JP5390389B2 - ギ酸からの水素生成 - Google Patents
ギ酸からの水素生成 Download PDFInfo
- Publication number
- JP5390389B2 JP5390389B2 JP2009532941A JP2009532941A JP5390389B2 JP 5390389 B2 JP5390389 B2 JP 5390389B2 JP 2009532941 A JP2009532941 A JP 2009532941A JP 2009532941 A JP2009532941 A JP 2009532941A JP 5390389 B2 JP5390389 B2 JP 5390389B2
- Authority
- JP
- Japan
- Prior art keywords
- reaction
- hydrogen gas
- catalyst
- formic acid
- carried out
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
- C01B3/02—Production of hydrogen; Production of gaseous mixtures containing hydrogen
- C01B3/22—Production of hydrogen; Production of gaseous mixtures containing hydrogen by decomposition of gaseous or liquid organic compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0215—Sulfur-containing compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0215—Sulfur-containing compounds
- B01J31/0225—Sulfur-containing compounds comprising sulfonic acid groups or the corresponding salts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
- C01B32/50—Carbon dioxide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/821—Ruthenium
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Combustion & Propulsion (AREA)
- Hydrogen, Water And Hydrids (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP06122534A EP1918247A1 (en) | 2006-10-18 | 2006-10-18 | Hydrogen production from formic acid |
| EP06122534.8 | 2006-10-18 | ||
| PCT/IB2007/054222 WO2008047312A1 (en) | 2006-10-18 | 2007-10-17 | Hydrogen production from formic acid |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2010506818A JP2010506818A (ja) | 2010-03-04 |
| JP2010506818A5 JP2010506818A5 (https=) | 2010-12-02 |
| JP5390389B2 true JP5390389B2 (ja) | 2014-01-15 |
Family
ID=37866268
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2009532941A Expired - Fee Related JP5390389B2 (ja) | 2006-10-18 | 2007-10-17 | ギ酸からの水素生成 |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US8133464B2 (https=) |
| EP (2) | EP1918247A1 (https=) |
| JP (1) | JP5390389B2 (https=) |
| KR (1) | KR101434699B1 (https=) |
| CN (1) | CN101541668B (https=) |
| BR (1) | BRPI0718482B1 (https=) |
| CA (1) | CA2666412C (https=) |
| ES (1) | ES2538258T3 (https=) |
| IL (1) | IL198178A0 (https=) |
| WO (1) | WO2008047312A1 (https=) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2025053106A1 (ja) | 2023-09-04 | 2025-03-13 | 株式会社Inpex | ガス処理方法及び二酸化炭素の処理方法 |
Families Citing this family (37)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102131730A (zh) * | 2008-07-28 | 2011-07-20 | 中原胜 | 氢气的制备方法 |
| JP5397806B2 (ja) * | 2009-03-12 | 2014-01-22 | 国立大学法人大阪大学 | 重水素(d2)および重水素化水素(hd)の少なくとも一方を製造する方法、並びにこれに使用するギ酸分解用触媒 |
| US8148553B2 (en) * | 2009-06-23 | 2012-04-03 | Wisconsin Alumni Research Foundation | Catalytic conversion of cellulose to liquid hydrocarbon fuels by progressive removal of oxygen to facilitate separation processes and achieve high selectivities |
| WO2012070620A1 (ja) * | 2010-11-25 | 2012-05-31 | 国立大学法人岡山大学 | 金属錯体化合物、当該金属錯体化合物を含む水素製造用触媒および水素化反応触媒、ならびに当該触媒を用いる水素の製造方法および水素化方法 |
| DE102011007661A1 (de) | 2011-04-19 | 2012-10-25 | Leibniz-Institut Für Katalyse E.V. An Der Universität Rostock | Verfahren zur Wasserstoffgewinnung durch katalytische Zersetzung von Ameisensäure |
| US20130004800A1 (en) * | 2011-06-30 | 2013-01-03 | Formic Acid-Hydrogen Energy Development Corporation | Hydrogen generation system and method for generating hydrogen for mobile and power generator |
