JP5601478B2 - 半導電性ゴム用組成物、ゴム架橋体および半導電性部品 - Google Patents
半導電性ゴム用組成物、ゴム架橋体および半導電性部品 Download PDFInfo
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- JP5601478B2 JP5601478B2 JP2011536171A JP2011536171A JP5601478B2 JP 5601478 B2 JP5601478 B2 JP 5601478B2 JP 2011536171 A JP2011536171 A JP 2011536171A JP 2011536171 A JP2011536171 A JP 2011536171A JP 5601478 B2 JP5601478 B2 JP 5601478B2
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- epichlorohydrin
- ethylene oxide
- rubber
- semiconductive
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- 229920001971 elastomer Polymers 0.000 title claims description 36
- 239000005060 rubber Substances 0.000 title claims description 36
- 239000000203 mixture Substances 0.000 title claims description 24
- 239000003431 cross linking reagent Substances 0.000 claims description 34
- 239000005977 Ethylene Substances 0.000 claims description 31
- 229920005558 epichlorohydrin rubber Polymers 0.000 claims description 23
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 21
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 19
- XSCHRSMBECNVNS-UHFFFAOYSA-N quinoxaline Chemical compound N1=CC=NC2=CC=CC=C21 XSCHRSMBECNVNS-UHFFFAOYSA-N 0.000 claims description 18
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 15
- 229910052717 sulfur Inorganic materials 0.000 claims description 15
- 239000011593 sulfur Substances 0.000 claims description 15
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical group C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 14
- 229920001577 copolymer Polymers 0.000 claims description 12
- 229920001897 terpolymer Polymers 0.000 claims description 12
- 238000004132 cross linking Methods 0.000 claims description 11
- JYEUMXHLPRZUAT-UHFFFAOYSA-N 1,2,3-triazine Chemical compound C1=CN=NN=C1 JYEUMXHLPRZUAT-UHFFFAOYSA-N 0.000 claims description 7
- 229920005561 epichlorohydrin homopolymer Polymers 0.000 claims description 6
- 125000004432 carbon atom Chemical group C* 0.000 claims description 5
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 4
- OIXNFJTTYAIBNF-UHFFFAOYSA-N 2-(chloromethyl)oxirane;oxirane Chemical compound C1CO1.ClCC1CO1 OIXNFJTTYAIBNF-UHFFFAOYSA-N 0.000 claims description 3
- WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 claims description 3
- 239000002202 Polyethylene glycol Substances 0.000 claims description 3
- 125000000217 alkyl group Chemical group 0.000 claims description 3
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 claims description 3
- 229920001223 polyethylene glycol Polymers 0.000 claims description 3
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- 239000000654 additive Substances 0.000 claims description 2
- 125000000547 substituted alkyl group Chemical group 0.000 claims description 2
- 239000004636 vulcanized rubber Substances 0.000 claims 4
- 230000000996 additive effect Effects 0.000 claims 1
