JP4897291B2 - インクジェット用抜染インクおよび抜染加工されたポリエステル系繊維布帛の製造方法 - Google Patents
インクジェット用抜染インクおよび抜染加工されたポリエステル系繊維布帛の製造方法 Download PDFInfo
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- JP4897291B2 JP4897291B2 JP2005514388A JP2005514388A JP4897291B2 JP 4897291 B2 JP4897291 B2 JP 4897291B2 JP 2005514388 A JP2005514388 A JP 2005514388A JP 2005514388 A JP2005514388 A JP 2005514388A JP 4897291 B2 JP4897291 B2 JP 4897291B2
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- ink
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- 239000004744 fabric Substances 0.000 title claims description 46
- 229920000728 polyester Polymers 0.000 title claims description 25
- 239000000835 fiber Substances 0.000 title claims description 23
- 238000004519 manufacturing process Methods 0.000 title claims description 9
- ZRALSGWEFCBTJO-UHFFFAOYSA-N Guanidine Chemical compound NC(N)=N ZRALSGWEFCBTJO-UHFFFAOYSA-N 0.000 claims description 22
- 239000002736 nonionic surfactant Substances 0.000 claims description 22
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 19
- 239000002253 acid Substances 0.000 claims description 12
- 150000003839 salts Chemical class 0.000 claims description 12
- CHJJGSNFBQVOTG-UHFFFAOYSA-N N-methyl-guanidine Natural products CNC(N)=N CHJJGSNFBQVOTG-UHFFFAOYSA-N 0.000 claims description 11
- SWSQBOPZIKWTGO-UHFFFAOYSA-N dimethylaminoamidine Natural products CN(C)C(N)=N SWSQBOPZIKWTGO-UHFFFAOYSA-N 0.000 claims description 11
- 239000000049 pigment Substances 0.000 claims description 11
- 238000010438 heat treatment Methods 0.000 claims description 10
- 238000004040 coloring Methods 0.000 claims description 8
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 7
- 238000007641 inkjet printing Methods 0.000 claims description 7
- 150000002989 phenols Chemical class 0.000 claims description 4
- 239000000976 ink Substances 0.000 description 84
- 239000000975 dye Substances 0.000 description 27
- 238000000034 method Methods 0.000 description 21
- 238000004042 decolorization Methods 0.000 description 20
- 238000007599 discharging Methods 0.000 description 19
- -1 polyoxyethylene Polymers 0.000 description 14
- 230000002829 reductive effect Effects 0.000 description 11
- 239000000986 disperse dye Substances 0.000 description 10
- 230000000694 effects Effects 0.000 description 10
- STIAPHVBRDNOAJ-UHFFFAOYSA-N carbamimidoylazanium;carbonate Chemical compound NC(N)=N.NC(N)=N.OC(O)=O STIAPHVBRDNOAJ-UHFFFAOYSA-N 0.000 description 8
- 230000000052 comparative effect Effects 0.000 description 7
- 239000003795 chemical substances by application Substances 0.000 description 6
- 238000001914 filtration Methods 0.000 description 6
- 238000007639 printing Methods 0.000 description 6
- JGIGXKSJLSQJGQ-UHFFFAOYSA-K trisodium 5-[[4-chloro-6-(N-methylanilino)-1,3,5-triazin-2-yl]amino]-4-hydroxy-3-[(2-sulfonatophenyl)diazenyl]naphthalene-2,7-disulfonate Chemical compound [Na+].[Na+].[Na+].CN(c1ccccc1)c1nc(Cl)nc(Nc2cc(cc3cc(c(N=Nc4ccccc4S([O-])(=O)=O)c(O)c23)S([O-])(=O)=O)S([O-])(=O)=O)n1 JGIGXKSJLSQJGQ-UHFFFAOYSA-K 0.000 description 6
