JP4933895B2 - 水性接着剤分散液 - Google Patents
水性接着剤分散液 Download PDFInfo
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- JP4933895B2 JP4933895B2 JP2006526549A JP2006526549A JP4933895B2 JP 4933895 B2 JP4933895 B2 JP 4933895B2 JP 2006526549 A JP2006526549 A JP 2006526549A JP 2006526549 A JP2006526549 A JP 2006526549A JP 4933895 B2 JP4933895 B2 JP 4933895B2
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- dispersion
- aqueous
- weight
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- adhesive composition
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- 229930182470 glycoside Natural products 0.000 description 1
- LHGVFZTZFXWLCP-UHFFFAOYSA-N guaiacol Chemical class COC1=CC=CC=C1O LHGVFZTZFXWLCP-UHFFFAOYSA-N 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- 125000000623 heterocyclic group Chemical group 0.000 description 1
- ZSIAUFGUXNUGDI-UHFFFAOYSA-N hexan-1-ol Chemical class CCCCCCO ZSIAUFGUXNUGDI-UHFFFAOYSA-N 0.000 description 1
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 1
- IKDUDTNKRLTJSI-UHFFFAOYSA-N hydrazine monohydrate Substances O.NN IKDUDTNKRLTJSI-UHFFFAOYSA-N 0.000 description 1
- 150000002429 hydrazines Chemical class 0.000 description 1
- VUGKRGOUQYGVIR-UHFFFAOYSA-N hydrazinylurea Chemical class NNNC(N)=O VUGKRGOUQYGVIR-UHFFFAOYSA-N 0.000 description 1
- 229920006270 hydrocarbon resin Polymers 0.000 description 1
- 150000002433 hydrophilic molecules Chemical class 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 1
- 238000005304 joining Methods 0.000 description 1
- 150000004658 ketimines Chemical class 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- 239000004611 light stabiliser Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000001630 malic acid Substances 0.000 description 1
- 235000011090 malic acid Nutrition 0.000 description 1
- 239000000594 mannitol Substances 0.000 description 1
- 235000010355 mannitol Nutrition 0.000 description 1
- 239000006224 matting agent Substances 0.000 description 1
- 238000000691 measurement method Methods 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- CRVGTESFCCXCTH-UHFFFAOYSA-N methyl diethanolamine Chemical compound OCCN(C)CCO CRVGTESFCCXCTH-UHFFFAOYSA-N 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 235000019426 modified starch Nutrition 0.000 description 1
- HDZGCSFEDULWCS-UHFFFAOYSA-N monomethylhydrazine Chemical compound CNN HDZGCSFEDULWCS-UHFFFAOYSA-N 0.000 description 1
- 238000003541 multi-stage reaction Methods 0.000 description 1
- AGVKXDPPPSLISR-UHFFFAOYSA-N n-ethylcyclohexanamine Chemical compound CCNC1CCCCC1 AGVKXDPPPSLISR-UHFFFAOYSA-N 0.000 description 1
- PSZYNBSKGUBXEH-UHFFFAOYSA-N naphthalene-1-sulfonic acid Chemical compound C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 PSZYNBSKGUBXEH-UHFFFAOYSA-N 0.000 description 1