- 238000002156 mixing Methods 0.000 description 16
- 238000004073 vulcanization Methods 0.000 description 14
- 230000000052 comparative effect Effects 0.000 description 12
- YXIWHUQXZSMYRE-UHFFFAOYSA-N 1,3-benzothiazole-2-thiol Chemical class C1=CC=C2SC(S)=NC2=C1 YXIWHUQXZSMYRE-UHFFFAOYSA-N 0.000 description 10
- 238000000034 method Methods 0.000 description 10
- 239000011777 magnesium Substances 0.000 description 9
- 239000002253 acid Substances 0.000 description 7
- 230000007613 environmental effect Effects 0.000 description 7
- KUAZQDVKQLNFPE-UHFFFAOYSA-N thiram Chemical compound CN(C)C(=S)SSC(=S)N(C)C KUAZQDVKQLNFPE-UHFFFAOYSA-N 0.000 description 7
- 229960002447 thiram Drugs 0.000 description 7
- 239000010457 zeolite Substances 0.000 description 7
- 229920000459 Nitrile rubber Polymers 0.000 description 6
- -1 etc. Chemical compound 0.000 description 6
- 239000005077 polysulfide Substances 0.000 description 6
- 229920001021 polysulfide Polymers 0.000 description 6
- 150000008117 polysulfides Polymers 0.000 description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 5
- 229910052749 magnesium Inorganic materials 0.000 description 5
- 229910052751 metal Inorganic materials 0.000 description 5
- 239000002184 metal Substances 0.000 description 5
- 229910052760 oxygen Inorganic materials 0.000 description 5
- STMDPCBYJCIZOD-UHFFFAOYSA-N 2-(2,4-dinitroanilino)-4-methylpentanoic acid Chemical compound CC(C)CC(C(O)=O)NC1=CC=C([N+]([O-])=O)C=C1[N+]([O-])=O STMDPCBYJCIZOD-UHFFFAOYSA-N 0.000 description 4
- PAZJFXNRVLDLFO-UHFFFAOYSA-N 4-sulfanylmorpholine Chemical class SN1CCOCC1 PAZJFXNRVLDLFO-UHFFFAOYSA-N 0.000 description 4
- ODINCKMPIJJUCX-UHFFFAOYSA-N Calcium oxide Chemical compound [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 4
- 239000004971 Cross linker Substances 0.000 description 4
- BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 description 4
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 4
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 description 4
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 4
- 229910021536 Zeolite Inorganic materials 0.000 description 4
- GDVKFRBCXAPAQJ-UHFFFAOYSA-A dialuminum;hexamagnesium;carbonate;hexadecahydroxide Chemical compound [OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Al+3].[Al+3].[O-]C([O-])=O GDVKFRBCXAPAQJ-UHFFFAOYSA-A 0.000 description 4
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 4
- AUZONCFQVSMFAP-UHFFFAOYSA-N disulfiram Chemical compound CCN(CC)C(=S)SSC(=S)N(CC)CC AUZONCFQVSMFAP-UHFFFAOYSA-N 0.000 description 4
- 229910001701 hydrotalcite Inorganic materials 0.000 description 4
- 229960001545 hydrotalcite Drugs 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 150000002736 metal compounds Chemical class 0.000 description 4
- 229920000058 polyacrylate Polymers 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 150000007942 carboxylates Chemical class 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 238000013329 compounding Methods 0.000 description 3
