JP5744068B2 - 化学強化ガラス - Google Patents
化学強化ガラス Download PDFInfo
- Publication number
- JP5744068B2 JP5744068B2 JP2012554252A JP2012554252A JP5744068B2 JP 5744068 B2 JP5744068 B2 JP 5744068B2 JP 2012554252 A JP2012554252 A JP 2012554252A JP 2012554252 A JP2012554252 A JP 2012554252A JP 5744068 B2 JP5744068 B2 JP 5744068B2
- Authority
- JP
- Japan
- Prior art keywords
- compressive stress
- glass
- melt
- stress zone
- alkali
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000005341 toughened glass Substances 0.000 title description 4
- 239000011521 glass Substances 0.000 claims description 109
- 150000002500 ions Chemical class 0.000 claims description 47
- 239000000155 melt Substances 0.000 claims description 44
- 239000003513 alkali Substances 0.000 claims description 42
- 239000000203 mixture Substances 0.000 claims description 39
- 150000003839 salts Chemical class 0.000 claims description 33
- 238000000034 method Methods 0.000 claims description 32
- 238000003426 chemical strengthening reaction Methods 0.000 claims description 30
- 229910018068 Li 2 O Inorganic materials 0.000 claims description 18
- 229910052783 alkali metal Inorganic materials 0.000 claims description 16
- 238000005728 strengthening Methods 0.000 claims description 14
- -1 alkali metal salts Chemical class 0.000 claims description 10
- 229910001416 lithium ion Inorganic materials 0.000 claims description 9
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 claims description 8
- 150000001340 alkali metals Chemical class 0.000 claims description 8
- 239000005345 chemically strengthened glass Substances 0.000 claims description 8
- 238000003860 storage Methods 0.000 claims description 8
- 229910018072 Al 2 O 3 Inorganic materials 0.000 claims description 5
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 5
- 150000001447 alkali salts Chemical class 0.000 claims description 5
- 239000006059 cover glass Substances 0.000 claims description 5
- 229910006404 SnO 2 Inorganic materials 0.000 claims description 4
- 230000006835 compression Effects 0.000 claims description 3
- 238000007906 compression Methods 0.000 claims description 3
- 238000004891 communication Methods 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 claims description 2
- 238000002156 mixing Methods 0.000 claims description 2
- 241000023320 Luma <angiosperm> Species 0.000 claims 1
- OSWPMRLSEDHDFF-UHFFFAOYSA-N methyl salicylate Chemical compound COC(=O)C1=CC=CC=C1O OSWPMRLSEDHDFF-UHFFFAOYSA-N 0.000 claims 1
- 241000894007 species Species 0.000 claims 1
- 239000006058 strengthened glass Substances 0.000 claims 1
- 239000000126 substance Substances 0.000 claims 1
- 239000011734 sodium Substances 0.000 description 31
- 229910052708 sodium Inorganic materials 0.000 description 17
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 description 14
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 description 14
- 230000035515 penetration Effects 0.000 description 13
- 239000000758 substrate Substances 0.000 description 10
- 239000005354 aluminosilicate glass Substances 0.000 description 8
- 229910001415 sodium ion Inorganic materials 0.000 description 8
- 229910002651 NO3 Inorganic materials 0.000 description 7
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 7
- 238000012545 processing Methods 0.000 description 7
- 235000010344 sodium nitrate Nutrition 0.000 description 7
- 239000004317 sodium nitrate Substances 0.000 description 7
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 6
- 238000005342 ion exchange Methods 0.000 description 6
- 229910052700 potassium Inorganic materials 0.000 description 6
- 235000010333 potassium nitrate Nutrition 0.000 description 6
- 239000004323 potassium nitrate Substances 0.000 description 6
- 239000006018 Li-aluminosilicate Substances 0.000 description 5
- 150000001768 cations Chemical class 0.000 description 5
- 229910052744 lithium Inorganic materials 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 3
- 229910001963 alkali metal nitrate Inorganic materials 0.000 description 3
