JP4218988B2 - 分枝鎖オレフィンコポリマーに由来する熱可塑性エラストマー組成物 - Google Patents
分枝鎖オレフィンコポリマーに由来する熱可塑性エラストマー組成物 Download PDFInfo
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- JP4218988B2 JP4218988B2 JP53506298A JP53506298A JP4218988B2 JP 4218988 B2 JP4218988 B2 JP 4218988B2 JP 53506298 A JP53506298 A JP 53506298A JP 53506298 A JP53506298 A JP 53506298A JP 4218988 B2 JP4218988 B2 JP 4218988B2
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- ethylene
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Applications Claiming Priority (7)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US3732397P | 1997-02-07 | 1997-02-07 | |
| US60/037,323 | 1997-02-07 | ||
| US4681297P | 1997-05-02 | 1997-05-02 | |
| US60/046,812 | 1997-05-02 | ||
| US6778297P | 1997-12-10 | 1997-12-10 | |
| US60/067,782 | 1997-12-10 | ||
| PCT/US1998/002735 WO1998034970A1 (en) | 1997-02-07 | 1998-02-06 | Thermoplastic elastomer compositions from branched olefin copolymers |
Publications (3)
| Publication Number | Publication Date |
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| JP2001527589A JP2001527589A (ja) | 2001-12-25 |
| JP2001527589A5 JP2001527589A5 (https=) | 2004-09-02 |
| JP4218988B2 true JP4218988B2 (ja) | 2009-02-04 |
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| JP53506298A Expired - Lifetime JP4218988B2 (ja) | 1997-02-07 | 1998-02-06 | 分枝鎖オレフィンコポリマーに由来する熱可塑性エラストマー組成物 |
| JP53506398A Pending JP2001511215A (ja) | 1997-02-07 | 1998-02-06 | ポリエチレンマクロマーを組み入れるプロピレンポリマー |
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| Application Number | Title | Priority Date | Filing Date |
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| JP53506398A Pending JP2001511215A (ja) | 1997-02-07 | 1998-02-06 | ポリエチレンマクロマーを組み入れるプロピレンポリマー |
Country Status (10)
| Country | Link |
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| US (4) | US6147180A (https=) |
| EP (2) | EP0958314B1 (https=) |
| JP (2) | JP4218988B2 (https=) |
| KR (2) | KR100564500B1 (https=) |
| CN (2) | CN1130406C (https=) |
| BR (2) | BR9807672A (https=) |
| CA (2) | CA2277063C (https=) |
| DE (2) | DE69809192T2 (https=) |
| ES (2) | ES2187005T3 (https=) |
| WO (2) | WO1998034971A1 (https=) |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| US7919561B2 (en) * | 1996-09-04 | 2011-04-05 | Exxonmobil Chemical Patents Inc. | Process of producing thermoplastic polymer blends |
| TW513442B (en) * | 1997-06-06 | 2002-12-11 | Idemitsu Petrochemical Co | Olefinic polymer |
| US6184327B1 (en) | 1997-12-10 | 2001-02-06 | Exxon Chemical Patents, Inc. | Elastomeric propylene polymers |
| US6197910B1 (en) | 1997-12-10 | 2001-03-06 | Exxon Chemical Patents, Inc. | Propylene polymers incorporating macromers |
| US6117962A (en) * | 1997-12-10 | 2000-09-12 | Exxon Chemical Patents Inc. | Vinyl-containing stereospecific polypropylene macromers |
| KR20060116870A (ko) * | 1999-07-26 | 2006-11-15 | 이데미쓰 고산 가부시키가이샤 | 올레핀계 분지상 매크로모노머, 올레핀계 그래프트공중합체 및 올레핀계 수지 조성물 |
| SG82087A1 (en) * | 1999-09-10 | 2001-07-24 | Sumitomo Chemical Co | Pressure sensitive adhesive |
