JP5629056B2 - 耐ホウ酸塩フィルム - Google Patents
耐ホウ酸塩フィルム Download PDFInfo
- Publication number
- JP5629056B2 JP5629056B2 JP2008515701A JP2008515701A JP5629056B2 JP 5629056 B2 JP5629056 B2 JP 5629056B2 JP 2008515701 A JP2008515701 A JP 2008515701A JP 2008515701 A JP2008515701 A JP 2008515701A JP 5629056 B2 JP5629056 B2 JP 5629056B2
- Authority
- JP
- Japan
- Prior art keywords
- mol
- sulfonic acid
- units
- component
- soluble package
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 title abstract description 5
- 229920001577 copolymer Polymers 0.000 claims abstract description 71
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 38
- 125000000542 sulfonic acid group Chemical group 0.000 claims abstract description 31
- IMROMDMJAWUWLK-UHFFFAOYSA-N Ethenol Chemical group OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 claims abstract description 28
- 102000004190 Enzymes Human genes 0.000 claims abstract description 27
- 108090000790 Enzymes Proteins 0.000 claims abstract description 27
- 150000001875 compounds Chemical class 0.000 claims abstract description 22
- 239000003599 detergent Substances 0.000 claims abstract description 22
- 238000004806 packaging method and process Methods 0.000 claims abstract description 11
- 239000002245 particle Substances 0.000 claims description 36
- 229940088598 enzyme Drugs 0.000 claims description 26
- 229920000536 2-Acrylamido-2-methylpropane sulfonic acid Polymers 0.000 claims description 15
- XHZPRMZZQOIPDS-UHFFFAOYSA-N 2-Methyl-2-[(1-oxo-2-propenyl)amino]-1-propanesulfonic acid Chemical compound OS(=O)(=O)CC(C)(C)NC(=O)C=C XHZPRMZZQOIPDS-UHFFFAOYSA-N 0.000 claims description 15
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 14
- 229910052796 boron Inorganic materials 0.000 claims description 14
- 238000000576 coating method Methods 0.000 claims description 14
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 claims description 13
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical group CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 13
- 230000007062 hydrolysis Effects 0.000 claims description 12
- 238000006460 hydrolysis reaction Methods 0.000 claims description 12
- 239000011248 coating agent Substances 0.000 claims description 11
- 239000007864 aqueous solution Substances 0.000 claims description 9
- 239000000203 mixture Substances 0.000 claims description 9
- 235000010339 sodium tetraborate Nutrition 0.000 claims description 7
- 229910021538 borax Inorganic materials 0.000 claims description 5
- 229960001922 sodium perborate Drugs 0.000 claims description 5
- YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 claims description 5
- BSVBQGMMJUBVOD-UHFFFAOYSA-N trisodium borate Chemical compound [Na+].[Na+].[Na+].[O-]B([O-])[O-] BSVBQGMMJUBVOD-UHFFFAOYSA-N 0.000 claims description 5
- 108010065511 Amylases Proteins 0.000 claims description 4
- 102000013142 Amylases Human genes 0.000 claims description 4
- 108091005804 Peptidases Proteins 0.000 claims description 4
- 239000004365 Protease Substances 0.000 claims description 4
- 235000019418 amylase Nutrition 0.000 claims description 4
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims description 4
- 239000004327 boric acid Substances 0.000 claims description 4
- 102000005575 Cellulases Human genes 0.000 claims description 3
- 108010084185 Cellulases Proteins 0.000 claims description 3
- 102000004882 Lipase Human genes 0.000 claims description 3
- 239000004367 Lipase Substances 0.000 claims description 3
- 108090001060 Lipase Proteins 0.000 claims description 3
- 102000035195 Peptidases Human genes 0.000 claims description 3
- 229940025131 amylases Drugs 0.000 claims description 3
- 235000019421 lipase Nutrition 0.000 claims description 3
- VEAJBTCMWLQEPZ-UHFFFAOYSA-N CC(CS(=O)(=O)O)C.C(=O)(C(=C)C)C(C(=O)N)=C Chemical compound CC(CS(=O)(=O)O)C.C(=O)(C(=C)C)C(C(=O)N)=C VEAJBTCMWLQEPZ-UHFFFAOYSA-N 0.000 claims 3
- 239000004382 Amylase Substances 0.000 claims 1
- 108010059892 Cellulase Proteins 0.000 claims 1
- 102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 claims 1
- 229940106157 cellulase Drugs 0.000 claims 1
- 235000019419 proteases Nutrition 0.000 claims 1
- 239000000178 monomer Substances 0.000 abstract description 19
- 238000010348 incorporation Methods 0.000 abstract description 3