- 238000000137 annealing Methods 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 239000011591 potassium Substances 0.000 description 3
- 229910052701 rubidium Inorganic materials 0.000 description 3
- 238000005496 tempering Methods 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 2
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 2
- 229910001417 caesium ion Inorganic materials 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000005329 float glass Substances 0.000 description 2
- VVNXEADCOVSAER-UHFFFAOYSA-N lithium sodium Chemical compound [Li].[Na] VVNXEADCOVSAER-UHFFFAOYSA-N 0.000 description 2
- 229910001414 potassium ion Inorganic materials 0.000 description 2
- 229910001419 rubidium ion Inorganic materials 0.000 description 2
- 239000005368 silicate glass Substances 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000005341 cation exchange Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 238000007524 flame polishing Methods 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229940006487 lithium cation Drugs 0.000 description 1
- IRPDISVJRAYFBI-UHFFFAOYSA-N nitric acid;potassium Chemical compound [K].O[N+]([O-])=O IRPDISVJRAYFBI-UHFFFAOYSA-N 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 1
- 239000011435 rock Substances 0.000 description 1
- 239000005361 soda-lime glass Substances 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 239000005393 tempered soda-lime glass Substances 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C21/00—Treatment of glass, not in the form of fibres or filaments, by diffusing ions or metals in the surface
- C03C21/001—Treatment of glass, not in the form of fibres or filaments, by diffusing ions or metals in the surface in liquid phase, e.g. molten salts, solutions
- C03C21/002—Treatment of glass, not in the form of fibres or filaments, by diffusing ions or metals in the surface in liquid phase, e.g. molten salts, solutions to perform ion-exchange between alkali ions
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C21/00—Treatment of glass, not in the form of fibres or filaments, by diffusing ions or metals in the surface
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
- C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
- C03C3/089—Glass compositions containing silica with 40% to 90% silica, by weight containing boron
- C03C3/091—Glass compositions containing silica with 40% to 90% silica, by weight containing boron containing aluminium
- C03C3/093—Glass compositions containing silica with 40% to 90% silica, by weight containing boron containing aluminium containing zinc or zirconium
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
- C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
- C03C3/095—Glass compositions containing silica with 40% to 90% silica, by weight containing rare earths
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
- C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
- C03C3/097—Glass compositions containing silica with 40% to 90% silica, by weight containing phosphorus, niobium or tantalum
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C4/00—Compositions for glass with special properties
- C03C4/18—Compositions for glass with special properties for ion-sensitive glass
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2204/00—Glasses, glazes or enamels with special properties
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31—Surface property or characteristic of web, sheet or block
- Y10T428/315—Surface modified glass [e.g., tempered, strengthened, etc.]
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Ceramic Engineering (AREA)
- Surface Treatment Of Glass (AREA)
- Glass Compositions (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102010009584.2 | 2010-02-26 | ||
| DE102010009584.2A DE102010009584B4 (de) | 2010-02-26 | 2010-02-26 | Chemisch vorgespanntes Glas, Verfahren zu seiner Herstellung sowie Verwendung desselben |