| JP4748908B2 (ja) * | 1999-09-10 | 2011-08-17 | ザ・ユニバーシティ・オブ・シドニー | ジペプチジルペプチダーゼ |
| US6803422B2 (en) * | 1999-09-13 | 2004-10-12 | Denki Kagaku Kogyo Kabushiki Kaisha | Cross-copolymerized olefin/aromatic vinyl compound/diene copolymer and process for its production |
| MY137183A (en) * | 2001-03-16 | 2009-01-30 | Dow Global Technologies Inc | Method of making interpolymers and products made therefrom |
| WO2002102862A1 (en) * | 2001-05-15 | 2002-12-27 | Denki Kagaku Kogyo Kabushiki Kaisha | Process for producing olefin/aromatic vinyl copolymer |
| US20030050411A1 (en) * | 2001-06-12 | 2003-03-13 | Dow Global Technologies Inc. | Use of polar monomers in olefin polymerization and polymers thereof |
| ATE405594T1 (de) * | 2002-01-15 | 2008-09-15 | Advanced Elastomer Systems | Thermoplastische elastomere |
| RU2326904C2 (ru) * | 2002-06-04 | 2008-06-20 | Юнион Карбайд Кемикалз Энд Пластикс Текнолоджи Корпорейшн | Полимерные композиции и способ изготовления труб |
| US7998579B2 (en) | 2002-08-12 | 2011-08-16 | Exxonmobil Chemical Patents Inc. | Polypropylene based fibers and nonwovens |
| CN100345896C (zh) | 2002-08-12 | 2007-10-31 | 埃克森美孚化学专利公司 | 增塑聚烯烃组合物 |
| US7531594B2 (en) | 2002-08-12 | 2009-05-12 | Exxonmobil Chemical Patents Inc. | Articles from plasticized polyolefin compositions |
| US8003725B2 (en) | 2002-08-12 | 2011-08-23 | Exxonmobil Chemical Patents Inc. | Plasticized hetero-phase polyolefin blends |
| US7271209B2 (en) | 2002-08-12 | 2007-09-18 | Exxonmobil Chemical Patents Inc. | Fibers and nonwovens from plasticized polyolefin compositions |
| US7550528B2 (en) | 2002-10-15 | 2009-06-23 | Exxonmobil Chemical Patents Inc. | Functionalized olefin polymers |
| US7223822B2 (en) * | 2002-10-15 | 2007-05-29 | Exxonmobil Chemical Patents Inc. | Multiple catalyst and reactor system for olefin polymerization and polymers produced therefrom |
| US7700707B2 (en) | 2002-10-15 | 2010-04-20 | Exxonmobil Chemical Patents Inc. | Polyolefin adhesive compositions and articles made therefrom |
| US7541402B2 (en) | 2002-10-15 | 2009-06-02 | Exxonmobil Chemical Patents Inc. | Blend functionalized polyolefin adhesive |
| US8653169B2 (en) | 2002-10-15 | 2014-02-18 | Exxonmobil Chemical Patents Inc. | Propylene copolymers for adhesive applications |
| US8618219B2 (en) | 2002-10-15 | 2013-12-31 | Exxonmobil Chemical Patents Inc. | Propylene copolymers for adhesive applications |
| WO2004046214A2 (en) | 2002-10-15 | 2004-06-03 | Exxonmobil Chemical Patents Inc. | Multiple catalyst system for olefin polymerization and polymers produced therefrom |
| WO2004037871A1 (en) * | 2002-10-24 | 2004-05-06 | Exxonmobil Chemical Patents Inc. | Branched crystalline polypropylene |
| US7439312B2 (en) | 2002-10-24 | 2008-10-21 | Exxonmobil Chemical Patents Inc. | Branched crystalline polypropylene |
| EP1422250A1 (en) * | 2002-11-20 | 2004-05-26 | ATOFINA Research | Branched polypropylene |
| JP2004175953A (ja) * | 2002-11-28 | 2004-06-24 | Kanegafuchi Chem Ind Co Ltd | ポリイソブチレン−ポリオレフィン共重合体とその製造方法 |
| US8192813B2 (en) | 2003-08-12 | 2012-06-05 | Exxonmobil Chemical Patents, Inc. | Crosslinked polyethylene articles and processes to produce same |
