-12-19 | |
| US61/139,145 | 2008-12-19 | ||
| PCT/US2009/068359 WO2010080459A1 (en) | 2008-12-19 | 2009-12-17 | Nanocalcite composites |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2012512950A JP2012512950A (ja) | 2012-06-07 |
| JP2012512950A5 JP2012512950A5 (cg-RX-API-DMAC7.html) | 2013-02-14 |
| JP5855943B2 true JP5855943B2 (ja) | 2016-02-09 |
Family
ID=41809175
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2011542415A Active JP5855943B2 (ja) | 2008-12-19 | 2009-12-17 | ナノカルサイト複合材料 |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US9221970B2 (cg-RX-API-DMAC7.html) |
| EP (2) | EP2373727B1 (cg-RX-API-DMAC7.html) |
| JP (1) | JP5855943B2 (cg-RX-API-DMAC7.html) |
| CN (1) | CN102317361B (cg-RX-API-DMAC7.html) |
| BR (1) | BRPI0922480A2 (cg-RX-API-DMAC7.html) |
| WO (1) | WO2010080459A1 (cg-RX-API-DMAC7.html) |
Families Citing this family (29)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2011515569A (ja) | 2008-03-28 | 2011-05-19 | スリーエム イノベイティブ プロパティズ カンパニー | 粒子の表面改質のための方法 |
| JP5711111B2 (ja) | 2008-03-28 | 2015-04-30 | スリーエム イノベイティブ プロパティズ カンパニー | 充填樹脂及び充填樹脂の製造方法 |
| CN102015913B (zh) | 2008-04-25 | 2013-09-25 | 3M创新有限公司 | 粒子表面改性的方法 |
| WO2009152404A1 (en) | 2008-06-12 | 2009-12-17 | 3M Innovative Properties Company | Methods of compounding nanoparticles with a resin |
| JP5855943B2 (ja) | 2008-12-19 | 2016-02-09 | スリーエム イノベイティブ プロパティズ カンパニー | ナノカルサイト複合材料 |
| EP2435178B1 (en) | 2009-05-26 | 2020-08-12 | 3M Innovative Properties Company | Process for making filled resins |
| KR20180002904A (ko) | 2009-10-21 | 2018-01-08 | 쓰리엠 이노베이티브 프로퍼티즈 컴파니 | 반응성 희석제를 이용한 무용매 작용화, 밀링, 및 배합 공정 |
| KR101656911B1 (ko) * | 2009-12-17 | 2016-09-12 | 쓰리엠 이노베이티브 프로퍼티즈 컴파니 | 높은 마그네슘 표면 농도의 나노방해석 복합물 |
| JP5823979B2 (ja) * | 2009-12-17 | 2015-11-25 | スリーエム イノベイティブ プロパティズ カンパニー | ナノカルサイト及びビニルエステル複合材料 |
| KR101910202B1 (ko) | 2010-02-11 | 2018-10-19 | 쓰리엠 이노베이티브 프로퍼티즈 컴파니 | 분산된 다중모드 표면 개질된 나노입자를 포함하는 수지 시스템 |
| JP5809241B2 (ja) | 2010-04-20 | 2015-11-10 | スリーエム イノベイティブ プロパティズ カンパニー | ポリマー表面修飾ナノ粒子を含有する感圧接着剤 |
| CN102985747B (zh) | 2010-06-17 | 2015-05-20 | 3M创新有限公司 | 复合材料压力容器 |
| DE102010044456A1 (de) * | 2010-09-06 | 2012-03-08 | Siemens Aktiengesellschaft | Infusionsharzformulierung für Faserverbundwerkstoffe |
| WO2012037265A2 (en) * | 2010-09-17 | 2012-03-22 | 3M Innovative Properties Company | Fiber-reinforced nanoparticle-loaded thermoset polymer composite wires and cables, and methods |
| PL2616504T3 (pl) * | 2010-09-17 | 2015-01-30 | 3M Innovative Properties Co | Wsparcie procesowe pultruzji nanocząstek |
| CN103261086B (zh) * | 2010-12-13 | 2016-08-03 | 3M创新有限公司 | 干燥的表面改性纳米方解石 |
| JP6083604B2 (ja) * | 2013-05-27 | 2017-02-22 | 国立研究開発法人海洋研究開発機構 | 応力履歴測定方法および応力センサー |
| US10442914B2 (en) | 2013-08-13 | 2019-10-15 | 3M Innovative Properties Company | Nanocomposites containing silica nanoparticles and dispersant, composites, articles, and methods of making same |
| US10011699B2 (en) | 2014-08-29 | 2018-07-03 | 3M Innovative Properties Company | Inductively curable composition |
| EP3436428B1 (en) | 2016-03-31 | 2024-07-10 | 3M Innovative Properties Company | Bisphenol m diphthalonitrile ether resin, bisphenol p diphthalonitrile ether resin, methods of making same, resin blends, and two component systems |
| KR20190080867A (ko) | 2016-10-06 | 2019-07-08 | 쓰리엠 이노베이티브 프로퍼티즈 컴파니 | 경화성 조성물 및 관련 방법 |
| CN110114384B (zh) | 2016-12-29 | 2022-06-07 | 3M创新有限公司 | 可固化组合物 |