- 238000007334 copolymerization reaction Methods 0.000 description 3
- 239000013078 crystal Substances 0.000 description 3
- 239000000945 filler Substances 0.000 description 3
- 229910044991 metal oxide Inorganic materials 0.000 description 3
- 150000004706 metal oxides Chemical class 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 150000004760 silicates Chemical class 0.000 description 3
- WZRRRFSJFQTGGB-UHFFFAOYSA-N 1,3,5-triazinane-2,4,6-trithione Chemical compound S=C1NC(=S)NC(=S)N1 WZRRRFSJFQTGGB-UHFFFAOYSA-N 0.000 description 2
- YFGKDYFYYPZZLE-UHFFFAOYSA-N 2-anilino-6-sulfanyl-1,3-dihydrotriazine-4-thione Chemical compound N1C(S)=CC(=S)NN1NC1=CC=CC=C1 YFGKDYFYYPZZLE-UHFFFAOYSA-N 0.000 description 2
- CPGFMWPQXUXQRX-UHFFFAOYSA-N 3-amino-3-(4-fluorophenyl)propanoic acid Chemical compound OC(=O)CC(N)C1=CC=C(F)C=C1 CPGFMWPQXUXQRX-UHFFFAOYSA-N 0.000 description 2
- HLBZWYXLQJQBKU-UHFFFAOYSA-N 4-(morpholin-4-yldisulfanyl)morpholine Chemical compound C1COCCN1SSN1CCOCC1 HLBZWYXLQJQBKU-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 2
- 239000000920 calcium hydroxide Substances 0.000 description 2
- 235000011116 calcium hydroxide Nutrition 0.000 description 2
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 2
- 239000000292 calcium oxide Substances 0.000 description 2
- 235000012255 calcium oxide Nutrition 0.000 description 2
- 239000000378 calcium silicate Substances 0.000 description 2
- 229910052918 calcium silicate Inorganic materials 0.000 description 2
- 235000012241 calcium silicate Nutrition 0.000 description 2
- OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 description 2
- 239000006229 carbon black Substances 0.000 description 2
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 2
- PGAXJQVAHDTGBB-UHFFFAOYSA-N dibutylcarbamothioylsulfanyl n,n-dibutylcarbamodithioate Chemical compound CCCCN(CCCC)C(=S)SSC(=S)N(CCCC)CCCC PGAXJQVAHDTGBB-UHFFFAOYSA-N 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 150000004679 hydroxides Chemical class 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 2
- 239000000347 magnesium hydroxide Substances 0.000 description 2
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 2
- 235000012254 magnesium hydroxide Nutrition 0.000 description 2
- 239000000395 magnesium oxide Substances 0.000 description 2
- 235000012245 magnesium oxide Nutrition 0.000 description 2
- OFHMODDLBXETIK-UHFFFAOYSA-N methyl 2,3-dichloropropanoate Chemical compound COC(=O)C(Cl)CCl OFHMODDLBXETIK-UHFFFAOYSA-N 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 150000002978 peroxides Chemical class 0.000 description 2
- 239000005011 phenolic resin Substances 0.000 description 2
- AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 239000004014 plasticizer Substances 0.000 description 2