| JP4902099B2 (ja) | 2003-10-09 | 2012-03-21 | 出光興産株式会社 | 極性基含有高級オレフィン重合体及びその製造方法 |
| WO2005073283A1 (en) * | 2004-01-22 | 2005-08-11 | Dow Global Technologies Inc. | Functionalized elastomer compositions |
| US7803728B2 (en) * | 2004-03-17 | 2010-09-28 | Dow Global Technologies Inc. | Fibers made from copolymers of ethylene/α-olefins |
| US7666918B2 (en) * | 2004-03-17 | 2010-02-23 | Dow Global Technologies, Inc. | Foams made from interpolymers of ethylene/α-olefins |
| US7863379B2 (en) | 2004-03-17 | 2011-01-04 | Dow Global Technologies Inc. | Impact modification of thermoplastics with ethylene/alpha-olefin interpolymers |
| US7608668B2 (en) | 2004-03-17 | 2009-10-27 | Dow Global Technologies Inc. | Ethylene/α-olefins block interpolymers |
| US7579408B2 (en) | 2004-03-17 | 2009-08-25 | Dow Global Technologies Inc. | Thermoplastic vulcanizate comprising interpolymers of ethylene/α-olefins |
| SG151301A1 (en) | 2004-03-17 | 2009-04-30 | Dow Global Technologies Inc | Catalyst composition comprising shuttling agent for ethylene multi- block copolymer formation |
| US7795321B2 (en) * | 2004-03-17 | 2010-09-14 | Dow Global Technologies Inc. | Rheology modification of interpolymers of ethylene/α-olefins and articles made therefrom |
| US7504347B2 (en) * | 2004-03-17 | 2009-03-17 | Dow Global Technologies Inc. | Fibers made from copolymers of propylene/α-olefins |
| US7671106B2 (en) | 2004-03-17 | 2010-03-02 | Dow Global Technologies Inc. | Cap liners, closures and gaskets from multi-block polymers |
| US7897689B2 (en) | 2004-03-17 | 2011-03-01 | Dow Global Technologies Inc. | Functionalized ethylene/α-olefin interpolymer compositions |
| US7514517B2 (en) | 2004-03-17 | 2009-04-07 | Dow Global Technologies Inc. | Anti-blocking compositions comprising interpolymers of ethylene/α-olefins |
| US7557147B2 (en) | 2004-03-17 | 2009-07-07 | Dow Global Technologies Inc. | Soft foams made from interpolymers of ethylene/alpha-olefins |
| US8273838B2 (en) * | 2004-03-17 | 2012-09-25 | Dow Global Technologies Llc | Propylene/α-olefins block interpolymers |
| US7622529B2 (en) | 2004-03-17 | 2009-11-24 | Dow Global Technologies Inc. | Polymer blends from interpolymers of ethylene/alpha-olefin with improved compatibility |
| US7524911B2 (en) | 2004-03-17 | 2009-04-28 | Dow Global Technologies Inc. | Adhesive and marking compositions made from interpolymers of ethylene/α-olefins |
| US7741397B2 (en) * | 2004-03-17 | 2010-06-22 | Dow Global Technologies, Inc. | Filled polymer compositions made from interpolymers of ethylene/α-olefins and uses thereof |
| US7582716B2 (en) | 2004-03-17 | 2009-09-01 | Dow Global Technologies Inc. | Compositions of ethylene/α-olefin multi-block interpolymer for blown films with high hot tack |
| AR053693A1 (es) | 2004-03-17 | 2007-05-16 | Dow Global Technologies Inc | Composiciones de interpolimero de etileno/alfa-olefina multibloque adecuado para peliculas |
| US7662881B2 (en) | 2004-03-17 | 2010-02-16 | Dow Global Technologies Inc. | Viscosity index improver for lubricant compositions |