- 229920002451 polyvinyl alcohol Polymers 0.000 description 40
- 239000004372 Polyvinyl alcohol Substances 0.000 description 33
- 229920000642 polymer Polymers 0.000 description 27
- 239000000047 product Substances 0.000 description 9
- 238000004140 cleaning Methods 0.000 description 7
- 238000006116 polymerization reaction Methods 0.000 description 7
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- LNTHITQWFMADLM-UHFFFAOYSA-N gallic acid Chemical compound OC(=O)C1=CC(O)=C(O)C(O)=C1 LNTHITQWFMADLM-UHFFFAOYSA-N 0.000 description 6
- 239000004615 ingredient Substances 0.000 description 6
- 239000000243 solution Substances 0.000 description 6
- 238000000034 method Methods 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 4
- 238000005538 encapsulation Methods 0.000 description 4
- 230000035484 reaction time Effects 0.000 description 4
- 229920003169 water-soluble polymer Polymers 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- 125000005907 alkyl ester group Chemical group 0.000 description 3
- 239000002775 capsule Substances 0.000 description 3
- 229940074391 gallic acid Drugs 0.000 description 3
- 235000004515 gallic acid Nutrition 0.000 description 3
- 150000003460 sulfonic acids Chemical class 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical group CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- 108090000854 Oxidoreductases Proteins 0.000 description 2
- 102000004316 Oxidoreductases Human genes 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 150000001642 boronic acid derivatives Chemical class 0.000 description 2
- 150000001735 carboxylic acids Chemical class 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 239000008199 coating composition Substances 0.000 description 2
- 238000004132 cross linking Methods 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- CDMADVZSLOHIFP-UHFFFAOYSA-N disodium;3,7-dioxido-2,4,6,8,9-pentaoxa-1,3,5,7-tetraborabicyclo[3.3.1]nonane;decahydrate Chemical compound O.O.O.O.O.O.O.O.O.O.[Na+].[Na+].O1B([O-])OB2OB([O-])OB1O2 CDMADVZSLOHIFP-UHFFFAOYSA-N 0.000 description 2
- 238000004090 dissolution Methods 0.000 description 2
- 238000007720 emulsion polymerization reaction Methods 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 2
- 238000001879 gelation Methods 0.000 description 2
- 239000008187 granular material Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000002861 polymer material Substances 0.000 description 2
- 239000002243 precursor Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000006467 substitution reaction Methods 0.000 description 2
- 238000010557 suspension polymerization reaction Methods 0.000 description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
- -1 vinyl sulfonic acid Chemical class 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 229920013683 Celanese Polymers 0.000 description 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
- 102000004195 Isomerases Human genes 0.000 description 1
- 108090000769 Isomerases Proteins 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- 108700020962 Peroxidase Proteins 0.000 description 1
- 102000003992 Peroxidases Human genes 0.000 description 1
- 108091007187 Reductases Proteins 0.000 description 1
- 241000283984 Rodentia Species 0.000 description 1
- 102000004357 Transferases Human genes 0.000 description 1
- 108090000992 Transferases Proteins 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 150000001266 acyl halides Chemical class 0.000 description 1
- 125000003158 alcohol group Chemical group 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 150000008064 anhydrides Chemical class 0.000 description 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
- 150000001733 carboxylic acid esters Chemical class 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 239000013626 chemical specie Substances 0.000 description 1
- 239000011162 core material Substances 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 108010002430 hemicellulase Proteins 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 125000004356 hydroxy functional group Chemical group O* 0.000 description 1