- 125000002091 cationic group Chemical group 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- 230000003287 optical effect Effects 0.000 description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- 239000003513 alkali Substances 0.000 description 4
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 3
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000001768 carboxy methyl cellulose Substances 0.000 description 3
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 3
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 3
- 239000003638 chemical reducing agent Substances 0.000 description 3
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- 239000000985 reactive dye Substances 0.000 description 3
- 238000003860 storage Methods 0.000 description 3
- DXRKLUVKXMAMOV-UHFFFAOYSA-N 3-heptadecylcatechol Chemical compound CCCCCCCCCCCCCCCCCC1=CC=CC(O)=C1O DXRKLUVKXMAMOV-UHFFFAOYSA-N 0.000 description 2
- 229920002125 Sokalan® Polymers 0.000 description 2
- 239000000980 acid dye Substances 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
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- 230000007547 defect Effects 0.000 description 2
- 230000002950 deficient Effects 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical class C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
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- JVBXVOWTABLYPX-UHFFFAOYSA-L sodium dithionite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])=O JVBXVOWTABLYPX-UHFFFAOYSA-L 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- YJYREIFZLKWHMM-UHFFFAOYSA-N (diaminomethylideneamino) hydrogen carbonate Chemical compound NC(N)=NOC(O)=O YJYREIFZLKWHMM-UHFFFAOYSA-N 0.000 description 1
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 description 1
- IHCCLXNEEPMSIO-UHFFFAOYSA-N 2-[4-[2-(2,3-dihydro-1H-inden-2-ylamino)pyrimidin-5-yl]piperidin-1-yl]-1-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethanone Chemical group C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)C1CCN(CC1)CC(=O)N1CC2=C(CC1)NN=N2 IHCCLXNEEPMSIO-UHFFFAOYSA-N 0.000 description 1
- RYYXDZDBXNUPOG-UHFFFAOYSA-N 4,5,6,7-tetrahydro-1,3-benzothiazole-2,6-diamine;dihydrochloride Chemical compound Cl.Cl.C1C(N)CCC2=C1SC(N)=N2 RYYXDZDBXNUPOG-UHFFFAOYSA-N 0.000 description 1
- DEXFNLNNUZKHNO-UHFFFAOYSA-N 6-[3-[4-[2-(2,3-dihydro-1H-inden-2-ylamino)pyrimidin-5-yl]piperidin-1-yl]-3-oxopropyl]-3H-1,3-benzoxazol-2-one Chemical group C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)C1CCN(CC1)C(CCC1=CC2=C(NC(O2)=O)C=C1)=O DEXFNLNNUZKHNO-UHFFFAOYSA-N 0.000 description 1
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- RNIHAPSVIGPAFF-UHFFFAOYSA-N Acrylamide-acrylic acid resin Chemical compound NC(=O)C=C.OC(=O)C=C RNIHAPSVIGPAFF-UHFFFAOYSA-N 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