| US7355089B2 (en) | 2004-03-17 | 2008-04-08 | Dow Global Technologies Inc. | Compositions of ethylene/α-olefin multi-block interpolymer for elastic films and laminates |
| US7671131B2 (en) | 2004-03-17 | 2010-03-02 | Dow Global Technologies Inc. | Interpolymers of ethylene/α-olefins blends and profiles and gaskets made therefrom |
| US7858706B2 (en) | 2004-03-17 | 2010-12-28 | Dow Global Technologies Inc. | Catalyst composition comprising shuttling agent for ethylene multi-block copolymer formation |
| US7622179B2 (en) | 2004-03-17 | 2009-11-24 | Dow Global Technologies Inc. | Three dimensional random looped structures made from interpolymers of ethylene/α-olefins and uses thereof |
| US7714071B2 (en) * | 2004-03-17 | 2010-05-11 | Dow Global Technologies Inc. | Polymer blends from interpolymers of ethylene/α-olefins and flexible molded articles made therefrom |
| NZ549262A (en) * | 2004-03-17 | 2010-08-27 | Dow Global Technologies Inc | Catalyst composition comprising shuttling agent for higher olefin multi-block copolymer formation |
| US7687442B2 (en) | 2004-03-17 | 2010-03-30 | Dow Global Technologies Inc. | Low molecular weight ethylene/α-olefin interpolymer as base lubricant oils |
| US7645829B2 (en) * | 2004-04-15 | 2010-01-12 | Exxonmobil Chemical Patents Inc. | Plasticized functionalized propylene copolymer adhesive composition |
| US8389615B2 (en) | 2004-12-17 | 2013-03-05 | Exxonmobil Chemical Patents Inc. | Elastomeric compositions comprising vinylaromatic block copolymer, polypropylene, plastomer, and low molecular weight polyolefin |
| AR054017A1 (es) | 2005-03-17 | 2007-05-30 | Dow Global Technologies Inc | Fundas de tapas cierres y juntas de polimeros multi-bloque |
| US7910658B2 (en) | 2005-03-17 | 2011-03-22 | Dow Global Technologies Llc | Compositions of ethylene/α-olefin multi-block interpolymer for elastic films and laminates |
| BRPI0609841B1 (pt) | 2005-03-17 | 2022-09-27 | Dow Global Technologies Inc | Composição de interpolímero de etileno/a-olefina e artigo |
| US8084537B2 (en) * | 2005-03-17 | 2011-12-27 | Dow Global Technologies Llc | Polymer blends from interpolymers of ethylene/α-olefin with improved compatibility |
| MX2007011337A (es) | 2005-03-17 | 2007-10-02 | Dow Global Technologies Inc | Composicion de catalizador que comprende un agente de transporte para la formacion de copolimero de bloques multiples tactico/atactico. |
| US9410009B2 (en) | 2005-03-17 | 2016-08-09 | Dow Global Technologies Llc | Catalyst composition comprising shuttling agent for tactic/ atactic multi-block copolymer formation |
| AR055044A1 (es) | 2005-03-17 | 2007-08-01 | Dow Global Technologies Inc | Modificacaion del impacto de los termoplasticos con interpolimeros de etileno/alfa- olefina |
| WO2006101968A2 (en) * | 2005-03-17 | 2006-09-28 | Dow Global Technologies Inc. | Compositions of ethylene/alpha-olefin multi-block interpolymer for elastic films and laminates |
| US7786216B2 (en) | 2005-03-17 | 2010-08-31 | Dow Global Technologies Inc. | Oil based blends of interpolymers of ethylene/α-olefins |