- 239000000025 natural resin Substances 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
- ZWRUINPWMLAQRD-UHFFFAOYSA-N nonan-1-ol Chemical class CCCCCCCCCO ZWRUINPWMLAQRD-UHFFFAOYSA-N 0.000 description 1
- OEIJHBUUFURJLI-UHFFFAOYSA-N octane-1,8-diol Chemical compound OCCCCCCCCO OEIJHBUUFURJLI-UHFFFAOYSA-N 0.000 description 1
- 229940055577 oleyl alcohol Drugs 0.000 description 1
- XMLQWXUVTXCDDL-UHFFFAOYSA-N oleyl alcohol Natural products CCCCCCC=CCCCCCCCCCCO XMLQWXUVTXCDDL-UHFFFAOYSA-N 0.000 description 1
- 125000001477 organic nitrogen group Chemical group 0.000 description 1
- 150000002902 organometallic compounds Chemical class 0.000 description 1
- HXSACZWWBYWLIS-UHFFFAOYSA-N oxadiazine-4,5,6-trione Chemical group O=C1ON=NC(=O)C1=O HXSACZWWBYWLIS-UHFFFAOYSA-N 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- GNLZSEMKVZGLGY-UHFFFAOYSA-N pentane-2,2-diol Chemical compound CCCC(C)(O)O GNLZSEMKVZGLGY-UHFFFAOYSA-N 0.000 description 1
- FHHJDRFHHWUPDG-UHFFFAOYSA-N peroxysulfuric acid Chemical class OOS(O)(=O)=O FHHJDRFHHWUPDG-UHFFFAOYSA-N 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- WVDDGKGOMKODPV-ZQBYOMGUSA-N phenyl(114C)methanol Chemical compound O[14CH2]C1=CC=CC=C1 WVDDGKGOMKODPV-ZQBYOMGUSA-N 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 125000005496 phosphonium group Chemical group 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920002587 poly(1,3-butadiene) polymer Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920002857 polybutadiene Polymers 0.000 description 1
- 229920001748 polybutylene Polymers 0.000 description 1
- 229920005906 polyester polyol Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920006324 polyoxymethylene Polymers 0.000 description 1
- 239000001205 polyphosphate Substances 0.000 description 1
- 235000011176 polyphosphates Nutrition 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 239000005033 polyvinylidene chloride Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 238000007142 ring opening reaction Methods 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- DUIOPKIIICUYRZ-UHFFFAOYSA-N semicarbazide Chemical compound NNC(N)=O DUIOPKIIICUYRZ-UHFFFAOYSA-N 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 125000005372 silanol group Chemical group 0.000 description 1
- FDNAPBUWERUEDA-UHFFFAOYSA-N silicon tetrachloride Chemical compound Cl[Si](Cl)(Cl)Cl FDNAPBUWERUEDA-UHFFFAOYSA-N 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 description 1
- 235000019982 sodium hexametaphosphate Nutrition 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 230000007928 solubilization Effects 0.000 description 1
