JP5764207B2 - 無水銀アルカリマンガン電池用電解二酸化マンガンの製造法 - Google Patents

無水銀アルカリマンガン電池用電解二酸化マンガンの製造法 Download PDF

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JP5764207B2
JP5764207B2 JP2013518940A JP2013518940A JP5764207B2 JP 5764207 B2 JP5764207 B2 JP 5764207B2 JP 2013518940 A JP2013518940 A JP 2013518940A JP 2013518940 A JP2013518940 A JP 2013518940A JP 5764207 B2 JP5764207 B2 JP 5764207B2
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manganese
manganese dioxide
electrolytic
stage
washing
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JP2013538936A (ja
JP2013538936A5 (enExample
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奇志 陳
奇志 陳
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広西有色金属集団▲ふい▼元▲めん▼業有限公司
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    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
    • C22B3/04—Extraction of metal compounds from ores or concentrates by wet processes by leaching
    • C22B3/06—Extraction of metal compounds from ores or concentrates by wet processes by leaching in inorganic acid solutions, e.g. with acids generated in situ; in inorganic salt solutions other than ammonium salt solutions
    • C22B3/08—Sulfuric acid, other sulfurated acids or salts thereof
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
    • C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
    • C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
    • C22B3/44—Treatment or purification of solutions, e.g. obtained by leaching by chemical processes
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B47/00—Obtaining manganese
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B47/00—Obtaining manganese
    • C22B47/0018—Treating ocean floor nodules
    • C22B47/0045—Treating ocean floor nodules by wet processes
    • C22B47/0081—Treatment or purification of solutions, e.g. obtained by leaching
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00—Electrolytic production of inorganic compounds or non-metals
    • C25B1/01—Products
    • C25B1/21—Manganese oxides
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00—Technologies related to metal processing
    • Y02P10/20—Recycling

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Metallurgy (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Mechanical Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Geology (AREA)
  • Environmental & Geological Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Ocean & Marine Engineering (AREA)
  • Oceanography (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
  • Manufacture And Refinement Of Metals (AREA)
JP2013518940A 2010-07-15 2011-07-09 無水銀アルカリマンガン電池用電解二酸化マンガンの製造法 Active JP5764207B2 (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
CN2010102279887A CN101892384B (zh) 2010-07-15 2010-07-15 无汞碱锰型电解二氧化锰的生产方法
CN201010227988.7 2010-07-15
PCT/CN2011/077011 WO2012006935A1 (zh) 2010-07-15 2011-07-09 无汞碱锰型电解二氧化锰的生产方法

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JP2013538936A JP2013538936A (ja) 2013-10-17
JP2013538936A5 JP2013538936A5 (enExample) 2015-06-18
JP5764207B2 true JP5764207B2 (ja) 2015-08-12

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US (1) US20130037416A1 (enExample)
JP (1) JP5764207B2 (enExample)
CN (1) CN101892384B (enExample)
WO (1) WO2012006935A1 (enExample)

Families Citing this family (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7666593B2 (en) 2005-08-26 2010-02-23 Helicos Biosciences Corporation Single molecule sequencing of captured nucleic acids
CN101892384B (zh) * 2010-07-15 2011-09-21 广西有色金属集团汇元锰业有限公司 无汞碱锰型电解二氧化锰的生产方法
CN102560526B (zh) * 2011-12-23 2015-03-25 苏州大学 一种高功率电解二氧化锰的制备方法
CN103074490B (zh) * 2013-01-09 2014-03-12 广西有色金属集团汇元锰业有限公司 一种多矿法生产电解金属锰过程中的净化方法
CN103205772B (zh) * 2013-04-15 2015-07-08 广西有色金属集团汇元锰业有限公司 电解二氧化锰的生产方法
CN103560240B (zh) * 2013-11-07 2015-11-25 广西桂柳化工有限责任公司 无汞碱性电池专用电解二氧化锰制备方法
CN103643252B (zh) * 2013-12-05 2016-05-18 中信大锰矿业有限责任公司大新锰矿分公司 一种二氧化锰电解悬浮剂
CN103710541B (zh) * 2013-12-24 2015-12-30 柳州豪祥特科技有限公司 湿法生产电解二氧化锰的方法
KR101528507B1 (ko) * 2015-01-13 2015-06-12 한국지질자원연구원 리튬계 전지로부터 코발트 및 망간의 동시 회수 방법
CN104928709B (zh) * 2015-06-24 2017-04-12 广西有色金属集团汇元锰业有限公司 二氧化锰的电解系统及其生产方法
CN106480471B (zh) * 2016-11-04 2018-05-22 柳州高新区欧亚自动化设备有限责任公司 EMD连续浸出工艺化合槽pH值控制装置及其控制方法
CN110143615A (zh) * 2019-06-19 2019-08-20 贵州红星发展大龙锰业有限责任公司 电解二氧化锰及电解二氧化锰深度除钾的方法
CN110127766A (zh) * 2019-07-02 2019-08-16 贵州中伟资源循环产业发展有限公司 一种电池级硫酸锰溶液的制备工艺
CN110747329B (zh) * 2019-11-26 2022-02-22 广西汇元锰业有限责任公司 基于蔗渣造纸白泥的电解二氧化锰生产方法
CN111620355A (zh) * 2020-06-03 2020-09-04 四川兴晟锂业有限责任公司 一种去除氢氧化钾溶液中钾离子的方法
CN112708753B (zh) * 2020-12-29 2023-05-12 武钢资源集团大冶铁矿有限公司 一种铁精矿深度脱硫处理方法及系统
CN113215387A (zh) * 2021-02-25 2021-08-06 宁夏天元锰材料研究院(有限公司) 一种碳酸锰低温分解活化的方法及系统
CN114477521B (zh) * 2021-12-31 2024-05-28 广西大新汇元新能源科技有限责任公司 一种电解二氧化锰废水处理及锰的回收利用方法
CN114481165B (zh) * 2021-12-31 2023-11-28 广西大新汇元新能源科技有限责任公司 基于半氧化锰矿生产电解二氧化锰的方法
CN114715945A (zh) * 2022-05-31 2022-07-08 广西下田锰矿有限责任公司 一种高效率纯化硫酸锰溶液的方法
CN115094441A (zh) * 2022-07-14 2022-09-23 广西桂柳新材料股份有限公司 锂电池用电解二氧化锰的生产方法
CN115074753A (zh) * 2022-07-14 2022-09-20 广西桂柳新材料股份有限公司 碱锰电池用电解二氧化锰后处理除杂方法
CN115724470B (zh) * 2022-09-26 2024-05-07 广西科技师范学院 一种硫酸锰溶液的净化方法
CN120483260B (zh) * 2025-04-17 2025-11-14 广西埃索凯新材料科技有限公司 一种二氧化硫还原氧化锰矿制备高纯硫酸锰联产电池用二氧化锰的方法
CN120519869B (zh) * 2025-07-25 2025-11-21 湘潭电化科技股份有限公司 低品位氧化锰矿制备电解二氧化锰的方法、电解二氧化锰及其应用

