JP4854904B2 - スチレン系ブロックコポリマーのカップリング方法 - Google Patents
スチレン系ブロックコポリマーのカップリング方法 Download PDFInfo
- Publication number
- JP4854904B2 JP4854904B2 JP2001576911A JP2001576911A JP4854904B2 JP 4854904 B2 JP4854904 B2 JP 4854904B2 JP 2001576911 A JP2001576911 A JP 2001576911A JP 2001576911 A JP2001576911 A JP 2001576911A JP 4854904 B2 JP4854904 B2 JP 4854904B2
- Authority
- JP
- Japan
- Prior art keywords
- coupling
- block
- block copolymer
- polymerized
- polymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 229920006132 styrene block copolymer Polymers 0.000 title claims abstract description 16
- 238000010168 coupling process Methods 0.000 title abstract description 46
- 238000005859 coupling reaction Methods 0.000 claims abstract description 53
- 229920000642 polymer Polymers 0.000 claims abstract description 43
- OECTYKWYRCHAKR-UHFFFAOYSA-N 4-vinylcyclohexene dioxide Chemical compound C1OC1C1CC2OC2CC1 OECTYKWYRCHAKR-UHFFFAOYSA-N 0.000 claims abstract description 23
- 239000000178 monomer Substances 0.000 claims abstract description 20
- 150000001993 dienes Chemical class 0.000 claims abstract description 14
- 229920001400 block copolymer Polymers 0.000 claims abstract description 10
- 239000000203 mixture Substances 0.000 claims abstract description 10
- -1 vinyl aromatic hydrocarbon Chemical class 0.000 claims abstract description 8
- 229920002554 vinyl polymer Polymers 0.000 claims abstract description 7
- 239000000853 adhesive Substances 0.000 claims description 3
- 230000001070 adhesive effect Effects 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- 230000008878 coupling Effects 0.000 abstract description 43
- 238000000034 method Methods 0.000 abstract description 13
- 230000008569 process Effects 0.000 abstract description 2
- 239000007822 coupling agent Substances 0.000 description 24
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 18
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 18
- 238000006116 polymerization reaction Methods 0.000 description 16
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 11
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 10
- 238000006243 chemical reaction Methods 0.000 description 10
- 239000002904 solvent Substances 0.000 description 9
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 6
- 229920005989 resin Polymers 0.000 description 6
- 239000011347 resin Substances 0.000 description 6
- 239000000243 solution Substances 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 125000003118 aryl group Chemical group 0.000 description 5
- 229920001577 copolymer Polymers 0.000 description 5
- 229910052744 lithium Inorganic materials 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- PAAZPARNPHGIKF-UHFFFAOYSA-N 1,2-dibromoethane Chemical compound BrCCBr PAAZPARNPHGIKF-UHFFFAOYSA-N 0.000 description 4
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 4
- 238000005481 NMR spectroscopy Methods 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 239000006184 cosolvent Substances 0.000 description 4
- 238000001035 drying Methods 0.000 description 4
- 238000005227 gel permeation chromatography Methods 0.000 description 4
- 229930195733 hydrocarbon Natural products 0.000 description 4
- 239000003999 initiator Substances 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- ABDKAPXRBAPSQN-UHFFFAOYSA-N veratrole Chemical compound COC1=CC=CC=C1OC ABDKAPXRBAPSQN-UHFFFAOYSA-N 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- LCFVJGUPQDGYKZ-UHFFFAOYSA-N Bisphenol A diglycidyl ether Chemical compound C=1C=C(OCC2OC2)C=CC=1C(C)(C)C(C=C1)=CC=C1OCC1CO1 LCFVJGUPQDGYKZ-UHFFFAOYSA-N 0.000 description 3
- 239000004593 Epoxy Substances 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 238000010539 anionic addition polymerization reaction Methods 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- DMEGYFMYUHOHGS-UHFFFAOYSA-N heptamethylene Natural products C1CCCCCC1 DMEGYFMYUHOHGS-UHFFFAOYSA-N 0.000 description 3
- 150000002430 hydrocarbons Chemical class 0.000 description 3
- WGOPGODQLGJZGL-UHFFFAOYSA-N lithium;butane Chemical compound [Li+].CC[CH-]C WGOPGODQLGJZGL-UHFFFAOYSA-N 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- 229920000647 polyepoxide Polymers 0.000 description 3
- CXWXQJXEFPUFDZ-UHFFFAOYSA-N tetralin Chemical compound C1=CC=C2CCCCC2=C1 CXWXQJXEFPUFDZ-UHFFFAOYSA-N 0.000 description 3
- APQIUTYORBAGEZ-UHFFFAOYSA-N 1,1-dibromoethane Chemical compound CC(Br)Br APQIUTYORBAGEZ-UHFFFAOYSA-N 0.000 description 2
- FGQLGYBGTRHODR-UHFFFAOYSA-N 2,2-diethoxypropane Chemical compound CCOC(C)(C)OCC FGQLGYBGTRHODR-UHFFFAOYSA-N 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- RGSFGYAAUTVSQA-UHFFFAOYSA-N Cyclopentane Chemical compound C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 2
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 2
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 2
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 2
- 239000005062 Polybutadiene Substances 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 150000001450 anions Chemical class 0.000 description 2
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- NNBZCPXTIHJBJL-UHFFFAOYSA-N decalin Chemical compound C1CCCC2CCCCC21 NNBZCPXTIHJBJL-UHFFFAOYSA-N 0.000 description 2
- 239000003822 epoxy resin Substances 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 2
- 229920001519 homopolymer Polymers 0.000 description 2
- AMXOYNBUYSYVKV-UHFFFAOYSA-M lithium bromide Chemical compound [Li+].[Br-] AMXOYNBUYSYVKV-UHFFFAOYSA-M 0.000 description 2
- 239000000155 melt Substances 0.000 description 2
- TZIHFWKZFHZASV-UHFFFAOYSA-N methyl formate Chemical compound COC=O TZIHFWKZFHZASV-UHFFFAOYSA-N 0.000 description 2
- 239000003607 modifier Substances 0.000 description 2
- 229920002857 polybutadiene Polymers 0.000 description 2
- 229920001195 polyisoprene Polymers 0.000 description 2
- 229920000346 polystyrene-polyisoprene block-polystyrene Polymers 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 229920000428 triblock copolymer Polymers 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 239000004831 Hot glue Substances 0.000 description 1
- XOBKSJJDNFUZPF-UHFFFAOYSA-N Methoxyethane Chemical compound CCOC XOBKSJJDNFUZPF-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 239000004820 Pressure-sensitive adhesive Substances 0.000 description 1
- 238000005054 agglomeration Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 125000002723 alicyclic group Chemical group 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 125000002029 aromatic hydrocarbon group Chemical class 0.000 description 1
- 230000001588 bifunctional effect Effects 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 150000004292 cyclic ethers Chemical class 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 229920000359 diblock copolymer Polymers 0.000 description 1
- GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical class C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 238000005485 electric heating Methods 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- 239000002808 molecular sieve Substances 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 150000002900 organolithium compounds Chemical class 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 238000011020 pilot scale process Methods 0.000 description 1
- 239000003505 polymerization initiator Substances 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 238000007086 side reaction Methods 0.000 description 1
- 150000004756 silanes Chemical class 0.000 description 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 238000005292 vacuum distillation Methods 0.000 description 1
- PXXNTAGJWPJAGM-UHFFFAOYSA-N vertaline Natural products C1C2C=3C=C(OC)C(OC)=CC=3OC(C=C3)=CC=C3CCC(=O)OC1CC1N2CCCC1 PXXNTAGJWPJAGM-UHFFFAOYSA-N 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
- C08F297/02—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type
- C08F297/023—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type using a coupling agent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
- C08F297/02—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type
- C08F297/04—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes
- C08F297/044—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes using a coupling agent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G81/00—Macromolecular compounds obtained by interreacting polymers in the absence of monomers, e.g. block polymers
- C08G81/02—Macromolecular compounds obtained by interreacting polymers in the absence of monomers, e.g. block polymers at least one of the polymers being obtained by reactions involving only carbon-to-carbon unsaturated bonds
- C08G81/021—Block or graft polymers containing only sequences of polymers of C08C or C08F
- C08G81/022—Block or graft polymers containing only sequences of polymers of C08C or C08F containing sequences of polymers of conjugated dienes and of polymers of alkenyl aromatic compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J153/00—Adhesives based on block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
- C09J153/02—Vinyl aromatic monomers and conjugated dienes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
- C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
- C08L2666/24—Graft or block copolymers according to groups C08L51/00, C08L53/00 or C08L55/02; Derivatives thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Inorganic Chemistry (AREA)
- Graft Or Block Polymers (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Other Resins Obtained By Reactions Not Involving Carbon-To-Carbon Unsaturated Bonds (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US19796600P | 2000-04-17 | 2000-04-17 | |
| US60/197,966 | 2000-04-17 | ||
| PCT/US2001/012074 WO2001079319A1 (en) | 2000-04-17 | 2001-04-12 | A process for coupling styrenic block copolymers |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2003531228A JP2003531228A (ja) | 2003-10-21 |
| JP2003531228A5 JP2003531228A5 (enExample) | 2008-05-22 |
| JP4854904B2 true JP4854904B2 (ja) | 2012-01-18 |
Family
ID=22731464
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2001576911A Expired - Fee Related JP4854904B2 (ja) | 2000-04-17 | 2001-04-12 | スチレン系ブロックコポリマーのカップリング方法 |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US6730745B2 (enExample) |
| EP (1) | EP1307494B1 (enExample) |
| JP (1) | JP4854904B2 (enExample) |
| AT (1) | ATE512177T1 (enExample) |
| AU (1) | AU2001251594A1 (enExample) |
| BR (1) | BR0110125A (enExample) |
| ES (1) | ES2366634T3 (enExample) |
| WO (1) | WO2001079319A1 (enExample) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002047469A (ja) * | 2000-08-03 | 2002-02-12 | Japan Elastomer Co Ltd | 粘着剤組成物 |
| US7662528B2 (en) * | 2006-02-17 | 2010-02-16 | Xerox Corporation | Charge generating composition |
| BRPI0709865B1 (pt) * | 2006-03-24 | 2018-05-29 | Kraton Polymers U.S. Llc | Processo para a preparação de copolímeros em bloco, copolímero em bloco, e, composição elastomérica |
| US20080226776A1 (en) | 2007-03-14 | 2008-09-18 | Concentrate Manufacturing Company Of Ireland | Tea extracts for reducing off-taste of non-nutritive sweeteners |
| CN109415475B (zh) | 2016-06-30 | 2022-04-05 | 科腾聚合物美国有限责任公司 | 性能改进的高乙烯基嵌段共聚物组合物及其用途 |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH01252682A (ja) * | 1988-04-01 | 1989-10-09 | Nitto Denko Corp | 粘着部材の製造方法 |
| JPH02117669A (ja) * | 1988-10-26 | 1990-05-02 | Daicel Chem Ind Ltd | ビニルシクロヘキサンモノエポキシドおよび／またはシクロヘキサンジエポキシドの製造方法 |
| JPH0616772A (ja) * | 1992-04-03 | 1994-01-25 | Shell Internatl Res Maatschappij Bv | 外部ブロック橋かけ結合のためのエポキシ化ジエンエラストマー |
| JPH08259646A (ja) * | 1995-03-22 | 1996-10-08 | Nippon Elastomer Kk | ブロック共重合体およびその製造方法 |
| WO1998039366A1 (en) * | 1997-03-05 | 1998-09-11 | Daicel Chemical Industries, Ltd. | Block copolymer having (meth)acryloyl groups in the side chains and composition containing the same |
| WO1999001490A1 (de) * | 1997-06-30 | 1999-01-14 | Basf Aktiengesellschaft | Glycidylether aliphatischer polyalkohole als kopplungsmittel in der anionischen polymerisation |
| JP2000290625A (ja) * | 1999-04-07 | 2000-10-17 | Nitto Denko Corp | 粘着剤組成物とその製造方法 |
| JP2001115124A (ja) * | 1998-12-08 | 2001-04-24 | Nitto Denko Corp | 粘着剤組成物およびその製造方法と粘着シ―ト類 |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3211684A (en) * | 1960-08-29 | 1965-10-12 | Bell & Richardson Inc De | Glass-resin coupling composition |
| US3134745A (en) | 1961-04-26 | 1964-05-26 | Dow Chemical Co | Polymeric polyols and method of making the same |
| US3468972A (en) | 1964-06-22 | 1969-09-23 | Phillips Petroleum Co | Control of branching and coupling in lithium-terminated polymers |
| NL135060C (enExample) | 1966-07-14 | |||
| US3595941A (en) | 1966-11-04 | 1971-07-27 | Phillips Petroleum Co | Method for controlling the mooney viscosity of alkali metal-terminated polymers |
| US3652723A (en) | 1970-11-16 | 1972-03-28 | Ford Motor Co | Thermoset molding powders employing polycarboxyl functional prepolymer and diepoxide crosslinking agent |
| US4096203A (en) | 1976-07-30 | 1978-06-20 | Shell Oil Company | Process to control cohesive strength of block copolymer composition |
| BE1006727A3 (fr) * | 1993-02-15 | 1994-11-29 | Fina Research | Procede de preparation de copolymeres sequences. |
| US5461095A (en) * | 1993-08-25 | 1995-10-24 | Shell Oil Company | Block copolymer composition, hot melt adhesive composition containing it, and process for the preparation thereof |
| DE19623415A1 (de) * | 1996-06-12 | 1997-12-18 | Basf Ag | Blockcopolymerisate und diese enthaltende thermoplastische Formmassen |
-
2001
- 2001-04-12 ES ES01924992T patent/ES2366634T3/es not_active Expired - Lifetime
- 2001-04-12 US US10/257,881 patent/US6730745B2/en not_active Expired - Lifetime
- 2001-04-12 BR BR0110125-0A patent/BR0110125A/pt not_active IP Right Cessation
- 2001-04-12 AU AU2001251594A patent/AU2001251594A1/en not_active Abandoned
- 2001-04-12 EP EP01924992A patent/EP1307494B1/en not_active Expired - Lifetime
- 2001-04-12 JP JP2001576911A patent/JP4854904B2/ja not_active Expired - Fee Related
- 2001-04-12 AT AT01924992T patent/ATE512177T1/de not_active IP Right Cessation
- 2001-04-12 WO PCT/US2001/012074 patent/WO2001079319A1/en not_active Ceased
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH01252682A (ja) * | 1988-04-01 | 1989-10-09 | Nitto Denko Corp | 粘着部材の製造方法 |
| JPH02117669A (ja) * | 1988-10-26 | 1990-05-02 | Daicel Chem Ind Ltd | ビニルシクロヘキサンモノエポキシドおよび／またはシクロヘキサンジエポキシドの製造方法 |
| JPH0616772A (ja) * | 1992-04-03 | 1994-01-25 | Shell Internatl Res Maatschappij Bv | 外部ブロック橋かけ結合のためのエポキシ化ジエンエラストマー |
| JPH08259646A (ja) * | 1995-03-22 | 1996-10-08 | Nippon Elastomer Kk | ブロック共重合体およびその製造方法 |
| WO1998039366A1 (en) * | 1997-03-05 | 1998-09-11 | Daicel Chemical Industries, Ltd. | Block copolymer having (meth)acryloyl groups in the side chains and composition containing the same |
| WO1999001490A1 (de) * | 1997-06-30 | 1999-01-14 | Basf Aktiengesellschaft | Glycidylether aliphatischer polyalkohole als kopplungsmittel in der anionischen polymerisation |
| JP2001115124A (ja) * | 1998-12-08 | 2001-04-24 | Nitto Denko Corp | 粘着剤組成物およびその製造方法と粘着シ―ト類 |
| JP2000290625A (ja) * | 1999-04-07 | 2000-10-17 | Nitto Denko Corp | 粘着剤組成物とその製造方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| US6730745B2 (en) | 2004-05-04 |
| EP1307494A1 (en) | 2003-05-07 |
| BR0110125A (pt) | 2003-02-11 |
| JP2003531228A (ja) | 2003-10-21 |
| ATE512177T1 (de) | 2011-06-15 |
| AU2001251594A1 (en) | 2001-10-30 |
| EP1307494B1 (en) | 2011-06-08 |
| WO2001079319A1 (en) | 2001-10-25 |
| US20030212214A1 (en) | 2003-11-13 |
| ES2366634T3 (es) | 2011-10-24 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| KR101432836B1 (ko) | 블록 공중합체 조성물 | |
| KR101389643B1 (ko) | 수소화된 블록 공중합체 조성물 | |
| JP2991790B2 (ja) | 官能性を付与されたエラストマーポリマーの製造方法 | |
| KR100830012B1 (ko) | 방사상 (ｓ-ｉ/ｂ)ｘ 중합체 유래의 접착제 조성물 | |
| TW200307698A (en) | Process for making a coupled block copolymer composition and the resulting composition | |
| JP3699109B2 (ja) | 接着剤用スチレン−イソプレンの三つのアームを有する高耐荷力ブロック共重合体組成物 | |
| KR100626442B1 (ko) | 커플링된 스티렌 블록 공중합체 및 이의 제조방법 | |
| US4148771A (en) | Method of making novel rubbery block copolymers and pressure-sensitive adhesives | |
| EP0711795B1 (en) | Low viscosity adhesive compositions containing asymmetric radial polymers | |
| JPH08337625A (ja) | 非対称性放射状重合体の製造方法 | |
| KR100401300B1 (ko) | 코어관능화된성상블록공중합체 | |
| TWI767030B (zh) | 星狀分枝化二烯橡膠 | |
| JP3519848B2 (ja) | イソプレン含有ブロックコポリマーの製造方法 | |
| JP4854904B2 (ja) | スチレン系ブロックコポリマーのカップリング方法 | |
| JPH07268023A (ja) | 安定な酸無水物環を有するポリマー | |
| JPH08505420A (ja) | エポキシ化ブロックコポリマー | |
| JP3427852B2 (ja) | グラフト化ブロツクコポリマー類の脱色方法 | |
| US20040044133A1 (en) | End-modified styrene-diene block copolymer prepared using polyfunctional coupling agent | |
| KR100191476B1 (ko) | 분지화 및 수소화된 블록 공중합체, 그의 제조방법 및 용도 | |
| JPH07188360A (ja) | 不斉ラジアルポリマーの製造方法 | |
| US8552114B2 (en) | Miktopolymer compositions | |
| KR102138230B1 (ko) | 카르복실산 헤미아세탈 에스테르 화합물, 이를 이용한 비닐방향족-공액디엔 블록 공중합체의 제조방법 및 상기 블록 공중합체를 포함하는 핫멜트 접착제 조성물 | |
| JPH03134008A (ja) | 星形に分枝したコポリマー、その水素化生成物およびリビングポリマー用のカプリング剤 | |
| SE468394B (sv) | Radiella och grenade segmentsampolymerer, kompositioner innehaallande dessa, deras framstaellning och anvaendning i bitumenkompositioner | |
| KR100758155B1 (ko) | 헤테로-브랜치를 갖는 라디알 폴리스티렌-폴리이소프렌블록 공중합체 및 그 제조 방법 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20080404 |
|
| A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20080404 |
|
| A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20110519 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20110524 |
|
| A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20110818 |
|
| A602 | Written permission of extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A602 Effective date: 20110825 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20110915 |
|
| TRDD | Decision of grant or rejection written | ||
| A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20111018 |
|
| A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 |
|
| A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20111026 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20141104 Year of fee payment: 3 |
|
| R150 | Certificate of patent or registration of utility model |
Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| LAPS | Cancellation because of no payment of annual fees |