CN101541668B - 由甲酸生产氢气 - Google Patents

由甲酸生产氢气 Download PDF

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Publication number
CN101541668B
CN101541668B CN2007800431462A CN200780043146A CN101541668B CN 101541668 B CN101541668 B CN 101541668B CN 2007800431462 A CN2007800431462 A CN 2007800431462A CN 200780043146 A CN200780043146 A CN 200780043146A CN 101541668 B CN101541668 B CN 101541668B
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reaction
hydrogen
formic acid
catalyst
carried out
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Chinese (zh)
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CN101541668A (zh
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G·劳伦斯基
C·菲莱
P·迪森
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Ecole Polytechnique Federale de Lausanne EPFL
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Ecole Polytechnique Federale de Lausanne EPFL
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    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
    • C01B3/02—Production of hydrogen; Production of gaseous mixtures containing hydrogen
    • C01B3/22—Production of hydrogen; Production of gaseous mixtures containing hydrogen by decomposition of gaseous or liquid organic compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0215—Sulfur-containing compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0215—Sulfur-containing compounds
    • B01J31/0225—Sulfur-containing compounds comprising sulfonic acid groups or the corresponding salts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00—Carbon; Compounds thereof
    • C01B32/50—Carbon dioxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/821—Ruthenium

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
CN2007800431462A 2006-10-18 2007-10-17 由甲酸生产氢气 Active CN101541668B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP06122534A EP1918247A1 (en) 2006-10-18 2006-10-18 Hydrogen production from formic acid
EP06122534.8 2006-10-18
PCT/IB2007/054222 WO2008047312A1 (en) 2006-10-18 2007-10-17 Hydrogen production from formic acid

Publications (2)

Publication Number Publication Date
CN101541668A CN101541668A (zh) 2009-09-23
CN101541668B true CN101541668B (zh) 2012-05-09

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CN2007800431462A Active CN101541668B (zh) 2006-10-18 2007-10-17 由甲酸生产氢气

Country Status (10)

Country Link
US (1) US8133464B2 (https=)
EP (2) EP1918247A1 (https=)
JP (1) JP5390389B2 (https=)
KR (1) KR101434699B1 (https=)
CN (1) CN101541668B (https=)
BR (1) BRPI0718482B1 (https=)
CA (1) CA2666412C (https=)
ES (1) ES2538258T3 (https=)
IL (1) IL198178A0 (https=)
WO (1) WO2008047312A1 (https=)

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CN102131730A (zh) * 2008-07-28 2011-07-20 中原胜 氢气的制备方法
JP5397806B2 (ja) * 2009-03-12 2014-01-22 国立大学法人大阪大学 重水素（ｄ２）および重水素化水素（ｈｄ）の少なくとも一方を製造する方法、並びにこれに使用するギ酸分解用触媒
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WO2012070620A1 (ja) * 2010-11-25 2012-05-31 国立大学法人岡山大学 金属錯体化合物、当該金属錯体化合物を含む水素製造用触媒および水素化反応触媒、ならびに当該触媒を用いる水素の製造方法および水素化方法
DE102011007661A1 (de) 2011-04-19 2012-10-25 Leibniz-Institut Für Katalyse E.V. An Der Universität Rostock Verfahren zur Wasserstoffgewinnung durch katalytische Zersetzung von Ameisensäure
US20130004800A1 (en) * 2011-06-30 2013-01-03 Formic Acid-Hydrogen Energy Development Corporation Hydrogen generation system and method for generating hydrogen for mobile and power generator
US8720390B2 (en) * 2011-09-19 2014-05-13 Northern Technologies International Corporation Fuel performance booster
WO2013111860A1 (ja) 2012-01-27 2013-08-01 独立行政法人産業技術総合研究所 ギ酸の脱水素化触媒、水素製造方法、重水素ガスまたは重水素化水素の製造方法
EP2767530A1 (en) 2013-02-15 2014-08-20 EOS Holding SA Direct carbon dioxide hydrogenation to formic acid in acidic media
WO2014134742A1 (en) 2013-03-06 2014-09-12 Granit S.A. Method for producing hydrogen gas from formic acid
US9127370B2 (en) 2013-09-18 2015-09-08 The United States Of America As Represented By The Secretary Of The Army Power-free apparatus for hydrogen generation from alcohol
HUP1300539A2 (hu) * 2013-09-18 2015-04-28 Debreceni Egyetem Katalizátor és eljárás hidrogéngáznak formiátból történõ elõállítására és hidrogénkarbonát hidrogénezésére, és az ezeket alkalmazó hidrogéntároló rendszer
JPWO2015053317A1 (ja) 2013-10-11 2017-03-09 国立研究開発法人産業技術総合研究所 ギ酸の脱水素化に用いる触媒、ギ酸の脱水素化方法、水素製造方法
KR101732881B1 (ko) * 2014-07-18 2017-05-08 한국과학기술연구원 개미산으로부터의 수소 발생 방법 및 장치
CN104190468B (zh) * 2014-08-04 2016-08-24 南京师范大学 一种用于高单酯含量甲基丙烯酸羟乙基磷酸酯合成的催化剂、制备方法及其催化合成工艺
JP6502091B2 (ja) * 2014-12-26 2019-04-17 国立研究開発法人産業技術総合研究所 高圧水素製造法および製造システム
CN107848794B (zh) * 2015-05-13 2021-08-24 耶路撒冷希伯来大学伊萨姆研究开发有限公司 用于储存和释放氢的方法和装置
CN105270201A (zh) * 2015-11-03 2016-01-27 上海合既得动氢机器有限公司 无尾气排放的水氢动力汽车
JP6548602B2 (ja) * 2016-03-30 2019-07-24 岩谷産業株式会社 水素供給装置及び水素供給方法
CN105833914B (zh) * 2016-04-13 2018-02-16 大连理工大学 一类双核配合物催化剂、制备方法及其应用于催化甲酸分解制氢
KR101866940B1 (ko) 2016-10-14 2018-07-24 한국에너지기술연구원 3차원 기공구조의 메조포러스 실리카 지지체를 포함하는 포름산 탈수소화 촉매 및 이의 제조방법
TWI607963B (zh) * 2017-01-19 2017-12-11 國立交通大學 氫氣製備方法、系統與用於其中的溶液
JP6861038B2 (ja) * 2017-01-25 2021-04-21 飯田グループホールディングス株式会社 水素供給システムおよび水素供給方法
EP3441137B1 (de) * 2017-08-08 2019-12-25 Evonik Operations GmbH Pd-katalysierten zersetzung von ameisensäure
DE102019205316A1 (de) * 2019-04-12 2020-10-15 Siemens Aktiengesellschaft Energieeffiziente Wasserstoffherstellung
CN110342461A (zh) * 2019-05-29 2019-10-18 安徽青木子德慧能源发展有限公司 一种基于甲酸裂解制取氢气的反应器系统及其启动方法
CN110342460A (zh) * 2019-05-29 2019-10-18 安徽青木子德慧能源发展有限公司 一种具有防溢泡功能的基于甲酸裂解制取氢气的反应器系统
CN112299371A (zh) * 2019-07-31 2021-02-02 中国科学院苏州纳米技术与纳米仿生研究所 一种供氢系统及供氢方法
JP7319155B2 (ja) * 2019-09-26 2023-08-01 日東電工株式会社 水素ガス製造方法及び水素ガス製造システム
EP4178908B1 (en) * 2020-07-08 2024-06-12 Toyota Motor Europe Contaminated hydrogen gas composition and its use as a reference for hydrogen fuels
CN112452315B (zh) * 2020-11-02 2023-07-21 浙江理工大学 一种高温抗烧结催化剂的应用
JP7588828B2 (ja) * 2021-01-27 2024-11-25 国立研究開発法人産業技術総合研究所 水素の連続製造方法及びそのシステム
CN114682305A (zh) * 2022-03-09 2022-07-01 石景贤 一种高效的低成本用于甲酸制氢的催化剂制备方法及应用
CN115594148A (zh) * 2022-10-19 2023-01-13 安徽青木子德慧能源发展有限公司（Cn） 一种基于甲酸裂解制取氢气的反应器系统及其启动方法
CN116654869B (zh) * 2023-05-18 2023-10-27 苏州市相城区清智智能网联汽车创新中心 一种甲酸制氢装置
JP2025035810A (ja) 2023-09-04 2025-03-14 株式会社Inpex ガス処理方法及び二酸化炭素の処理方法
US20250167271A1 (en) * 2023-11-22 2025-05-22 Nuscale Power, Llc Sodium Formate Hydrogen Extraction System Operation And Production Of Hydrogen And Methanol
WO2025245504A1 (en) * 2024-05-23 2025-11-27 Watt Power Inc. Production of formate, glycolate, and hydrogen from carbohydrates using violene catalysts

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Also Published As

Publication number Publication date
BRPI0718482A2 (pt) 2013-11-26
KR101434699B1 (ko) 2014-08-26
CA2666412A1 (en) 2008-04-24
WO2008047312A1 (en) 2008-04-24
US20100068131A1 (en) 2010-03-18
EP2086873A1 (en) 2009-08-12
EP2086873B1 (en) 2015-03-04
IL198178A0 (en) 2009-12-24
CN101541668A (zh) 2009-09-23
KR20090073230A (ko) 2009-07-02
JP2010506818A (ja) 2010-03-04
US8133464B2 (en) 2012-03-13
ES2538258T3 (es) 2015-06-18
EP1918247A1 (en) 2008-05-07
CA2666412C (en) 2015-04-14
JP5390389B2 (ja) 2014-01-15
AU2007311485A1 (en) 2008-04-24
BRPI0718482B1 (pt) 2018-05-15

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Application publication date: 20090923

Assignee: Xiamen Guoluopu Energy Technology Co.,Ltd.

Assignor: ECOLE POLYTECHNIQUE FEDERALE DE LAUSANNE

Contract record no.: X2024990000165

Denomination of invention: Hydrogen production from formic acid

Granted publication date: 20120509

License type: Exclusive License

Record date: 20240422