JP4695390B2 - 酸キャップされた四級化ポリマー及びそのようなポリマーを含む組成物 - Google Patents
酸キャップされた四級化ポリマー及びそのようなポリマーを含む組成物 Download PDFInfo
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- C09D5/16—Antifouling paints; Underwater paints
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- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
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- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
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- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/52—Amides or imides
- C08F220/54—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide
- C08F220/60—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide containing nitrogen in addition to the carbonamido nitrogen
- C08F220/603—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide containing nitrogen in addition to the carbonamido nitrogen and containing oxygen in addition to the carbonamido oxygen and nitrogen
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Description
式(I)
のアミン又はホスフィン官能性モノマーの四級化、
6個以上の炭素原子を含む脂肪族、芳香族、又はアルカリール炭化水素基を有する酸から誘導されたカルボキシレート基による該四級化されたアンモニウム又はホスホニウムモノマーの対イオンの置き換え(これは、対イオンでキャップされている四級化されたモノマーをもたらし、ここで、対イオンは、6個以上の炭素原子を含む脂肪族炭化水素基を有する酸のアニオン性残基から成る)、
長鎖の、酸でキャップされた第四級アンモニウムモノマーの少なくとも一つのタイプ及び/又は長鎖の、酸でキャップされた第四級ホスホニウム官能性モノマーの少なくとも一つのタイプの重合
の段階を含む。
の第四級アンモニウム官能性モノマーをもたらす。反応条件は、第三級アミンRXRyRZNの四級化のために欧州特許出願公開第291 074号公報に開示されているようであり得、ここで、RX、Ry、及びRZは炭化水素残基を表す。例えば、式(I)のアミン官能性モノマー及び炭酸ジエステルは、0.2〜5のモル比で使用され得る。通常、該反応は、20〜200℃の反応温度で溶剤の存在下又は不存在下において行われ得る。好ましくは、約90psi〜100psi(6.1 105Pa〜6.8 105Pa)の高められた圧力下に、アルコール、好ましくはメタノールの存在下に115〜135℃の温度で達成される。
トリメチルアンモニウムプロピルメタクリルアミドのメチルカーボネート塩が、下記の方法においてパルミチン酸を使用して中和された。
実施例1において製造されたトリメチルアンモニウムプロピルメタクリルアミドパルミテート塩が、50%固体のポリマー溶液が得られるようにイソボルニルメタクリレート(iBoMA)(20:80)と重合された。
下記の物質が、高速分散装置を使用して表示された重量%において混合されて、本発明に従う銅含有防汚塗料を形成した。
下記の物質が、高速分散装置を使用して表示された重量%において混合されて、本発明に従う銅を含まない防汚塗料を形成した。
下記の物質が、高速分散装置を使用して表示された重量%において混合されて、本発明に従う亜鉛及び銅を含まない防汚塗料を形成した。
Claims (14)
- 殺海洋生物性を有する成分、並びにポリマーの骨格に結合され、かつ、対イオンにより中和されている第四級アンモニウム基及び/又は第四級ホスホニウム基を含むポリマーを含む防汚コーティング組成物であって、
前記ポリマーは、下記式(I)のモノマーから作られ、
式(I)
前記対イオンが、6個以上の炭素原子を含む脂肪族、芳香族、又はアルカリル炭化水素基を有し、更にカルボキシレート基を有する酸のアニオン性残基から成る、前記防汚コーティング組成物。 - 前記対イオンが8〜50個の炭素原子を含むことを特徴とする請求項1に記載のコーティング組成物。
- 更にロジン物質を含むことを特徴とする請求項1又は2に記載のコーティング組成物。
- 前記コーティング組成物が、20:80〜95:5の重量比でロジン物質とフィルム形成性補助樹脂とのブレンドを含むバインダーを含有し、ここで、該フィルム形成性補助樹脂が、前記対イオンにより中和されている第四級アンモニウム基及び/又は第四級ホスホニウム基を含むポリマーの20〜100重量%、及び非加水分解性で、水不溶性のフィルム形成性ポリマーの最大80重量%を含むことを特徴とする請求項3に記載のコーティング組成物。
- 前記バインダーが、55:45〜80:20の重量比でロジン物質とフィルム形成性補助樹脂とのブレンドを含むことを特徴とする請求項4に記載のコーティング組成物。
- 前記フィルム形成性補助樹脂が、前記対イオンにより中和されている第四級アンモニウム基及び/又は第四級ホスホニウム基を含むポリマーの30〜90重量%、及び前記非加水分解性で、水不溶性のフィルム形成性ポリマーの70〜10重量%を含むことを特徴とする請求項4又は5に記載のコーティング組成物。
- 前記非加水分解性で、水不溶性のフィルム形成性ポリマーがアクリレートエステルポリマー又はビニルエーテルポリマーであることを特徴とする請求項4から6のいずれかに記載のコーティング組成物。
- 前記バインダーが、バインダーポリマー合計に基づいて最大50重量%で存在する非ポリマー状可塑剤を含むことを特徴とする請求項4から7のいずれかに記載のコーティング組成物。
- 船体、ブイ、掘削用基壇、油井リグ、配管、又は他の水中に沈められるところの人工構造物の保護のために請求項1から8のいずれかに記載のコーティング組成物を使用する方法。
- ポリマーの骨格に結合され、かつ、6個以上の炭素原子を含む脂肪族、芳香族、又はアルカリル炭化水素基を有し、更にカルボキシレート基を有する酸のアニオン性残基から成る対イオンにより中和されている第四級アンモニウム基及び/又は第四級ホスホニウム基を含むポリマーの製造方法であって、
式(I)
のアミン又はホスフィン官能性モノマーを四級化する工程、
6個以上の炭素原子を含む脂肪族、芳香族、又はアルカリル炭化水素基を有する酸から誘導されたカルボキシレート基によって該四級化されたアンモニウム又はホスホニウムモノマーの対イオンを置き換える工程、および
前記カルボキシレート基を有する酸でキャップされた第四級アンモニウムモノマーの少なくとも一つのタイプ及び/又は前記カルボキシレート基を有する酸でキャップされた第四級ホスホニウム官能性モノマーの少なくとも一つのタイプを重合する工程を含む、ポリマーの製造方法。 - 前記四級化されたアンモニウム又はホスホニウムモノマーの対イオンが、8個以上の炭素原子を含む脂肪族、芳香族、又はアルカリル炭化水素基を有する酸から誘導されたカルボキシレート基によって置き換えられる、請求項10に記載のポリマーの製造方法。