| CN107500330A (zh) * | 2017-08-10 | 2017-12-22 | 青阳县永诚钙业有限责任公司 | 一种新型方解石的制备方法 |
| EP3728506A1 (en) | 2017-12-22 | 2020-10-28 | 3M Innovative Properties Company | Multilayered polyetherketoneketone articles and methods thereof |
| CN113227261A (zh) * | 2018-10-30 | 2021-08-06 | 禾大公司 | 在水或极性溶剂中分散细颗粒的方法 |
| KR102563071B1 (ko) * | 2019-02-28 | 2023-08-03 | 동우 화인켐 주식회사 | 양자점, 이를 포함하는 양자점 발광다이오드, 양자점 필름, 광 변환 수지 조성물, 상기 광 변환 수지 조성물을 이용하여 형성되는 컬러필터, 광 변환 적층기재 및 상기 컬러필터 또는 상기 광 변환 적층기재를 포함하는 화상표시장치 |
| US12065761B2 (en) * | 2019-06-27 | 2024-08-20 | Khalifa University of Science and Technology | Additive fabrication method of transparent rock micromodels with in-situ mineral coating |
| US11485833B2 (en) * | 2019-10-23 | 2022-11-01 | Hexcel Corporation | Thermoplastic toughened matrix resins containing nanoparticles |
| JP2023508110A (ja) | 2019-12-30 | 2023-02-28 | スリーエム イノベイティブ プロパティズ カンパニー | バルク拡散体 |
Family Cites Families (43)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3956230A (en) * | 1968-02-01 | 1976-05-11 | Champion International Corporation | Compatibilization of hydroxyl-containing fillers and thermoplastic polymers |
| US4478963A (en) | 1980-08-08 | 1984-10-23 | The B. F. Goodrich Company | Filler particles coated with reactive liquid polymers in a matrix resin |
| DE3263184D1 (en) | 1981-01-15 | 1985-05-30 | Battelle Development Corp | Photo setting composition for coating substrates with an abrasion-resistant transparent or translucent film |
| DE3141955A1 (de) | 1981-10-22 | 1983-05-05 | Siemens AG, 1000 Berlin und 8000 München | Reaktionsharzmassen und daraus hergestellte formstoffe |
| JPH0822910B2 (ja) * | 1990-01-08 | 1996-03-06 | 四国化成工業株式会社 | 炭酸カルシウム組成物を含有する高分子組成物の製法 |
| JPH06107937A (ja) * | 1992-09-28 | 1994-04-19 | Hitachi Chem Co Ltd | 不飽和ポリエステル樹脂組成物、シート状成形材料および繊維強化プラスチック成形品の製造法 |
| JP2918418B2 (ja) | 1993-05-18 | 1999-07-12 | 積水化学工業株式会社 | 室温硬化性組成物 |
| US5648407A (en) | 1995-05-16 | 1997-07-15 | Minnesota Mining And Manufacturing Company | Curable resin sols and fiber-reinforced composites derived therefrom |
| EP0858361B1 (en) | 1995-09-18 | 2001-11-21 | Minnesota Mining And Manufacturing Company | Component separation system including condensing mechanism |
| US5694701A (en) | 1996-09-04 | 1997-12-09 | Minnesota Mining And Manufacturing Company | Coated substrate drying system |
| JP3623646B2 (ja) | 1997-04-04 | 2005-02-23 | 丸尾カルシウム株式会社 | 水系塗料用体質顔料 |
| DE19738481C2 (de) | 1997-09-03 | 1999-08-12 | Solvay Alkali Gmbh | In Wässrigen Systemen mit oberflächenaktiven Stoffen gecoatetes Calciumcarbonat sowie Verfahren zur gesteuerten bimolekularen Beschichtung von Calciumcarbonat - Teichen |
| CN1133678C (zh) * | 1998-04-17 | 2004-01-07 | 三洋化成工业株式会社 | 可固化组合物及其固化制品 |
| US6616794B2 (en) | 1998-05-04 | 2003-09-09 | Tpl, Inc. | Integral capacitance for printed circuit board using dielectric nanopowders |
| ATE305950T1 (de) | 1999-02-19 | 2005-10-15 | Du Pont | Verstärkte polyamide mit hohem modul |
| DE60022667T2 (de) | 1999-10-28 | 2006-06-14 | 3M Innovative Properties Co | Dentalmaterialien mit siliciumdioxid-nanoteilchen |
| US20030055207A1 (en) | 2000-10-02 | 2003-03-20 | Nyacol Nano Technologies, Inc. | Surface-modified Ca(CO3) and polymers containing same |
| US6890968B2 (en) | 2001-05-16 | 2005-05-10 | Kerr Corporation | Prepolymerized filler in dental restorative composite |
| CN100349801C (zh) * | 2001-11-16 | 2007-11-21 | 丸尾钙株式会社 | 经表面处理的碳酸钙、其制备方法以及混合有该碳酸钙而成的树脂组合物 |