- 229960001860 salicylate Drugs 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 229910000029 sodium carbonate Inorganic materials 0.000 description 2
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 2
- 239000011787 zinc oxide Substances 0.000 description 2
- 235000014692 zinc oxide Nutrition 0.000 description 2
- LFMQNMXVVXHZCC-UHFFFAOYSA-N 1,3-benzothiazol-2-yl n,n-diethylcarbamodithioate Chemical compound C1=CC=C2SC(SC(=S)N(CC)CC)=NC2=C1 LFMQNMXVVXHZCC-UHFFFAOYSA-N 0.000 description 1
- YFBUDXNMBTUSOC-UHFFFAOYSA-N 1,4-dihydroquinoxaline-2,3-dithione Chemical compound C1=CC=C2NC(=S)C(=S)NC2=C1 YFBUDXNMBTUSOC-UHFFFAOYSA-N 0.000 description 1
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- QOMSTRJEWDASHF-UHFFFAOYSA-N 2-(cyclohexylamino)-6-sulfanyl-1,3-dihydrotriazine-4-thione Chemical compound N1C(S)=CC(=S)NN1NC1CCCCC1 QOMSTRJEWDASHF-UHFFFAOYSA-N 0.000 description 1
- HXCOSFGSSXUTEZ-UHFFFAOYSA-N 2-(dibutylamino)-6-sulfanyl-1,3-dihydrotriazine-4-thione Chemical compound CCCCN(CCCC)N1NC(S)=CC(=S)N1 HXCOSFGSSXUTEZ-UHFFFAOYSA-N 0.000 description 1
- WZOCKHCXCJYKTM-UHFFFAOYSA-N 2-(diethylamino)-6-sulfanyl-1,3-dihydrotriazine-4-thione Chemical compound CCN(CC)N1NC(S)=CC(=S)N1 WZOCKHCXCJYKTM-UHFFFAOYSA-N 0.000 description 1
- CDJBUGDCQMHTSX-UHFFFAOYSA-N 2-(hexylamino)-6-sulfanyl-1,3-dihydrotriazine-4-thione Chemical compound CCCCCCNN1NC(S)=CC(=S)N1 CDJBUGDCQMHTSX-UHFFFAOYSA-N 0.000 description 1
- MHKLKWCYGIBEQF-UHFFFAOYSA-N 4-(1,3-benzothiazol-2-ylsulfanyl)morpholine Chemical compound C1COCCN1SC1=NC2=CC=CC=C2S1 MHKLKWCYGIBEQF-UHFFFAOYSA-N 0.000 description 1
- 239000004135 Bone phosphate Substances 0.000 description 1
- BWGNESOTFCXPMA-UHFFFAOYSA-N Dihydrogen disulfide Chemical compound SS BWGNESOTFCXPMA-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 229910000003 Lead carbonate Inorganic materials 0.000 description 1
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
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- REDUMNSTOASOGZ-UHFFFAOYSA-N [Sn].P(O)(O)O Chemical compound [Sn].P(O)(O)O REDUMNSTOASOGZ-UHFFFAOYSA-N 0.000 description 1
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- 150000001252 acrylic acid derivatives Chemical class 0.000 description 1
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- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 230000003712 anti-aging effect Effects 0.000 description 1
- RQPZNWPYLFFXCP-UHFFFAOYSA-L barium dihydroxide Chemical compound [OH-].[OH-].[Ba+2] RQPZNWPYLFFXCP-UHFFFAOYSA-L 0.000 description 1
- 229910001863 barium hydroxide Inorganic materials 0.000 description 1
- AYJRCSIUFZENHW-DEQYMQKBSA-L barium(2+);oxomethanediolate Chemical compound [Ba+2].[O-][14C]([O-])=O AYJRCSIUFZENHW-DEQYMQKBSA-L 0.000 description 1
- 125000005605 benzo group Chemical group 0.000 description 1
- 150000001642 boronic acid derivatives Chemical class 0.000 description 1