- 前記アミン官能性モノマーが、炭酸ジエステルを使用して四級化され、式(II)
- 請求項12に記載のポリマーの製造方法によって得られるポリマー。
- 請求項13に記載のポリマーを防汚コーティング組成物に使用する方法。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP02255612 | 2002-08-09 | ||
EP02255612.0 | 2002-08-09 | ||
PCT/EP2003/007693 WO2004018533A1 (en) | 2002-08-09 | 2003-07-16 | Aci-capped quaternised polymer and compositions comprising such polymer |
Publications (3)
Publication Number | Publication Date |
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JP2006510748A JP2006510748A (ja) | 2006-03-30 |
JP2006510748A5 JP2006510748A5 (ja) | 2006-09-28 |
JP4695390B2 true JP4695390B2 (ja) | 2011-06-08 |
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JP2004530027A Expired - Lifetime JP4695390B2 (ja) | 2002-08-09 | 2003-07-16 | 酸キャップされた四級化ポリマー及びそのようなポリマーを含む組成物 |
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Country | Link |
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US (2) | US7001933B2 (ja) |
EP (1) | EP1534760B9 (ja) |
JP (1) | JP4695390B2 (ja) |
KR (1) | KR101045922B1 (ja) |
CN (1) | CN1330677C (ja) |
AU (1) | AU2003250076B2 (ja) |
BR (1) | BRPI0313260B1 (ja) |
CA (1) | CA2495549C (ja) |
CY (1) | CY1113438T1 (ja) |
DK (1) | DK1534760T3 (ja) |
ES (1) | ES2394636T3 (ja) |
HK (1) | HK1079535A1 (ja) |
MX (1) | MXPA05001535A (ja) |
MY (1) | MY148366A (ja) |
NO (1) | NO333476B1 (ja) |
NZ (1) | NZ538655A (ja) |
PL (1) | PL211454B1 (ja) |
PT (1) | PT1534760E (ja) |
RU (1) | RU2333920C2 (ja) |
TW (1) | TWI335930B (ja) |
UA (1) | UA81258C2 (ja) |
WO (1) | WO2004018533A1 (ja) |
ZA (1) | ZA200501975B (ja) |
Families Citing this family (27)
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DK1641862T3 (da) | 2003-07-07 | 2007-02-26 | Akzo Nobel Coatings Int Bv | Silylesterpolymersammensætninger |
US7598299B2 (en) * | 2004-02-03 | 2009-10-06 | Akzo Nobel Coatings International B.V. | Anti-fouling compositions comprising a polymer with salt groups |
US7893047B2 (en) * | 2006-03-03 | 2011-02-22 | Arch Chemicals, Inc. | Biocide composition comprising pyrithione and pyrrole derivatives |
JP2010501469A (ja) * | 2006-04-28 | 2010-01-21 | アルベマール・コーポレーシヨン | 第四級アンモニウム化合物を含有するコーティング、コーティング配合物および組成物 |
US9365460B2 (en) * | 2006-11-09 | 2016-06-14 | Akzo Nobel N.V. | Pigment dispersion |
ES2438577T3 (es) * | 2008-08-13 | 2014-01-17 | Akzo Nobel Coatings International B.V. | Polímero con grupos salinos y composición de recubrimiento anti-incrustante que comprende dicho polímero |
KR20110103987A (ko) * | 2008-12-01 | 2011-09-21 | 인베이스크 테라퓨틱, 인크. | 레닌-안지오텐신 알도스테론계 억제제 및 리포산 화합물을 포함하는 조성물, 및 레닌-안지오텐신 알도스테론계 관련 질환의 치료를 위한 이의 용도 |
EP2468825A1 (en) | 2010-12-21 | 2012-06-27 | Akzo Nobel Coatings International B.V. | Antifouling coating composition |
JP5529832B2 (ja) * | 2010-12-22 | 2014-06-25 | ダウ グローバル テクノロジーズ エルエルシー | Dcoitまたはoitまたはbbitの1種と、グリホサート化合物との相乗的組み合わせ |
RU2476206C1 (ru) | 2011-11-22 | 2013-02-27 | Виктор Львович Лимонов | Фармацевтическая композиция для приготовления инфузионных растворов антимикробных препаратов, способ ее получения (варианты) |
US9290669B2 (en) | 2011-12-02 | 2016-03-22 | Akzo Nobel Coatings International B.V. | Waterborne antifouling coating composition |
BR112014014745B1 (pt) | 2011-12-22 | 2021-11-03 | Akzo Nobel Coatings International B.V. | Processo de aplicação de um revestimento de proteção a um navio, fabricação e/ou fornecimento de um revestimento de proteção, e mídia legível por computador |
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