JP5328148B2 - 改良接着特性を有する水性ポリエステル−ポリウレタン分散液 - Google Patents
改良接着特性を有する水性ポリエステル−ポリウレタン分散液 Download PDFInfo
- Publication number
- JP5328148B2 JP5328148B2 JP2007503231A JP2007503231A JP5328148B2 JP 5328148 B2 JP5328148 B2 JP 5328148B2 JP 2007503231 A JP2007503231 A JP 2007503231A JP 2007503231 A JP2007503231 A JP 2007503231A JP 5328148 B2 JP5328148 B2 JP 5328148B2
- Authority
- JP
- Japan
- Prior art keywords
- weight
- parts
- polyester
- polyol
- daltons
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/0804—Manufacture of polymers containing ionic or ionogenic groups
- C08G18/0819—Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups
- C08G18/0828—Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups containing sulfonate groups or groups forming them
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
- C08G18/12—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step using two or more compounds having active hydrogen in the first polymerisation step
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/30—Low-molecular-weight compounds
- C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
- C08G18/3225—Polyamines
- C08G18/3228—Polyamines acyclic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
- C08G18/4205—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups
- C08G18/4208—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups containing aromatic groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/73—Polyisocyanates or polyisothiocyanates acyclic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
- C08G18/75—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic
- C08G18/751—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring
- C08G18/752—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group
- C08G18/753—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group containing one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group having a primary carbon atom next to the isocyanate or isothiocyanate group
- C08G18/755—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group containing one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group having a primary carbon atom next to the isocyanate or isothiocyanate group and at least one isocyanate or isothiocyanate group linked to a secondary carbon atom of the cycloaliphatic ring, e.g. isophorone diisocyanate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/04—Coating
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
- C09D175/06—Polyurethanes from polyesters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2475/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
- C08J2475/04—Polyurethanes
- C08J2475/06—Polyurethanes from polyesters
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Polyurethanes Or Polyureas (AREA)
- Paints Or Removers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Adhesives Or Adhesive Processes (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102004013259.3 | 2004-03-18 | ||
| DE102004013259A DE102004013259A1 (de) | 2004-03-18 | 2004-03-18 | Wässrige PUR-Dispersionen mit verbesserter Haftung |
| PCT/EP2005/002332 WO2005092941A1 (de) | 2004-03-18 | 2005-03-05 | Wässrige pur-dispersionen mit verbesserter haftung |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2007529578A JP2007529578A (ja) | 2007-10-25 |
| JP2007529578A5 JP2007529578A5 (enExample) | 2008-03-27 |
| JP5328148B2 true JP5328148B2 (ja) | 2013-10-30 |
Family
ID=34895428
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2007503231A Expired - Fee Related JP5328148B2 (ja) | 2004-03-18 | 2005-03-05 | 改良接着特性を有する水性ポリエステル−ポリウレタン分散液 |
Country Status (12)
| Country | Link |
|---|---|
| US (2) | US20050209399A1 (enExample) |
| EP (1) | EP1727843B1 (enExample) |
| JP (1) | JP5328148B2 (enExample) |
| KR (1) | KR101161893B1 (enExample) |
| CN (1) | CN100537628C (enExample) |
| AT (1) | ATE527293T1 (enExample) |
| CA (1) | CA2560126C (enExample) |
| DE (1) | DE102004013259A1 (enExample) |
| ES (1) | ES2373314T3 (enExample) |
