JP5036033B2 - 水処理用多孔質膜及びその製造方法 - Google Patents
水処理用多孔質膜及びその製造方法 Download PDFInfo
- Publication number
- JP5036033B2 JP5036033B2 JP2006528871A JP2006528871A JP5036033B2 JP 5036033 B2 JP5036033 B2 JP 5036033B2 JP 2006528871 A JP2006528871 A JP 2006528871A JP 2006528871 A JP2006528871 A JP 2006528871A JP 5036033 B2 JP5036033 B2 JP 5036033B2
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- JP
- Japan
- Prior art keywords
- weight
- polyvinylidene fluoride
- fluoride resin
- porous membrane
- parts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 81
- 239000012528 membrane Substances 0.000 title claims abstract description 64
- 238000004519 manufacturing process Methods 0.000 title claims description 12
- 239000011342 resin composition Substances 0.000 claims abstract description 3
- 239000002033 PVDF binder Substances 0.000 claims description 87
- 229920002981 polyvinylidene fluoride Polymers 0.000 claims description 87
- 229920005989 resin Polymers 0.000 claims description 56
- 239000011347 resin Substances 0.000 claims description 56
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 46
- 239000004014 plasticizer Substances 0.000 claims description 32
- 239000002904 solvent Substances 0.000 claims description 30
- 239000012510 hollow fiber Substances 0.000 claims description 27
- 239000000203 mixture Substances 0.000 claims description 22
- 238000007127 saponification reaction Methods 0.000 claims description 15
- 230000003204 osmotic effect Effects 0.000 claims description 5
- 238000009736 wetting Methods 0.000 claims description 5
- 239000004372 Polyvinyl alcohol Substances 0.000 description 16
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 15
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 15
- 229920000642 polymer Polymers 0.000 description 14
- 230000035699 permeability Effects 0.000 description 13
- 238000001914 filtration Methods 0.000 description 12
- 239000011148 porous material Substances 0.000 description 11
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 10
- 230000000052 comparative effect Effects 0.000 description 8
- 239000003480 eluent Substances 0.000 description 8
- 230000004907 flux Effects 0.000 description 8
- 239000000047 product Substances 0.000 description 8
- BQCIDUSAKPWEOX-UHFFFAOYSA-N 1,1-Difluoroethene Chemical compound FC(F)=C BQCIDUSAKPWEOX-UHFFFAOYSA-N 0.000 description 7
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 7
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 7
- 239000013078 crystal Substances 0.000 description 7
- 239000000463 material Substances 0.000 description 7
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 6
- 238000012423 maintenance Methods 0.000 description 6
- 229920000728 polyester Polymers 0.000 description 6
- 239000000243 solution Substances 0.000 description 6
- 239000002253 acid Substances 0.000 description 5
- 230000007423 decrease Effects 0.000 description 5
- 230000001771 impaired effect Effects 0.000 description 5
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical group CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 4
- IMROMDMJAWUWLK-UHFFFAOYSA-N Ethenol Chemical compound OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 description 4
- 229920003232 aliphatic polyester Polymers 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 238000000605 extraction Methods 0.000 description 4
- 238000001125 extrusion Methods 0.000 description 4
- 125000003010 ionic group Chemical group 0.000 description 4
- 238000002844 melting Methods 0.000 description 4
- 230000008018 melting Effects 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 3