- 238000005063 solubilization Methods 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 239000012798 spherical particle Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 229910052572 stoneware Inorganic materials 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000001384 succinic acid Substances 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-O sulfonium group Chemical group [SH3+] RWSOTUBLDIXVET-UHFFFAOYSA-O 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 238000010345 tape casting Methods 0.000 description 1
- 229960003080 taurine Drugs 0.000 description 1
- 150000003505 terpenes Chemical class 0.000 description 1
- 235000007586 terpenes Nutrition 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 150000005622 tetraalkylammonium hydroxides Chemical class 0.000 description 1
- HLZKNKRTKFSKGZ-UHFFFAOYSA-N tetradecan-1-ol Chemical compound CCCCCCCCCCCCCCO HLZKNKRTKFSKGZ-UHFFFAOYSA-N 0.000 description 1
- BSYVTEYKTMYBMK-UHFFFAOYSA-N tetrahydrofurfuryl alcohol Chemical compound OCC1CCCO1 BSYVTEYKTMYBMK-UHFFFAOYSA-N 0.000 description 1
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- KSBAEPSJVUENNK-UHFFFAOYSA-L tin(ii) 2-ethylhexanoate Chemical compound [Sn+2].CCCCC(CC)C([O-])=O.CCCCC(CC)C([O-])=O KSBAEPSJVUENNK-UHFFFAOYSA-L 0.000 description 1
- 238000004448 titration Methods 0.000 description 1
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 1
- IMFACGCPASFAPR-UHFFFAOYSA-N tributylamine Chemical compound CCCCN(CCCC)CCCC IMFACGCPASFAPR-UHFFFAOYSA-N 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- IMNIMPAHZVJRPE-UHFFFAOYSA-N triethylenediamine Chemical compound C1CN2CCN1CC2 IMNIMPAHZVJRPE-UHFFFAOYSA-N 0.000 description 1
- AAAQKTZKLRYKHR-UHFFFAOYSA-N triphenylmethane Chemical compound C1=CC=CC=C1C(C=1C=CC=CC=1)C1=CC=CC=C1 AAAQKTZKLRYKHR-UHFFFAOYSA-N 0.000 description 1
- AVWRKZWQTYIKIY-UHFFFAOYSA-N urea-1-carboxylic acid Chemical compound NC(=O)NC(O)=O AVWRKZWQTYIKIY-UHFFFAOYSA-N 0.000 description 1
- 150000003673 urethanes Chemical class 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- PAPBSGBWRJIAAV-UHFFFAOYSA-N ε-Caprolactone Chemical compound O=C1CCCCCO1 PAPBSGBWRJIAAV-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/02—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/703—Isocyanates or isothiocyanates transformed in a latent form by physical means
- C08G18/705—Dispersions of isocyanates or isothiocyanates in a liquid medium
- C08G18/706—Dispersions of isocyanates or isothiocyanates in a liquid medium the liquid medium being water
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/36—Silica
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J175/00—Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
- C09J175/04—Polyurethanes
- C09J175/06—Polyurethanes from polyesters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2170/00—Compositions for adhesives
- C08G2170/80—Compositions for aqueous adhesives