- 150000003949 imides Chemical class 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000004530 micro-emulsion Substances 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 235000011837 pasties Nutrition 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 239000000575 pesticide Substances 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- UIIIBRHUICCMAI-UHFFFAOYSA-N prop-2-ene-1-sulfonic acid Chemical compound OS(=O)(=O)CC=C UIIIBRHUICCMAI-UHFFFAOYSA-N 0.000 description 1
- 238000010526 radical polymerization reaction Methods 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 125000001273 sulfonato group Chemical class [O-]S(*)(=O)=O 0.000 description 1
- 125000000472 sulfonyl group Chemical group *S(*)(=O)=O 0.000 description 1
- 239000000375 suspending agent Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 150000003573 thiols Chemical class 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- NLVXSWCKKBEXTG-UHFFFAOYSA-N vinylsulfonic acid Chemical compound OS(=O)(=O)C=C NLVXSWCKKBEXTG-UHFFFAOYSA-N 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38672—Granulated or coated enzymes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0039—Coated compositions or coated components in the compositions, (micro)capsules
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
- C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
- C11D17/042—Water soluble or water disintegrable containers or substrates containing cleaning compositions or additives for cleaning compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3753—Polyvinylalcohol; Ethers or esters thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3769—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
- Y10T428/1352—Polymer or resin containing [i.e., natural or synthetic]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
- Y10T428/2991—Coated
- Y10T428/2998—Coated including synthetic resin or polymer
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Health & Medical Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Wrappers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Detergent Compositions (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US11/147,831 US20060275567A1 (en) | 2005-06-07 | 2005-06-07 | Borate resistant films |
| US11/147,831 | 2005-06-07 | ||
| PCT/US2006/016586 WO2006132729A1 (en) | 2005-06-07 | 2006-05-02 | Borate resistant films |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2008542521A JP2008542521A (ja) | 2008-11-27 |
| JP2008542521A5 JP2008542521A5 (https=) | 2012-04-05 |
| JP5629056B2 true JP5629056B2 (ja) | 2014-11-19 |
Family
ID=36952593
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2008515701A Expired - Fee Related JP5629056B2 (ja) | 2005-06-07 | 2006-05-02 | 耐ホウ酸塩フィルム |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US20060275567A1 (https=) |
| EP (1) | EP1907524B1 (https=) |
| JP (1) | JP5629056B2 (https=) |
| KR (1) | KR20080025723A (https=) |
| CN (1) | CN101268178B (https=) |
| AT (1) | ATE550419T1 (https=) |
| BR (1) | BRPI0610883A2 (https=) |
| CA (1) | CA2609757C (https=) |
| MX (1) | MX2007015460A (https=) |
| TW (1) | TW200710219A (https=) |
| WO (1) | WO2006132729A1 (https=) |
Families Citing this family (26)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8772220B2 (en) * | 2007-08-24 | 2014-07-08 | Sekisui Specialty Chemicals America, Llc | Chemical delivery product and process for making the same |
| GB0803165D0 (en) | 2008-02-21 | 2008-04-02 | Unilever Plc | Encapsulated benefit agent |
| WO2012155957A1 (en) * | 2011-05-16 | 2012-11-22 | Statoil Petroleum As | Method of replacing a flexible container provided inside a subsea storage tank, replaceable flexible container and method of installing a storage container on the seabed |
| DE102011106036A1 (de) * | 2011-06-30 | 2013-01-03 | Dechema Gesellschaft Für Chemische Technik Und Biotechnologie E.V. | Verfahren zur Herstellung von alkalischen Polymerelektrolyt-Membranen für galvanische Elemente |
| US10087401B2 (en) | 2012-03-16 | 2018-10-02 | Monosol, Llc | Water soluble compositions incorporating enzymes, and method of making same |
| TWI548655B (zh) | 2012-10-22 | 2016-09-11 | 積水特殊化學美國有限責任公司 | 用於嚴苛化學品包裝的聚乙烯吡咯啶酮（ｐｖｐ）共聚物 |
| EP2740785A1 (en) * | 2012-12-06 | 2014-06-11 | The Procter and Gamble Company | Use of composition to reduce weeping and migration through a water soluble film |
| KR101357225B1 (ko) * | 2013-08-21 | 2014-02-11 | (주)파라스 | 일회용 수용성 스틱세제 |
