JP5461396B2 - 修飾されたポリマー組成物、修飾方法およびフリーラジカル発生剤 - Google Patents
修飾されたポリマー組成物、修飾方法およびフリーラジカル発生剤 Download PDFInfo
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- JP5461396B2 JP5461396B2 JP2010515415A JP2010515415A JP5461396B2 JP 5461396 B2 JP5461396 B2 JP 5461396B2 JP 2010515415 A JP2010515415 A JP 2010515415A JP 2010515415 A JP2010515415 A JP 2010515415A JP 5461396 B2 JP5461396 B2 JP 5461396B2
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- RMKZLFMHXZAGTM-UHFFFAOYSA-N [dimethoxy(propyl)silyl]oxymethyl prop-2-enoate Chemical compound CCC[Si](OC)(OC)OCOC(=O)C=C RMKZLFMHXZAGTM-UHFFFAOYSA-N 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
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- 229910052782 aluminium Inorganic materials 0.000 description 1
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- 235000019270 ammonium chloride Nutrition 0.000 description 1
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- 239000012967 coordination catalyst Substances 0.000 description 1
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- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 125000006165 cyclic alkyl group Chemical group 0.000 description 1
- HPXRVTGHNJAIIH-UHFFFAOYSA-N cyclohexanol Chemical compound OC1CCCCC1 HPXRVTGHNJAIIH-UHFFFAOYSA-N 0.000 description 1
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- 230000001419 dependent effect Effects 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- 230000005684 electric field Effects 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- NHOGGUYTANYCGQ-UHFFFAOYSA-N ethenoxybenzene Chemical compound C=COC1=CC=CC=C1 NHOGGUYTANYCGQ-UHFFFAOYSA-N 0.000 description 1
- YCUBDDIKWLELPD-UHFFFAOYSA-N ethenyl 2,2-dimethylpropanoate Chemical compound CC(C)(C)C(=O)OC=C YCUBDDIKWLELPD-UHFFFAOYSA-N 0.000 description 1
- FWDBOZPQNFPOLF-UHFFFAOYSA-N ethenyl(triethoxy)silane Chemical compound CCO[Si](OCC)(OCC)C=C FWDBOZPQNFPOLF-UHFFFAOYSA-N 0.000 description 1
- NKSJNEHGWDZZQF-UHFFFAOYSA-N ethenyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C=C NKSJNEHGWDZZQF-UHFFFAOYSA-N 0.000 description 1
- XSCFNOMFYIWSOB-UHFFFAOYSA-N ethenyl-bis(2-methoxyethoxy)silane Chemical compound COCCO[SiH](C=C)OCCOC XSCFNOMFYIWSOB-UHFFFAOYSA-N 0.000 description 1
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- 125000003187 heptyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
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- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
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- 239000004707 linear low-density polyethylene Substances 0.000 description 1
- 229920005679 linear ultra low density polyethylene Polymers 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 238000000691 measurement method Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- XJRBAMWJDBPFIM-UHFFFAOYSA-N methyl vinyl ether Chemical compound COC=C XJRBAMWJDBPFIM-UHFFFAOYSA-N 0.000 description 1
- 238000006011 modification reaction Methods 0.000 description 1
- 150000002763 monocarboxylic acids Chemical class 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- 230000000269 nucleophilic effect Effects 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000000962 organic group Chemical group 0.000 description 1
- 125000001979 organolithium group Chemical group 0.000 description 1
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- 238000005453 pelletization Methods 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 150000002989 phenols Chemical group 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
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- 229920005631 polypropylene heterophasic copolymer Polymers 0.000 description 1
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- 238000000746 purification Methods 0.000 description 1
- 125000004076 pyridyl group Chemical group 0.000 description 1
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- 150000003384 small molecules Chemical class 0.000 description 1
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- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
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- 125000002948 undecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/14—Peroxides
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C409/00—Peroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C409/00—Peroxy compounds
- C07C409/02—Peroxy compounds the —O—O— group being bound between a carbon atom, not further substituted by oxygen atoms, and hydrogen, i.e. hydroperoxides
- C07C409/04—Peroxy compounds the —O—O— group being bound between a carbon atom, not further substituted by oxygen atoms, and hydrogen, i.e. hydroperoxides the carbon atom being acyclic
- C07C409/06—Compounds containing rings other than six-membered aromatic rings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/0025—Crosslinking or vulcanising agents; including accelerators
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms
- C08L23/083—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms with aliphatic polyenes, i.e. containing two or more carbon-to-carbon double bonds
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Organic Insulating Materials (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Insulated Conductors (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Macromonomer-Based Addition Polymer (AREA)
- Processes Specially Adapted For Manufacturing Cables (AREA)
- Polymerization Catalysts (AREA)
- Graft Or Block Polymers (AREA)
Applications Claiming Priority (3)
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|---|---|---|---|
| EP07112305.3A EP2014707B1 (en) | 2007-07-12 | 2007-07-12 | Modified polymer compositions, modification process and free radical generating agents for i.a. wire and cable applications |