| PCT/EP2011/000954 WO2011104035A2 (de) | 2010-02-26 | 2011-02-28 | Chemisch vorgespanntes glas |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2013520388A JP2013520388A (ja) | 2013-06-06 |
| JP5744068B2 true JP5744068B2 (ja) | 2015-07-01 |
Family
ID=44065881
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2012554252A Active JP5744068B2 (ja) | 2010-02-26 | 2011-02-28 | 化学強化ガラス |
Country Status (6)
| Country | Link |
|---|---|
| US (3) | US20120321898A1 (zh) |
| JP (1) | JP5744068B2 (zh) |
| KR (1) | KR101506378B1 (zh) |
| CN (1) | CN102906042B (zh) |
| DE (1) | DE102010009584B4 (zh) |
| WO (1) | WO2011104035A2 (zh) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US10968134B2 (en) | 2016-11-07 | 2021-04-06 | Corning Incorporated | Low viscosity glasses and methods and systems for manufacture |
| US11111173B2 (en) | 2016-11-07 | 2021-09-07 | Corning Incorporated | Lithium containing glasses |
| US11485674B2 (en) | 2018-03-29 | 2022-11-01 | Corning Incorporated | Glasses having high fracture toughness |
Families Citing this family (84)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8959953B2 (en) * | 2005-09-12 | 2015-02-24 | Saxon Glass Technologies, Inc. | Method for making strengthened glass |
| CN102167507B (zh) * | 2010-02-26 | 2016-03-16 | 肖特玻璃科技(苏州)有限公司 | 用于3d紧密模压的薄锂铝硅玻璃 |
| US20120052271A1 (en) | 2010-08-26 | 2012-03-01 | Sinue Gomez | Two-step method for strengthening glass |
| DE102014108058A1 (de) * | 2014-06-06 | 2015-12-17 | Schott Ag | Optisches Element mit hoher Kratzbeständigkeit |
| US9359251B2 (en) * | 2012-02-29 | 2016-06-07 | Corning Incorporated | Ion exchanged glasses via non-error function compressive stress profiles |
| KR20130124754A (ko) * | 2012-05-07 | 2013-11-15 | 삼성전기주식회사 | 터치패널 및 그 제조방법 |
| US9139469B2 (en) | 2012-07-17 | 2015-09-22 | Corning Incorporated | Ion exchangeable Li-containing glass compositions for 3-D forming |
| DE102012215864A1 (de) * | 2012-09-07 | 2014-03-13 | Schott Ag | Transparentes durchschusshemmendes Laminat |
| US20140178689A1 (en) * | 2012-10-05 | 2014-06-26 | Saxon Glass Technologies, Inc. | Strengthened glass and methods for making using differential time |
| DE102012019985B4 (de) | 2012-10-11 | 2020-11-05 | Zwiesel Kristallglas Ag | Verfahren zum Härten von Kristallglas |
| US9796621B2 (en) | 2012-10-15 | 2017-10-24 | Saxon Glass Technologies, Inc. | Strengthened glass and methods for making using heat treatment |
| US9308616B2 (en) | 2013-01-21 | 2016-04-12 | Innovative Finishes LLC | Refurbished component, electronic device including the same, and method of refurbishing a component of an electronic device |
| US9684097B2 (en) | 2013-05-07 | 2017-06-20 | Corning Incorporated | Scratch-resistant articles with retained optical properties |
| US9110230B2 (en) | 2013-05-07 | 2015-08-18 | Corning Incorporated | Scratch-resistant articles with retained optical properties |
| US9366784B2 (en) | 2013-05-07 | 2016-06-14 | Corning Incorporated | Low-color scratch-resistant articles with a multilayer optical film |
| US9703011B2 (en) | 2013-05-07 | 2017-07-11 | Corning Incorporated | Scratch-resistant articles with a gradient layer |
| US9359261B2 (en) | 2013-05-07 | 2016-06-07 | Corning Incorporated | Low-color scratch-resistant articles with a multilayer optical film |
| DE102013214426A1 (de) * | 2013-07-24 | 2015-01-29 | Schott Ag | Verbundelement und dessen Verwendung |
| US11079309B2 (en) | 2013-07-26 | 2021-08-03 | Corning Incorporated | Strengthened glass articles having improved survivability |
| US10160688B2 (en) | 2013-09-13 | 2018-12-25 | Corning Incorporated | Fracture-resistant layered-substrates and articles including the same |
| DE102013019003A1 (de) | 2013-11-13 | 2015-05-13 | Taiwan Glass Ind. Corp. | Alkali-Alumino-Silikatglas |
| US10118858B2 (en) | 2014-02-24 | 2018-11-06 | Corning Incorporated | Strengthened glass with deep depth of compression |
| DE102014208023A1 (de) | 2014-04-29 | 2015-10-29 | Volkswagen Aktiengesellschaft | Verfahren zur Herstellung eines mindestens eine durch chemisches Vorspannen erzeugte Sollbruchstelle aufweisenden Glaselements |