Description
即ち、本発明は、下記の成分(a)及び(b)を含有する水性ポリマー分散液に関する:
(a)60〜350nm(好ましくは、20〜80nm)の平均粒径を有する少なくとも1種のポリウレタンの分散液、及び
(b)20〜400nm(好ましくは、30〜100nm、特に好ましくは、40〜80nm)の粒径を有するSiO2粒子を含有する少なくとも1種の二酸化珪素の水性分散液。
(A1)ポリイソシアネート、
(A2)400〜8000の平均分子量を有するポリマー性ポリオール及び/又はポリアミン、
(A3)所望による分子量が400までのモノアルコール、ポリアルコール、モノアミン、ポリアミン又はアミノアルコール、
(A4)少なくとも1個のイオン性基又は潜在的イオン性基を有する化合物、
(A5)非イオン性の親水化化合物。
本発明において、潜在的イオン性基とは、イオン性基を生成することができる基である。
(A1)7〜45重量%、
(A2)50〜91重量%、
(A3)随意に0〜30重量%、
(A4)[イオン性又は潜在的にイオン性の化合物]0〜12重量%、及び
(A5)0〜15重量%。
(A1)10〜30重量%、
(A2)65〜90重量%、
(A3)随意に0〜10重量%、
(A4)[イオン性又は潜在的にイオン性の化合物]3〜9重量%、及び
(A5)0〜10重量%。
(A1)8〜27重量%、
(A2)65〜85重量%、
(A3)随意に0〜8重量%、
(A4)[イオン性又は潜在的にイオン性の化合物]3〜8重量%、及び
(A5)0〜8重量%。
好ましい成分(A3)としては、下記の化合物が具体的に例示される:
i)アルカンジオール及びアルカントリオール、例えば、エタンジオール、1,2−及び1,3−プロパンジオール、1,4−及び2,3−ブタンジオール、1,5−ペンタンジオール、1,3−ジメチルプロパンジオール、1,6−ヘキサンジオール、ネオペンチルグリコール、1,4−シクロヘキサンジメタノール、2−メチル−1,3−プロパンジオール、2−エチル−2−ブチルプロパンジオール、トリメチルペンタンジオール、ジエチルオクタンジオール位置異性体、1,2−及び1,4−シクロヘキサンジオール、水素化ビスフェノールA[2,2−ビス(4−ヒドロキシシクロヘキシル)−プロパン]、2,2−ジメチル−3−ヒドロキシプロピオン酸2,2−ジメチル−3−ヒドロキシプロピルエステル、トリメチロールエタン、トリメチロールプロパン、並びにグリセロール。
HO−(CH2)x−CO−O−(CH2)y−OH (I)
HO−(CH2)x−O−CO−R−CO−O−(CH2)x−OH (II)
(式中、Rは炭素原子数が1〜10、好ましくは2〜6のアルキレン基又はアリーレン基を示し、xは2〜6の数を示し、yは3〜5の数を示す)
モノ−及びジヒドロキシカルボン酸、モノ−及びジアミノカルボン酸、モノ−及びジヒドロキシスルホン酸、モノ−及びジアミノスルホン酸、モノ−及びジヒドロキシホスホン酸、モノ−及びジアミノホスホン酸並びにこれらの塩類、例えば、ジメチロールプロピオン酸、ジメチロール酪酸、ヒドロキシピバリン酸、N−(2−アミノエチル)−β−アラニン、2−(2−アミノ−エチルアミノ)−エタンスルホン酸、1,2−又は1,3−プロピレンジアミン−β−エチルスルホン酸、エチレンジアミン−プロピル−若しくは−ブチルスルホン酸、リンゴ酸、クエン酸、グリコール酸、乳酸、グリシン、アラニン、タウリン、リシン、3,5−ジアミノ安息香酸、及びIPDIとアクリル酸との付加物(EP−A0916647の実施例1参照)並びにこれらのアルカリ金属塩及び/又はアンモニウム塩;亜硫酸水素ナトリウムと2−ブテン−1,4−ジオールとの付加物、ポリエーテル−スルホネート、2−ブテンジオールとNaHSO3とのプロポキシル化付加物(例えば、DE−A2446440、第5頁〜第9頁、式I〜III参照)、カチオン性基へ変換可能なユニットを有する化合物、例えば、親水性ビルダー成分としてのN−メチル−ジエタノールアミン。
飽和モノアルコール、例えば、メタノール、エタノール、n−プロパノール、イソプロパノール、n−ブタノール、イソブタノール、sec−ブタノール、ペンタノール異性体、ヘキサノール異性体、オクタノール異性体、ノナノール異性体、n−デカノール、n−ドデカノール、n−テトラデカノール、n−ヘキサデカノール、n−オクタデカノール、シクロヘキサノール、メチルシクロヘキサノール異性体、ヒドロキシメチルシクロヘキサン異性体、3−エチル−3−ヒドロキシメチルオキセタン及びテトラヒドロフルフリルアルコール等、ジエチレングリコールモノアルキルエーテル、例えば、ジエチレングリコールモノブチルエーテル等、不飽和アルコール、例えば、アリルアルコール、1,1−ジメチルアリルアルコール及びオレイルアルコール等、芳香族アルコール、例えば、フェノール、クレゾール異性体及びメトキシフェノール異性体等、芳香族−脂肪族アルコール、例えば、ベンジルアルコール、アニシルアルコール及び桂皮アルコール等、第2モノアミン、例えば、ジメチルアミン、ジエチルアミン、ジプロピルアミン、ジイソプロピルアミン、ジブチルアミン、ビス−(2−エチルヘキシル)−アミン、N−メチル−及びN−エチルシクロヘキシルアミン及びジシクロヘキシルアミン等、複素環式第2アミン、例えば、モルホリン、ピロリジン、ピペリジン及び1H−ピラゾール等。好ましいスターター分子は飽和モノアルコールである。スターター分子としてジエチレングリコールモノブチルエーテルを使用することは特に好ましい。
SiO2粒子は、その粒子表面上にヒドロキシル基を有していることも好ましい。
使用したポリウレタン分散液、二酸化珪素及び架橋剤をそれぞれ以下の表1,表2及び表3に示す。
1.2.1 衝撃活性化後の軟質PVC上での剥離強さの測定
この試験は、EN1392に従っておこなった。軟質PVC[ジオクチルフタレート(DOP)30%含有]製の2枚の試験体(100mm×30mm)の表面を研磨紙[グレイン(grain):80]で粗面化させ、上記試験体の両方の粗面上に上記の分散液を刷毛塗りした後、これらの試験体を室温で60分間乾燥させ、次いで、衝撃活性化処理に付した。接着性表面を、ファンク社製IRランプ「ショック・アクチベーター(Shock Activator)2000」を用いる照射処理に10秒間付した。この照射処理中において、接着性試験体の表面温度は90℃+/−2℃に達した。接着剤を塗布した試験体を熱活性化処理に付した後、直ちにこれらの試験体の活性化接着剤層を相互に接着させ、該接着体をゲージ圧4barの条件下で60秒間加圧した。得られた接着体の引裂試験を、市販の引張試験機を使用して室温でおこなった。剥離強さは接着直後と三日間経過後に測定した。試験体は温度が23℃で、相対湿度が50%の条件下で貯蔵した。