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 235000010216 calcium carbonate Nutrition 0.000 description 1
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 1
- 239000008116 calcium stearate Substances 0.000 description 1
- 235000013539 calcium stearate Nutrition 0.000 description 1
- PYSZASIZWHHPHJ-UHFFFAOYSA-L calcium;phthalate Chemical compound [Ca+2].[O-]C(=O)C1=CC=CC=C1C([O-])=O PYSZASIZWHHPHJ-UHFFFAOYSA-L 0.000 description 1
- CSNJTIWCTNEOSW-UHFFFAOYSA-N carbamothioylsulfanyl carbamodithioate Chemical compound NC(=S)SSC(N)=S CSNJTIWCTNEOSW-UHFFFAOYSA-N 0.000 description 1
- 238000000748 compression moulding Methods 0.000 description 1
- 150000003946 cyclohexylamines Chemical class 0.000 description 1
- UEZWYKZHXASYJN-UHFFFAOYSA-N cyclohexylthiophthalimide Chemical compound O=C1C2=CC=CC=C2C(=O)N1SC1CCCCC1 UEZWYKZHXASYJN-UHFFFAOYSA-N 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical compound C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 description 1
- 150000002118 epoxides Chemical class 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- 125000001033 ether group Chemical group 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
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- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 231100001261 hazardous Toxicity 0.000 description 1
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- OCWMFVJKFWXKNZ-UHFFFAOYSA-L lead(2+);oxygen(2-);sulfate Chemical compound [O-2].[O-2].[O-2].[Pb+2].[Pb+2].[Pb+2].[Pb+2].[O-]S([O-])(=O)=O OCWMFVJKFWXKNZ-UHFFFAOYSA-L 0.000 description 1
- YJOMWQQKPKLUBO-UHFFFAOYSA-L lead(2+);phthalate Chemical compound [Pb+2].[O-]C(=O)C1=CC=CC=C1C([O-])=O YJOMWQQKPKLUBO-UHFFFAOYSA-L 0.000 description 1
- UMKARVFXJJITLN-UHFFFAOYSA-N lead;phosphorous acid Chemical compound [Pb].OP(O)O UMKARVFXJJITLN-UHFFFAOYSA-N 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
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- 229910000021 magnesium carbonate Inorganic materials 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000002808 molecular sieve Substances 0.000 description 1
- 125000000896 monocarboxylic acid group Chemical group 0.000 description 1
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- 238000000465 moulding Methods 0.000 description 1
- IUJLOAKJZQBENM-UHFFFAOYSA-N n-(1,3-benzothiazol-2-ylsulfanyl)-2-methylpropan-2-amine Chemical compound C1=CC=C2SC(SNC(C)(C)C)=NC2=C1 IUJLOAKJZQBENM-UHFFFAOYSA-N 0.000 description 1
- DEQZTKGFXNUBJL-UHFFFAOYSA-N n-(1,3-benzothiazol-2-ylsulfanyl)cyclohexanamine Chemical compound C1CCCCC1NSC1=NC2=CC=CC=C2S1 DEQZTKGFXNUBJL-UHFFFAOYSA-N 0.000 description 1
- 150000002823 nitrates Chemical class 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- JFOJYGMDZRCSPA-UHFFFAOYSA-J octadecanoate;tin(4+) Chemical compound [Sn+4].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O JFOJYGMDZRCSPA-UHFFFAOYSA-J 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