| US11267973B2 (en) | 2014-05-12 | 2022-03-08 | Corning Incorporated | Durable anti-reflective articles |
| US9335444B2 (en) | 2014-05-12 | 2016-05-10 | Corning Incorporated | Durable and scratch-resistant anti-reflective articles |
| TWI773291B (zh) | 2014-06-19 | 2022-08-01 | 美商康寧公司 | 無易碎應力分布曲線的玻璃 |
| CN108609866B (zh) * | 2014-07-25 | 2021-12-07 | 康宁股份有限公司 | 具有深的压缩深度的强化玻璃 |
| US9790593B2 (en) | 2014-08-01 | 2017-10-17 | Corning Incorporated | Scratch-resistant materials and articles including the same |
| EP3896042A1 (en) | 2014-10-08 | 2021-10-20 | Corning Incorporated | Glasses and glass ceramics including a metal oxide concentration gradient |
| US10150698B2 (en) | 2014-10-31 | 2018-12-11 | Corning Incorporated | Strengthened glass with ultra deep depth of compression |
| JP6839077B2 (ja) | 2014-11-04 | 2021-03-03 | コーニング インコーポレイテッド | 深部非脆弱性応力プロファイル及びその作成方法 |
| US9696498B2 (en) * | 2015-05-04 | 2017-07-04 | Huawei Technologies Co., Ltd. | Three-dimensional (3D) photonic chip-to-fiber interposer |
| EP3157880B1 (en) * | 2015-05-28 | 2020-11-18 | Corning Incorporated | Strengthened glass with deep depth of compression |
| DE102016210811A1 (de) | 2015-06-16 | 2016-12-22 | Ceramtec-Etec Gmbh | Transparente Keramik als Komponente für bruchfeste Optiken |
| US11613103B2 (en) | 2015-07-21 | 2023-03-28 | Corning Incorporated | Glass articles exhibiting improved fracture performance |
| US10579106B2 (en) | 2015-07-21 | 2020-03-03 | Corning Incorporated | Glass articles exhibiting improved fracture performance |
| EP3770649A1 (en) | 2015-09-14 | 2021-01-27 | Corning Incorporated | High light transmission and scratch-resistant anti-reflective articles |
| DE102015115511A1 (de) | 2015-09-15 | 2017-03-16 | Schott Ag | Transparenter Schutzverbund |
| KR102634633B1 (ko) | 2015-12-11 | 2024-02-08 | 코닝 인코포레이티드 | 금속 산화물 농도 구배를 포함하는 융합-형성가능한 유리계 제품 |
| US10131567B2 (en) | 2016-01-08 | 2018-11-20 | Corning Incorporated | Chemically strengthenable lithium aluminosilicate glasses with inherent damage resistance |
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| WO2019194110A1 (ja) | 2018-04-04 | 2019-10-10 | Ａｇｃ株式会社 | 化学強化用ガラス |
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2010
- 2010-02-26 DE DE102010009584.2A patent/DE102010009584B4/de active Active
-
2011
- 2011-02-28 CN CN201180011321.6A patent/CN102906042B/zh active Active
- 2011-02-28 JP JP2012554252A patent/JP5744068B2/ja active Active
- 2011-02-28 WO PCT/EP2011/000954 patent/WO2011104035A2/de active Application Filing
- 2011-02-28 KR KR1020127023584A patent/KR101506378B1/ko active IP Right Grant
- 2011-02-28 US US13/580,810 patent/US20120321898A1/en not_active Abandoned
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
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| US10968134B2 (en) | 2016-11-07 | 2021-04-06 | Corning Incorporated | Low viscosity glasses and methods and systems for manufacture |
| US11111173B2 (en) | 2016-11-07 | 2021-09-07 | Corning Incorporated | Lithium containing glasses |
| US11932574B2 (en) | 2016-11-07 | 2024-03-19 | Corning Incorporated | Lithium containing glasses |
| US11945747B2 (en) | 2016-11-07 | 2024-04-02 | Corning Incorporated | Low viscosity glasses and methods and systems for manufacture |
| US11485674B2 (en) | 2018-03-29 | 2022-11-01 | Corning Incorporated | Glasses having high fracture toughness |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2011104035A9 (de) | 2011-11-10 |
| US20120321898A1 (en) | 2012-12-20 |
| WO2011104035A2 (de) | 2011-09-01 |
| US12017952B2 (en) | 2024-06-25 |
| US20190276355A1 (en) | 2019-09-12 |
| US10351471B2 (en) | 2019-07-16 |
| KR20140027861A (ko) | 2014-03-07 |
| DE102010009584A1 (de) | 2011-09-01 |
| WO2011104035A3 (de) | 2012-01-05 |
| JP2013520388A (ja) | 2013-06-06 |
| CN102906042B (zh) | 2015-06-10 |
| KR101506378B1 (ko) | 2015-03-26 |
| CN102906042A (zh) | 2013-01-30 |
| DE102010009584B4 (de) | 2015-01-08 |
| US20160347655A1 (en) | 2016-12-01 |
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