| EP07112305.3 | 2007-07-12 | ||
| PCT/EP2008/005640 WO2009007117A1 (en) | 2007-07-12 | 2008-07-10 | Modified polymer compositions, modification process and free radical generating agents |
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| JP2010533215A JP2010533215A (ja) | 2010-10-21 |
| JP2010533215A5 JP2010533215A5 (enExample) | 2011-08-25 |
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| JP2010515416A Expired - Fee Related JP5439369B2 (ja) | 2007-07-12 | 2008-07-10 | 不飽和ポリマー組成物 |
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| EP (3) | EP2014707B1 (enExample) |
| JP (2) | JP5461396B2 (enExample) |
| KR (2) | KR101436189B1 (enExample) |
| CN (2) | CN101802073A (enExample) |
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| EA (2) | EA021922B1 (enExample) |
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| ES (1) | ES2363299T3 (enExample) |
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| EP2014707B1 (en) † | 2007-07-12 | 2014-04-23 | Borealis Technology Oy | Modified polymer compositions, modification process and free radical generating agents for i.a. wire and cable applications |
| EP2015315B1 (en) | 2007-07-12 | 2012-12-12 | Borealis Technology Oy | Process for preparing and crosslinking a cable comprising a polymer composition and a crosslinked cable |
| ATE552596T1 (de) | 2007-07-12 | 2012-04-15 | Borealis Tech Oy | Verfahren zur herstellung und vernetzung eines kabels mit einer polymerzusammensetzung und ein vernetztes kabel |
| EP2256159A1 (en) * | 2009-05-26 | 2010-12-01 | Borealis AG | Polymer composition for crosslinked pipes |
| EP2256158B1 (en) * | 2009-05-26 | 2014-07-02 | Borealis AG | Polymer composition for crosslinked articles |
| MX346513B (es) | 2009-11-11 | 2017-03-23 | Borealis Ag | Cable y su proceso de produccion. |
| EP2865690A1 (en) * | 2009-11-11 | 2015-04-29 | Borealis AG | A polymer composition comprising a polyolefin produced in a high pressure process, a high pressure process and an article |
| MX356041B (es) * | 2009-11-11 | 2018-05-10 | Borealis Ag | Composicion polimerica y un cable de energia que comprende la composicion polimerica. |
| EA022361B1 (ru) | 2009-11-11 | 2015-12-30 | Бореалис Аг | Сшитая полимерная композиция, кабель с улучшенными электрическими свойствами и способ его получения |
| CN103003351B (zh) * | 2010-06-10 | 2015-09-02 | 北欧化工股份公司 | 一种组合物及其应用 |
| US9150682B2 (en) | 2010-07-22 | 2015-10-06 | Borealis Ag | Modified polymer compositions, modification process and free radical generating agents for i.a. wire and cable applications |
| FR2963352B1 (fr) * | 2010-07-27 | 2014-03-14 | Arkema France | Procede pour preparer un cable et utilisation de peroxydes organiques pour reduire l'etape de degazage dans un procede pour preparer un cable |
| EP3591670A1 (en) | 2010-11-03 | 2020-01-08 | Borealis AG | A polymer composition and a power cable comprising the polymer composition |
| WO2015041885A1 (en) * | 2013-09-20 | 2015-03-26 | Dow Global Technologies Llc | Process for degassing crosslinked power cables |
| EP3034552B2 (en) * | 2014-12-15 | 2024-08-28 | Borealis AG | Synergistic visbreaking composition of peroxide and hydroxylamine ester for increasing the visbreaking efficiency |
| CN107614594B (zh) * | 2015-05-22 | 2021-06-01 | 陶氏环球技术有限责任公司 | 用于制造具有交联绝缘层的电缆的方法以及用此方法制造的电缆 |
| EP4458898A1 (en) | 2017-04-27 | 2024-11-06 | Dow Global Technologies Llc | Polyethylene blend composition |
| KR102325239B1 (ko) * | 2017-06-07 | 2021-11-10 | 엑손모빌 케미칼 패턴츠 인코포레이티드 | 높은 용융 유량 및 높은 굴곡 탄성률을 갖는, 분자량 분포가 넓은 폴리프로필렌 |
| US11708431B2 (en) * | 2017-12-18 | 2023-07-25 | Borealis Ag | Polymer composition comprising a polyethylene |
| WO2019121712A1 (en) * | 2017-12-18 | 2019-06-27 | Borealis Ag | Crosslinkable composition without antioxidant and beneficial methane formation with reduced crosslinking |
| US11555083B2 (en) | 2017-12-18 | 2023-01-17 | Borealis Ag | Cable made from crosslinkable composition without antioxidant and with beneficial methane formation |
| US11505630B2 (en) | 2021-03-15 | 2022-11-22 | Chevron Phillips Chemical Company Lp | Peroxide treated blow molding polymers with increased weight swell and constant die swell |
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| US2528523A (en) † | 1948-06-12 | 1950-11-07 | Du Pont | Process for extruding and insolubilizing polymers of ethylene |
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| FR1509307A (fr) † | 1966-01-17 | 1968-01-12 | Gen Electric | Perfectionnements aux compositions à base de polyéthylènes |
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| US3666737A (en) * | 1970-08-06 | 1972-05-30 | Goodyear Tire & Rubber | Method and process of preparing improved polyethers |
| US3738866A (en) † | 1970-08-19 | 1973-06-12 | Gen Electric | Flame resistant polyolefin composition and article formed thereof |
| DE2338709C2 (de) * | 1973-07-31 | 1975-05-22 | Basf Ag, 6700 Ludwigshafen | Farblose Oligomere des Disopropylbenzols, Verfahren zu ihrer Herstellung und ihre Verwendung |
| DE2420784C3 (de) * | 1974-04-29 | 1979-02-15 | Siemens Ag, 1000 Berlin Und 8000 Muenchen | Verfahren zur Herstellung von durch energiereiche Strahlen vernetzten Formkörpern aus Polyolefinen |
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| PL1695996T3 (pl) * | 2005-02-28 | 2009-01-30 | Borealis Tech Oy | Kompozycje polimerowe z opóźnionym powstawaniem skaz |
| US20080115872A1 (en) * | 2006-11-16 | 2008-05-22 | Paul Harry Sandstrom | Butyl rubber which contains organoperoxide and isobutyene adsorbing activated carbon, pneumatic tire with built-in sealant and method |
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