| TWI283235B (en) * | 2001-11-16 | 2007-07-01 | Maruo Calcium | Surface-treated calcium carbonate, production method thereof, and resin composition containing the calcium carbonate |
| DE10200928A1 (de) | 2002-01-12 | 2003-09-25 | Basf Coatings Ag | Organische Dispersionen von oberflächenmodifizierten Nanopartikeln, Verfahren zu ihrer Herstellung und ihre Verwendung |
| US20030198780A1 (en) * | 2002-04-17 | 2003-10-23 | Campese John A. | Resin formulation |
| US6656975B1 (en) * | 2002-05-21 | 2003-12-02 | Dow Corning Corporation | Silicone dispersions |
| CN1209418C (zh) * | 2002-09-16 | 2005-07-06 | 鲍振林 | 一种废旧塑料和粉煤灰的改性组合物 |
| US7863367B2 (en) * | 2002-10-03 | 2011-01-04 | Maruo Calcium Company Limited | Surface treated calcium carbonate and a resin composition containing the same |
| EP1426390B1 (en) | 2002-11-14 | 2006-05-31 | Rohm And Haas Company | Curable clay composition: composition, processes, and uses thereof |
| EP1557442A1 (de) * | 2004-01-23 | 2005-07-27 | SOLVAY (Société Anonyme) | Verfahren zur Oberflächenbehandlung von gefälltem Calciumcarbonat |
| EP1720887B1 (en) * | 2004-02-23 | 2008-04-02 | Dow Gloval Technologies Inc. | Aqueous-based adhesive for bonding low surface energy substrates |
| JP2006188552A (ja) | 2004-12-28 | 2006-07-20 | Toho Earthtech Inc | 粘稠性樹脂組成物 |
| EP1715348B2 (en) | 2005-07-15 | 2019-05-08 | Agilent Technologies, Inc. | Handling unit for microfluidic devices with clamping means |
| US7457620B2 (en) | 2005-07-15 | 2008-11-25 | Cisco Technology, Inc. | Off-channel beacons in a wireless network |
| ITMI20051464A1 (it) | 2005-07-28 | 2007-01-29 | Macri Chemicals Srl | Composizioni di vernici e loro impiego per il rivestimento di superfici di substrati |
| DE102005040157A1 (de) | 2005-08-25 | 2007-03-01 | Degussa Ag | Paste aus nanoskaligem Pulver und Dispergiermittel |
| US8152915B2 (en) | 2005-09-02 | 2012-04-10 | Basf Se | Process for preparation of a novel pigmented composition for use in gravure inks |
| FR2891546B1 (fr) | 2005-10-04 | 2010-09-03 | Solvay | Utilisation de particules de carbonate de calcium dans des compositions polymeriques transparentes, compositions polymeriques transparentes et procede de fabrication de ces compositions |
| WO2007108217A1 (ja) | 2006-03-20 | 2007-09-27 | Kotobuki Industries Co., Ltd. | ナノ粒子分散液の製造方法、ナノ粒子分散液及びナノ粒子分散液製造装置 |
| US8530573B2 (en) | 2006-05-10 | 2013-09-10 | Designer Molecules, Inc. | Modified calcium carbonate-filled adhesive compositions and methods for use thereof |
| EP2059567A2 (en) | 2006-08-29 | 2009-05-20 | 3M Innovative Properties Company | Resin systems including reactive surface-modified nanoparticles |
| JP5544162B2 (ja) | 2007-02-28 | 2014-07-09 | 株式会社カネカ | ゴム状重合体粒子分散熱硬化性樹脂組成物、及びその製造方法 |
| US7596986B2 (en) | 2007-03-01 | 2009-10-06 | 3M Innovative Properties Company | Method of testing liquid drop impact and apparatus |
| EP2036944A1 (en) * | 2007-09-14 | 2009-03-18 | SOLVAY (Société Anonyme) | Polymer compositions |
| JP5855943B2 (ja) | 2008-12-19 | 2016-02-09 | スリーエム イノベイティブ プロパティズ カンパニー | ナノカルサイト複合材料 |
| KR20180002904A (ko) | 2009-10-21 | 2018-01-08 | 쓰리엠 이노베이티브 프로퍼티즈 컴파니 | 반응성 희석제를 이용한 무용매 작용화, 밀링, 및 배합 공정 |
-
2009
- 2009-12-17 JP JP2011542415A patent/JP5855943B2/ja active Active
- 2009-12-17 US US13/133,878 patent/US9221970B2/en active Active
- 2009-12-17 BR BRPI0922480A patent/BRPI0922480A2/pt not_active Application Discontinuation