| US7737215B2 (en) | 2005-03-17 | 2010-06-15 | Dow Global Technologies Inc. | Compositions of ethylene/α-olefin multi-block interpolymer for elastic films and laminates |
| TWI375682B (en) * | 2005-03-17 | 2012-11-01 | Dow Global Technologies Llc | Fibers made from copolymers of ethylene/α -olefins |
| MY148607A (en) * | 2005-03-17 | 2013-05-15 | Dow Global Technologies Inc | Ethylene/?-olefins block interpolymers |
| MX2007011340A (es) | 2005-03-17 | 2007-10-03 | Dow Global Technologies Inc | Composicion de catalizador que comprende un agente de transporte para la formacion de copolimero de bloques multiples regio-irregular. |
| AU2006227663A1 (en) * | 2005-03-17 | 2006-09-28 | Dow Global Technologies Inc. | Polymer blends from interpolymer of ethylene/alpha-olefin with improved compatibility |
| JP5318567B2 (ja) * | 2005-05-12 | 2013-10-16 | ダウ グローバル テクノロジーズ エルエルシー | 光沢の少ない熱成形押出しシート材 |
| GB0511320D0 (en) | 2005-06-03 | 2005-07-13 | Exxonmobil Chem Patents Inc | Elastomeric structures |
| US7928164B2 (en) * | 2005-06-22 | 2011-04-19 | Exxonmobil Chemical Patents Inc. | Homogeneous polymer blend and process of making the same |
| US9745461B2 (en) | 2005-06-22 | 2017-08-29 | Exxonmobil Chemical Patents Inc. | Vulcanized polymer blends |
| US20060293462A1 (en) * | 2005-06-22 | 2006-12-28 | Sunny Jacob | Heterogeneous polymer blend and process of making the same |
| US9644092B2 (en) | 2005-06-22 | 2017-05-09 | Exxonmobil Chemical Patents Inc. | Heterogeneous in-situ polymer blend |
| US8022142B2 (en) * | 2008-12-15 | 2011-09-20 | Exxonmobil Chemical Patents Inc. | Thermoplastic olefin compositions |
| US8288480B2 (en) | 2005-06-22 | 2012-10-16 | Exxonmobil Chemical Patents Inc. | In-reactor polymer blends |
| US7951872B2 (en) | 2005-06-22 | 2011-05-31 | Exxonmobil Chemical Patents Inc. | Heterogeneous polymer blend with continuous elastomeric phase and process of making the same |
| WO2007001694A1 (en) * | 2005-06-24 | 2007-01-04 | Exxonmobil Chemical Patents Inc. | Functionalized propylene copolymer adheside composition |
| WO2007011530A2 (en) | 2005-07-15 | 2007-01-25 | Exxonmobil Chemical Patents, Inc. | Elastomeric compositions |
| AR058448A1 (es) | 2005-09-15 | 2008-02-06 | Dow Global Technologies Inc | Control de arquitectura del polimero y distribucoin de peso molecular va el agente de transferencia multi- centrado |
| KR20080055837A (ko) * | 2005-09-15 | 2008-06-19 | 다우 글로벌 테크놀로지스 인크. | 중합가능한 셔틀링제를 통한 촉매성 올레핀 블럭 공중합체 |
| US7906587B2 (en) | 2005-09-16 | 2011-03-15 | Dow Global Technologies Llc | Polymer blends from interpolymer of ethylene/α olefin with improved compatibility |
| US7695812B2 (en) | 2005-09-16 | 2010-04-13 | Dow Global Technologies, Inc. | Fibers made from copolymers of ethylene/α-olefins |
| AR058496A1 (es) * | 2005-10-26 | 2008-02-06 | Dow Global Technologies Inc | Articulos elasticos de multiples capas |
| EP1954730B2 (en) | 2005-11-23 | 2019-10-23 | Dow Global Technologies LLC | Heterogeneous, compositionally phase separated, ethylene alpha-olefin interpolymers |
| BRPI0620567B1 (pt) | 2005-12-09 | 2018-05-29 | Dow Global Technologies Inc. | Processo para produzir uma composição de interpolímero de etileno/(alfa)-olefina |