| US8720390B2 (en) * | 2011-09-19 | 2014-05-13 | Northern Technologies International Corporation | Fuel performance booster |
| WO2013111860A1 (ja) | 2012-01-27 | 2013-08-01 | 独立行政法人産業技術総合研究所 | ギ酸の脱水素化触媒、水素製造方法、重水素ガスまたは重水素化水素の製造方法 |
| EP2767530A1 (en) | 2013-02-15 | 2014-08-20 | EOS Holding SA | Direct carbon dioxide hydrogenation to formic acid in acidic media |
| WO2014134742A1 (en) | 2013-03-06 | 2014-09-12 | Granit S.A. | Method for producing hydrogen gas from formic acid |
| US9127370B2 (en) | 2013-09-18 | 2015-09-08 | The United States Of America As Represented By The Secretary Of The Army | Power-free apparatus for hydrogen generation from alcohol |
| HUP1300539A2 (hu) * | 2013-09-18 | 2015-04-28 | Debreceni Egyetem | Katalizátor és eljárás hidrogéngáznak formiátból történõ elõállítására és hidrogénkarbonát hidrogénezésére, és az ezeket alkalmazó hidrogéntároló rendszer |
| JPWO2015053317A1 (ja) | 2013-10-11 | 2017-03-09 | 国立研究開発法人産業技術総合研究所 | ギ酸の脱水素化に用いる触媒、ギ酸の脱水素化方法、水素製造方法 |
| KR101732881B1 (ko) * | 2014-07-18 | 2017-05-08 | 한국과학기술연구원 | 개미산으로부터의 수소 발생 방법 및 장치 |
| CN104190468B (zh) * | 2014-08-04 | 2016-08-24 | 南京师范大学 | 一种用于高单酯含量甲基丙烯酸羟乙基磷酸酯合成的催化剂、制备方法及其催化合成工艺 |
| JP6502091B2 (ja) * | 2014-12-26 | 2019-04-17 | 国立研究開発法人産業技術総合研究所 | 高圧水素製造法および製造システム |
| CN107848794B (zh) * | 2015-05-13 | 2021-08-24 | 耶路撒冷希伯来大学伊萨姆研究开发有限公司 | 用于储存和释放氢的方法和装置 |
| CN105270201A (zh) * | 2015-11-03 | 2016-01-27 | 上海合既得动氢机器有限公司 | 无尾气排放的水氢动力汽车 |
| JP6548602B2 (ja) * | 2016-03-30 | 2019-07-24 | 岩谷産業株式会社 | 水素供給装置及び水素供給方法 |
| CN105833914B (zh) * | 2016-04-13 | 2018-02-16 | 大连理工大学 | 一类双核配合物催化剂、制备方法及其应用于催化甲酸分解制氢 |
| KR101866940B1 (ko) | 2016-10-14 | 2018-07-24 | 한국에너지기술연구원 | 3차원 기공구조의 메조포러스 실리카 지지체를 포함하는 포름산 탈수소화 촉매 및 이의 제조방법 |
| TWI607963B (zh) * | 2017-01-19 | 2017-12-11 | 國立交通大學 | 氫氣製備方法、系統與用於其中的溶液 |
| JP6861038B2 (ja) * | 2017-01-25 | 2021-04-21 | 飯田グループホールディングス株式会社 | 水素供給システムおよび水素供給方法 |
| EP3441137B1 (de) * | 2017-08-08 | 2019-12-25 | Evonik Operations GmbH | Pd-katalysierten zersetzung von ameisensäure |
| DE102019205316A1 (de) * | 2019-04-12 | 2020-10-15 | Siemens Aktiengesellschaft | Energieeffiziente Wasserstoffherstellung |
| CN110342461A (zh) * | 2019-05-29 | 2019-10-18 | 安徽青木子德慧能源发展有限公司 | 一种基于甲酸裂解制取氢气的反应器系统及其启动方法 |
| CN110342460A (zh) * | 2019-05-29 | 2019-10-18 | 安徽青木子德慧能源发展有限公司 | 一种具有防溢泡功能的基于甲酸裂解制取氢气的反应器系统 |
| CN112299371A (zh) * | 2019-07-31 | 2021-02-02 | 中国科学院苏州纳米技术与纳米仿生研究所 | 一种供氢系统及供氢方法 |
| JP7319155B2 (ja) * | 2019-09-26 | 2023-08-01 | 日東電工株式会社 | 水素ガス製造方法及び水素ガス製造システム |
| EP4178908B1 (en) * | 2020-07-08 | 2024-06-12 | Toyota Motor Europe | Contaminated hydrogen gas composition and its use as a reference for hydrogen fuels |
| CN112452315B (zh) * | 2020-11-02 | 2023-07-21 | 浙江理工大学 | 一种高温抗烧结催化剂的应用 |
| JP7588828B2 (ja) * | 2021-01-27 | 2024-11-25 | 国立研究開発法人産業技術総合研究所 | 水素の連続製造方法及びそのシステム |
| CN114682305A (zh) * | 2022-03-09 | 2022-07-01 | 石景贤 | 一种高效的低成本用于甲酸制氢的催化剂制备方法及应用 |
| CN115594148A (zh) * | 2022-10-19 | 2023-01-13 | 安徽青木子德慧能源发展有限公司(Cn) | 一种基于甲酸裂解制取氢气的反应器系统及其启动方法 |
| CN116654869B (zh) * | 2023-05-18 | 2023-10-27 | 苏州市相城区清智智能网联汽车创新中心 | 一种甲酸制氢装置 |
| US20250167271A1 (en) * | 2023-11-22 | 2025-05-22 | Nuscale Power, Llc | Sodium Formate Hydrogen Extraction System Operation And Production Of Hydrogen And Methanol |
| WO2025245504A1 (en) * | 2024-05-23 | 2025-11-27 | Watt Power Inc. | Production of formate, glycolate, and hydrogen from carbohydrates using violene catalysts |