材料:
ブナ材試験体(50×150×4mm)
PVCフィルム[「レノリット(Renolit)32052096ストラクトン」;レノリット・ボルムス社(独国)製]
デスモデュール(Desmodur)(登録商標)DN
接着剤の塗布:
一成分系接着剤の塗布は、ドクターナイフを使用しておこなった(塗布厚:200μm)。
接着剤を塗布した後、室温で少なくとも3時間放置した。
加圧条件:
接合温度77℃において、4barの圧力を10秒間印加した。
乾燥室内での試験条件:
試験は、2.5kgの負荷を印加する条件下で80℃の空気を循環させる乾燥室内でおこなった。
接着剤は1成分系として、ドクターナイフを使用して木材試験体に塗布した(塗布厚:200μm)。フィルムは、エッジを3回折り重ねた後で全長が12cmになるように切断した。接着剤を塗布してから3時間経過後、木材試験体を膜プレス上において、4barの有効圧を10秒間印加させることによってフィルムに接合させた(接合温度:77℃)。
配合物を調製するために、ポリウレタン分散液をガラス製ビーカー内へ最初に導入し、次いで、二酸化珪素を撹拌下で添加した。2成分接着剤を調製するために、分散液100重量部を、乳化可能な架橋性イソシアネート3重量部と少なくとも2分間均一に混合させた。この混合物は約2時間にわたって使用可能であった。種々の配合物の配合処方を以下の表4に示す。
1.4.1 軟質PVC上での剥離強さの測定
該剥離強さの測定値を以下の表5に示す。
3種類の配合物のIHRの測定値を以下の表6に示す。
Claims (9)
- 下記の成分(a)及び(b)を、不揮発性成分の重量に基づいて、それぞれ55〜99重量%及び1〜45重量%含有する水性接着剤組成物:
(a)60〜350nmの平均粒径を有するポリウレタンの分散液、及び
(b)20〜400nmの粒径を有するSiO2粒子を含有する二酸化珪素の水性分散液。 - SiO2粒子が30〜100nmの粒径を有する請求項1記載の水性接着剤組成物。
- SiO2粒子が40〜80nmの粒径を有する請求項1記載の水性接着剤組成物。
- SiO2粒子が離散した未架橋一次粒子の形態にある請求項1から3いずれかに記載の
水性接着剤組成物。 - SiO2粒子が、該粒子の表面上にヒドロキシル基を有する請求項1から4いずれかに
記載の水性接着剤組成物。 - 二酸化珪素の水性分散液(b)が水性シリカゾルである請求項1から5いずれかに記載
の水性接着剤組成物。 - 請求項1から6いずれかに記載の水性接着剤組成物の製造方法であって、ポリウレタン
の分散液(a)を二酸化珪素の水性分散液(b)と混合し、次いで、所望により、得られる混合物に常套の接着剤用の助剤及び添加剤を添加することを含む該水性接着剤組成物の製造方法。 - 請求項1から6いずれかに記載の水性接着剤組成物によって接着された支持体。
- 支持体が靴の構造部材又は靴である請求項8記載の支持体。
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DE10343675A DE10343675A1 (de) | 2003-09-18 | 2003-09-18 | Wässrige Klebstoff-Dispersionen |
DE10343675.8 | 2003-09-18 | ||
PCT/EP2004/009933 WO2005035684A1 (de) | 2003-09-18 | 2004-09-07 | Wässrige klebstoff-dispersionen |
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US20130101540A1 (en) * | 2011-10-21 | 2013-04-25 | Bayer Materialscience Llc | Aqueous dispersions of polyurethane and nanoparticles |
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EP1664227A1 (de) | 2006-06-07 |
DE10343675A1 (de) | 2005-04-14 |
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UA84168C2 (en) | 2008-09-25 |
TWI382073B (zh) | 2013-01-11 |
US20050131109A1 (en) | 2005-06-16 |
MXPA06002937A (es) | 2006-05-31 |
KR20060083210A (ko) | 2006-07-20 |
CN1852961A (zh) | 2006-10-25 |
RU2006112558A (ru) | 2007-11-10 |
US8114931B2 (en) | 2012-02-14 |
CA2538956C (en) | 2013-01-15 |
DE502004010359D1 (de) | 2009-12-24 |
ATE448284T1 (de) | 2009-11-15 |
AU2004280361B2 (en) | 2010-09-23 |
HK1097290A1 (en) | 2007-06-22 |
KR101158133B1 (ko) | 2012-06-19 |
WO2005035684A1 (de) | 2005-04-21 |
EP1664227B1 (de) | 2009-11-11 |
ES2334572T3 (es) | 2010-03-12 |
PL1664227T3 (pl) | 2010-04-30 |
AU2004280361A1 (en) | 2005-04-21 |
CA2538956A1 (en) | 2005-04-21 |
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