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- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 238000010094 polymer processing Methods 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 239000012744 reinforcing agent Substances 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- 229910052665 sodalite Inorganic materials 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
- 235000017550 sodium carbonate Nutrition 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical class [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 1
- 150000003463 sulfur Chemical class 0.000 description 1
- 229940052367 sulfur,colloidal Drugs 0.000 description 1
- 125000003698 tetramethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 150000003557 thiazoles Chemical class 0.000 description 1
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 1
- 229910001887 tin oxide Inorganic materials 0.000 description 1
- XWKBMOUUGHARTI-UHFFFAOYSA-N tricalcium;diphosphite Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])[O-].[O-]P([O-])[O-] XWKBMOUUGHARTI-UHFFFAOYSA-N 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 150000003752 zinc compounds Chemical class 0.000 description 1
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1
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- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- G03G15/00—Apparatus for electrographic processes using a charge pattern
- G03G15/02—Apparatus for electrographic processes using a charge pattern for laying down a uniform charge, e.g. for sensitising; Corona discharge devices
- G03G15/0208—Apparatus for electrographic processes using a charge pattern for laying down a uniform charge, e.g. for sensitising; Corona discharge devices by contact, friction or induction, e.g. liquid charging apparatus
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- C08G65/32—Polymers modified by chemical after-treatment
- C08G65/329—Polymers modified by chemical after-treatment with organic compounds
- C08G65/331—Polymers modified by chemical after-treatment with organic compounds containing oxygen
- C08G65/332—Polymers modified by chemical after-treatment with organic compounds containing oxygen containing carboxyl groups, or halides, or esters thereof
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Description
本発明の半導電性ゴム組成物は、加硫前の組成物を指し、少なくとも(a)エピクロルヒドリン系ゴム、(b)エチレンオキサイド変性(メタ)アクリレート、(c)硫黄系架橋剤、キノキサリン系架橋剤、およびトリアジン系架橋剤からなる群より選択される少なくとも1種の架橋剤を含有する。
本発明における(a)エピクロルヒドリン系ゴムとは、エピクロルヒドリン単独重合体またはエピクロルヒドリンと共重合可能な他のエポキシド、例えばエチレンオキサイド、プロピレンオキサイド、アリルグリシジルエーテル等との共重合体をいう。これらを例示すれば、エピクロルヒドリン単独重合体、エピクロルヒドリン−エチレンオキサイド共重合体、エピクロルヒドリン−プロピレンオキサイド共重合体、エピクロルヒドリン−エチレンオキサイド−アリルグリシジルエーテル三元共重合体、エピクロルヒドリン−エチレンオキサイド−プロピレンオキサイド−アリルグリシジルエーテル四元共重合体等を挙げることができる。これら単独重合体または共重合体の分子量は特に制限されないが、通常ムーニー粘度表示でML1+4(100℃)=30〜150程度である。
本発明で使用される(b)エチレンオキサイド変性(メタ)アクリレートは一般式(I)で示される。