| RU (1) | RU2006136503A (enExample) |
| SI (1) | SI1727843T1 (enExample) |
| WO (1) | WO2005092941A1 (enExample) |
Families Citing this family (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102005056434A1 (de) * | 2005-11-26 | 2007-05-31 | Bayer Materialscience Ag | Wässrige, Urethangruppen enthaltende, hydroxyfunktionelle Polyester-Dispersionen |
| JP4609658B2 (ja) * | 2005-12-28 | 2011-01-12 | 大日本印刷株式会社 | 化粧シート |
| KR100828789B1 (ko) * | 2006-07-05 | 2008-05-09 | 현대자동차주식회사 | 박막형 수성 소프트 질감도료 |
| JP5604785B2 (ja) * | 2006-09-14 | 2014-10-15 | 横浜ゴム株式会社 | ウレタンエマルジョン |
| DE102006048926A1 (de) * | 2006-10-17 | 2008-04-24 | Bayer Materialscience Ag | Wässriges Beschichtungsmittel auf Basis eines Bindemittelgemisches als Basislack |
| DE102006058202A1 (de) * | 2006-12-11 | 2008-06-12 | Merck Patent Gmbh | Verfahren zur Herstellung von Dispersionen |
| DE102007059090A1 (de) * | 2007-12-07 | 2009-06-10 | Benecke-Kaliko Ag | Polymermischung |
| CN101265318B (zh) * | 2008-05-15 | 2012-12-12 | 海聚高分子材料科技(广州)有限公司 | 一种高性能水性聚氨酯分散体及其应用 |
| SI2630174T1 (sl) * | 2010-10-19 | 2014-10-30 | Bayer Intellectual Property Gmbh | Vodni pripravki, ki imajo lastnosti mehkega otipa |
| WO2012089827A1 (en) * | 2010-12-30 | 2012-07-05 | BECKERS HIGH PERFORMANCE COATINGS (TIANJIN) Ltd. | Soft touch coating composition |
| EP2663584B1 (en) * | 2011-01-13 | 2015-02-25 | Huntsman International LLC | A process for making polyurea particles |
| CN102432796B (zh) * | 2011-08-03 | 2015-01-21 | 上海才德化工有限公司 | 由水性聚酯合成的水性聚氨酯及其制备方法 |
| CN102532463B (zh) * | 2011-12-26 | 2014-01-01 | 四川达威科技股份有限公司 | 一种皮革涂饰用水性聚氨酯及其制备方法 |
| EP3020743B1 (en) * | 2014-11-17 | 2017-08-16 | Covestro Deutschland AG | Polyurethaneureas for wood coatings |
| KR101766013B1 (ko) * | 2015-06-16 | 2017-08-07 | 현대자동차주식회사 | 고탄성 수성 접착제 조성물 및 이를 이용한 성형품의 표면처리 방법 |
| US20190211158A1 (en) * | 2016-09-12 | 2019-07-11 | Dsm Ip Assets B.V. | Dispersion |
| US20190040181A1 (en) * | 2017-08-02 | 2019-02-07 | Covestro Llc | One component polyurethane dispersion for vinyl windows |
| US20190040252A1 (en) * | 2017-08-02 | 2019-02-07 | Covestro Llc | One component polyurethane dispersion for vinyl windows |
| US11059935B2 (en) * | 2017-08-02 | 2021-07-13 | Covestro Llc | One component polyurethane dispersion for vinyl windows and other substrates |
| US11028296B2 (en) * | 2017-08-02 | 2021-06-08 | Covestro Llc | One component polyurethane dispersion for vinyl windows and other substrates |
| KR20200102985A (ko) * | 2017-12-21 | 2020-09-01 | 코베스트로 도이칠란트 아게 | 조정가능한 접착 강도를 갖는 특정 폴리우레탄우레아 기재의 접착제, 그의 제조 및 용도 |
| CN115232283B (zh) * | 2022-07-26 | 2024-04-09 | 万华化学集团股份有限公司 | 一种聚氨酯-聚脲水分散体及其制备方法和应用 |
Family Cites Families (26)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL135755C (enExample) * | 1966-02-02 | 1900-01-01 | ||
| ES349312A1 (es) * | 1966-02-02 | 1969-05-01 | Teijin Ltd | Un procedimiento para aumentar la adherencia al caucho de un articulo configurado de un poliester cristalino. |
| US3905928A (en) * | 1974-02-15 | 1975-09-16 | Burlington Industries Inc | Hot melt size and yarn sized therewith |
| DE2314512C3 (de) * | 1973-03-23 | 1980-10-09 | Bayer Ag, 5090 Leverkusen | Thermoplastische, nichtionische, in Wasser despergierbare im wesentlichen lineare Polyurethanelastomere |
| DE2345256A1 (de) * | 1973-09-07 | 1975-03-20 | Bayer Ag | Verfahren zur herstellung von mikroporoesen flaechengebilden |
| US3890264A (en) | 1974-03-04 | 1975-06-17 | Tenneco Chem | Surface-coating compositions containing polyoxymethyleneoxazolidines |
| DE2550860C2 (de) * | 1975-11-12 | 1983-05-26 | Bayer Ag, 5090 Leverkusen | Verfahren zur Herstellung von stabilen Dispersionen |
| DE2651506C2 (de) * | 1976-11-11 | 1986-04-30 | Bayer Ag, 5090 Leverkusen | Verfahren zur Herstellung von in Wasser dispergierbaren Polyurethanen |
| DE2708442C2 (de) * | 1977-02-26 | 1984-10-25 | Bayer Ag, 5090 Leverkusen | Verfahren zur Herstellung von modifizierten wäßrigen Kunststoff-Dispersionen |
| DE2804609A1 (de) * | 1978-02-03 | 1979-08-09 | Bayer Ag | Waessrige loesungen oder dispersionen von polyisocyanat-polyadditionsprodukten, ein verfahren zu ihrer herstellung, sowie ihre verwendung als klebemittel |
| DE2807479A1 (de) * | 1978-02-22 | 1979-08-23 | Bayer Ag | Ueberzugsmittel |
| DE2827156A1 (de) * | 1978-06-21 | 1980-01-10 | Bayer Ag | Waessrige dispersionen oder loesungen von oligomeren oder polymeren kunststoffen, ein verfahren zu ihrer herstellung, sowie ihre verwendung |
| DE2900574A1 (de) * | 1979-01-09 | 1980-07-17 | Bayer Ag | Verwendung von wasserloeslichen elektrolyten als zusatzmittel in waessrigen kunststoffdispersionen und eine, einen wasserloeslichen elektrolyten enthaltende, waessrige kunststoffdispersion |
| JPH0822900B2 (ja) * | 1984-07-30 | 1996-03-06 | 大日本インキ化学工業株式会社 | 水性ポリエステルウレタン樹脂組成物 |
| DE4024567A1 (de) * | 1990-08-02 | 1992-02-06 | Basf Ag | Herstellung von waessrigen polyurethandispersionen |
| DE4137429A1 (de) * | 1991-11-14 | 1993-05-19 | Bayer Ag | Waessrige bindemittelkombination, ein verfahren zu ihrer herstellung und ihre verwendung |
| DE4406159A1 (de) * | 1994-02-25 | 1995-08-31 | Bayer Ag | Wäßrige Polyester-Polyurethan-Dispersionen und ihre Verwendung in Beschichtungsmitteln |
| JP3896578B2 (ja) * | 1996-10-08 | 2007-03-22 | 日本ポリウレタン工業株式会社 | 水性ポリウレタン系エマルジョン塗料 |
| EP0959087B1 (de) * | 1998-05-22 | 2003-10-15 | Bayer Aktiengesellschaft | Wasserdispergierbare Polyether-modifizierte Polyisocyanatgemische |
| AT410213B (de) * | 1998-08-04 | 2003-03-25 | Solutia Austria Gmbh | Wasserverdünnbare bindemittel für ''soft-feel''-lacke |
| DE19914884A1 (de) * | 1999-04-01 | 2000-10-05 | Bayer Ag | Polyurethan-Dispersionen mit Alkoxysilan-Endgruppen für Glasfaserschlichten |
| DE10007821A1 (de) | 2000-02-21 | 2001-08-23 | Bayer Ag | Wasserdispergierbare Polyisocyanatgemische |
| DE10024624A1 (de) * | 2000-05-18 | 2001-11-22 | Bayer Ag | Modifizierte Polyisocyanate |
| DE10138765A1 (de) * | 2001-08-07 | 2003-02-20 | Bayer Ag | Wässrige Dispersionen hydrophiler Polyurethanharze |
| DE102004002525A1 (de) * | 2004-01-16 | 2005-08-04 | Bayer Materialscience Ag | Beschichtungsmittelzusammensetzung |
| DE602004013378T2 (de) * | 2004-04-13 | 2009-07-02 | Lamberti S.P.A., Albizzate | Wässrige klebstoffzusammensetzungen |
-
2004
- 2004-03-18 DE DE102004013259A patent/DE102004013259A1/de not_active Withdrawn
-
2005
- 2005-03-05 AT AT05715754T patent/ATE527293T1/de active
- 2005-03-05 EP EP05715754A patent/EP1727843B1/de not_active Expired - Lifetime
- 2005-03-05 CA CA2560126A patent/CA2560126C/en not_active Expired - Fee Related
- 2005-03-05 SI SI200531441T patent/SI1727843T1/sl unknown
- 2005-03-05 CN CNB2005800087593A patent/CN100537628C/zh not_active Expired - Lifetime
- 2005-03-05 JP JP2007503231A patent/JP5328148B2/ja not_active Expired - Fee Related
- 2005-03-05 RU RU2006136503/04A patent/RU2006136503A/ru not_active Application Discontinuation
- 2005-03-05 KR KR1020067018973A patent/KR101161893B1/ko not_active Expired - Fee Related
- 2005-03-05 ES ES05715754T patent/ES2373314T3/es not_active Expired - Lifetime
- 2005-03-05 WO PCT/EP2005/002332 patent/WO2005092941A1/de not_active Ceased
- 2005-03-14 US US11/080,278 patent/US20050209399A1/en not_active Abandoned
-
2007
- 2007-07-11 US US11/827,252 patent/US8063138B2/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| EP1727843A1 (de) | 2006-12-06 |
| RU2006136503A (ru) | 2008-04-27 |
| WO2005092941A1 (de) | 2005-10-06 |
| KR20070005630A (ko) | 2007-01-10 |
| EP1727843B1 (de) | 2011-10-05 |
| KR101161893B1 (ko) | 2012-07-03 |
| CA2560126C (en) | 2013-01-08 |
| US20050209399A1 (en) | 2005-09-22 |
| SI1727843T1 (sl) | 2012-03-30 |
| US8063138B2 (en) | 2011-11-22 |
| DE102004013259A1 (de) | 2005-09-29 |
| JP2007529578A (ja) | 2007-10-25 |
| CA2560126A1 (en) | 2005-10-06 |
| CN100537628C (zh) | 2009-09-09 |
| ES2373314T3 (es) | 2012-02-02 |
| US20080035024A1 (en) | 2008-02-14 |
| ATE527293T1 (de) | 2011-10-15 |
| CN1934152A (zh) | 2007-03-21 |
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