JP5301181B2 - 湿式電解コンデンサ用の中性電解質 - Google Patents
湿式電解コンデンサ用の中性電解質 Download PDFInfo
- Publication number
- JP5301181B2 JP5301181B2 JP2008071059A JP2008071059A JP5301181B2 JP 5301181 B2 JP5301181 B2 JP 5301181B2 JP 2008071059 A JP2008071059 A JP 2008071059A JP 2008071059 A JP2008071059 A JP 2008071059A JP 5301181 B2 JP5301181 B2 JP 5301181B2
- Authority
- JP
- Japan
- Prior art keywords
- acid
- cathode
- anode
- electrolyte
- electrolytic capacitor
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000003990 capacitor Substances 0.000 title claims abstract description 81
- 239000003792 electrolyte Substances 0.000 title claims abstract description 71
- 230000007935 neutral effect Effects 0.000 title abstract description 9
- 239000000203 mixture Substances 0.000 claims description 15
- 239000010955 niobium Substances 0.000 claims description 12
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 claims description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 12
- 229910052758 niobium Inorganic materials 0.000 claims description 11
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 claims description 11
- 150000003839 salts Chemical class 0.000 claims description 9
- 150000008064 anhydrides Chemical class 0.000 claims description 8
- 150000008040 ionic compounds Chemical class 0.000 claims description 8
- 229910052715 tantalum Inorganic materials 0.000 claims description 8
- 150000005338 nitrobenzoic acids Chemical class 0.000 claims description 6
- 238000007710 freezing Methods 0.000 claims description 4
- 230000008014 freezing Effects 0.000 claims description 4
- CCXSGQZMYLXTOI-UHFFFAOYSA-N 13506-76-8 Chemical compound CC1=CC=CC([N+]([O-])=O)=C1C(O)=O CCXSGQZMYLXTOI-UHFFFAOYSA-N 0.000 claims description 3
- XDTTUTIFWDAMIX-UHFFFAOYSA-N 3-methyl-4-nitrobenzoic acid Chemical compound CC1=CC(C(O)=O)=CC=C1[N+]([O-])=O XDTTUTIFWDAMIX-UHFFFAOYSA-N 0.000 claims description 3
- 239000003125 aqueous solvent Substances 0.000 claims description 3
- YPQAFWHSMWWPLX-UHFFFAOYSA-N 1975-50-4 Chemical compound CC1=C(C(O)=O)C=CC=C1[N+]([O-])=O YPQAFWHSMWWPLX-UHFFFAOYSA-N 0.000 claims description 2
- BBEWSMNRCUXQRF-UHFFFAOYSA-N 4-methyl-3-nitrobenzoic acid Chemical compound CC1=CC=C(C(O)=O)C=C1[N+]([O-])=O BBEWSMNRCUXQRF-UHFFFAOYSA-N 0.000 claims description 2
- DGDAVTPQCQXLGU-UHFFFAOYSA-N 5437-38-7 Chemical compound CC1=CC=CC(C(O)=O)=C1[N+]([O-])=O DGDAVTPQCQXLGU-UHFFFAOYSA-N 0.000 claims description 2
- 238000009835 boiling Methods 0.000 claims description 2
- 239000008367 deionised water Substances 0.000 claims description 2
- 229910021641 deionized water Inorganic materials 0.000 claims description 2
- 150000007522 mineralic acids Chemical class 0.000 claims description 2
- 238000005868 electrolysis reaction Methods 0.000 claims 1
- 150000007524 organic acids Chemical class 0.000 claims 1
- 238000000576 coating method Methods 0.000 description 45
- 239000011248 coating agent Substances 0.000 description 43
- 239000002245 particle Substances 0.000 description 39
- 239000002253 acid Substances 0.000 description 19
- 238000000034 method Methods 0.000 description 19
- 239000002184 metal Substances 0.000 description 18
- 229910052751 metal Inorganic materials 0.000 description 17
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 16
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 15
- 229910000484 niobium oxide Inorganic materials 0.000 description 15
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 14
- 239000011230 binding agent Substances 0.000 description 14
- 229920001940 conductive polymer Polymers 0.000 description 14
- -1 methyl isobutyl Chemical group 0.000 description 14
- 239000000463 material Substances 0.000 description 12
- 229910001220 stainless steel Inorganic materials 0.000 description 12
- 239000008199 coating composition Substances 0.000 description 11
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 10
- 229910052782 aluminium Inorganic materials 0.000 description 10
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 10
- 239000002904 solvent Substances 0.000 description 10
- 239000010935 stainless steel Substances 0.000 description 10
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 9
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 9
- 239000000123 paper Substances 0.000 description 9
- 239000000758 substrate Substances 0.000 description 9
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 8
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 8
- 239000011231 conductive filler Substances 0.000 description 8
- 229910052759 nickel Inorganic materials 0.000 description 8
- 239000007787 solid Substances 0.000 description 8
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 7
- 238000011068 loading method Methods 0.000 description 7
- URLJKFSTXLNXLG-UHFFFAOYSA-N niobium(5+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[Nb+5].[Nb+5] URLJKFSTXLNXLG-UHFFFAOYSA-N 0.000 description 7
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 6
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 6
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 6
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 6
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 6
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 6
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 6
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 6
- 229920006125 amorphous polymer Polymers 0.000 description 6
- JFDZBHWFFUWGJE-UHFFFAOYSA-N benzonitrile Chemical compound N#CC1=CC=CC=C1 JFDZBHWFFUWGJE-UHFFFAOYSA-N 0.000 description 6
- 238000001035 drying Methods 0.000 description 6
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 6
- 238000012360 testing method Methods 0.000 description 6
- 229910052719 titanium Inorganic materials 0.000 description 6
- 239000010936 titanium Substances 0.000 description 6
- 229920001609 Poly(3,4-ethylenedioxythiophene) Polymers 0.000 description 5
- 239000006229 carbon black Substances 0.000 description 5
- 239000000919 ceramic Substances 0.000 description 5
- 239000004020 conductor Substances 0.000 description 5
- 150000002148 esters Chemical class 0.000 description 5
- WABPQHHGFIMREM-UHFFFAOYSA-N lead(0) Chemical compound [Pb] WABPQHHGFIMREM-UHFFFAOYSA-N 0.000 description 5
- 229910052763 palladium Inorganic materials 0.000 description 5
- SVTBMSDMJJWYQN-UHFFFAOYSA-N 2-methylpentane-2,4-diol Chemical compound CC(O)CC(C)(C)O SVTBMSDMJJWYQN-UHFFFAOYSA-N 0.000 description 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 4
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 4
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 4
- 150000007513 acids Chemical class 0.000 description 4
- 229910045601 alloy Inorganic materials 0.000 description 4
- 239000000956 alloy Substances 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 229910052802 copper Inorganic materials 0.000 description 4
- 239000010949 copper Substances 0.000 description 4
- 235000014113 dietary fatty acids Nutrition 0.000 description 4
- 239000000194 fatty acid Substances 0.000 description 4
- 229930195729 fatty acid Natural products 0.000 description 4
- 230000009477 glass transition Effects 0.000 description 4
- 229910052739 hydrogen Inorganic materials 0.000 description 4
- 239000011133 lead Substances 0.000 description 4
- 229910044991 metal oxide Inorganic materials 0.000 description 4
- 150000004706 metal oxides Chemical class 0.000 description 4
- 150000002739 metals Chemical class 0.000 description 4
- 229910052750 molybdenum Inorganic materials 0.000 description 4
- 239000011733 molybdenum Substances 0.000 description 4
- 239000000178 monomer Substances 0.000 description 4
- 229920000642 polymer Polymers 0.000 description 4
- 229920000137 polyphosphoric acid Polymers 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 4
- 239000011253 protective coating Substances 0.000 description 4
- 229910052709 silver Inorganic materials 0.000 description 4
- 239000004332 silver Substances 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
- WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 description 3
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- ROSDCCJGGBNDNL-UHFFFAOYSA-N [Ta].[Pb] Chemical compound [Ta].[Pb] ROSDCCJGGBNDNL-UHFFFAOYSA-N 0.000 description 3
- 230000001070 adhesive effect Effects 0.000 description 3
- 229910021529 ammonia Inorganic materials 0.000 description 3
- 239000003054 catalyst Substances 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 3
- 238000000151 deposition Methods 0.000 description 3
- 150000004985 diamines Chemical class 0.000 description 3
- 238000007598 dipping method Methods 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 3
- 239000003112 inhibitor Substances 0.000 description 3
- 150000002500 ions Chemical class 0.000 description 3
- 150000002576 ketones Chemical class 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 235000019198 oils Nutrition 0.000 description 3
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 3
- 229920003023 plastic Polymers 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- 229910052697 platinum Inorganic materials 0.000 description 3
- WOCIAKWEIIZHES-UHFFFAOYSA-N ruthenium(iv) oxide Chemical compound O=[Ru]=O WOCIAKWEIIZHES-UHFFFAOYSA-N 0.000 description 3
- 238000003860 storage Methods 0.000 description 3
- 150000003626 triacylglycerols Chemical class 0.000 description 3
- ARCGXLSVLAOJQL-UHFFFAOYSA-N trimellitic acid Chemical class OC(=O)C1=CC=C(C(O)=O)C(C(O)=O)=C1 ARCGXLSVLAOJQL-UHFFFAOYSA-N 0.000 description 3
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 2
- WZCQRUWWHSTZEM-UHFFFAOYSA-N 1,3-phenylenediamine Chemical compound NC1=CC=CC(N)=C1 WZCQRUWWHSTZEM-UHFFFAOYSA-N 0.000 description 2
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 description 2
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 2
- CCTFMNIEFHGTDU-UHFFFAOYSA-N 3-methoxypropyl acetate Chemical compound COCCCOC(C)=O CCTFMNIEFHGTDU-UHFFFAOYSA-N 0.000 description 2
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 2
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 2
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 2
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
- AFVFQIVMOAPDHO-UHFFFAOYSA-N Methanesulfonic acid Chemical compound CS(O)(=O)=O AFVFQIVMOAPDHO-UHFFFAOYSA-N 0.000 description 2
- FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical compound CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 description 2
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 2
- 239000005642 Oleic acid Substances 0.000 description 2
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 2
- GLUUGHFHXGJENI-UHFFFAOYSA-N Piperazine Chemical compound C1CNCCN1 GLUUGHFHXGJENI-UHFFFAOYSA-N 0.000 description 2
- 239000002202 Polyethylene glycol Substances 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 2
- 239000004963 Torlon Substances 0.000 description 2
- 229920003997 Torlon® Polymers 0.000 description 2
- DTQVDTLACAAQTR-UHFFFAOYSA-N Trifluoroacetic acid Chemical compound OC(=O)C(F)(F)F DTQVDTLACAAQTR-UHFFFAOYSA-N 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 2
- 235000011054 acetic acid Nutrition 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 150000001408 amides Chemical class 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 238000000137 annealing Methods 0.000 description 2
- 238000002048 anodisation reaction Methods 0.000 description 2
- 150000004984 aromatic diamines Chemical class 0.000 description 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 2
- KVNRLNFWIYMESJ-UHFFFAOYSA-N butyronitrile Chemical compound CCCC#N KVNRLNFWIYMESJ-UHFFFAOYSA-N 0.000 description 2
- 239000001768 carboxy methyl cellulose Substances 0.000 description 2
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 2
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 2
- 229910017052 cobalt Inorganic materials 0.000 description 2
- 239000010941 cobalt Substances 0.000 description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 2
- 238000004891 communication Methods 0.000 description 2
- 239000007799 cork Substances 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 230000002999 depolarising effect Effects 0.000 description 2
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 2
- XXJWXESWEXIICW-UHFFFAOYSA-N diethylene glycol monoethyl ether Chemical compound CCOCCOCCO XXJWXESWEXIICW-UHFFFAOYSA-N 0.000 description 2
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 2
- 238000003618 dip coating Methods 0.000 description 2
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 2
- 239000002270 dispersing agent Substances 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- 229920001971 elastomer Polymers 0.000 description 2
- 150000002170 ethers Chemical class 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- 239000011888 foil Substances 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- LNTHITQWFMADLM-UHFFFAOYSA-N gallic acid Chemical compound OC(=O)C1=CC(O)=C(O)C(O)=C1 LNTHITQWFMADLM-UHFFFAOYSA-N 0.000 description 2
- 150000002334 glycols Chemical class 0.000 description 2
- 239000010439 graphite Substances 0.000 description 2
- 229910002804 graphite Inorganic materials 0.000 description 2
- 229910052735 hafnium Inorganic materials 0.000 description 2
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 2
- 229940051250 hexylene glycol Drugs 0.000 description 2
- 229910052741 iridium Inorganic materials 0.000 description 2
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 2
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 2
- 229960004592 isopropanol Drugs 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- 229910052749 magnesium Inorganic materials 0.000 description 2
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 description 2
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 2
- 239000002923 metal particle Substances 0.000 description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- KRDOSDPABCAONA-UHFFFAOYSA-N n-anilinooxyaniline Chemical compound C=1C=CC=CC=1NONC1=CC=CC=C1 KRDOSDPABCAONA-UHFFFAOYSA-N 0.000 description 2
- ZKATWMILCYLAPD-UHFFFAOYSA-N niobium pentoxide Inorganic materials O=[Nb](=O)O[Nb](=O)=O ZKATWMILCYLAPD-UHFFFAOYSA-N 0.000 description 2
- 150000004767 nitrides Chemical class 0.000 description 2
- 150000002825 nitriles Chemical class 0.000 description 2
- VIKNJXKGJWUCNN-XGXHKTLJSA-N norethisterone Chemical compound O=C1CC[C@@H]2[C@H]3CC[C@](C)([C@](CC4)(O)C#C)[C@@H]4[C@@H]3CCC2=C1 VIKNJXKGJWUCNN-XGXHKTLJSA-N 0.000 description 2
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 2
- 235000021313 oleic acid Nutrition 0.000 description 2
- 229910052762 osmium Inorganic materials 0.000 description 2
- SYQBFIAQOQZEGI-UHFFFAOYSA-N osmium atom Chemical compound [Os] SYQBFIAQOQZEGI-UHFFFAOYSA-N 0.000 description 2
- 239000003002 pH adjusting agent Substances 0.000 description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
- 229920001223 polyethylene glycol Polymers 0.000 description 2
- 239000002491 polymer binding agent Substances 0.000 description 2
- 239000002685 polymerization catalyst Substances 0.000 description 2
- 229920000128 polypyrrole Polymers 0.000 description 2
- 239000004810 polytetrafluoroethylene Substances 0.000 description 2
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- KWYUFKZDYYNOTN-UHFFFAOYSA-M potassium hydroxide Inorganic materials [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 2
- 239000002243 precursor Substances 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- FVSKHRXBFJPNKK-UHFFFAOYSA-N propionitrile Chemical compound CCC#N FVSKHRXBFJPNKK-UHFFFAOYSA-N 0.000 description 2
- 239000012260 resinous material Substances 0.000 description 2
- 230000004044 response Effects 0.000 description 2
- 229910052702 rhenium Inorganic materials 0.000 description 2
- WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 description 2
- 229910052703 rhodium Inorganic materials 0.000 description 2
- 239000010948 rhodium Substances 0.000 description 2
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 2
- 229910052707 ruthenium Inorganic materials 0.000 description 2
- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 description 2
- 238000007650 screen-printing Methods 0.000 description 2
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Inorganic materials [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 2
- 125000006850 spacer group Chemical group 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- HXJUTPCZVOIRIF-UHFFFAOYSA-N sulfolane Chemical compound O=S1(=O)CCCC1 HXJUTPCZVOIRIF-UHFFFAOYSA-N 0.000 description 2
- 150000003457 sulfones Chemical class 0.000 description 2
- 150000003462 sulfoxides Chemical class 0.000 description 2
- 230000001629 suppression Effects 0.000 description 2
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 2
- 229920001169 thermoplastic Polymers 0.000 description 2
- 229920006259 thermoplastic polyimide Polymers 0.000 description 2
- 229910052718 tin Inorganic materials 0.000 description 2
- 239000011135 tin Substances 0.000 description 2
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 2
- SRPWOOOHEPICQU-UHFFFAOYSA-N trimellitic anhydride Chemical compound OC(=O)C1=CC=C2C(=O)OC(=O)C2=C1 SRPWOOOHEPICQU-UHFFFAOYSA-N 0.000 description 2
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 2
- 229910052721 tungsten Inorganic materials 0.000 description 2
- 239000010937 tungsten Substances 0.000 description 2
- 238000003466 welding Methods 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
- 239000011701 zinc Substances 0.000 description 2
- 229910052726 zirconium Inorganic materials 0.000 description 2
- BWRBVBFLFQKBPT-UHFFFAOYSA-N (2-nitrophenyl)methanol Chemical compound OCC1=CC=CC=C1[N+]([O-])=O BWRBVBFLFQKBPT-UHFFFAOYSA-N 0.000 description 1
- CUXYLFPMQMFGPL-UHFFFAOYSA-N (9Z,11E,13E)-9,11,13-Octadecatrienoic acid Natural products CCCCC=CC=CC=CCCCCCCCC(O)=O CUXYLFPMQMFGPL-UHFFFAOYSA-N 0.000 description 1
- OYHQOLUKZRVURQ-NTGFUMLPSA-N (9Z,12Z)-9,10,12,13-tetratritiooctadeca-9,12-dienoic acid Chemical compound C(CCCCCCC\C(=C(/C\C(=C(/CCCCC)\[3H])\[3H])\[3H])\[3H])(=O)O OYHQOLUKZRVURQ-NTGFUMLPSA-N 0.000 description 1
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 1
- WBYWAXJHAXSJNI-VOTSOKGWSA-M .beta-Phenylacrylic acid Natural products [O-]C(=O)\C=C\C1=CC=CC=C1 WBYWAXJHAXSJNI-VOTSOKGWSA-M 0.000 description 1
- 125000001140 1,4-phenylene group Chemical group [H]C1=C([H])C([*:2])=C([H])C([H])=C1[*:1] 0.000 description 1
- CBCKQZAAMUWICA-UHFFFAOYSA-N 1,4-phenylenediamine Chemical compound NC1=CC=C(N)C=C1 CBCKQZAAMUWICA-UHFFFAOYSA-N 0.000 description 1
- SUGXZLKUDLDTKX-UHFFFAOYSA-N 1-(2-nitrophenyl)ethanone Chemical compound CC(=O)C1=CC=CC=C1[N+]([O-])=O SUGXZLKUDLDTKX-UHFFFAOYSA-N 0.000 description 1
- ARKIFHPFTHVKDT-UHFFFAOYSA-N 1-(3-nitrophenyl)ethanone Chemical compound CC(=O)C1=CC=CC([N+]([O-])=O)=C1 ARKIFHPFTHVKDT-UHFFFAOYSA-N 0.000 description 1
- HXKKHQJGJAFBHI-UHFFFAOYSA-N 1-aminopropan-2-ol Chemical compound CC(O)CN HXKKHQJGJAFBHI-UHFFFAOYSA-N 0.000 description 1
- RTBFRGCFXZNCOE-UHFFFAOYSA-N 1-methylsulfonylpiperidin-4-one Chemical compound CS(=O)(=O)N1CCC(=O)CC1 RTBFRGCFXZNCOE-UHFFFAOYSA-N 0.000 description 1
- KKTRZAZFCRHFFW-UHFFFAOYSA-N 1-nitrocyclohexa-3,5-diene-1,2-dicarboxylic acid Chemical compound OC(=O)C1C=CC=CC1(C(O)=O)[N+]([O-])=O KKTRZAZFCRHFFW-UHFFFAOYSA-N 0.000 description 1
- GKWLILHTTGWKLQ-UHFFFAOYSA-N 2,3-dihydrothieno[3,4-b][1,4]dioxine Chemical compound O1CCOC2=CSC=C21 GKWLILHTTGWKLQ-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 1
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 1
- LBLYYCQCTBFVLH-UHFFFAOYSA-N 2-Methylbenzenesulfonic acid Chemical compound CC1=CC=CC=C1S(O)(=O)=O LBLYYCQCTBFVLH-UHFFFAOYSA-N 0.000 description 1
- WXHLLJAMBQLULT-UHFFFAOYSA-N 2-[[6-[4-(2-hydroxyethyl)piperazin-1-yl]-2-methylpyrimidin-4-yl]amino]-n-(2-methyl-6-sulfanylphenyl)-1,3-thiazole-5-carboxamide;hydrate Chemical compound O.C=1C(N2CCN(CCO)CC2)=NC(C)=NC=1NC(S1)=NC=C1C(=O)NC1=C(C)C=CC=C1S WXHLLJAMBQLULT-UHFFFAOYSA-N 0.000 description 1
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 description 1
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 1
- HDTYPEMKRNDJSO-UHFFFAOYSA-N 2-methyl-n-(2-methylanilino)oxyaniline Chemical compound CC1=CC=CC=C1NONC1=CC=CC=C1C HDTYPEMKRNDJSO-UHFFFAOYSA-N 0.000 description 1
- JOMNTHCQHJPVAZ-UHFFFAOYSA-N 2-methylpiperazine Chemical compound CC1CNCCN1 JOMNTHCQHJPVAZ-UHFFFAOYSA-N 0.000 description 1
- CFBYEGUGFPZCNF-UHFFFAOYSA-N 2-nitroanisole Chemical compound COC1=CC=CC=C1[N+]([O-])=O CFBYEGUGFPZCNF-UHFFFAOYSA-N 0.000 description 1
- CMWKITSNTDAEDT-UHFFFAOYSA-N 2-nitrobenzaldehyde Chemical compound [O-][N+](=O)C1=CC=CC=C1C=O CMWKITSNTDAEDT-UHFFFAOYSA-N 0.000 description 1
- IQUPABOKLQSFBK-UHFFFAOYSA-N 2-nitrophenol Chemical compound OC1=CC=CC=C1[N+]([O-])=O IQUPABOKLQSFBK-UHFFFAOYSA-N 0.000 description 1
- AGBXYHCHUYARJY-UHFFFAOYSA-N 2-phenylethenesulfonic acid Chemical compound OS(=O)(=O)C=CC1=CC=CC=C1 AGBXYHCHUYARJY-UHFFFAOYSA-N 0.000 description 1
- WGYFINWERLNPHR-UHFFFAOYSA-N 3-nitroanisole Chemical compound COC1=CC=CC([N+]([O-])=O)=C1 WGYFINWERLNPHR-UHFFFAOYSA-N 0.000 description 1
- ZETIVVHRRQLWFW-UHFFFAOYSA-N 3-nitrobenzaldehyde Chemical compound [O-][N+](=O)C1=CC=CC(C=O)=C1 ZETIVVHRRQLWFW-UHFFFAOYSA-N 0.000 description 1
- CWNPOQFCIIFQDM-UHFFFAOYSA-N 3-nitrobenzyl alcohol Chemical compound OCC1=CC=CC([N+]([O-])=O)=C1 CWNPOQFCIIFQDM-UHFFFAOYSA-N 0.000 description 1
- RTZZCYNQPHTPPL-UHFFFAOYSA-N 3-nitrophenol Chemical compound OC1=CC=CC([N+]([O-])=O)=C1 RTZZCYNQPHTPPL-UHFFFAOYSA-N 0.000 description 1
- KFIRODWJCYBBHY-UHFFFAOYSA-N 3-nitrophthalic acid Chemical compound OC(=O)C1=CC=CC([N+]([O-])=O)=C1C(O)=O KFIRODWJCYBBHY-UHFFFAOYSA-N 0.000 description 1
- UCSYVYFGMFODMY-UHFFFAOYSA-N 3-phenoxyaniline Chemical compound NC1=CC=CC(OC=2C=CC=CC=2)=C1 UCSYVYFGMFODMY-UHFFFAOYSA-N 0.000 description 1
- YBRVSVVVWCFQMG-UHFFFAOYSA-N 4,4'-diaminodiphenylmethane Chemical compound C1=CC(N)=CC=C1CC1=CC=C(N)C=C1 YBRVSVVVWCFQMG-UHFFFAOYSA-N 0.000 description 1
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
- ALYNCZNDIQEVRV-UHFFFAOYSA-N 4-aminobenzoic acid Chemical compound NC1=CC=C(C(O)=O)C=C1 ALYNCZNDIQEVRV-UHFFFAOYSA-N 0.000 description 1
- 229940090248 4-hydroxybenzoic acid Drugs 0.000 description 1
- YQYGPGKTNQNXMH-UHFFFAOYSA-N 4-nitroacetophenone Chemical compound CC(=O)C1=CC=C([N+]([O-])=O)C=C1 YQYGPGKTNQNXMH-UHFFFAOYSA-N 0.000 description 1
- BXRFQSNOROATLV-UHFFFAOYSA-N 4-nitrobenzaldehyde Chemical compound [O-][N+](=O)C1=CC=C(C=O)C=C1 BXRFQSNOROATLV-UHFFFAOYSA-N 0.000 description 1
- JKTYGPATCNUWKN-UHFFFAOYSA-N 4-nitrobenzyl alcohol Chemical compound OCC1=CC=C([N+]([O-])=O)C=C1 JKTYGPATCNUWKN-UHFFFAOYSA-N 0.000 description 1
- BTJIUGUIPKRLHP-UHFFFAOYSA-N 4-nitrophenol Chemical compound OC1=CC=C([N+]([O-])=O)C=C1 BTJIUGUIPKRLHP-UHFFFAOYSA-N 0.000 description 1
- SLBQXWXKPNIVSQ-UHFFFAOYSA-N 4-nitrophthalic acid Chemical compound OC(=O)C1=CC=C([N+]([O-])=O)C=C1C(O)=O SLBQXWXKPNIVSQ-UHFFFAOYSA-N 0.000 description 1
- WOYZXEVUWXQVNV-UHFFFAOYSA-N 4-phenoxyaniline Chemical compound C1=CC(N)=CC=C1OC1=CC=CC=C1 WOYZXEVUWXQVNV-UHFFFAOYSA-N 0.000 description 1
- QRRSIFNWHCKMSW-UHFFFAOYSA-N 5-methyl-2-nitrobenzoic acid Chemical compound CC1=CC=C([N+]([O-])=O)C(C(O)=O)=C1 QRRSIFNWHCKMSW-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- 239000005711 Benzoic acid Substances 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- UMUMWEUDHJGQPK-UHFFFAOYSA-N C(C1=CC=CC=C1)=C1C(C2=CC=CC(=C2C=C1)N)N Chemical compound C(C1=CC=CC=C1)=C1C(C2=CC=CC(=C2C=C1)N)N UMUMWEUDHJGQPK-UHFFFAOYSA-N 0.000 description 1
- 150000000703 Cerium Chemical class 0.000 description 1
- WBYWAXJHAXSJNI-SREVYHEPSA-N Cinnamic acid Chemical compound OC(=O)\C=C/C1=CC=CC=C1 WBYWAXJHAXSJNI-SREVYHEPSA-N 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- RGHNJXZEOKUKBD-UHFFFAOYSA-N D-gluconic acid Natural products OCC(O)C(O)C(O)C(O)C(O)=O RGHNJXZEOKUKBD-UHFFFAOYSA-N 0.000 description 1
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 1
- 240000001624 Espostoa lanata Species 0.000 description 1
- 235000009161 Espostoa lanata Nutrition 0.000 description 1
- VTLYFUHAOXGGBS-UHFFFAOYSA-N Fe3+ Chemical compound [Fe+3] VTLYFUHAOXGGBS-UHFFFAOYSA-N 0.000 description 1
- RGHNJXZEOKUKBD-SQOUGZDYSA-N Gluconic acid Natural products OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)=O RGHNJXZEOKUKBD-SQOUGZDYSA-N 0.000 description 1
- WHUUTDBJXJRKMK-UHFFFAOYSA-N Glutamic acid Natural products OC(=O)C(N)CCC(O)=O WHUUTDBJXJRKMK-UHFFFAOYSA-N 0.000 description 1
- CKLJMWTZIZZHCS-REOHCLBHSA-N L-aspartic acid Chemical compound OC(=O)[C@@H](N)CC(O)=O CKLJMWTZIZZHCS-REOHCLBHSA-N 0.000 description 1
- WHUUTDBJXJRKMK-VKHMYHEASA-N L-glutamic acid Chemical compound OC(=O)[C@@H](N)CCC(O)=O WHUUTDBJXJRKMK-VKHMYHEASA-N 0.000 description 1
- 239000005639 Lauric acid Substances 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 1
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 1
- 229920000557 Nafion® Polymers 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- BNUHAJGCKIQFGE-UHFFFAOYSA-N Nitroanisol Chemical compound COC1=CC=C([N+]([O-])=O)C=C1 BNUHAJGCKIQFGE-UHFFFAOYSA-N 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 239000002033 PVDF binder Substances 0.000 description 1
- 235000021314 Palmitic acid Nutrition 0.000 description 1
- 229920002845 Poly(methacrylic acid) Polymers 0.000 description 1
- 239000004962 Polyamide-imide Substances 0.000 description 1
- 239000004642 Polyimide Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 229920001800 Shellac Polymers 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 1
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- 229920004738 ULTEM® Polymers 0.000 description 1
- 150000008065 acid anhydrides Chemical class 0.000 description 1
- 229920005822 acrylic binder Polymers 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 239000000783 alginic acid Substances 0.000 description 1
- 229920000615 alginic acid Polymers 0.000 description 1
- 235000010443 alginic acid Nutrition 0.000 description 1
- 229960001126 alginic acid Drugs 0.000 description 1
- 150000004781 alginic acids Chemical class 0.000 description 1
- 229910000272 alkali metal oxide Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 229910001860 alkaline earth metal hydroxide Inorganic materials 0.000 description 1
- 229910052915 alkaline earth metal silicate Inorganic materials 0.000 description 1
- 125000005907 alkyl ester group Chemical group 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- CUXYLFPMQMFGPL-SUTYWZMXSA-N all-trans-octadeca-9,11,13-trienoic acid Chemical compound CCCC\C=C\C=C\C=C\CCCCCCCC(O)=O CUXYLFPMQMFGPL-SUTYWZMXSA-N 0.000 description 1
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 description 1
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 description 1
- DTOSIQBPPRVQHS-PDBXOOCHSA-N alpha-linolenic acid Chemical compound CC\C=C/C\C=C/C\C=C/CCCCCCCC(O)=O DTOSIQBPPRVQHS-PDBXOOCHSA-N 0.000 description 1
- 235000020661 alpha-linolenic acid Nutrition 0.000 description 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
- 229960004050 aminobenzoic acid Drugs 0.000 description 1
- JFCQEDHGNNZCLN-UHFFFAOYSA-N anhydrous glutaric acid Natural products OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 description 1
- 229920006318 anionic polymer Polymers 0.000 description 1
- 238000007743 anodising Methods 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000012300 argon atmosphere Substances 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 235000003704 aspartic acid Nutrition 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- CFJRGWXELQQLSA-UHFFFAOYSA-N azanylidyneniobium Chemical compound [Nb]#N CFJRGWXELQQLSA-UHFFFAOYSA-N 0.000 description 1
- HNYOPLTXPVRDBG-UHFFFAOYSA-N barbituric acid Chemical compound O=C1CC(=O)NC(=O)N1 HNYOPLTXPVRDBG-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- SRSXLGNVWSONIS-UHFFFAOYSA-N benzenesulfonic acid Chemical compound OS(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-N 0.000 description 1
- 229940092714 benzenesulfonic acid Drugs 0.000 description 1
- MVIOINXPSFUJEN-UHFFFAOYSA-N benzenesulfonic acid;hydrate Chemical compound O.OS(=O)(=O)C1=CC=CC=C1 MVIOINXPSFUJEN-UHFFFAOYSA-N 0.000 description 1
- 235000010233 benzoic acid Nutrition 0.000 description 1
- 229960004365 benzoic acid Drugs 0.000 description 1
- OQFSQFPPLPISGP-UHFFFAOYSA-N beta-carboxyaspartic acid Natural products OC(=O)C(N)C(C(O)=O)C(O)=O OQFSQFPPLPISGP-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 1
- 239000004327 boric acid Substances 0.000 description 1
- ZADPBFCGQRWHPN-UHFFFAOYSA-N boronic acid Chemical compound OBO ZADPBFCGQRWHPN-UHFFFAOYSA-N 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical class [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 description 1
- 159000000007 calcium salts Chemical class 0.000 description 1
- 238000007707 calorimetry Methods 0.000 description 1
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 238000009750 centrifugal casting Methods 0.000 description 1
- 238000001311 chemical methods and process Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- 235000013985 cinnamic acid Nutrition 0.000 description 1
- 229930016911 cinnamic acid Natural products 0.000 description 1
- 235000015165 citric acid Nutrition 0.000 description 1
- 239000011300 coal pitch Substances 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 150000001879 copper Chemical class 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 229920006037 cross link polymer Polymers 0.000 description 1
- 238000002484 cyclic voltammetry Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 230000000994 depressogenic effect Effects 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- ZOMNIUBKTOKEHS-UHFFFAOYSA-L dimercury dichloride Chemical class Cl[Hg][Hg]Cl ZOMNIUBKTOKEHS-UHFFFAOYSA-L 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000000313 electron-beam-induced deposition Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 150000002190 fatty acyls Chemical group 0.000 description 1
- 235000019253 formic acid Nutrition 0.000 description 1
- 229940074391 gallic acid Drugs 0.000 description 1
- 235000004515 gallic acid Nutrition 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 239000000174 gluconic acid Substances 0.000 description 1
- 235000012208 gluconic acid Nutrition 0.000 description 1
- 235000013922 glutamic acid Nutrition 0.000 description 1
- 239000004220 glutamic acid Substances 0.000 description 1
- 125000005456 glyceride group Chemical group 0.000 description 1
- PEDCQBHIVMGVHV-UHFFFAOYSA-N glycerol group Chemical group OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 150000003949 imides Chemical class 0.000 description 1
- 238000002847 impedance measurement Methods 0.000 description 1
- 238000007373 indentation Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 150000002505 iron Chemical class 0.000 description 1
- 229940102253 isopropanolamine Drugs 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- 150000002603 lanthanum Chemical class 0.000 description 1
- HEPLMSKRHVKCAQ-UHFFFAOYSA-N lead nickel Chemical compound [Ni].[Pb] HEPLMSKRHVKCAQ-UHFFFAOYSA-N 0.000 description 1
- 229960004488 linolenic acid Drugs 0.000 description 1
- KQQKGWQCNNTQJW-UHFFFAOYSA-N linolenic acid Natural products CC=CCCC=CCC=CCCCCCCCC(O)=O KQQKGWQCNNTQJW-UHFFFAOYSA-N 0.000 description 1
- 239000000944 linseed oil Substances 0.000 description 1
- 235000021388 linseed oil Nutrition 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000011244 liquid electrolyte Substances 0.000 description 1
- 229910052912 lithium silicate Inorganic materials 0.000 description 1
- 229940018564 m-phenylenediamine Drugs 0.000 description 1
- 159000000003 magnesium salts Chemical class 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 239000001630 malic acid Substances 0.000 description 1
- 235000011090 malic acid Nutrition 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000000873 masking effect Effects 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 229910052914 metal silicate Inorganic materials 0.000 description 1
- 229940098779 methanesulfonic acid Drugs 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- WBYWAXJHAXSJNI-UHFFFAOYSA-N methyl p-hydroxycinnamate Natural products OC(=O)C=CC1=CC=CC=C1 WBYWAXJHAXSJNI-UHFFFAOYSA-N 0.000 description 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 229910052755 nonmetal Inorganic materials 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 239000004006 olive oil Substances 0.000 description 1
- 235000008390 olive oil Nutrition 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- BPUBBGLMJRNUCC-UHFFFAOYSA-N oxygen(2-);tantalum(5+) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[Ta+5].[Ta+5] BPUBBGLMJRNUCC-UHFFFAOYSA-N 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 239000011301 petroleum pitch Substances 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 229920000083 poly(allylamine) Polymers 0.000 description 1
- 229920001197 polyacetylene Polymers 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 229920002312 polyamide-imide Polymers 0.000 description 1
- 229920000767 polyaniline Polymers 0.000 description 1
- 238000012643 polycondensation polymerization Methods 0.000 description 1
- 229920001601 polyetherimide Polymers 0.000 description 1
- 229920001721 polyimide Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920000123 polythiophene Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 235000019260 propionic acid Nutrition 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
- 238000006722 reduction reaction Methods 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 229910001925 ruthenium oxide Inorganic materials 0.000 description 1
- 229960004889 salicylic acid Drugs 0.000 description 1
- 235000003441 saturated fatty acids Nutrition 0.000 description 1
- 150000004671 saturated fatty acids Chemical class 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000004208 shellac Substances 0.000 description 1
- ZLGIYFNHBLSMPS-ATJNOEHPSA-N shellac Chemical compound OCCCCCC(O)C(O)CCCCCCCC(O)=O.C1C23[C@H](C(O)=O)CCC2[C@](C)(CO)[C@@H]1C(C(O)=O)=C[C@@H]3O ZLGIYFNHBLSMPS-ATJNOEHPSA-N 0.000 description 1
- 235000013874 shellac Nutrition 0.000 description 1
- 229940113147 shellac Drugs 0.000 description 1
- 239000002893 slag Substances 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 238000004544 sputter deposition Methods 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 159000000008 strontium salts Chemical class 0.000 description 1
- 229920001909 styrene-acrylic polymer Polymers 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 150000003460 sulfonic acids Chemical class 0.000 description 1
- MZLGASXMSKOWSE-UHFFFAOYSA-N tantalum nitride Chemical compound [Ta]#N MZLGASXMSKOWSE-UHFFFAOYSA-N 0.000 description 1
- 229910001936 tantalum oxide Inorganic materials 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- 125000005270 trialkylamine group Chemical group 0.000 description 1
- IMFACGCPASFAPR-UHFFFAOYSA-N tributylamine Chemical compound CCCCN(CCCC)CCCC IMFACGCPASFAPR-UHFFFAOYSA-N 0.000 description 1
- ITMCEJHCFYSIIV-UHFFFAOYSA-N triflic acid Chemical compound OS(=O)(=O)C(F)(F)F ITMCEJHCFYSIIV-UHFFFAOYSA-N 0.000 description 1
- 239000002383 tung oil Substances 0.000 description 1
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 1
- 150000004670 unsaturated fatty acids Chemical class 0.000 description 1
- 238000001771 vacuum deposition Methods 0.000 description 1
- 239000004034 viscosity adjusting agent Substances 0.000 description 1
- 150000003746 yttrium Chemical class 0.000 description 1
- 150000003751 zinc Chemical class 0.000 description 1
- 150000003754 zirconium Chemical class 0.000 description 1
Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G9/00—Electrolytic capacitors, rectifiers, detectors, switching devices, light-sensitive or temperature-sensitive devices; Processes of their manufacture
- H01G9/004—Details
- H01G9/022—Electrolytes; Absorbents
- H01G9/035—Liquid electrolytes, e.g. impregnating materials
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G9/00—Electrolytic capacitors, rectifiers, detectors, switching devices, light-sensitive or temperature-sensitive devices; Processes of their manufacture
- H01G9/004—Details
- H01G9/022—Electrolytes; Absorbents
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G9/00—Electrolytic capacitors, rectifiers, detectors, switching devices, light-sensitive or temperature-sensitive devices; Processes of their manufacture
- H01G9/145—Liquid electrolytic capacitors
Landscapes
- Engineering & Computer Science (AREA)
- Power Engineering (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Electric Double-Layer Capacitors Or The Like (AREA)
Description
始めに、以下の組成からセラミックボディを形成した。
材料 重量%
脱イオン(DI)水 19.05
非イオン性界面活性剤 0.19
アニオンポリマー分散剤 1.30
アクリルバインダー 9.76
Nb2O5粉末 69.70
湿式電解コンデンサを、例1のセラミックボディから形成した。始めに、ステンレス鋼メッシュ(McMasterから入手した150×150メッシュ)を、2.2 cm×1.1 cmの矩形に切断した。カソードリード線(150μmゲージの焼なまししたステンレス鋼304ワイヤー)を、2.5 cmの長さに切断した。これらの矩形及びワイヤーを、先ず超音波浴内で45°Cの石鹸水を使用して30分間洗浄し、次いで脱イオン(“DI”)水を用いて4回すすいだ。85°Cのオーブン内で30分間に亘って乾燥した後に、サンプルを外界温度のアセトン内で20分間に亘って再度脱脂した。サンプルを85°Cのオーブン内で乾燥して残留アセトンの全てを除去し、DI水で5回すすぎ、次いで85°Cのオーブン内で乾燥した。矩形メッシュの1.1 cmの辺の中央に、スポット溶接機を使用してカソードリード線を溶接した。深さは約1.0 mmであった。次いで、矩形メッシュを1.0体積%のH2SO4及び0.1体積%のHClの溶液内において1分間に亘ってエッチングし、DI水で45回脱脂し、次いでブロワーを用いて外界温度で乾燥させた。得られたメッシュ基体の厚みは、約130μmであった。
C=1/(2×π×f×Z”)
但し、
C:容量(F)
f:周波数(Hz)
Z”:インピーダンスの虚数部分(Ω)
である。
C=ΔQ/ΔU
但し、
C:カソード容量
Q:電荷
U:カソード電位
である。
例2に記述したようにしてコンデンサを形成した。但し、カソードインク内にカーボンブラックは使用しなかった。得られたカソードローディングは、0.0107 gであった。0.1Hzにおいて測定された容量は、2.0V、5.0V、及び8.0Vのバイアスに対してそれぞれ、2.57 mF、2.42 mF、及び2.37 mFであった。ESRは1000Hzの周波数において1.98Ωであった。カソード容量は550.0 mFであると推定された。
例2に記述したようにしてコンデンサを形成した。但し、1.0 gのTorlon TF 4000を添加した。カソードローディングは、0.0113 gであった。0.1Hzにおいて測定された容量は、2.0V、5.0V、及び8.0Vのバイアスに対してそれぞれ、2.54 mF、2.41 mF、及び2.35 mFであった。ESRは1000Hzの周波数において1.35Ωであった。カソード容量は550.0 mFであると推定された。
例2に記述したようにしてコンデンサを形成した。但し、0.4 gのアセチレンカーボン(Chevron)を導電性充填材として使用した。カソードローディングは、0.0060 gであった。0.1Hzにおいて測定された容量は、2.0V、5.0V、及び8.0Vのバイアスに対してそれぞれ、2.60 mF、2.36 mF、及び2.23 mFであった。ESRは1000Hzの周波数において1.15Ωであった。カソード容量は500.0 mFであると推定された。
例5に記述したようにしてコンデンサを形成した。但し、ステンレス鋼メッシュは、SS Monel 304 120×120メッシュであった。カソードローディングは、0.0074 gであった。0.1Hzにおいて測定された容量は、2.0V、5.0V、及び8.0Vのバイアスに対してそれぞれ、2.64 mF、2.46 mF、及び2.39 mFであった。ESRは1000Hzの周波数において1.24Ωであった。カソード容量は403.4 mFであると推定された。
例6に記述したようにしてコンデンサを形成した。但し、ステンレス鋼メッシュは、SS Monel 316 150×150メッシュであった。0.1Hzにおいて測定された容量は、2.0V、5.0V、及び8.0Vのバイアスに対してそれぞれ、2.69 mF、2.47 mF、及び2.37 mFであった。ESRは1000Hzの周波数において1.24Ωであった。カソード容量は384.9 mFであると推定された。
例5に記述したようにしてコンデンサを形成した。但し、カソード基体は110 PPI(Inco)のニッケルフォームであった。カソードローディングは、0.013 gであった。0.1Hzにおいて測定された容量は、2.0V、5.0V、及び8.0Vのバイアスに対してそれぞれ、2.66 mF、2.37 mF、及び2.28 mFであった。ESRは1000Hzの周波数において1.13Ωであった。カソード容量は1250 mFであると推定された。
例7に記述したようにしてコンデンサを形成した。但し、0.4 gのBP2000カーボンブラックを導電性充填材として使用した。カソードローディングは、0.074 gであった。0.1Hzにおいて測定された容量は、2.0V、5.0V、及び8.0Vのバイアスに対してそれぞれ、2.54 mF、2.38 mF、及び2.32 mFであった。ESRは1000Hzの周波数において1.16Ωであった。カソード容量は372.3 mFであると推定された。
10片のNbOアノード、11片のカソード、及び20片のセパレータ紙を例2に記述したようにして準備し、カソード、セパレータ、及びアノードの順序にスタックした。各矩形アノードの長さは11.0 mm、幅は11.0 mm、そして厚みは0.7 mmであった。アノードのサイズに一致させるために、カソードも11.0 mm平方に切断した。例2と同一のサイズのセパレータ紙は単にU字形に折り曲げ、アノードの片を包み込んだ。アノードリード線及びカソードリード線は、スタックから反対方向に引き出した。スタック全体をScotchテープの片で包んだ。アノードのタンタルリード線及びカソードのステンレス鋼リード線は全て6.0 mmの長さに切り揃えた。アノードリード線は直径0.2 mmの1本のヘビーゲージのステンレス鋼ワイヤーに溶接し、カソードリード線は別のワイヤーに溶接した。スタックの厚みは10.0 mmであった。アノード・セパレータ・カソードアセンブリは、例2において使用した水性電解質内で30分間に亘って真空含浸させた。0.1Hzにおいて測定された容量は、2.0V、5.0V、及び8.0Vのバイアスに対してそれぞれ、14.53 mF、12.84 mF、及び12.34 mFであった。1000Hzの周波数におけるESRは0.22Ωであった。
アノード及びカソードを例2に記述したようにして準備したが、寸法は若干変更されている。即ち、アノード及びカソード基体は、1.0 cm平方に切断した。例2と同一のサイズのセパレータ紙をU字形に折り曲げ、アノードを包み込んだ。図2に示すように、2つのNbOアノードを3つのカソードと共に水平にスタックした。アノードのタンタルリード線及びカソードのステンレス鋼リード線は6.0 mmの長さに切り揃えた。レーザー溶接機を使用し、アルゴン雰囲気保護の下で、アノードタンタルリード線は直径0.2 mmのヘビーゲージのタンタルワイヤーに溶接し、カソードステンレス鋼リード線はヘビーゲージのステンレス鋼ワイヤーに溶接した。両ヘビーゲージ線は、スポット溶接機を使用してニオブロッドに溶接した。次いで、ニッケルリード線をこれらのニオブロッドに溶接した。次に、このアセンブリをScotchテープで包んで圧縮を高め、ケース内に挿入する前に作用電解質(以下の表2に記載)内で30分間に亘って真空含浸させた。
アノード及びカソードを例2に記述したようにして準備した。アノードは、5.16 mm×3.88 mm×0.58 mmの矩形にスライスした。これらのアノードの形成に2つの異なる形成用電解質を使用した。電解質は、1.0重量%のH3PO4(リン酸)と、0.5重量%のH3PO4+0.5重量%のH5PO4(ポリリン酸)の混合体とであった。これらのアノードを、先ず24V、85°Cで120分に亘ってアノード酸化処理した。若干のアノードは、後に真空焼なまし及び/または表1に示すような第2の調剤を通過させた。容量は、「ガルバノスタティック充電/放電」法を使用し、例11に記載した電解質B内の大きいTaスラグカソードに対するこれらのアノードの直流セル容量を測定することによって決定した。漏洩電流は、1.0重量%のH3PO4内で測定した。2.0Vのバイアスにおける直流容量、及び16Vの定格電圧を印加してから2時間後に測定した漏洩電流を使用して、85°Cにおける正規化された漏洩電流を計算した。その結果を、以下の表4に示す。
21 誘電体フィルム
23 シール
40 コンデンサ
41 カソード電流コレクタ
42 アノードリード線
43 カソード
44 作用電解質
62 アノードリード線
64 カソード
65 アノード
72 カソードリード線
100 アノードのアレイ
117 セパレータ
119 コンテナ
121 コンテナのトップ
123 コンテナのボトム
125 蓋
127 シール部材
144 作用電解質
162 アノード端子
172 カソード端子
175 導電性ロッド
200 コンデンサ
Claims (11)
- 湿式電解コンデンサであって、
アノードと、
カソード電流コレクタと、
上記カソード電流コレクタと上記アノードとの間に配置されている作用電解質と、
を含み、
上記作用電解質は、ニトロ芳香族減極剤を上記電解質の1乃至200 ppm含み、
上記電解質は、5.0から8.0までのpHと、25°Cの温度において決定された10ミリジーメンス/センチメートルまたはそれ以上の導電率とを有していることを特徴とする湿式電解コンデンサ。 - 上記pHは、5.5から7.5までであることを特徴とする請求項1に記載の湿式電解コンデンサ。
- 上記導電率は、30ミリジーメンス/センチメートルまたはそれ以上であることを特徴とする請求項1又は2に記載の湿式電解コンデンサ。
- 上記作用電解質は、水性溶剤からなることを特徴とする請求項1〜3のいずれか1項に記載の湿式電解コンデンサ。
- 上記水性溶剤は、脱イオン水を含むことを特徴とする請求項4に記載の湿式電解コンデンサ。
- 上記作用電解質はイオン化合物を含み、上記イオン化合物は、無機酸、有機酸、それらの無水物または塩、またはこれらの何れかの混合物を含むことを特徴とする請求項1〜5のいずれか1項に記載の湿式電解コンデンサ。
- 上記作用電解質は、更に、塩基性pH調節剤を含むことを特徴とする請求項1〜6のいずれか1項に記載の湿式電解コンデンサ。
- 上記作用電解質は、−20°Cまたはそれより低い凝固点と、85°Cまたはそれより高い沸点とを有していることを特徴とする請求項1〜7のいずれか1項に記載の湿式電解コンデンサ。
- 上記ニトロ芳香族減極剤は、アルキル置換ニトロ安息香酸、その無水物または塩、またはこれらの何れかの混合物を含むことを特徴とする請求項8に記載の湿式電解コンデンサ。
- 上記アルキル置換ニトロ安息香酸は、2-メチル-3-ニトロ安息香酸、2-メチル-6-ニトロ安息香酸、3-メチル-2-ニトロ安息香酸、3-メチル-4-ニトロ安息香酸、3-メチル-6-ニトロ安息香酸、または4-メチル-3-ニトロ安息香酸を含むことを特徴とする請求項9に記載の湿式電解コンデンサ。
- 上記アノードは、タンタル、ニオブ、またはそれらの導電性酸化物を含むことを特徴とする請求項1〜10のいずれか1項に記載の湿式電解コンデンサ。
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US11/725,965 | 2007-03-20 | ||
US11/725,965 US7460356B2 (en) | 2007-03-20 | 2007-03-20 | Neutral electrolyte for a wet electrolytic capacitor |
Publications (3)
Publication Number | Publication Date |
---|---|
JP2008235895A JP2008235895A (ja) | 2008-10-02 |
JP2008235895A5 JP2008235895A5 (ja) | 2011-05-06 |
JP5301181B2 true JP5301181B2 (ja) | 2013-09-25 |
Family
ID=39204259
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2008071059A Expired - Fee Related JP5301181B2 (ja) | 2007-03-20 | 2008-03-19 | 湿式電解コンデンサ用の中性電解質 |
Country Status (6)
Country | Link |
---|---|
US (1) | US7460356B2 (ja) |
JP (1) | JP5301181B2 (ja) |
KR (1) | KR20080085754A (ja) |
CN (1) | CN101271769A (ja) |
DE (1) | DE102008000330B4 (ja) |
GB (1) | GB2447724B (ja) |
Families Citing this family (33)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP4372173B2 (ja) * | 2007-03-16 | 2009-11-25 | 株式会社東芝 | 化学的機械的研磨方法および半導体装置の製造方法 |
US8023250B2 (en) | 2008-09-12 | 2011-09-20 | Avx Corporation | Substrate for use in wet capacitors |
JP5411156B2 (ja) * | 2008-10-29 | 2014-02-12 | 昭和電工株式会社 | コンデンサ素子の製造方法 |
US8279585B2 (en) | 2008-12-09 | 2012-10-02 | Avx Corporation | Cathode for use in a wet capacitor |
GB2468942B (en) * | 2009-03-23 | 2014-02-19 | Avx Corp | High voltage electrolytic capacitors |
US8405956B2 (en) | 2009-06-01 | 2013-03-26 | Avx Corporation | High voltage electrolytic capacitors |
US8223473B2 (en) * | 2009-03-23 | 2012-07-17 | Avx Corporation | Electrolytic capacitor containing a liquid electrolyte |
US20100268292A1 (en) * | 2009-04-16 | 2010-10-21 | Vishay Sprague, Inc. | Hermetically sealed wet electrolytic capacitor |
WO2011074194A1 (ja) * | 2009-12-17 | 2011-06-23 | 三洋化成工業株式会社 | 電解コンデンサ用電解液およびそれを用いた電解コンデンサ |
WO2011099261A1 (ja) | 2010-02-15 | 2011-08-18 | パナソニック株式会社 | 電解コンデンサ |
EP2550702B1 (de) * | 2010-03-24 | 2019-06-26 | Samsung SDI Co., Ltd. | Überwachungssystem für eine energiespeicherzelle |
US8824121B2 (en) * | 2010-09-16 | 2014-09-02 | Avx Corporation | Conductive polymer coating for wet electrolytic capacitor |
US8477479B2 (en) * | 2011-01-12 | 2013-07-02 | Avx Corporation | Leadwire configuration for a planar anode of a wet electrolytic capacitor |
US8687347B2 (en) * | 2011-01-12 | 2014-04-01 | Avx Corporation | Planar anode for use in a wet electrolytic capacitor |
JP6185392B2 (ja) * | 2011-02-04 | 2017-08-23 | ヴィシャイ スプレイグ, インコーポレイテッドVishay Sprague, Inc. | 密封型電界コンデンサ |
CN102956364B (zh) * | 2011-08-17 | 2015-10-28 | 海洋王照明科技股份有限公司 | 一种双电层电容器电解液以及双电层电容器 |
US9105401B2 (en) | 2011-12-02 | 2015-08-11 | Avx Corporation | Wet electrolytic capacitor containing a gelled working electrolyte |
US9941055B2 (en) * | 2012-02-27 | 2018-04-10 | Kemet Electronics Corporation | Solid electrolytic capacitor with interlayer crosslinking |
GB2512486B (en) * | 2013-03-15 | 2018-07-18 | Avx Corp | Wet electrolytic capacitor |
GB2512481B (en) | 2013-03-15 | 2018-05-30 | Avx Corp | Wet electrolytic capacitor for use at high temperatures |
US10290430B2 (en) * | 2014-11-24 | 2019-05-14 | Avx Corporation | Wet Electrolytic Capacitor for an Implantable Medical Device |
US9947479B2 (en) * | 2015-11-16 | 2018-04-17 | Vishay Sprague, Inc. | Volumetric efficiency wet electrolyte capacitor having a fill port and terminations for surface mounting |
US10176930B2 (en) | 2016-01-14 | 2019-01-08 | Vishay Sprague, Inc. | Low profile flat wet electrolytic tantalum capacitor |
US10879009B2 (en) | 2016-03-29 | 2020-12-29 | Sanyo Chemical Industries, Ltd. | Electrolyte solution for electrolytic capacitors, and electrolytic capacitor |
US9870868B1 (en) | 2016-06-28 | 2018-01-16 | Avx Corporation | Wet electrolytic capacitor for use in a subcutaneous implantable cardioverter-defibrillator |
US9870869B1 (en) | 2016-06-28 | 2018-01-16 | Avx Corporation | Wet electrolytic capacitor |
DE102017124139B4 (de) * | 2017-10-17 | 2020-02-13 | Tdk Electronics Ag | Elektrolytkondensator |
US11189431B2 (en) | 2018-07-16 | 2021-11-30 | Vishay Sprague, Inc. | Low profile wet electrolytic tantalum capacitor |
US11024464B2 (en) | 2018-08-28 | 2021-06-01 | Vishay Israel Ltd. | Hermetically sealed surface mount polymer capacitor |
CN110730994B (zh) * | 2018-10-09 | 2022-05-17 | 丰宾电子(深圳)有限公司 | 混合型铝电解电容器及其制造方法 |
EP3664113A4 (en) * | 2018-10-09 | 2021-05-19 | CapXon Electronic (Shenzhen) Co., Ltd | HYBRID ALUMINUM ELECTROLYTE CAPACITOR AND METHOD FOR MANUFACTURING THEREOF |
DE112020002426T5 (de) * | 2019-05-17 | 2022-01-27 | Avx Corporation | Festelektrolytkondensator |
US11742149B2 (en) | 2021-11-17 | 2023-08-29 | Vishay Israel Ltd. | Hermetically sealed high energy electrolytic capacitor and capacitor assemblies with improved shock and vibration performance |
Family Cites Families (158)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US187616A (en) * | 1877-02-20 | Improvement in harvesters | ||
US240149A (en) * | 1881-04-12 | Invalid-bedstead | ||
US227496A (en) * | 1880-05-11 | Henry s | ||
US134874A (en) * | 1873-01-14 | Improvement in hydraulic mains of gas-works | ||
US172774A (en) * | 1876-01-25 | Improvement in gas-regulators | ||
US177193A (en) * | 1876-05-09 | Improvement in chairs | ||
US91020A (en) * | 1869-06-08 | John horton | ||
US139850A (en) * | 1873-06-17 | Improvement in car-couplings | ||
US190530A (en) * | 1877-05-08 | Improvement in spectacles | ||
US28787A (en) * | 1860-06-19 | Spoke-machine | ||
US34299A (en) * | 1862-02-04 | Inkstand | ||
US89711A (en) * | 1869-05-04 | Improved washing-machine | ||
US243183A (en) * | 1881-06-21 | Gun-lock | ||
US90106A (en) * | 1869-05-18 | Improved composition for pavements, roofing, drain-pipes | ||
US179753A (en) * | 1876-07-11 | Improvement in shoes | ||
US240152A (en) * | 1881-04-12 | Sieve for thrashing-machines | ||
US225327A (en) * | 1880-03-09 | Signaling apparatus for tele phon e-li n es | ||
US2147A (en) * | 1841-06-26 | dircks | ||
US2582993A (en) * | 1948-10-29 | 1952-01-22 | Glenn N Howatt | Method of producing high dielectric high insulation ceramic plates |
US3082360A (en) * | 1953-05-13 | 1963-03-19 | Sprague Electric Co | Electrolytic capacitors |
US2966719A (en) * | 1954-06-15 | 1961-01-03 | American Lava Corp | Manufacture of ceramics |
US3138746A (en) * | 1960-05-02 | 1964-06-23 | Francis J P J Burger | Electrolytic capacitors and electrolyte therefor |
US3345545A (en) | 1964-11-27 | 1967-10-03 | Johnson Matthey & Mallory Ltd | Solid electrolytic capacitor having minimum anode impedance |
JPS5241465B1 (ja) * | 1967-10-25 | 1977-10-18 | ||
US3835055A (en) * | 1967-10-27 | 1974-09-10 | Safco Condensateurs | Electrolytes for low series-resistance,aluminum electrolytic capacitors |
CH515996A (de) * | 1968-06-06 | 1971-11-30 | Starck Hermann C Fa | Verfahren zur Herstellung von hochreinem Niob und/oder Tantal |
US3544434A (en) | 1968-10-29 | 1970-12-01 | Ronald R Giller | Thick film capactors for miniaturized circuitry |
US4085435A (en) * | 1976-06-14 | 1978-04-18 | Avx Corporation | Tantalum chip capacitor |
US3953703A (en) | 1974-10-03 | 1976-04-27 | Materials Research Corporation | Method for drying ceramic tape |
US4071878A (en) * | 1975-02-18 | 1978-01-31 | N L Industries, Inc. | Method for producing capacitors and ceramic body therefore |
US4214071A (en) * | 1975-04-11 | 1980-07-22 | Westinghouse Electric Corp. | Amide-imide polymers |
US4031436A (en) * | 1975-05-09 | 1977-06-21 | United Chemi-Con, Inc. | Electrolyte capacitors |
US4109377A (en) | 1976-02-03 | 1978-08-29 | International Business Machines Corporation | Method for preparing a multilayer ceramic |
US4121949A (en) | 1976-04-30 | 1978-10-24 | P. R. Mallory & Co. Inc. | Method of making a cathode electrode for an electrolytic capacitor |
US4071876A (en) * | 1976-12-17 | 1978-01-31 | Gte Automatic Electric Laboratories Incorporated | Pluggable protector holder for surge arrestor gas tubes |
US4149876A (en) * | 1978-06-06 | 1979-04-17 | Fansteel Inc. | Process for producing tantalum and columbium powder |
US4466841A (en) | 1980-12-08 | 1984-08-21 | Emhart Industries, Inc. | Cathode electrode for an electrical device and method of making same |
US4408257A (en) | 1980-12-08 | 1983-10-04 | Emhart Industries, Inc. | Cathode electrode for an electrical device |
GB2115223B (en) | 1982-02-18 | 1985-07-10 | Standard Telephones Cables Ltd | Multilayer ceramic dielectric capacitors |
US5230956A (en) * | 1982-05-28 | 1993-07-27 | Amoco Corporation | Polyamide-imide sized fibers |
US4494174A (en) * | 1982-09-27 | 1985-01-15 | Sprague Electric Company | Wet-electrolyte capacitor package |
US4469610A (en) * | 1983-07-18 | 1984-09-04 | Nippon Chemi-Con Corporation | Electrolyte for an electrolytic capacitor |
US4523255A (en) * | 1983-09-19 | 1985-06-11 | Sprague Electric Company | Cathode for an electrolytic capacitor |
JPS60229947A (ja) * | 1984-04-28 | 1985-11-15 | Youbea Le-Ron Kogyo Kk | ポリアミドイミド系樹脂組成物 |
US4535389A (en) | 1984-09-21 | 1985-08-13 | Sprague Electric Company | Electrolytic capacitor |
US4684399A (en) | 1986-03-04 | 1987-08-04 | Cabot Corporation | Tantalum powder process |
EP0246825B1 (en) | 1986-05-20 | 1991-02-27 | Mitsubishi Petrochemical Co., Ltd. | Quaternary salt solution electrolyte for electrolytic capacitors |
US4683516A (en) * | 1986-08-08 | 1987-07-28 | Kennecott Corporation | Extended life capacitor and method |
US4786342A (en) | 1986-11-10 | 1988-11-22 | Coors Porcelain Company | Method for producing cast tape finish on a dry-pressed substrate |
US4981942A (en) * | 1987-03-31 | 1991-01-01 | Amoco Corporation | Polyamide-imide composition based on bisphenoxyphenyl diamines |
JPH01158715A (ja) * | 1987-12-15 | 1989-06-21 | Nichicon Corp | 電解コンデンサの駆動用電解液 |
US4780797A (en) | 1987-12-16 | 1988-10-25 | Tansitor Electronic, Inc. | Capacitor tantalum surface for use as a counterelectrode device and method |
JPH065656B2 (ja) * | 1988-02-19 | 1994-01-19 | 株式会社村田製作所 | セラミック積層体の製造方法 |
JPH01253911A (ja) * | 1988-04-04 | 1989-10-11 | Asahi Glass Co Ltd | 電解コンデンサ |
JP2561323B2 (ja) * | 1988-07-12 | 1996-12-04 | ニチコン株式会社 | 電解コンデンサの駆動用電解液 |
US5002710A (en) * | 1989-01-12 | 1991-03-26 | Rutgers University A Not For Profit Corporation Of The State Of New Jersey | Composition useful for producing thin ceramic sheets |
US5045170A (en) | 1989-05-02 | 1991-09-03 | Globe-Union, Inc. | Electrodies containing a conductive metal oxide |
CN1048892A (zh) * | 1989-05-24 | 1991-01-30 | 奥本大学 | 混合纤维复合材料结构及其制法和用途 |
US4992910A (en) * | 1989-11-06 | 1991-02-12 | The Evans Findings Company, Inc. | Electrical component package |
US4945452A (en) * | 1989-11-30 | 1990-07-31 | Avx Corporation | Tantalum capacitor and method of making same |
US5160653A (en) * | 1990-02-28 | 1992-11-03 | Aerovox M, Inc. | Electrolytic capacitor and electrolyte therefor |
US5043849A (en) | 1990-04-17 | 1991-08-27 | Tansistor Electronics, Inc. | Electrolytic capacitor with codeposited noble metal/base metal cathode element and method for making |
US5183340A (en) * | 1990-09-19 | 1993-02-02 | Amoco Corporation | Bearing and bearing assembly |
US5098485A (en) * | 1990-09-19 | 1992-03-24 | Evans Findings Company | Method of making electrically insulating metallic oxides electrically conductive |
US5309479A (en) * | 1991-04-29 | 1994-05-03 | Hughes Aircraft Company | Low Cost Ku band transmitter |
US5105341A (en) * | 1991-06-03 | 1992-04-14 | Yosemite Investment, Inc. | Wet tantalum capacitor with liner |
US5198968A (en) * | 1992-07-23 | 1993-03-30 | Avx Corporation | Compact surface mount solid state capacitor and method of making same |
US5357399A (en) | 1992-09-25 | 1994-10-18 | Avx Corporation | Mass production method for the manufacture of surface mount solid state capacitor and resulting capacitor |
US5400211A (en) * | 1992-10-01 | 1995-03-21 | The Evans Findings Company, Inc. | Packaged electrical component |
US5419824A (en) * | 1992-11-12 | 1995-05-30 | Weres; Oleh | Electrode, electrode manufacturing process and electrochemical cell |
US5306479A (en) | 1992-11-20 | 1994-04-26 | Teledyne Industries, Inc. (California Corp.) | Process for synthesizing niobium dioxide and mixed metal oxides containing niobium |
US5754394A (en) * | 1993-03-22 | 1998-05-19 | Evans Capacitor Company Incorporated | Capacitor including a cathode having a nitride coating |
US5982609A (en) | 1993-03-22 | 1999-11-09 | Evans Capacitor Co., Inc. | Capacitor |
US5369547A (en) | 1993-03-22 | 1994-11-29 | The Evans Findings Co., Ltd. | Capacitor |
US5469325A (en) * | 1993-03-22 | 1995-11-21 | Evans Findings Co. | Capacitor |
US6594140B1 (en) | 1993-03-22 | 2003-07-15 | Evans Capacitor Company Incorporated | Capacitor |
US5448447A (en) | 1993-04-26 | 1995-09-05 | Cabot Corporation | Process for making an improved tantalum powder and high capacitance low leakage electrode made therefrom |
US5394295A (en) * | 1993-05-28 | 1995-02-28 | Avx Corporation | Manufacturing method for solid state capacitor and resulting capacitor |
JP2765462B2 (ja) | 1993-07-27 | 1998-06-18 | 日本電気株式会社 | 固体電解コンデンサおよびその製造方法 |
US5495386A (en) * | 1993-08-03 | 1996-02-27 | Avx Corporation | Electrical components, such as capacitors, and methods for their manufacture |
US5687057A (en) | 1993-10-06 | 1997-11-11 | Philips Electronics North America Corporation | Longer life electrolytic capacitors and electrolyte therefor |
JPH07135126A (ja) | 1993-11-10 | 1995-05-23 | Nec Corp | 固体電解コンデンサ及びその製造方法 |
JP2904392B2 (ja) * | 1993-12-17 | 1999-06-14 | 株式会社栗本鐵工所 | 竪型連続遊星ボールミル |
US5419977A (en) * | 1994-03-09 | 1995-05-30 | Medtronic, Inc. | Electrochemical device having operatively combined capacitor |
US5442978A (en) | 1994-05-19 | 1995-08-22 | H. C. Starck, Inc. | Tantalum production via a reduction of K2TAF7, with diluent salt, with reducing agent provided in a fast series of slug additions |
US5862035A (en) | 1994-10-07 | 1999-01-19 | Maxwell Energy Products, Inc. | Multi-electrode double layer capacitor having single electrolyte seal and aluminum-impregnated carbon cloth electrodes |
US5621607A (en) | 1994-10-07 | 1997-04-15 | Maxwell Laboratories, Inc. | High performance double layer capacitors including aluminum carbon composite electrodes |
JP3068430B2 (ja) * | 1995-04-25 | 2000-07-24 | 富山日本電気株式会社 | 固体電解コンデンサ及びその製造方法 |
US5726118A (en) * | 1995-08-08 | 1998-03-10 | Norit Americas, Inc. | Activated carbon for separation of fluids by adsorption and method for its preparation |
JPH0955341A (ja) | 1995-08-11 | 1997-02-25 | Nisshinbo Ind Inc | 電気二重層キャパシタ用分極性電極及び該分極性電極を使用した電気二重層キャパシタ |
SK283830B6 (sk) | 1995-08-14 | 2004-02-03 | Universal Resources Ag | Dvojvrstvový kondenzátor |
US5786980A (en) | 1996-02-02 | 1998-07-28 | Evans Capacitor Company, Incorporated | Electrical component package and packaged electrical component |
ES2155670T3 (es) | 1996-03-08 | 2001-05-16 | Du Pont | Molino de energia de fluido mejorado. |
US5812367A (en) | 1996-04-04 | 1998-09-22 | Matsushita Electric Industrial Co., Ltd. | Solid electrolytic capacitors comprising a conductive layer made of a polymer of pyrrole or its derivative |
US5714000A (en) * | 1996-05-06 | 1998-02-03 | Agritec, Inc. | Fine-celled foam composition and method |
JP3863232B2 (ja) | 1996-09-27 | 2006-12-27 | ローム株式会社 | 固体電解コンデンサに使用するコンデンサ素子の構造及びコンデンサ素子におけるチップ体の固め成形方法 |
US6165623A (en) | 1996-11-07 | 2000-12-26 | Cabot Corporation | Niobium powders and niobium electrolytic capacitors |
JP3254163B2 (ja) | 1997-02-28 | 2002-02-04 | 昭和電工株式会社 | コンデンサ |
TW388043B (en) * | 1997-04-15 | 2000-04-21 | Sanyo Electric Co | Solid electrolyte capacitor |
US6051326A (en) * | 1997-04-26 | 2000-04-18 | Cabot Corporation | Valve metal compositions and method |
US5894403A (en) * | 1997-05-01 | 1999-04-13 | Wilson Greatbatch Ltd. | Ultrasonically coated substrate for use in a capacitor |
US5926362A (en) * | 1997-05-01 | 1999-07-20 | Wilson Greatbatch Ltd. | Hermetically sealed capacitor |
US5920455A (en) * | 1997-05-01 | 1999-07-06 | Wilson Greatbatch Ltd. | One step ultrasonically coated substrate for use in a capacitor |
CN1220226C (zh) | 1997-06-20 | 2005-09-21 | 松下电器产业株式会社 | 电解电容器及其制造方法 |
US5973913A (en) | 1997-08-12 | 1999-10-26 | Covalent Associates, Inc. | Nonaqueous electrical storage device |
US6104600A (en) | 1998-02-02 | 2000-08-15 | Asahi Glass Company Ltd. | Electric double layer capacitor |
JPH11274011A (ja) | 1998-03-23 | 1999-10-08 | Matsushita Electric Ind Co Ltd | アルミ電解コンデンサ |
US6051044A (en) | 1998-05-04 | 2000-04-18 | Cabot Corporation | Nitrided niobium powders and niobium electrolytic capacitors |
US6208502B1 (en) * | 1998-07-06 | 2001-03-27 | Aerovox, Inc. | Non-symmetric capacitor |
EP0989572B1 (en) * | 1998-08-28 | 2007-01-03 | Wilson Greatbatch Ltd. | Electrolyte for use in a capacitor |
US6391275B1 (en) * | 1998-09-16 | 2002-05-21 | Cabot Corporation | Methods to partially reduce a niobium metal oxide and oxygen reduced niobium oxides |
US6416730B1 (en) * | 1998-09-16 | 2002-07-09 | Cabot Corporation | Methods to partially reduce a niobium metal oxide oxygen reduced niobium oxides |
US6322912B1 (en) * | 1998-09-16 | 2001-11-27 | Cabot Corporation | Electrolytic capacitor anode of valve metal oxide |
US6072692A (en) * | 1998-10-08 | 2000-06-06 | Asahi Glass Company, Ltd. | Electric double layer capacitor having an electrode bonded to a current collector via a carbon type conductive adhesive layer |
EP1050954B1 (en) * | 1998-10-21 | 2004-12-15 | Matsushita Electric Industrial Co., Ltd. | Circuit for driving piezoelectric transformer |
JP2000223376A (ja) | 1998-11-25 | 2000-08-11 | Ngk Insulators Ltd | 電気化学キャパシタの製造方法 |
US6094339A (en) | 1998-12-04 | 2000-07-25 | Evans Capacitor Company Incorporated | Capacitor with spiral anode and planar cathode |
US6301093B1 (en) | 1999-01-14 | 2001-10-09 | Honda Giken Kogyo Kabushiki Kaisha | Electrochemical capacitor |
US6181546B1 (en) * | 1999-01-19 | 2001-01-30 | Aktsionernoe Obschestvo Zakrytogo Tipa “Elton” | Double layer capacitor |
US6332900B1 (en) | 1999-02-08 | 2001-12-25 | Wilson Greatbatch Ltd. | Physical vapor deposited electrode component and method of manufacture |
US6479581B1 (en) | 1999-03-12 | 2002-11-12 | Solvay Advanced Polymers, Llc | Aqueous-based polyamide-amic acid compositions |
US6191936B1 (en) * | 1999-04-12 | 2001-02-20 | Vishay Sprague, Inc. | Capacitor having textured pellet and method for making same |
US6375704B1 (en) * | 1999-05-12 | 2002-04-23 | Cabot Corporation | High capacitance niobium powders and electrolytic capacitor anodes |
US6126097A (en) | 1999-08-21 | 2000-10-03 | Nanotek Instruments, Inc. | High-energy planetary ball milling apparatus and method for the preparation of nanometer-sized powders |
DE19941094A1 (de) * | 1999-08-30 | 2003-07-10 | Epcos Ag | Kondensator und Verfahren zum Herstellen eines Anodenkörpers und eines Anodenableiters hierfür |
JP2001185459A (ja) | 1999-10-15 | 2001-07-06 | Mitsubishi Chemicals Corp | 電気化学キャパシタ |
US6563695B1 (en) * | 1999-11-16 | 2003-05-13 | Cabot Supermetals K.K. | Powdered tantalum, niobium, production process thereof, and porous sintered body and solid electrolytic capacitor using the powdered tantalum or niobium |
US6283985B1 (en) * | 1999-12-01 | 2001-09-04 | Cardiac Pacemakers, Inc. | Reforming wet-tantalum capacitors in implantable defibrillators and other medical devices |
DE60113195T2 (de) | 2000-06-27 | 2006-07-06 | Asahi Glass Co., Ltd. | Aktivkohlematerial, Verfahren zu dessen Herstellung und elektrischer Doppelschichtkondensator, welcher dieses verwendet |
US6377442B1 (en) * | 2000-09-21 | 2002-04-23 | Pacesetter, Inc. | Floating anode DC electrolytic capacitor |
JP2002203749A (ja) * | 2000-12-28 | 2002-07-19 | Daiso Co Ltd | 積層型電気二重層キャパシタ |
US6507480B2 (en) * | 2001-02-26 | 2003-01-14 | Matsushita Electric Industrial Co., Ltd. | Electric double layer capacitor |
US6562255B1 (en) * | 2001-03-19 | 2003-05-13 | Pacesetter, Inc. | Conductive electrolyte for high voltage capacitors |
US6674635B1 (en) * | 2001-06-11 | 2004-01-06 | Avx Corporation | Protective coating for electrolytic capacitors |
KR100414357B1 (ko) * | 2001-07-13 | 2004-01-07 | 주식회사 네스캡 | 전도성 고분자를 코팅한 금속산화물 전기화학의사커패시터의 전극 및 이의 제조방법 |
US6576524B1 (en) * | 2001-07-20 | 2003-06-10 | Evans Capacitor Company Incorporated | Method of making a prismatic capacitor |
JP4570303B2 (ja) * | 2001-12-28 | 2010-10-27 | ルビコン株式会社 | 電解コンデンサおよび電解コンデンサ駆動用電解液 |
DE10203143A1 (de) * | 2002-01-28 | 2003-08-07 | Epcos Ag | Elektroden, deren Herstellung und Kondensatoren mit den Elektroden |
US6687117B2 (en) * | 2002-01-31 | 2004-02-03 | Wilson Greatbatch Technologies, Inc. | Electrolytes for capacitors |
US6743370B1 (en) * | 2002-05-23 | 2004-06-01 | Pacesetter, Inc. | Conductive electrolyte for high voltage capacitors |
US7377948B2 (en) * | 2002-06-05 | 2008-05-27 | Reveo, Inc. | Layered electrochemical cell and manufacturing method therefor |
US7002790B2 (en) * | 2002-09-30 | 2006-02-21 | Medtronic, Inc. | Capacitor in an implantable medical device |
US7160615B2 (en) * | 2002-11-29 | 2007-01-09 | Honda Motor Co., Ltd. | Granules for formation of an electrode of an electric double layer capacitor, manufacturing method thereof, electrode sheet, polarized electrode, and electric double layer capacitor using a polarized electrode |
CA2453328A1 (en) * | 2002-12-16 | 2004-06-16 | Wilson Greatbatch Technologies, Inc. | Dual anode capacitor interconnect design |
US6859353B2 (en) * | 2002-12-16 | 2005-02-22 | Wilson Greatbatch Technologies, Inc. | Capacitor interconnect design |
US6859354B2 (en) * | 2003-05-30 | 2005-02-22 | Kemet Electronic Corporation | Low freezing electrolyte for an electrolytic capacitor |
US6842328B2 (en) * | 2003-05-30 | 2005-01-11 | Joachim Hossick Schott | Capacitor and method for producing a capacitor |
US6721170B1 (en) * | 2003-06-11 | 2004-04-13 | Evans Capacitor Company, Inc. | Packaged hybrid capacitor |
US6888717B2 (en) * | 2003-06-13 | 2005-05-03 | Kemet Electronics Corporation | Working electrolyte for electrolytic capacitors |
JP2005045101A (ja) * | 2003-07-24 | 2005-02-17 | Japan Carlit Co Ltd:The | 電解コンデンサ用電解液及び電解コンデンサ |
US7169284B1 (en) * | 2003-09-22 | 2007-01-30 | Pacesetter, Inc. | High surface area cathode for electrolytic capacitors using conductive polymer |
KR100649580B1 (ko) * | 2003-12-15 | 2006-11-28 | 삼성전기주식회사 | 스핀코팅에 의한 적층세라믹 커패시터의 제조방법 및적층세라믹 커패시터 |
US7038901B2 (en) * | 2004-02-13 | 2006-05-02 | Wilson Greatbatch Technologies, Inc. | Silicate additives for capacitor working electrolytes |
US7012799B2 (en) * | 2004-04-19 | 2006-03-14 | Wilson Greatbatch Technologies, Inc. | Flat back case for an electrolytic capacitor |
US7116548B2 (en) | 2004-04-23 | 2006-10-03 | Kemet Electronics Corporation | Fluted anode with minimal density gradients and capacitor comprising same |
JP2005333017A (ja) * | 2004-05-20 | 2005-12-02 | Japan Carlit Co Ltd:The | 電解コンデンサ用電解液及び電解コンデンサ |
US7099143B1 (en) | 2005-05-24 | 2006-08-29 | Avx Corporation | Wet electrolytic capacitors |
JP5072112B2 (ja) * | 2006-06-07 | 2012-11-14 | テイカ株式会社 | 導電性高分子合成用反応促進剤、導電性高分子および固体電解コンデンサ |
-
2007
- 2007-03-20 US US11/725,965 patent/US7460356B2/en active Active
-
2008
- 2008-02-05 GB GB0802095A patent/GB2447724B/en not_active Expired - Fee Related
- 2008-02-18 DE DE102008000330.1A patent/DE102008000330B4/de active Active
- 2008-03-19 KR KR1020080025316A patent/KR20080085754A/ko not_active Application Discontinuation
- 2008-03-19 JP JP2008071059A patent/JP5301181B2/ja not_active Expired - Fee Related
- 2008-03-19 CN CNA2008100854745A patent/CN101271769A/zh active Pending
Also Published As
Publication number | Publication date |
---|---|
US7460356B2 (en) | 2008-12-02 |
GB0802095D0 (en) | 2008-03-12 |
DE102008000330A1 (de) | 2008-09-25 |
JP2008235895A (ja) | 2008-10-02 |
DE102008000330A9 (de) | 2009-01-08 |
CN101271769A (zh) | 2008-09-24 |
US20080232029A1 (en) | 2008-09-25 |
GB2447724A (en) | 2008-09-24 |
DE102008000330B4 (de) | 2023-08-03 |
KR20080085754A (ko) | 2008-09-24 |
GB2447724B (en) | 2011-07-27 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP5301181B2 (ja) | 湿式電解コンデンサ用の中性電解質 | |
JP5323372B2 (ja) | 湿式電解コンデンサ用のカソードコーティング | |
JP5220448B2 (ja) | 電解コンデンサに使用するためのアノード | |
US7649730B2 (en) | Wet electrolytic capacitor containing a plurality of thin powder-formed anodes | |
US7799099B2 (en) | Method of manufacturing a current collector for a double electric layer capacitor | |
TWI423284B (zh) | 具有聚合物外層之電解電容器及製造其之方法 | |
JP2010067966A (ja) | 湿式コンデンサ用基板 | |
JP2023053035A (ja) | 電解コンデンサ | |
JP2023166604A (ja) | 電解コンデンサ | |
KR20100066400A (ko) | 습식 커패시터에 사용하기 위한 캐쏘드 | |
RU2492540C2 (ru) | Токосъемник отрицательного электрода для гетерогенного электрохимического конденсатора и способ его изготовления | |
CN101180695A (zh) | 湿式电解电容器 | |
WO2014050913A1 (ja) | 固体電解コンデンサ及びその製造方法 | |
JP7343847B2 (ja) | 電解コンデンサ及びその製造方法 | |
JP2007173454A (ja) | 固体電解コンデンサ | |
KR20220110507A (ko) | 고체 전해 콘덴서 및 그 제조 방법 | |
JP4501270B2 (ja) | コンデンサ用リード線およびこれを用いた固体電解コンデンサ |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20110317 |
|
A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20110317 |
|
A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20121206 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20121217 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20130318 |
|
TRDD | Decision of grant or rejection written | ||
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20130520 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20130619 |
|
R150 | Certificate of patent or registration of utility model |
Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
LAPS | Cancellation because of no payment of annual fees |