- 229920002907 Guar gum Polymers 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- VCUFZILGIRCDQQ-KRWDZBQOSA-N N-[[(5S)-2-oxo-3-(2-oxo-3H-1,3-benzoxazol-6-yl)-1,3-oxazolidin-5-yl]methyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical group O=C1O[C@H](CN1C1=CC2=C(NC(O2)=O)C=C1)CNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F VCUFZILGIRCDQQ-KRWDZBQOSA-N 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- SJEYSFABYSGQBG-UHFFFAOYSA-M Patent blue Chemical compound [Na+].C1=CC(N(CC)CC)=CC=C1C(C=1C(=CC(=CC=1)S([O-])(=O)=O)S([O-])(=O)=O)=C1C=CC(=[N+](CC)CC)C=C1 SJEYSFABYSGQBG-UHFFFAOYSA-M 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- FHKPLLOSJHHKNU-INIZCTEOSA-N [(3S)-3-[8-(1-ethyl-5-methylpyrazol-4-yl)-9-methylpurin-6-yl]oxypyrrolidin-1-yl]-(oxan-4-yl)methanone Chemical group C(C)N1N=CC(=C1C)C=1N(C2=NC=NC(=C2N=1)O[C@@H]1CN(CC1)C(=O)C1CCOCC1)C FHKPLLOSJHHKNU-INIZCTEOSA-N 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- XREZMAAQVYVESP-UHFFFAOYSA-N acetyloxymethyl 2-[n-[2-(acetyloxymethoxy)-2-oxoethyl]-2-[2-[2-[bis[2-(acetyloxymethoxy)-2-oxoethyl]amino]-4-fluorophenoxy]ethoxy]-5-fluoroanilino]acetate Chemical compound CC(=O)OCOC(=O)CN(CC(=O)OCOC(C)=O)C1=CC(F)=CC=C1OCCOC1=CC=C(F)C=C1N(CC(=O)OCOC(C)=O)CC(=O)OCOC(C)=O XREZMAAQVYVESP-UHFFFAOYSA-N 0.000 description 1
- 229920006322 acrylamide copolymer Polymers 0.000 description 1
- 239000003463 adsorbent Substances 0.000 description 1
- 150000001447 alkali salts Chemical class 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- 150000008378 aryl ethers Chemical class 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- CEDDGDWODCGBFQ-UHFFFAOYSA-N carbamimidoylazanium;hydron;phosphate Chemical compound NC(N)=N.OP(O)(O)=O CEDDGDWODCGBFQ-UHFFFAOYSA-N 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 150000007942 carboxylates Chemical class 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 239000000982 direct dye Substances 0.000 description 1
- 238000010018 discharge printing Methods 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 238000009415 formwork Methods 0.000 description 1
- DXTIKTAIYCJTII-UHFFFAOYSA-N guanidine acetate Chemical compound CC([O-])=O.NC([NH3+])=N DXTIKTAIYCJTII-UHFFFAOYSA-N 0.000 description 1
- 239000000665 guar gum Substances 0.000 description 1
- 235000010417 guar gum Nutrition 0.000 description 1
- 229960002154 guar gum Drugs 0.000 description 1
- 101150032210 hel-1 gene Proteins 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 150000002484 inorganic compounds Chemical class 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 239000011630 iodine Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 1
- 229920002401 polyacrylamide Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 235000019422 polyvinyl alcohol Nutrition 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 239000002964 rayon Substances 0.000 description 1
- 239000000661 sodium alginate Substances 0.000 description 1
- 235000010413 sodium alginate Nutrition 0.000 description 1
- 229940005550 sodium alginate Drugs 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/15—Locally discharging the dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/15—Locally discharging the dyes
- D06P5/158—Locally discharging the dyes with other compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/30—Ink jet printing
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/60—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing polyethers