- 239000001361 adipic acid Substances 0.000 description 3
- 235000011037 adipic acid Nutrition 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 239000002826 coolant Substances 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 3
- 239000000284 extract Substances 0.000 description 3
- 238000005227 gel permeation chromatography Methods 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 230000007774 longterm Effects 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000012046 mixed solvent Substances 0.000 description 3
- BDJRBEYXGGNYIS-UHFFFAOYSA-N nonanedioic acid Chemical compound OC(=O)CCCCCCCC(O)=O BDJRBEYXGGNYIS-UHFFFAOYSA-N 0.000 description 3
- 230000035515 penetration Effects 0.000 description 3
- 238000006116 polymerization reaction Methods 0.000 description 3
- 229920002689 polyvinyl acetate Polymers 0.000 description 3
- 239000011118 polyvinyl acetate Substances 0.000 description 3
- 229920001290 polyvinyl ester Polymers 0.000 description 3
- 239000008400 supply water Substances 0.000 description 3
- 238000011144 upstream manufacturing Methods 0.000 description 3
- NIQCNGHVCWTJSM-UHFFFAOYSA-N Dimethyl phthalate Chemical compound COC(=O)C1=CC=CC=C1C(=O)OC NIQCNGHVCWTJSM-UHFFFAOYSA-N 0.000 description 2
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 238000005345 coagulation Methods 0.000 description 2
- 230000015271 coagulation Effects 0.000 description 2
- 238000011109 contamination Methods 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 150000002148 esters Chemical group 0.000 description 2
- 229920001519 homopolymer Polymers 0.000 description 2
- 239000010842 industrial wastewater Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- 239000003507 refrigerant Substances 0.000 description 2
- 238000005201 scrubbing Methods 0.000 description 2
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 229920001567 vinyl ester resin Polymers 0.000 description 2
- 229920002554 vinyl polymer Polymers 0.000 description 2
- 239000002351 wastewater Substances 0.000 description 2
- UOCLXMDMGBRAIB-UHFFFAOYSA-N 1,1,1-trichloroethane Chemical compound CC(Cl)(Cl)Cl UOCLXMDMGBRAIB-UHFFFAOYSA-N 0.000 description 1
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
- 241000283690 Bos taurus Species 0.000 description 1
- CHDVXKLFZBWKEN-UHFFFAOYSA-N C=C.F.F.F.Cl Chemical compound C=C.F.F.F.Cl CHDVXKLFZBWKEN-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- PYVHTIWHNXTVPF-UHFFFAOYSA-N F.F.F.F.C=C Chemical compound F.F.F.F.C=C PYVHTIWHNXTVPF-UHFFFAOYSA-N 0.000 description 1
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 1
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 1
- FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical compound CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 241000282887 Suidae Species 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 239000012670 alkaline solution Substances 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- KKPMZLPPEXRJOM-UHFFFAOYSA-N butane-1,3-diol;hexanedioic acid Chemical compound CC(O)CCO.OC(=O)CCCCC(O)=O KKPMZLPPEXRJOM-UHFFFAOYSA-N 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 239000000920 calcium hydroxide Substances 0.000 description 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 238000003889 chemical engineering Methods 0.000 description 1
- 150000008280 chlorinated hydrocarbons Chemical class 0.000 description 1
- KYKAJFCTULSVSH-UHFFFAOYSA-N chloro(fluoro)methane Chemical compound F[C]Cl KYKAJFCTULSVSH-UHFFFAOYSA-N 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 235000013365 dairy product Nutrition 0.000 description 1