- 2009-12-17 EP EP09806065.0A patent/EP2373727B1/en not_active Revoked
- 2009-12-17 CN CN200980156640.9A patent/CN102317361B/zh active Active
- 2009-12-17 EP EP13164215.9A patent/EP2617762A1/en not_active Withdrawn
- 2009-12-17 WO PCT/US2009/068359 patent/WO2010080459A1/en not_active Ceased
Also Published As
| Publication number | Publication date |
|---|---|
| US20110245376A1 (en) | 2011-10-06 |
| CN102317361A (zh) | 2012-01-11 |
| EP2373727A1 (en) | 2011-10-12 |
| US9221970B2 (en) | 2015-12-29 |
| JP2012512950A (ja) | 2012-06-07 |
| BRPI0922480A2 (pt) | 2018-06-05 |
| CN102317361B (zh) | 2014-07-02 |
| EP2617762A1 (en) | 2013-07-24 |
| WO2010080459A1 (en) | 2010-07-15 |
| EP2373727B1 (en) | 2014-01-22 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP5855943B2 (ja) | ナノカルサイト複合材料 | |
| EP2490983B1 (en) | Solventless functionalization, milling, and compounding process with reactive diluents | |
| EP1710264B1 (de) | Phosphororganische Verbindungen enthaltende Prepolymere und Verwendungen dafür | |
| JP5823979B2 (ja) | ナノカルサイト及びビニルエステル複合材料 | |
| US20120296012A1 (en) | Room temperature ionic liquid-epoxy systems as dispersants and matrix materials for nanocomposites | |
| KR20160043981A (ko) | 층상 나노입자 및 분산제를 함유하는 나노복합재, 복합재, 물품, 및 이의 제조 방법 | |
| JP5681205B2 (ja) | 高いマグネシウム表面濃度のナノカルサイト複合材料 | |
| Kong et al. | Improved mechanical and thermal properties of trifunctional epoxy resins through controlling molecular networks by ionic liquids | |
| Baniasad et al. | Investigation the potential of imide covalent organic frameworks (COFs) to enhance the toughness and mechanical properties of epoxy resin | |
| Antolín‐Cerón et al. | Preparation and characterization of nanocomposites made from chemoenzymatically prepared polyester urethanes and functionalized multiwalled carbon nanotubes | |
| Abobo et al. | Effect of organoclay reinforcement on the mechanical and thermal properties of unsaturated polyester resin composites. | |
| JP2007302746A (ja) | リン含有変性エポキシ樹脂、難燃性マトリックス樹脂組成物、プリプレグ及び複合材料 | |
| JP2007291237A5 (cg-RX-API-DMAC7.html) |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20121217 |
|
| A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20121217 |
|
| A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20130523 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20130528 |
|
| A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20130827 |
|
| A602 | Written permission of extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A602 Effective date: 20130903 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20131128 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20140218 |
|
| A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20140516 |
|
| A602 | Written permission of extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A602 Effective date: 20140523 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20140818 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20150120 |
|
| A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20150417 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20150721 |
|
| TRDD | Decision of grant or rejection written | ||
| A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20151110 |
|
| A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20151210 |
|
| R150 | Certificate of patent or registration of utility model |
Ref document number: 5855943 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |