JP5481483B2 - カルベン誘導体を用いたポリ乳酸の製造方法 - Google Patents

カルベン誘導体を用いたポリ乳酸の製造方法 Download PDF

Info

Publication number
JP5481483B2
JP5481483B2 JP2011524173A JP2011524173A JP5481483B2 JP 5481483 B2 JP5481483 B2 JP 5481483B2 JP 2011524173 A JP2011524173 A JP 2011524173A JP 2011524173 A JP2011524173 A JP 2011524173A JP 5481483 B2 JP5481483 B2 JP 5481483B2
Authority
JP
Japan
Prior art keywords
group
carbon dioxide
polylactic acid
carbon atoms
carbene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
JP2011524173A
Other languages
English (en)
Japanese (ja)
Other versions
JP2012501360A (ja
JP2012501360A5 (enExample
Inventor
李振江
▲敢▼▲蘇▼力
王燕芹
郭▲暢▼
宋▲平▼
盛石川
欧▲陽▼平▲凱▼
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nanjing Tech University
Original Assignee
Nanjing Tech University
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nanjing Tech University filed Critical Nanjing Tech University
Publication of JP2012501360A publication Critical patent/JP2012501360A/ja
Publication of JP2012501360A5 publication Critical patent/JP2012501360A5/ja
Application granted granted Critical
Publication of JP5481483B2 publication Critical patent/JP5481483B2/ja
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/06—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from hydroxycarboxylic acids
    • C08G63/08—Lactones or lactides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78—Preparation processes
    • C08G63/81—Preparation processes using solvents
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78—Preparation processes
    • C08G63/82—Preparation processes characterised by the catalyst used
    • C08G63/823—Preparation processes characterised by the catalyst used for the preparation of polylactones or polylactides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/04—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing carboxylic acids or their salts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polyesters Or Polycarbonates (AREA)
  • Biological Depolymerization Polymers (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
JP2011524173A 2008-09-01 2009-09-02 カルベン誘導体を用いたポリ乳酸の製造方法 Expired - Fee Related JP5481483B2 (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
CN200810146617.9 2008-09-01
CN2008101466179A CN101665565B (zh) 2008-09-01 2008-09-01 一种用卡宾衍生物催化制备聚乳酸的方法
PCT/CN2009/073677 WO2010022685A1 (zh) 2008-09-01 2009-09-02 用卡宾衍生物催化制备聚乳酸的方法

Publications (3)

Publication Number Publication Date
JP2012501360A JP2012501360A (ja) 2012-01-19
JP2012501360A5 JP2012501360A5 (enExample) 2014-02-13
JP5481483B2 true JP5481483B2 (ja) 2014-04-23

Family

ID=41720855

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2011524173A Expired - Fee Related JP5481483B2 (ja) 2008-09-01 2009-09-02 カルベン誘導体を用いたポリ乳酸の製造方法

Country Status (5)

Country Link
US (1) US9029497B2 (enExample)
EP (1) EP2392606B1 (enExample)
JP (1) JP5481483B2 (enExample)
CN (1) CN101665565B (enExample)
WO (1) WO2010022685A1 (enExample)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20140029373A (ko) * 2010-12-10 2014-03-10 클라리언트 파이넌스 (비브이아이)리미티드 락톤 개환 중합에 사용하기 위한 ｎ-헤테로사이클릭 카르벤 기반 지르코늄 착물
CN102167802A (zh) * 2011-01-13 2011-08-31 南京工业大学 一种用N-杂环卡宾催化制备聚α-羟基酸的方法
EP2644636A1 (de) * 2012-03-26 2013-10-02 Basf Se Verfahren zur herstellung von polyetherpolyolen
CN103160380A (zh) * 2013-03-28 2013-06-19 南京工业大学 一种1,2,3-三唑卡宾二氧化碳加合物催化制备生物柴油的方法
CN104892916B (zh) * 2015-06-11 2017-01-11 南京大学 有机胍—无毒醇催化丙交酯活性开环聚合受控合成聚乳酸的工艺
CN105273175B (zh) * 2015-10-21 2017-06-13 南京工业大学 有机小分子催化剂调控的聚丙交酯制备方法
CN105327713B (zh) * 2015-11-16 2017-06-16 湖北大学 一种金刚烷支撑NHC‑Pd催化剂及其制备方法和用途
CN105218793A (zh) * 2015-11-17 2016-01-06 南京工业大学 一种用卡宾衍生物催化制备聚酯多元醇的方法
US10570252B2 (en) 2017-03-08 2020-02-25 International Business Machines Corporation Flame retardant lactide monomors for polylactide synthesis
US10072121B1 (en) 2017-03-08 2018-09-11 International Business Machines Corporation Bottlebrush polymers derived from poly(methylidenelactide)
US10202489B2 (en) 2017-03-08 2019-02-12 International Business Machines Corporation Lactide copolymers and ring-opened lactide copolymers
US10035877B1 (en) 2017-03-08 2018-07-31 International Business Machines Corporation Matrix-bondable lactide monomors for polylactide synthesis
CN106947067B (zh) * 2017-04-28 2022-01-04 南京工业大学 一种聚酯的制备方法
JP7090487B2 (ja) * 2018-06-25 2022-06-24 株式会社クラレ ポリエステル重合用触媒、並びにポリエステル樹脂及びその製造方法
CN111548480B (zh) * 2019-12-08 2022-04-22 南京工业大学 一种含呋喃环的聚合物的合成方法

Family Cites Families (29)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3736646A (en) 1971-10-18 1973-06-05 American Cyanamid Co Method of attaching surgical needles to multifilament polyglycolic acid absorbable sutures
US4057537A (en) 1975-01-28 1977-11-08 Gulf Oil Corporation Copolymers of L-(-)-lactide and epsilon caprolactone
US4045418A (en) 1975-01-28 1977-08-30 Gulf Oil Corporation Copolymers of D,L-lactide and epsilon caprolactone
US5235031A (en) 1992-03-13 1993-08-10 E. I. Du Pont De Nemours And Company Polymerization of lactide
US5357034A (en) 1992-09-08 1994-10-18 Camelot Technologies Inc. Lactide polymerization
JP2621813B2 (ja) * 1994-01-21 1997-06-18 株式会社島津製作所 ポリ乳酸の製造法
EP0664309B1 (en) * 1994-01-21 1999-06-02 Shimadzu Corporation Method for producing polylactic acid
US5574129A (en) * 1994-05-10 1996-11-12 The Japan Steel Works, Ltd. Process for producing lactic acid polymers and a process for the direct production of shaped articles from lactic acid polymers
JP2847617B2 (ja) 1994-05-10 1999-01-20 株式会社日本製鋼所 高分子量ポリ乳酸及びその成形体の製造方法
JP2850101B2 (ja) 1994-09-09 1999-01-27 株式会社日本製鋼所 ポリ乳酸の製造方法
US5696219A (en) * 1997-01-21 1997-12-09 Dow Corning Corporation Silyl ester initiators for cyclosiloxane ring opening polymerization
DE10020898B4 (de) * 2000-04-20 2004-02-05 Inventa-Fischer Gmbh Verfahren zur Herstellung von Polymilchsäure und Vorrichtung hierzu
WO2002060891A1 (fr) * 2001-01-31 2002-08-08 Toyota Jidosha Kabushiki Kaisha Procédé de production de lactide et procédé de production d'acide polylactique à partir d'acide lactique fermenté
JP4048764B2 (ja) 2001-01-31 2008-02-20 トヨタ自動車株式会社 発酵乳酸を原料とするラクチドの製造方法及びポリ乳酸の製造方法
CN1164639C (zh) 2001-06-29 2004-09-01 武汉大学 一种制备聚乳酸的方法
CN1212343C (zh) 2003-11-27 2005-07-27 中国科学院长春应用化学研究所 环酯开环聚合催化剂及制备方法
FR2864543B1 (fr) * 2003-12-30 2006-03-03 Rhodia Chimie Sa Procede de preparation de polyorganosiloxanes (pos) par polymerisation par ouverture de cycle(s) et/ou redistribution de pos, en presence de carbene(s) et compositions de pos mises en oeuvre dans ce procede
WO2006053071A2 (en) * 2004-11-09 2006-05-18 E.I. Dupont De Nemours And Company Ring opening polymerization of cyclic amides using n-heterocyclic carbene catalysts
US7622543B2 (en) * 2004-11-09 2009-11-24 E.I. Du Pont De Nemours And Company Polymerization of macrocyclic polyester oligomers using N-heterocyclic carbene catalysts
JP4368289B2 (ja) * 2004-11-15 2009-11-18 独立行政法人科学技術振興機構 α−アルキリデン−１，３−ジオキソラン−２−オン類の製造方法
CN1277859C (zh) * 2005-04-15 2006-10-04 浙江大学 一种脂肪族聚酯的制备方法
CN1706878A (zh) * 2005-04-15 2005-12-14 浙江大学 无金属n－杂环卡宾催化剂及其制备方法
CN100393771C (zh) 2006-03-03 2008-06-11 中国科学院长春应用化学研究所 用于丙交酯开环聚合的席夫碱铝催化剂及制备方法和用法
CN100406491C (zh) 2006-03-03 2008-07-30 中国科学院长春应用化学研究所 一种烯醇式丙交酯开环聚合催化剂及制备方法和其用法
DE102006038934A1 (de) * 2006-08-18 2008-02-21 Evonik Degussa Gmbh Herstellung von α-Hydroxyketonen über Carbenkatalysierte Umpolungsreaktion von Aldehyden
FR2910004A1 (fr) * 2006-12-14 2008-06-20 Rhodia Recherches & Tech Procede d'oligomerisation et/ou polymerisation du composes insatures
CN101230076A (zh) * 2007-09-30 2008-07-30 赢创德固赛有限责任公司 含有n杂环卡宾配体的钌的同核双金属和异核双金属亚烷基配合物及其用途
CN101205242A (zh) * 2007-09-30 2008-06-25 埃沃尼克德古萨有限责任公司 含有n-杂环卡宾配体的钌的亚烷基络合物及其在烯烃复分解反应中作为高活性高选择性催化剂的用途
CN101665567B (zh) * 2008-09-01 2011-11-23 南京工业大学 卡宾衍生物催化的环状化合物可调控开环聚合方法

Also Published As

Publication number Publication date
US20110152493A1 (en) 2011-06-23
JP2012501360A (ja) 2012-01-19
EP2392606B1 (en) 2018-03-28
EP2392606A4 (en) 2013-07-31
US9029497B2 (en) 2015-05-12
EP2392606A1 (en) 2011-12-07
CN101665565A (zh) 2010-03-10
WO2010022685A1 (zh) 2010-03-04
CN101665565B (zh) 2012-01-04

Similar Documents

Publication Publication Date Title
JP5481483B2 (ja) カルベン誘導体を用いたポリ乳酸の製造方法
JP5385390B2 (ja) カルベン誘導体によって触媒される環状化合物の制御可能な開環重合の方法
Amgoune et al. Controlled ring-opening polymerization of lactide by group 3 metal complexes
CN113563370B (zh) 一种壳聚糖负载铜材料催化制备α位有取代基的β-硼基酮的制备方法
Ren et al. Stereoregular polycarbonate synthesis: alternating copolymerization of CO2 with aliphatic terminal epoxides catalyzed by multichiral cobalt (III) complexes
JP2012501360A5 (enExample)
CN107022069A (zh) 一种利用仿生催化剂催化γ‑戊内酯开环聚合的方法
CN112679718B (zh) 一种用于制备聚碳酸环己烯酯的催化剂
CN110003452B (zh) 一种催化剂组合物及聚丙交酯的制备方法
CN109705328A (zh) 苯酚-噁唑啉稀土金属催化剂、制备方法及应用
Żukowska et al. Consequences of the electronic tuning of latent ruthenium-based olefin metathesis catalysts on their reactivity
CN104710447A (zh) 一种含有吡咯基团的手性铝配合物及其制备方法和聚乳酸的制备方法
CN1226256C (zh) 生产金刚醇和金刚酮的方法
CN109206604B (zh) 一种催化剂组合物及聚丙交酯的制备方法
CN114904573B (zh) 一种光诱导修饰二芳基二氢吩嗪类有机光催化剂的方法
CN111995633B (zh) 一种三齿稀土金属配合物、制备方法和应用
KR101864005B1 (ko) 고리형 에스테르기를 가진 모노머의 중합 반응의 촉매 및 이를 이용한 폴리머의 제조 방법
CN107827915A (zh) 一种胺双酚四齿配体三价稀土金属配合物及应用
CN110143978B (zh) 一种结构不对称双核金属有机配合物及其制备和应用
CN115710284B (zh) 一种用于乳酸合成丙交酯的催化剂及其制备方法和应用
CN112759616B (zh) 三碟烯卡宾钯化合物及其应用
CN115260217B (zh) 一类桥连双噁唑啉稀土金属催化剂、制备方法及应用
JP7123002B2 (ja) １，６－ヘキサンジオールの製造方法
CN116333288A (zh) 一种氨基喹啉金属铝催化剂的制备方法及其合成可降解高分子材料的应用
JP2021504098A (ja) 二酸化炭素およびオレフィンからの不飽和カルボン酸塩およびその誘導体の生成プロセスのための触媒組成物

Legal Events

Date Code Title Description
A977 Report on retrieval

Free format text: JAPANESE INTERMEDIATE CODE: A971007

Effective date: 20130206

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20130226

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20130308

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20131022

A524 Written submission of copy of amendment under article 19 pct

Free format text: JAPANESE INTERMEDIATE CODE: A524

Effective date: 20131216

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A821

Effective date: 20131216

TRDD Decision of grant or rejection written
A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

Effective date: 20140121

A61 First payment of annual fees (during grant procedure)

Free format text: JAPANESE INTERMEDIATE CODE: A61

Effective date: 20140217

R150 Certificate of patent or registration of utility model

Ref document number: 5481483

Country of ref document: JP

Free format text: JAPANESE INTERMEDIATE CODE: R150

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

LAPS Cancellation because of no payment of annual fees