- D06P1/613—Polyethers without nitrogen
- D06P1/6131—Addition products of hydroxyl groups-containing compounds with oxiranes
- D06P1/6135—Addition products of hydroxyl groups-containing compounds with oxiranes from aromatic alcohols or from phenols, naphthols
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
- D06P1/642—Compounds containing nitrogen
- D06P1/649—Compounds containing carbonamide, thiocarbonamide or guanyl groups
- D06P1/6494—Compounds containing a guanyl group R-C-N=, e.g. (bi)guanadine, dicyandiamid amidines
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/34—Material containing ester groups
- D06P3/52—Polyesters
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/34—Material containing ester groups
- D06P3/52—Polyesters
- D06P3/522—Polyesters using basic dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/34—Material containing ester groups
- D06P3/52—Polyesters
- D06P3/54—Polyesters using dispersed dyestuffs
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Coloring (AREA)
- Ink Jet Recording Methods And Recording Media Thereof (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Description
ポリオキシエチレンクロロフェニルエーテル(HLB13.5、EO付加モル数6)を20部、C.I. Reactive Red 24(アゾ系)を0.02部、炭酸グアニジン3部、純水76.98部を混合、2時間攪拌し、東洋濾紙No.5Aにて減圧濾過後、真空脱気処理し、インクジェット用インクを得た。
ポリエステル100%の起毛布帛に、難還元脱色性分散染料であるC.I. Disperse Blue 60を用いて浸染処理を行ない、つぎにカルボキシメチルセルロース(ファインガムHEL−1、第一工業製薬(株)製)を付与量20g/m2になるようディップニップ法にて付与、乾燥し、インク受容層を設けた染色起毛布を得た。
印写装置:オンデマンド方式シリアル走査型インクジェット印写装置(ピエゾ変換方式)
ノズル径:50μm
駆動電圧:100V
周波数 :5kHz
解像度 :360dpi
付与量 :20、40、60、80、100g/m2
印写柄 :付与量毎のマトリックス柄
ポリオキシエチレントリスチレン化フェニルエーテル(HLB12、EO付加モル数14)を8部、C.I. Reactive Red 24を0.02部、炭酸グアニジンを3部、純水88.98部を混合、2時間攪拌し、東洋濾紙No.5Aにて減圧濾過後、真空脱気処理し、インクジェット用インクを得た。
ポリオキシエチレンノニルフェニルエーテル(HLB7.4、EO付加モル数3)を10部、C.I. Reactive Red 24を0.02部、炭酸グアニジンを3部、純水86.98部を混合、2時間攪拌し、東洋濾紙No.5Aにて減圧濾過後、真空脱気処理し、インクジェット用インクを得た。
ポリオキシエチレンスチレン化フェニルエーテル(HLB16.9、EO付加モル数50)を5部、C.I. Reactive Red 24を0.02部、炭酸グアニジンを3部、純水91.98部を混合、2時間攪拌し、東洋濾紙No.5Aにて減圧濾過後、真空脱気処理し、インクジェット用インクを得た。
ポリオキシエチレンクロロフェニルエーテル(HLB13.5、EO付加モル数6)を20部、C.I. Reactive Red 24を0.02部、純水79.98部を混合、2時間攪拌し、東洋濾紙No.5Aにて減圧濾過後、真空脱気処理し、インクジェット用インクを得た。
炭酸グアニジンを3部、C.I. Reactive Red 24を0.02部、純水96.98部を混合、2時間攪拌し、東洋濾紙No.5Aにて減圧濾過後、真空脱気処理し、インクジェット用インクを得た。
(株)東京計器BL型粘度計 BLローター(60rpm、25℃)を用いて測定した。
1ドットパターンを普通紙に60分間連続印写し、目視でドットの乱れ、および詰まりを確認した。
◎ 60分間、吐出不良は全く無し
○ 10分間、吐出不良は全く無し
△ ノズル詰まりは無いが、吐出不良ノズル有り
× 詰まりノズル有り、吐出不可能
(株)島津製作所製UV2200を用いて、インクを400nm〜700nmの範囲でスペクトル測定を行い、最大吸収ピーク波長での光学密度を測定した。
マクベスRD918(マクベス社製)を用いて抜色前後の反射濃度を測定し、抜色前の反射濃度を100%として評価した。
◎ すべての付与量において、50%以上抜色されている
○ すべての付与量において、30%以上抜色されている
△ すべての付与量において、10%以上抜色されている
× すべての付与量において、抜色が10%より少ない
目視により評価した。
○ すべての付与量において、抜色前後で色相変化無し
△ すべての付与量において、わずかに色相変化が認められる
× すべての付与量において、色相の違いが一見して判別できる
Claims (5)
- HLB値が9〜16であり、エチレンオキサイド付加モル数が30以下である非イオン性界面活性剤、グアニジン弱酸塩、および水からなり、
前記非イオン性界面活性剤が、ハロゲン化フェノールのエチレンオキサイド付加物であるインクジェット用抜染インク。 - さらに水溶性色素を含む請求項1記載のインクジェット用抜染インク。
- 前記非イオン性界面活性剤の含有量が5〜30重量%、前記グアニジン弱酸塩の含有量が0.1〜5重量%である請求項1記載のインクジェット用抜染インク。
- 色素が付与されたポリエステル系繊維を含む布帛に、HLB値が9〜16であり、エチレンオキサイド付加モル数が30以下である非イオン性界面活性剤、グアニジン弱酸塩、および水からなるインクジェット用抜染インクをインクジェットにて噴射する工程、150〜190℃で湿熱処理または乾熱処理する工程、およびソーピング処理する工程を含み、