Family Cites Families (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1874827A (en) * 1931-05-12 1932-08-30 Burgess Battery Co Production of manganese dioxide
US2424958A (en) * 1943-08-31 1947-08-05 Dorr Co Process of electrodepositing a manganese dioxide compound
US3348912A (en) * 1963-09-23 1967-10-24 Utah Construction & Mining Co Method of preparing manganese sulfate from pyrite reduced manganese dioxide ores
JPS5121959B1 (enExample) * 1969-06-16 1976-07-06
JPS49197A (enExample) * 1972-04-21 1974-01-05
JPS5216880B2 (enExample) * 1973-09-20 1977-05-12
DE2949791A1 (de) * 1979-12-11 1981-06-19 Krupp Polysius Ag, 4720 Beckum Vorrats- und mischsilo fuer schuettgut
JPS5988324A (ja) * 1982-11-12 1984-05-22 Japan Metals & Chem Co Ltd 電解二酸化マンガン用硫酸マンガン溶液の精製法
JPS60103192A (ja) * 1983-11-09 1985-06-07 Japan Metals & Chem Co Ltd 電解槽内蓄積物の処理法
JPS60236458A (ja) * 1984-05-10 1985-11-25 Toshiba Battery Co Ltd 水銀無添加電池
US4549943A (en) * 1984-11-01 1985-10-29 Union Carbide Corporation Suspension bath and process for production of electrolytic manganese dioxide
JPS6244586A (ja) * 1985-08-20 1987-02-26 Toshiba Battery Co Ltd 電池用電解二酸化マンガンの製造方法
CN87102046A (zh) * 1987-06-23 1987-12-09 桂阳县电解锰厂 用二氧化锰矿制取硫酸锰溶液的方法
CN1027294C (zh) * 1991-06-04 1995-01-04 上海钢铁研究所 电解二氧化锰用的钛合金阳极
JP3493835B2 (ja) * 1995-10-16 2004-02-03 松下電器産業株式会社 二酸化マンガンの製造法及びそれを用いたアルカリ乾電池
US6589693B1 (en) * 1999-08-05 2003-07-08 Eveready Battery Company, Inc. High discharge electrolytic manganese dioxide and an electrode and alkaline cell incorporating the same
JP4730488B2 (ja) * 2000-04-04 2011-07-20 東ソー株式会社 マンガン鉱石処理物の製造方法
DE60143686D1 (de) * 2000-09-01 2011-02-03 Tosoh Corp Elektrolytisches Mangandioxidpulver und Verfahren zu seiner Herstellung
JP3553541B2 (ja) * 2001-11-26 2004-08-11 三井金属鉱業株式会社 電池用正極活物質及び電解二酸化マンガンの製造方法並びに電池
US6896817B2 (en) * 2002-04-15 2005-05-24 Gregory S. Bowers Essentially insoluble heavy metal sulfide slurry for wastewater treatment
CN1861815A (zh) * 2005-05-14 2006-11-15 广西汇元锰业有限公司 连续浸出氧化锰矿的方法
CN1907866A (zh) * 2005-08-01 2007-02-07 李忠红 锰矿石直接制备四氧化三锰的方法
CN101456594A (zh) * 2007-12-14 2009-06-17 杜祖德 利用低品位锰矿渣制取硫酸锰的方法
WO2009120384A2 (en) * 2008-03-28 2009-10-01 Siemens Water Technologies Corp. Hybrid aerobic and anaerobic wastewater and sludge treatment systems and methods
CN101684562A (zh) * 2008-09-28 2010-03-31 熊一言 氧化锰矿的制液工艺
CN101550556A (zh) * 2009-04-01 2009-10-07 广西靖西县一洲锰业有限公司 碱性锌锰电池用电解二氧化锰的制备方法
CN101892384B (zh) * 2010-07-15 2011-09-21 广西有色金属集团汇元锰业有限公司 无汞碱锰型电解二氧化锰的生产方法

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WO2012006935A1 (zh) 2012-01-19
CN101892384B (zh) 2011-09-21
JP2013538936A (ja) 2013-10-17
CN101892384A (zh) 2010-11-24
US20130037416A1 (en) 2013-02-14

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