CN105602513A - 纵向水密封耐腐蚀船用特种电缆 - Google Patents

纵向水密封耐腐蚀船用特种电缆 Download PDF

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Publication number
CN105602513A
CN105602513A CN201511010855.3A CN201511010855A CN105602513A CN 105602513 A CN105602513 A CN 105602513A CN 201511010855 A CN201511010855 A CN 201511010855A CN 105602513 A CN105602513 A CN 105602513A
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Prior art keywords
cable
special cable
corrosion
longitudinally water
stop anti
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Inventor
杜娟
朱有明
朱金鑫
路永鸣
苗福庆
钱永红
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YANGZHOU JIN XIN CABLE CO Ltd
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YANGZHOU JIN XIN CABLE CO Ltd
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Priority to CN201511010855.3A priority Critical patent/CN105602513A/zh
Publication of CN105602513A publication Critical patent/CN105602513A/zh
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J175/00—Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
    • C09J175/04—Polyurethanes
    • C09J175/08—Polyurethanes from polyethers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/38—Low-molecular-weight compounds having heteroatoms other than oxygen
    • C08G18/3855—Low-molecular-weight compounds having heteroatoms other than oxygen having sulfur
    • C08G18/3863—Low-molecular-weight compounds having heteroatoms other than oxygen having sulfur containing groups having sulfur atoms between two carbon atoms, the sulfur atoms being directly linked to carbon atoms or other sulfur atoms
    • C08G18/3865—Low-molecular-weight compounds having heteroatoms other than oxygen having sulfur containing groups having sulfur atoms between two carbon atoms, the sulfur atoms being directly linked to carbon atoms or other sulfur atoms containing groups having one sulfur atom between two carbon atoms
    • C08G18/3868—Low-molecular-weight compounds having heteroatoms other than oxygen having sulfur containing groups having sulfur atoms between two carbon atoms, the sulfur atoms being directly linked to carbon atoms or other sulfur atoms containing groups having one sulfur atom between two carbon atoms the sulfur atom belonging to a sulfide group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/4825—Polyethers containing two hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
    • C08G18/7614—Polyisocyanates or polyisothiocyanates cyclic aromatic containing only one aromatic ring
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02—Non-macromolecular additives
    • C09J11/04—Non-macromolecular additives inorganic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00—Applications
    • C08L2203/20—Applications use in electrical or conductive gadgets
    • C08L2203/202—Applications use in electrical or conductive gadgets use in electrical wires or wirecoating

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Inorganic Chemistry (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Sealing Material Composition (AREA)
  • Adhesives Or Adhesive Processes (AREA)

Abstract

本发明公开了纵向水密封耐腐蚀船用特种电缆，以异氰酸酯、聚氧化丙烯二醇、乙烯基树脂、3,5-二甲硫基甲苯二胺、N，N-二环已基-2-笨并噻唑次磺酰胺、纳米材料为原料，采用成熟的原位聚合法和无机纳米材料反加料法合成一款胶黏剂；本发明提供纵向水密封耐腐蚀船用特种电缆，此电缆能在外部环境恶劣条件下不凝固、耐曲折，保证了长时间使用后水汽不会因电缆的摆动而渗入到电缆内部裂缝中。