式中において、低抵抗化、環境依存性、経時変化における抵抗の安定性、ポリマーとの相溶性の点において、nは1〜20であることが好ましく、6〜16であることがより好ましく、7〜11であることが特に好ましい。
R1〜R4は、水素原子、または炭素数1〜5のアルキル基であることが好ましく、水素原子、メチル基、またはエチル基であることが特に好ましい。
式中において、低抵抗化、環境依存性、経時変化における抵抗の安定性、ポリマーとの相溶性の点において、nは6〜16であることが好ましく、7〜11であることがより好ましい。
本発明で用いられる架橋剤としては、(c)硫黄系架橋剤、キノキサリン系架橋剤、およびトリアジン系架橋剤からなる群より選択される。
また、本発明においては、通常これらの架橋剤と共に使用される公知の加硫促進剤を用いることができる。
本発明で用いられる受酸剤としては、公知の受酸剤を使用できるが、好ましくは金属化合物および/または無機マイクロポーラス・クリスタルである。金属化合物としては、周期表第II族(2族および12族)金属の酸化物、水酸化物、炭酸塩、カルボン酸塩、ケイ酸塩、ホウ酸塩、亜リン酸塩、周期表III族(3族および13族)金属の酸化物、水酸化物、カルボン酸塩、ケイ酸塩、硫酸塩、硝酸塩、リン酸塩、周期表第IV族(4族および14族)金属の酸化物、塩基性炭酸塩、塩基性カルボン酸塩、塩基性亜リン酸塩、塩基性亜硫酸塩、三塩基性硫酸塩等の金属化合物が挙げられる。
MgXZnYAlZ(OH)(2(X+Y)+3Z−2)CO3・wH2O (3)
[式中、xとyはそれぞれx+y=1〜10の関係を有する0〜10の実数、zは1〜5の実数、wは0〜10の実数をそれぞれ示す。]
本発明によるゴム架橋体を製造するには、従来ポリマー加工の分野において用いられている任意の混合手段、例えばミキシングロール、バンバリーミキサー、各種ニーダー類等を用いることができる。本発明の半導電性電子部品は、本発明の組成物を通常100〜200℃に加熱することで得られる。加硫時間は温度により異なるが、通常0.5〜300分の間である。加硫成型の方法としては特に限定されるものではないが、例えば金型による圧縮成型、射出成型、スチーム缶やエアーオーブン等による加熱の方法などが好適に用いられる。
*1 エピクロルヒドリン系ゴム:エピクロルヒドリン−エチレンオキシド−アリルグリシジルエーテル共重合体 ダイソー社製 「エピオン301」
*2 エチレンオキサイド変性(メタ)アクリレートA:メトキシポリエチレングリコール#400メタクリレート(平均エチレンオキサイドユニット数9(n=9))、
*3 エチレンオキサイド変性(メタ)アクリレートB:メトキシポリエチレングリコール#1000メタクリレート(平均エチレンオキサイドユニット数23(n=23))
*4 OH基含有アクリルポリマーA:東亜合成株式会社製「ARUFON UH−2000」
*5 OH基含有アクリルポリマーB:東亜合成株式会社製「ARUFON UH−2170」
*6 COOH基含有アクリルポリマー:東亜合成株式会社製「ARUFON UC−3000」
*7 チウラム系加硫促進剤:大内新興化学工業社製 「ノクセラーTS」
*8 チアゾール系加硫促進剤:大内新興化学工業社製 「ノクセラーDM」
*9 液状NBR:JSR株式会社製JSR N280
*10 可塑剤:ダイソー社製「DB−02」
*11 チウラム系加硫促進剤:大内新興化学工業社製 「ノクセラーTT」
*12 モルホリンスルフィド系加硫促進剤:大内新興化学工業社製 「バルノックR」
*13 ハイドロタルサイト:合成ハイドロタルサイト 協和化学工業社製 「DHT−4A」
*14 DBU塩系加硫促進剤:DBUのフェノール樹脂塩 ダイソー社製 「P−152」
*15 キノキサリン系架橋剤:6−メチルキノキサリン−2,3−ジチオカーボネート
ダイソー社製 「ダイソネットXL−21S」
下記表2、6、7に示す各材料をニーダーミキサーおよびオープンロールで混練し、未加硫ゴムシートを作製した。得られた未加硫ゴムシートを用い、170℃で15分プレス加硫した。得られた架橋シートを23℃/50%RH環境下にて状態調整を行った後、JIS K6271に準拠し、二重リング電極を用いた三菱油化株式会社製ハイレスタを用いて体積固有抵抗値を測定した。
下記表3、8,9に示す各材料をニーダーミキサーおよびオープンロールで混練し、未加硫ゴムシートを作製した。得られた未加硫ゴムシートを用い、170℃で15分プレス加硫した。得られた架橋シートを10℃/15%RH、23℃/50%RH、35℃/85%RH環境下にて状態調整を行った後、JIS K6271に準拠し、二重リング電極を用いた三菱油化株式会社製ハイレスタを用いて体積固有抵抗値を測定し、架橋物の環境依存性を評価した。
ゴム硬度についてはJIS K6253に準拠し、高分子計器株式会社製ASKER タイプAデュロメーターを用いて測定した。
Claims (7)
- 前記一般式(II)で示されるメトキシポリエチレングリコールメタクリレートが、エチレンオキサイドユニットを6〜16個有する(前記一般式(II)のnが6〜16である構造を有する)ことを特徴とする請求項2に記載の半導電性加硫ゴム用組成物。
- 前記(a)エピクロルヒドリン系ゴムが、エピクロルヒドリンの単独重合体、エピクロルヒドリン−エチレンオキサイド二元共重合体、エピクロルヒドリン−エチレンオキサイド−アリルグリシジルエーテル三元共重合体から選択される少なくとも一種である請求項1〜3いずれかに記載の半導電性加硫ゴム用組成物。
- 前記(a)エピクロルヒドリン系ゴムが、エピクロルヒドリン−エチレンオキサイド−アリルグリシジルエーテルの三元共重合体、あるいはエピクロルヒドリン−エチレンオキサイド−アリルグリシジルエーテルの三元共重合体とエピクロルヒドリン単独重合体とブレンドされた物、エピクロルヒドリン−エチレンオキサイド−アリルグリシジルエーテルの三元共重合体とエピクロルヒドリン−エチレンオキサイド二元共重合体とブレンドされた物であることを特徴とする請求項1〜3いずれかに記載の半導電性加硫ゴム用組成物。
- 請求項1〜5いずれかに記載の半導電性組成物を架橋して得られるゴム架橋体。
- 請求項6に記載のゴム架橋体を用いた半導電性部品。
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Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS62112653A (ja) * | 1985-11-11 | 1987-05-23 | Osaka Soda Co Ltd | 導電性ゴム組成物 |
JPH0359045A (ja) * | 1989-07-28 | 1991-03-14 | Dainippon Ink & Chem Inc | ゴム用縮合系可塑剤及びゴム組成物 |
JPH07292235A (ja) * | 1994-04-20 | 1995-11-07 | Sanyo Chem Ind Ltd | 耐寒性可塑剤 |
JPH1095891A (ja) * | 1996-09-26 | 1998-04-14 | Tokai Rubber Ind Ltd | フッ素含有熱可塑性架橋物およびその製法 |
JP2002155171A (ja) * | 2000-09-07 | 2002-05-28 | Kao Corp | ゴム組成物 |
Family Cites Families (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2996538A (en) * | 1957-11-25 | 1961-08-15 | Dow Chemical Co | Preparation of monomeric polyglycol acrylate and methacrylate esters |
US3475519A (en) * | 1966-12-20 | 1969-10-28 | Formica Corp | Transparent blends of polyalkyl methacrylates with rubbery epichlorohydrin polymers |
JPH0643541B2 (ja) * | 1985-05-14 | 1994-06-08 | 内山工業株式会社 | ブレンドゴム組成物 |
CA2083099A1 (en) * | 1991-11-21 | 1993-05-22 | Keisaku Yamamoto | Rubber compositions and vulcanized rubber compositions |
JP3301378B2 (ja) | 1998-03-24 | 2002-07-15 | ダイソー株式会社 | ポリエーテル共重合体および架橋高分子固体電解質 |
JP4337151B2 (ja) | 1998-08-21 | 2009-09-30 | ダイソー株式会社 | 導電性ゴムロールおよび加硫可能な導電性ゴムロール用材料 |
JP3578705B2 (ja) * | 2000-08-10 | 2004-10-20 | 株式会社荒井製作所 | 半導電性ローラ用ゴム組成物およびそれを用いた半導電性ローラ |
JP2002341525A (ja) * | 2001-05-14 | 2002-11-27 | Fuji Photo Film Co Ltd | ポジ型フォトレジスト転写材料およびそれを用いた基板表面の加工方法 |
JP2005148467A (ja) | 2003-11-17 | 2005-06-09 | Bridgestone Corp | 導電性ローラおよびそれを用いた画像形成装置 |
US20070041752A1 (en) * | 2005-08-08 | 2007-02-22 | Yoshihisa Mizumoto | Semiconductive roller |
US7872075B2 (en) * | 2005-10-07 | 2011-01-18 | Exxonmobil Chemical Patents Inc. | Peroxide-cured thermoplastic vulcanizates and process for making the same |
JP5196929B2 (ja) * | 2007-09-18 | 2013-05-15 | 東海ゴム工業株式会社 | 電子写真機器用導電性組成物、電子写真機器用導電性架橋体および電子写真機器用導電性部材 |
JP2009069783A (ja) * | 2007-09-18 | 2009-04-02 | Tokai Rubber Ind Ltd | 電子写真機器用導電性組成物、電子写真機器用導電性架橋体および電子写真機器用導電性部材 |
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2010
- 2010-10-14 EP EP10823443.6A patent/EP2489700A4/en not_active Withdrawn
- 2010-10-14 WO PCT/JP2010/068060 patent/WO2011046175A1/ja active Application Filing
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Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS62112653A (ja) * | 1985-11-11 | 1987-05-23 | Osaka Soda Co Ltd | 導電性ゴム組成物 |
JPH0359045A (ja) * | 1989-07-28 | 1991-03-14 | Dainippon Ink & Chem Inc | ゴム用縮合系可塑剤及びゴム組成物 |
JPH07292235A (ja) * | 1994-04-20 | 1995-11-07 | Sanyo Chem Ind Ltd | 耐寒性可塑剤 |
JPH1095891A (ja) * | 1996-09-26 | 1998-04-14 | Tokai Rubber Ind Ltd | フッ素含有熱可塑性架橋物およびその製法 |
JP2002155171A (ja) * | 2000-09-07 | 2002-05-28 | Kao Corp | ゴム組成物 |
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US8735503B2 (en) | 2014-05-27 |
KR101755057B1 (ko) | 2017-07-06 |
EP2489700A4 (en) | 2014-07-02 |
KR20120085799A (ko) | 2012-08-01 |
US20120208966A1 (en) | 2012-08-16 |
JPWO2011046175A1 (ja) | 2013-03-07 |
CN102597113A (zh) | 2012-07-18 |
EP2489700A1 (en) | 2012-08-22 |
WO2011046175A1 (ja) | 2011-04-21 |
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