前記非イオン性界面活性剤が、ハロゲン化フェノールのエチレンオキサイド付加物である抜染加工されたポリエステル系繊維布帛の製造方法。 - 前記色素が付与されたポリエステル系繊維を含む布帛に、インク受容層を付与する工程を含む、請求項4記載の抜染加工されたポリエステル系繊維布帛の製造方法。
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JP2005514388A JP4897291B2 (ja) | 2003-09-30 | 2004-09-16 | インクジェット用抜染インクおよび抜染加工されたポリエステル系繊維布帛の製造方法 |
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JP2005514388A JP4897291B2 (ja) | 2003-09-30 | 2004-09-16 | インクジェット用抜染インクおよび抜染加工されたポリエステル系繊維布帛の製造方法 |
PCT/JP2004/013528 WO2005033221A1 (ja) | 2003-09-30 | 2004-09-16 | インクジェット用抜染インクおよび抜染加工されたポリエステル系繊維布帛の製造方法 |
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US (1) | US20050237369A1 (ja) |
EP (1) | EP1669419A4 (ja) |
JP (1) | JP4897291B2 (ja) |
CN (1) | CN1860191A (ja) |
WO (1) | WO2005033221A1 (ja) |
Families Citing this family (12)
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US8075963B2 (en) * | 2006-02-07 | 2011-12-13 | Eastman Kodak Company | Material for forming images by inkjet printing |
JP2007224128A (ja) * | 2006-02-22 | 2007-09-06 | Shima Seiki Mfg Ltd | 抜染インク、インクジェット抜染方法および抜染対象物 |
US8337978B2 (en) | 2010-08-18 | 2012-12-25 | Hewlett-Packard Development Company, L.P. | Recording material containing nonionic surfactants |
US8764894B2 (en) | 2010-10-29 | 2014-07-01 | Hewlett-Packard Development Company, L.P. | Ink dispersion |
US8628183B2 (en) | 2011-02-15 | 2014-01-14 | Hewlett-Packard Development Company, L.P. | Ink coating composition |
CN102704292B (zh) * | 2012-05-25 | 2013-10-30 | 浙江理工大学 | 一种纺织品印花用环保型膏状拔染剂及其制备方法 |
WO2014046110A1 (ja) * | 2012-09-24 | 2014-03-27 | 株式会社カネカ | パイル布帛及びその製造方法 |
EP3374561A4 (en) * | 2015-11-09 | 2019-07-03 | Kornit Digital Ltd. | DECOLORATION REAGENT FOR INKJET COMPOSITIONS |
CN106049115A (zh) * | 2016-03-31 | 2016-10-26 | 南通纺织丝绸产业技术研究院 | 一种喷墨拔染印花织物的制备方法 |
JP7275575B2 (ja) | 2018-12-27 | 2023-05-18 | セイコーエプソン株式会社 | 水性インクジェット用組成物 |
JP7239236B1 (ja) * | 2022-11-30 | 2023-03-14 | エレファンテック株式会社 | 脱色装置、脱色方法 |
JP7300233B1 (ja) * | 2023-03-07 | 2023-06-29 | エレファンテック株式会社 | 脱色装置、脱色方法 |
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2004
- 2004-09-16 EP EP04773186A patent/EP1669419A4/en not_active Withdrawn
- 2004-09-16 CN CNA2004800285265A patent/CN1860191A/zh active Pending
- 2004-09-16 JP JP2005514388A patent/JP4897291B2/ja not_active Expired - Fee Related
- 2004-09-16 WO PCT/JP2004/013528 patent/WO2005033221A1/ja active Application Filing
- 2004-09-16 US US10/519,578 patent/US20050237369A1/en not_active Abandoned
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JPS57154482A (en) * | 1981-03-19 | 1982-09-24 | Komatsu Seiren Co | Coloring and discharge style of synthetic fiber material |
JP2000096461A (ja) * | 1998-09-22 | 2000-04-04 | Nicca Chemical Co Ltd | 合成系繊維材料用抜染剤、抜染加工方法および抜染加工合成系繊維材料 |
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EP1669419A1 (en) | 2006-06-14 |
JPWO2005033221A1 (ja) | 2007-11-15 |
EP1669419A4 (en) | 2009-06-03 |
CN1860191A (zh) | 2006-11-08 |
US20050237369A1 (en) | 2005-10-27 |
WO2005033221A1 (ja) | 2005-04-14 |
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