| JP6512516B2 (ja) * | 2013-12-25 | 2019-05-15 | 株式会社クラレ | 変性ポリビニルアルコールおよびそれを含有する水溶性フィルム |
| US20170191005A1 (en) | 2014-05-22 | 2017-07-06 | Conopco, Inc., D/B/A Unilever | Aqueous liquid detergent formulation comprising enzyme particles |
| WO2016056570A1 (ja) * | 2014-10-09 | 2016-04-14 | 株式会社クラレ | 樹脂組成物及びフィルム |
| CA2962792C (en) * | 2014-10-13 | 2019-08-13 | The Procter & Gamble Company | Articles comprising water-soluble polyvinyl alcohol blend film and related methods |
| TWI677525B (zh) * | 2014-10-13 | 2019-11-21 | 美商摩諾索公司 | 水溶性聚乙烯醇摻合物膜、相關方法及相關物品 |
| TWI689547B (zh) | 2014-10-13 | 2020-04-01 | 美商摩諾索公司 | 具有塑化劑摻合物的水溶性聚乙烯醇膜、相關方法及相關物品 |
| JP6978315B2 (ja) * | 2014-10-13 | 2021-12-08 | モノソル リミテッド ライアビリティ カンパニー | 水溶性ポリビニルアルコールブレンドフィルム、関連方法及び関連物品 |
| AU2015333791B2 (en) | 2014-10-13 | 2017-11-09 | The Procter & Gamble Company | Articles comprising water-soluble polyvinyl alcohol film with plasticizer blend and related methods |
| JP6787131B2 (ja) * | 2015-09-11 | 2020-11-18 | 三菱ケミカル株式会社 | 水溶性フィルムを用いた薬剤包装体、並びに水溶性フィルムの製造方法 |
| PL3443030T3 (pl) | 2016-04-13 | 2022-10-10 | Monosol, Llc | Folia rozpuszczalna w wodzie, opakowania z folią oraz sposoby jej wytwarzania i stosowania |
| HUE068143T2 (hu) | 2016-06-13 | 2024-12-28 | Procter & Gamble | Különbözõ filmek kombinációjából készült, vízoldható, háztartási tisztítókészítményeket tartalmazó egyadagos termékek |
| EP3469060A1 (en) | 2016-06-13 | 2019-04-17 | The Procter & Gamble Company | Water-soluble unit dose articles made from a combination of different films and containing household care compositions |
| CN109312276A (zh) | 2016-06-13 | 2019-02-05 | 蒙诺苏尔有限公司 | 由不同薄膜的组合制得的水溶性单位剂量制品 |
| WO2017218441A1 (en) | 2016-06-13 | 2017-12-21 | The Procter & Gamble Company | Water-soluble unit dose articles made from a combination of different films and containing household care compositions |
| WO2017218414A1 (en) | 2016-06-13 | 2017-12-21 | Monosol, Llc | Use of a first film and a second film to improve seal strength of a water-soluble |
| US10899518B2 (en) | 2016-06-13 | 2021-01-26 | Monosol, Llc | Water-soluble packets |
| CN112334522B (zh) | 2018-05-02 | 2023-09-08 | 蒙诺苏尔有限公司 | 水溶性聚乙烯醇掺合物膜、相关方法和相关制品 |
| USD1088343S1 (en) | 2022-05-11 | 2025-08-12 | People Against Dirty Holdings Limited | Packet |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4828744A (en) * | 1981-11-10 | 1989-05-09 | The Clorox Company | Borate solution soluble polyvinyl alcohol films |
| US4885105A (en) * | 1987-05-14 | 1989-12-05 | The Clorox Company | Films from PVA modified with nonhydrolyzable anionic comonomers |
| US5324649A (en) * | 1991-10-07 | 1994-06-28 | Genencor International, Inc. | Enzyme-containing granules coated with hydrolyzed polyvinyl alcohol or copolymer thereof |
| DE4426008A1 (de) * | 1994-07-22 | 1996-01-25 | Cassella Ag | Hydrophile, hochquellfähige Hydrogele |
| JP3609894B2 (ja) * | 1996-04-05 | 2005-01-12 | 株式会社クラレ | ホウ酸系物質包装用フィルム |
| DE69801547T2 (de) * | 1997-06-11 | 2002-04-18 | Kuraray Co., Ltd | Wasserlöslicher Folie |
| JP3784533B2 (ja) * | 1997-06-11 | 2006-06-14 | 株式会社クラレ | 水溶性フィルム |
| US6933141B1 (en) * | 1999-10-01 | 2005-08-23 | Novozymes A/S | Enzyme granulate |
| EP1328612B1 (en) * | 2000-10-27 | 2007-04-25 | Genencor International, Inc. | Particle with substituted polyvinyl alcohol coating |
| JP3470892B2 (ja) * | 2001-03-16 | 2003-11-25 | 敏之 山室 | 展性材料およびその使用方法 |
| JP4056859B2 (ja) * | 2002-11-11 | 2008-03-05 | 日本合成化学工業株式会社 | 水溶性フィルム |
| US7022656B2 (en) | 2003-03-19 | 2006-04-04 | Monosol, Llc. | Water-soluble copolymer film packet |
| US6818709B1 (en) * | 2003-07-11 | 2004-11-16 | Celanese International Corporation | Production of vinyl alcohol copolymers |
| JP2005139240A (ja) * | 2003-11-04 | 2005-06-02 | Japan Vam & Poval Co Ltd | 水溶性フィルムおよび個別包装材 |
-
2005
- 2005-06-07 US US11/147,831 patent/US20060275567A1/en not_active Abandoned
-
2006
- 2006-05-02 EP EP06758834A patent/EP1907524B1/en not_active Revoked
- 2006-05-02 CN CN2006800202399A patent/CN101268178B/zh not_active Expired - Fee Related
- 2006-05-02 AT AT06758834T patent/ATE550419T1/de active
- 2006-05-02 MX MX2007015460A patent/MX2007015460A/es unknown
- 2006-05-02 BR BRPI0610883-0A patent/BRPI0610883A2/pt not_active Application Discontinuation
- 2006-05-02 CA CA2609757A patent/CA2609757C/en not_active Expired - Fee Related