- JQGRPPCZXQJUAF-UHFFFAOYSA-N decanedioic acid;propane-1,2-diol Chemical compound CC(O)CO.OC(=O)CCCCCCCCC(O)=O JQGRPPCZXQJUAF-UHFFFAOYSA-N 0.000 description 1
- FBSAITBEAPNWJG-UHFFFAOYSA-N dimethyl phthalate Natural products CC(=O)OC1=CC=CC=C1OC(C)=O FBSAITBEAPNWJG-UHFFFAOYSA-N 0.000 description 1
- 229960001826 dimethylphthalate Drugs 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000010828 elution Methods 0.000 description 1
- YCUBDDIKWLELPD-UHFFFAOYSA-N ethenyl 2,2-dimethylpropanoate Chemical compound CC(C)(C)C(=O)OC=C YCUBDDIKWLELPD-UHFFFAOYSA-N 0.000 description 1
- WNMORWGTPVWAIB-UHFFFAOYSA-N ethenyl 2-methylpropanoate Chemical compound CC(C)C(=O)OC=C WNMORWGTPVWAIB-UHFFFAOYSA-N 0.000 description 1
- MEGHWIAOTJPCHQ-UHFFFAOYSA-N ethenyl butanoate Chemical compound CCCC(=O)OC=C MEGHWIAOTJPCHQ-UHFFFAOYSA-N 0.000 description 1
- GFJVXXWOPWLRNU-UHFFFAOYSA-N ethenyl formate Chemical compound C=COC=O GFJVXXWOPWLRNU-UHFFFAOYSA-N 0.000 description 1
- QBDADGJLZNIRFQ-UHFFFAOYSA-N ethenyl octanoate Chemical compound CCCCCCCC(=O)OC=C QBDADGJLZNIRFQ-UHFFFAOYSA-N 0.000 description 1
- UIWXSTHGICQLQT-UHFFFAOYSA-N ethenyl propanoate Chemical compound CCC(=O)OC=C UIWXSTHGICQLQT-UHFFFAOYSA-N 0.000 description 1
- 125000002573 ethenylidene group Chemical group [*]=C=C([H])[H] 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 210000003608 fece Anatomy 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- XUCNUKMRBVNAPB-UHFFFAOYSA-N fluoroethene Chemical compound FC=C XUCNUKMRBVNAPB-UHFFFAOYSA-N 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 238000009499 grossing Methods 0.000 description 1
- -1 hexafluoropropylene, ethylene Chemical group 0.000 description 1
- MEBJLVMIIRFIJS-UHFFFAOYSA-N hexanedioic acid;propane-1,2-diol Chemical compound CC(O)CO.OC(=O)CCCCC(O)=O MEBJLVMIIRFIJS-UHFFFAOYSA-N 0.000 description 1
- 239000008240 homogeneous mixture Substances 0.000 description 1
- 229920001600 hydrophobic polymer Polymers 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 239000010871 livestock manure Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 239000012982 microporous membrane Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- FNSYDPIUFNHOJK-UHFFFAOYSA-N nonanedioic acid;propane-1,2-diol Chemical compound CC(O)CO.OC(=O)CCCCCCCC(O)=O FNSYDPIUFNHOJK-UHFFFAOYSA-N 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 238000005191 phase separation Methods 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 239000002798 polar solvent Substances 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920000131 polyvinylidene Polymers 0.000 description 1
- RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 description 1
- HNJBEVLQSNELDL-UHFFFAOYSA-N pyrrolidin-2-one Chemical compound O=C1CCCN1 HNJBEVLQSNELDL-UHFFFAOYSA-N 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000010865 sewage Substances 0.000 description 1
- 239000002893 slag Substances 0.000 description 1
- 230000003381 solubilizing effect Effects 0.000 description 1
- 239000012798 spherical particle Substances 0.000 description 1
- 238000009987 spinning Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000006228 supernatant Substances 0.000 description 1
- 238000010557 suspension polymerization reaction Methods 0.000 description 1
- 239000012085 test solution Substances 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/06—Organic material
- B01D71/30—Polyalkenyl halides
- B01D71/32—Polyalkenyl halides containing fluorine atoms
- B01D71/34—Polyvinylidene fluoride
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
- B01D67/0002—Organic membrane manufacture
- B01D67/0023—Organic membrane manufacture by inducing porosity into non porous precursor membranes
- B01D67/0025—Organic membrane manufacture by inducing porosity into non porous precursor membranes by mechanical treatment, e.g. pore-stretching
- B01D67/0027—Organic membrane manufacture by inducing porosity into non porous precursor membranes by mechanical treatment, e.g. pore-stretching by stretching
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
- B01D67/0002—Organic membrane manufacture
- B01D67/0023—Organic membrane manufacture by inducing porosity into non porous precursor membranes
- B01D67/003—Organic membrane manufacture by inducing porosity into non porous precursor membranes by selective elimination of components, e.g. by leaching
- B01D67/0031—Organic membrane manufacture by inducing porosity into non porous precursor membranes by selective elimination of components, e.g. by leaching by elimination of at least one of the blocks of a block copolymer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
- B01D69/02—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor characterised by their properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
- B01D69/08—Hollow fibre membranes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/06—Organic material
- B01D71/38—Polyalkenylalcohols; Polyalkenylesters; Polyalkenylethers; Polyalkenylaldehydes; Polyalkenylketones; Polyalkenylacetals; Polyalkenylketals
- B01D71/381—Polyvinylalcohol
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2323/00—Details relating to membrane preparation
- B01D2323/15—Use of additives
- B01D2323/20—Plasticizers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2325/00—Details relating to properties of membranes
- B01D2325/24—Mechanical properties, e.g. strength
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2325/00—Details relating to properties of membranes
- B01D2325/30—Chemical resistance
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Artificial Filaments (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2006528871A JP5036033B2 (ja) | 2004-06-28 | 2005-06-27 | 水処理用多孔質膜及びその製造方法 |
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2004190060 | 2004-06-28 | ||
| JP2004190060 | 2004-06-28 | ||
| JP2006528871A JP5036033B2 (ja) | 2004-06-28 | 2005-06-27 | 水処理用多孔質膜及びその製造方法 |
| PCT/JP2005/012262 WO2006001528A1 (ja) | 2004-06-28 | 2005-06-27 | 水処理用多孔質膜及びその製造方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPWO2006001528A1 JPWO2006001528A1 (ja) | 2008-04-17 |
| JP5036033B2 true JP5036033B2 (ja) | 2012-09-26 |
Family
ID=35781932
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2006528871A Expired - Fee Related JP5036033B2 (ja) | 2004-06-28 | 2005-06-27 | 水処理用多孔質膜及びその製造方法 |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US20080078718A1 (de) |
| EP (1) | EP1776996A4 (de) |
| JP (1) | JP5036033B2 (de) |
| KR (1) | KR20070036151A (de) |
| CN (1) | CN100475321C (de) |
| AU (1) | AU2005257513A1 (de) |
| CA (1) | CA2572492A1 (de) |
| WO (1) | WO2006001528A1 (de) |
Families Citing this family (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2008093503A (ja) * | 2006-10-06 | 2008-04-24 | Asahi Kasei Chemicals Corp | 多孔性中空糸膜の製造方法 |
| WO2008120509A1 (ja) * | 2007-04-03 | 2008-10-09 | Asahi Kasei Chemicals Corporation | 分離膜用洗浄剤、該洗浄剤の製造方法及び洗浄方法 |
| JP5568835B2 (ja) * | 2007-10-01 | 2014-08-13 | 栗田工業株式会社 | 逆浸透膜、逆浸透膜装置及び逆浸透膜の親水化処理方法 |
| AU2010254037B2 (en) * | 2009-05-29 | 2014-05-01 | Arkema Inc. | Aqueous polyvinylidene fluoride composition |
| US20120015246A1 (en) | 2010-05-27 | 2012-01-19 | Arkema Inc. | Waterborne fluoropolymer composition |
| JP5626269B2 (ja) * | 2011-06-22 | 2014-11-19 | ダイキン工業株式会社 | 高分子多孔質膜及び高分子多孔質膜の製造方法 |
| AU2012294783B2 (en) * | 2011-08-05 | 2017-08-10 | Arkema Inc. | Polymer blend membranes |
| KR101502865B1 (ko) * | 2012-11-23 | 2015-03-17 | 도레이케미칼 주식회사 | 폴리비닐덴플루오라이드(pvdf) 중공사막의 제조방법 |
| KR101373504B1 (ko) * | 2012-11-23 | 2014-03-12 | 웅진케미칼 주식회사 | 폴리비닐덴플루오라이드(pvdf) 중공사막 |
| CN103013003A (zh) * | 2012-12-18 | 2013-04-03 | 青岛中科润美润滑材料技术有限公司 | Pvdf/pva/cs复合膜 |
| JP6201324B2 (ja) | 2013-01-28 | 2017-09-27 | 日油株式会社 | 多孔質濾過膜用ファウリング抑制剤組成物、並びに多孔質濾過膜及びその製造方法 |
| TW201518373A (zh) * | 2013-06-26 | 2015-05-16 | Daikin Ind Ltd | 組成物、高分子多孔質膜及親水化劑 |
| CN107073411B (zh) * | 2014-11-03 | 2021-05-07 | 3M创新有限公司 | 微孔聚偏二氟乙烯平膜 |
| CN104587842A (zh) * | 2014-12-23 | 2015-05-06 | 江苏蓝天沛尔膜业有限公司 | 一种用于工业污水处理的mbr平片滤膜的制备方法 |
| KR101902631B1 (ko) * | 2016-09-27 | 2018-09-28 | 롯데케미칼 주식회사 | 중공사막 및 이의 제조방법 |
| KR102015709B1 (ko) * | 2017-11-24 | 2019-08-28 | 롯데케미칼 주식회사 | 중공사막 및 이의 제조방법 |
| KR102584858B1 (ko) * | 2018-12-20 | 2023-10-04 | 롯데케미칼 주식회사 | 여과막 형성용 조성물, 이를 이용한 여과막 제조방법 및 여과막 |
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| US4248913A (en) * | 1979-05-24 | 1981-02-03 | Abcor, Inc. | Process for preparing a membrane |
| JPS58205503A (ja) * | 1982-05-22 | 1983-11-30 | Kanebo Ltd | 油水分離膜及びその製造方法 |
| JPS61161103A (ja) * | 1985-01-10 | 1986-07-21 | Terumo Corp | 親水性多孔質膜およびその製法 |
| JPS61257203A (ja) * | 1985-05-10 | 1986-11-14 | Terumo Corp | 親水性多孔質膜およびその製造方法 |
| JPS6438103A (en) * | 1987-08-05 | 1989-02-08 | Terumo Corp | Hydrophilic porous film and its production |
| JPH0522557A (ja) | 1991-07-09 | 1993-01-29 | Murata Mach Ltd | フアクシミリ装置 |
| JP3200095B2 (ja) * | 1991-07-24 | 2001-08-20 | 旭化成株式会社 | 親水性耐熱膜及びその製造方法 |
| JP3216910B2 (ja) * | 1992-05-22 | 2001-10-09 | 株式会社クラレ | 多孔質中空糸膜 |
| JPH06319967A (ja) * | 1993-05-07 | 1994-11-22 | Nippon Millipore Kk | 連続多相分離構造をもつ多孔質中空繊維膜及びその製造法 |
| US5514461A (en) * | 1993-10-05 | 1996-05-07 | Kureha Chemical Industry Co., Ltd. | Vinylidene fluoride porous membrane and method of preparing the same |
| US6074718A (en) * | 1996-02-06 | 2000-06-13 | Koch Membrane Systems, Inc. | Self supporting hollow fiber membrane and method of construction |
| JP2000176259A (ja) * | 1998-12-11 | 2000-06-27 | Kuraray Co Ltd | ポリビニルアルコール系中空繊維膜およびその製造方法 |
| AU5613700A (en) * | 1999-07-16 | 2001-02-05 | Baxter International Inc. | Polyvinylidene difluoride membranes and methods for making such membranes |
| WO2004081109A1 (ja) * | 2003-03-13 | 2004-09-23 | Kureha Chemical Industry Company Limited | フッ化ビニリデン系樹脂多孔膜およびその製造方法 |
-
2005
- 2005-06-27 JP JP2006528871A patent/JP5036033B2/ja not_active Expired - Fee Related
- 2005-06-27 US US11/630,896 patent/US20080078718A1/en not_active Abandoned
- 2005-06-27 KR KR1020077002080A patent/KR20070036151A/ko not_active Abandoned
- 2005-06-27 CN CNB200580020693XA patent/CN100475321C/zh not_active Expired - Fee Related
- 2005-06-27 EP EP05755155A patent/EP1776996A4/de not_active Withdrawn
- 2005-06-27 AU AU2005257513A patent/AU2005257513A1/en not_active Abandoned
- 2005-06-27 WO PCT/JP2005/012262 patent/WO2006001528A1/ja not_active Ceased
- 2005-06-27 CA CA002572492A patent/CA2572492A1/en not_active Abandoned
Also Published As
| Publication number | Publication date |
|---|---|
| WO2006001528A1 (ja) | 2006-01-05 |
| EP1776996A1 (de) | 2007-04-25 |
| KR20070036151A (ko) | 2007-04-02 |
| US20080078718A1 (en) | 2008-04-03 |
| CA2572492A1 (en) | 2006-01-05 |
| CN100475321C (zh) | 2009-04-08 |
| EP1776996A4 (de) | 2008-04-30 |
| AU2005257513A1 (en) | 2006-01-05 |
| JPWO2006001528A1 (ja) | 2008-04-17 |
| CN1972737A (zh) | 2007-05-30 |
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