Description

纵向水密封耐腐蚀船用特种电缆
技术领域
本发明涉及电缆，具体涉及纵向水密封耐腐蚀船用特种电缆。
背景技术
目前国内市场上的密封胶在电缆加工完成之后一段时间会在内部产生凝固，长时间使用后会有破损现象，不耐折曲、不耐低温，刚产生时能保证不渗水，时间长了后水汽会因电缆的摆动而渗入到电缆内部裂缝中。
发明内容
本发明提供纵向水密封耐腐蚀船用特种电缆，此电缆能在外部环境恶劣条件下不凝固、耐曲折，保证了长时间使用后水汽不会因电缆的摆动而渗入到电缆内部裂缝中。
本发明采取的技术方案如下：纵向水密封耐腐蚀船用特种电缆，以异氰酸酯、聚氧化丙烯二醇、乙烯基树脂、3,5-二甲硫基甲苯二胺、N，N-二环已基-2-笨并噻唑次磺酰胺、纳米材料为原料，采用成熟的原位聚合法和无机纳米材料反加料法合成一款胶黏剂；
主要反应如下：
(1)TDI改性纳米SiO2原理
(2)席夫碱工艺
(3)预聚体反应机理
(4)预聚体扩链反应
本发明的有益效果在于：本发明提供纵向水密封耐腐蚀船用特种电缆，此电缆能在外部环境恶劣条件下不凝固、耐曲折，保证了长时间使用后水汽不会因电缆的摆动而渗入到电缆内部裂缝中。
具体实施方式
下面将对本发明作进一步描述：
纵向水密封耐腐蚀船用特种电缆，以异氰酸酯、聚氧化丙烯二醇、乙烯基树脂、3,5-二甲硫基甲苯二胺、N，N-二环已基-2-笨并噻唑次磺酰胺、纳米材料为原料，结合相应助剂，采用成熟的原位聚合法和无机纳米材料反加料法合成一款胶黏剂；此胶黏剂具有密封性好，该胶黏剂使用范围广，玻璃化转变温度低，能在外部环境恶劣条件下不凝固、耐折曲，大大提高了电缆的密封性能和使用寿命。
主要反应如下：
(1)TDI改性纳米SiO2原理
(2)席夫碱工艺
(3)预聚体反应机理
(4)预聚体扩链反应
本发明提供纵向水密封耐腐蚀船用特种电缆，此电缆能在外部环境恶劣条件下不凝固、耐曲折，保证了长时间使用后水汽不会因电缆的摆动而渗入到电缆内部裂缝中。
本发明的实施例只是介绍其具体实施方式，不在于限制其保护范围。本行业的技术人员在本实施例的启发下可以做出某些修改，故凡依照本发明专利范围所做的等效变化或修饰，均属于本发明专利权利要求范围内。

Claims (1)

1.纵向水密封耐腐蚀船用特种电缆，其特征在于，以异氰酸酯、聚氧化丙烯二醇、乙烯基树脂、3,5-二甲硫基甲苯二胺、N，N-二环已基-2-笨并噻唑次磺酰胺、纳米材料为原料，采用成熟的原位聚合法和无机纳米材料反加料法合成一款胶黏剂；
主要反应如下：
（1）TDI改性纳米SiO2原理
席夫碱工艺
（3）预聚体反应机理
（4）预聚体扩链反应
。
CN201511010855.3A 2015-12-30 2015-12-30 纵向水密封耐腐蚀船用特种电缆 Pending CN105602513A (zh)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110003838A (zh) * 2019-03-13 2019-07-12 扬州市金鑫电缆有限公司 一种水密电缆填充密封胶制备方法及其在电缆制品中的应用

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1664227B1 (de) * 2003-09-18 2009-11-11 Bayer MaterialScience AG Wässrige klebstoff-dispersionen
CN102153984A (zh) * 2011-01-26 2011-08-17 山西省应用化学研究所 一种单组份高耐热性水性聚氨酯胶粘剂的制备方法
CN103013423A (zh) * 2012-12-20 2013-04-03 南通高盟新材料有限公司 耐高温水性聚氨酯胶黏剂的制备方法
CN105153990A (zh) * 2015-09-02 2015-12-16 太仓顺如成建筑材料有限公司 一种纳米改性聚氨酯胶粘剂的制备方法

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1664227B1 (de) * 2003-09-18 2009-11-11 Bayer MaterialScience AG Wässrige klebstoff-dispersionen
CN102153984A (zh) * 2011-01-26 2011-08-17 山西省应用化学研究所 一种单组份高耐热性水性聚氨酯胶粘剂的制备方法
CN103013423A (zh) * 2012-12-20 2013-04-03 南通高盟新材料有限公司 耐高温水性聚氨酯胶黏剂的制备方法
CN105153990A (zh) * 2015-09-02 2015-12-16 太仓顺如成建筑材料有限公司 一种纳米改性聚氨酯胶粘剂的制备方法

Non-Patent Citations (4)

* Cited by examiner, † Cited by third party
Title
周亚民等: "纳米SiO2改性及纳米SiO2聚氨酯密封胶的制备", 《新型建筑材料》 *
山西省化工研究所编: "《聚氨酯弹性体手册》", 31 January 2001, 化学工业出版社 *
陈亮等: "舰船用纵向高压水密封电力电缆的研制", 《电线电缆》 *
马世昌: "《化学物质辞典》", 30 April 1999, 陕西科学技术出版社 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110003838A (zh) * 2019-03-13 2019-07-12 扬州市金鑫电缆有限公司 一种水密电缆填充密封胶制备方法及其在电缆制品中的应用

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