- 2006-05-02 KR KR1020087000301A patent/KR20080025723A/ko not_active Withdrawn
- 2006-05-02 JP JP2008515701A patent/JP5629056B2/ja not_active Expired - Fee Related
- 2006-05-02 WO PCT/US2006/016586 patent/WO2006132729A1/en not_active Ceased
- 2006-06-07 TW TW095120286A patent/TW200710219A/zh unknown
Also Published As
| Publication number | Publication date |
|---|---|
| CN101268178A (zh) | 2008-09-17 |
| KR20080025723A (ko) | 2008-03-21 |
| CA2609757A1 (en) | 2006-12-14 |
| CN101268178B (zh) | 2012-10-03 |
| TW200710219A (en) | 2007-03-16 |
| EP1907524B1 (en) | 2012-03-21 |
| EP1907524A1 (en) | 2008-04-09 |
| CA2609757C (en) | 2013-04-09 |
| ATE550419T1 (de) | 2012-04-15 |
| US20060275567A1 (en) | 2006-12-07 |
| JP2008542521A (ja) | 2008-11-27 |
| MX2007015460A (es) | 2008-02-25 |
| WO2006132729A1 (en) | 2006-12-14 |
| BRPI0610883A2 (pt) | 2010-08-03 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP5629056B2 (ja) | 耐ホウ酸塩フィルム | |
| JP4825207B2 (ja) | ビニルアルコールとイタコン酸のコポリマー、及びその使用 | |
| JP5409629B2 (ja) | 会合性増粘剤分散液 | |
| JP2018030649A (ja) | 遅延放出用の水溶性フィルム | |
| CN100354403C (zh) | 聚合物颗粒的制造方法 | |
| TW201619272A (zh) | 水溶性聚乙烯醇摻合物膜、相關方法及相關物品 | |
| CN102666716A (zh) | 官能化的聚乙烯醇膜 | |
| CN103732730A (zh) | 织物护理制剂和方法 | |
| CN1633464A (zh) | 可控释放材料 | |
| KR20100113482A (ko) | 증점제 분산액의 제조 방법 | |
| JP2008542521A5 (https=) | ||
| AU2016202579A1 (en) | Particles with hydroxyl vinylic copolymer coating sensitive to ionic strength | |
| JP2019507810A (ja) | ポリマーフィルム及びポリマーフィルムを含有する洗剤パケット | |
| CN1434108A (zh) | 触发响应组合物 | |
| AU2003254725B2 (en) | Tablet coating | |
| US5549852A (en) | Polymer composition as detergent builder | |
| JPS59136301A (ja) | 懸濁重合安定剤 | |
| US20230416658A1 (en) | Compositions comprising protonated triazacyclic compounds and manganese(ii) acetate, manufacturing thereof, and bleaching and cleaning agent comprising same | |
| CN111051446A (zh) | 用于包装高碱性洗涤剂的冷水溶性聚合物膜 | |
| CN120988414A (zh) | 一种水溶膜及其制备方法 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20090427 |
|
| A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20090427 |
|
| A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20110830 |
|
| RD04 | Notification of resignation of power of attorney |
Free format text: JAPANESE INTERMEDIATE CODE: A7424 Effective date: 20110913 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20111017 |
|
| A711 | Notification of change in applicant |
Free format text: JAPANESE INTERMEDIATE CODE: A711 Effective date: 20111226 |
|
| A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20120110 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A821 Effective date: 20111226 |
|
| A602 | Written permission of extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A602 Effective date: 20120125 |
|
| A524 | Written submission of copy of amendment under article 19 pct |
Free format text: JAPANESE INTERMEDIATE CODE: A524 Effective date: 20120217 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A821 Effective date: 20120217 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20120823 |
|
| A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20121101 |
|
| A602 | Written permission of extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A602 Effective date: 20121108 |
|
| A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20121205 |
|
| A602 | Written permission of extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A602 Effective date: 20121212 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20130225 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20131203 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20140228 |
|
| A02 | Decision of refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A02 Effective date: 20140409 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20140807 |
|
| A911 | Transfer to examiner for re-examination before appeal (zenchi) |
Free format text: JAPANESE INTERMEDIATE CODE: A911 Effective date: 20140814 |
|
| TRDD | Decision of grant or rejection written | ||
| A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20140905 |
|
| A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20141003 |
|
| R150 | Certificate of patent or registration of utility model |
Ref document number: 5629056 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| LAPS | Cancellation because of no payment of annual fees |