Family Cites Families (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US416081A (en) * | 1889-11-26 | Railroad-tie | ||
| FR1228452A (fr) * | 1958-04-18 | 1960-08-31 | Bataafsche Petroleum | Procédé pour la décomposition catalytique et sélective de l'acide formique |
| JPS595341B2 (ja) * | 1975-06-17 | 1984-02-03 | 住友化学工業株式会社 | ギサンノブンカイホウホウ |
| US4160816A (en) * | 1977-12-05 | 1979-07-10 | Rca Corporation | Process for storing solar energy in the form of an electrochemically generated compound |
| US4597363A (en) * | 1981-02-27 | 1986-07-01 | Melvin Emelock | Hydrogen generator for motor vehicle |
| JPS61222902A (ja) * | 1985-03-29 | 1986-10-03 | Mitsubishi Heavy Ind Ltd | 水素含有ガスの製造方法 |
| US4731486A (en) * | 1986-11-18 | 1988-03-15 | Union Carbide Corporation | Hydroformylation using low volatile phosphine ligands |
| US5606107A (en) * | 1995-06-07 | 1997-02-25 | Monsanto Company | Formic acid and formaldehyde destruction in waste streams |
| JP4120717B2 (ja) * | 1998-06-03 | 2008-07-16 | 三菱瓦斯化学株式会社 | 一酸化炭素及び水素の混合ガスの製造方法 |
| JP2001198469A (ja) * | 1999-11-05 | 2001-07-24 | Sekisui Chem Co Ltd | 水素貯蔵・供給用金属担持触媒及びこれを利用した水素貯蔵・供給システム |
| JP2001164270A (ja) * | 1999-12-03 | 2001-06-19 | Kansai Research Institute | ガスの製造方法及び製造装置 |
| US6596423B2 (en) * | 2001-03-26 | 2003-07-22 | Brookhaven Science Associates, Llc | Method for low temperature catalytic production of hydrogen |
| JP4481060B2 (ja) | 2004-03-31 | 2010-06-16 | 蟻酸・水素エネルギー開発株式会社 | 水熱反応を利用した水素の製造方法 |
| US7569203B2 (en) * | 2006-02-21 | 2009-08-04 | Drexel University | Production and uses of carbon suboxides |
| KR100818262B1 (ko) * | 2006-12-18 | 2008-04-01 | 삼성에스디아이 주식회사 | 연료 개질반응용 촉매 및 이를 이용한 수소 제조방법 |
-
2006
- 2006-10-18 EP EP06122534A patent/EP1918247A1/en not_active Withdrawn
-
2007
- 2007-10-17 CN CN2007800431462A patent/CN101541668B/zh active Active
- 2007-10-17 JP JP2009532941A patent/JP5390389B2/ja not_active Expired - Fee Related
- 2007-10-17 BR BRPI0718482-4A patent/BRPI0718482B1/pt not_active IP Right Cessation
- 2007-10-17 ES ES07826768.9T patent/ES2538258T3/es active Active
- 2007-10-17 WO PCT/IB2007/054222 patent/WO2008047312A1/en not_active Ceased
- 2007-10-17 CA CA2666412A patent/CA2666412C/en active Active
- 2007-10-17 US US12/311,954 patent/US8133464B2/en active Active
- 2007-10-17 EP EP07826768.9A patent/EP2086873B1/en active Active
- 2007-10-17 KR KR1020097010156A patent/KR101434699B1/ko not_active Expired - Fee Related
-
2009
- 2009-04-16 IL IL198178A patent/IL198178A0/en unknown
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2025053106A1 (ja) | 2023-09-04 | 2025-03-13 | 株式会社Inpex | ガス処理方法及び二酸化炭素の処理方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| BRPI0718482A2 (pt) | 2013-11-26 |
| KR101434699B1 (ko) | 2014-08-26 |
| CA2666412A1 (en) | 2008-04-24 |
| WO2008047312A1 (en) | 2008-04-24 |
| US20100068131A1 (en) | 2010-03-18 |
| CN101541668B (zh) | 2012-05-09 |
| EP2086873A1 (en) | 2009-08-12 |
| EP2086873B1 (en) | 2015-03-04 |
| IL198178A0 (en) | 2009-12-24 |
| CN101541668A (zh) | 2009-09-23 |
| KR20090073230A (ko) | 2009-07-02 |
| JP2010506818A (ja) | 2010-03-04 |
| US8133464B2 (en) | 2012-03-13 |
| ES2538258T3 (es) | 2015-06-18 |
| EP1918247A1 (en) | 2008-05-07 |
| CA2666412C (en) | 2015-04-14 |
| AU2007311485A1 (en) | 2008-04-24 |
| BRPI0718482B1 (pt) | 2018-05-15 |
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