| US8153243B2 (en) * | 2005-12-09 | 2012-04-10 | Dow Global Technologies Llc | Interpolymers suitable for multilayer films |
| US20070255026A1 (en) * | 2006-04-28 | 2007-11-01 | Fina Technology, Inc. | Process for polyolefin production using fluorinated transition metal catalysts having a low pH |
| US20070255022A1 (en) * | 2006-04-28 | 2007-11-01 | Fina Technology, Inc. | Fluorinated transition metal catalysts and formation thereof |
| US8110518B2 (en) * | 2006-04-28 | 2012-02-07 | Fina Technology, Inc. | Fluorinated transition metal catalysts and formation thereof |
| TW200829745A (en) * | 2006-09-06 | 2008-07-16 | Dow Global Technologies Inc | Fibers and knit fabrics comprising olefin block interpolymers |
| ATE448286T1 (de) * | 2006-10-05 | 2009-11-15 | Chisso Corp | Flüssigkristallzusammensetzung und flüssigkristallanzeigevorrichtung |
| US7745544B2 (en) * | 2006-11-30 | 2010-06-29 | Exxonmobil Chemical Patents Inc. | Catalytic epoxidation and hydroxylation of olefin/diene copolymers |
| WO2008067545A2 (en) * | 2006-11-30 | 2008-06-05 | Dow Global Technologies Inc. | Fabric comprising elastic fibres of cross-linked ethylene polymer |
| TW200902780A (en) * | 2006-11-30 | 2009-01-16 | Dow Global Technologies Inc | Olefin block compositions for heavy weight stretch fabrics |
| JP2010511800A (ja) | 2006-11-30 | 2010-04-15 | ダウ グローバル テクノロジーズ インコーポレイティド | 防皺性を有する伸縮性布地のためのオレフィンブロック組成物 |
| DK2099873T3 (en) * | 2006-12-07 | 2016-01-25 | Grace Gmbh & Co Kg | Matting Agent |
| AU2008206336A1 (en) * | 2007-01-16 | 2008-07-24 | Dow Global Technologies Inc. | Colorfast fabrics and garments of olefin block compositions |
| EP2122023A1 (en) * | 2007-01-16 | 2009-11-25 | Dow Global Technologies Inc. | Cone dyed yarns of olefin block compositions |
| US7615589B2 (en) * | 2007-02-02 | 2009-11-10 | Exxonmobil Chemical Patents Inc. | Properties of peroxide-cured elastomer compositions |
| BRPI0807769A2 (pt) * | 2007-02-20 | 2014-06-17 | Dsm Ip Assets Bv | Copolímero grafitizado. |
| US20080287614A1 (en) * | 2007-05-15 | 2008-11-20 | Sonoco Development, Inc. | Polypropylene-Based Polymer Blend of Enhanced Melt Strength |
| US8241753B2 (en) * | 2007-06-04 | 2012-08-14 | Exxonmobil Chemical Patents Inc. | Composite thermoplastic elastomer structures with high adhesion performance and uses for the same |
| US20080306215A1 (en) * | 2007-06-06 | 2008-12-11 | Abhimanyu Onkar Patil | Functionalization of olefin/diene copolymers |
| BRPI0812613A2 (pt) * | 2007-07-09 | 2019-02-19 | Dow Global Technologies Inc | fibra adequada para artigos têxteis, composição adequada para fibras e pano |
| EP2203512A1 (en) * | 2007-09-28 | 2010-07-07 | Dow Global Technologies Inc. | Thermoplastic olefin composition with improved heat distortion temperature |
| EP2052857A1 (en) | 2007-10-22 | 2009-04-29 | Dow Global Technologies Inc. | Multilayer films |
| US8138285B2 (en) * | 2007-10-26 | 2012-03-20 | Fina Technology, Inc. | Fluorinated impregnated catalyst systems and methods of forming the same |
| US8143353B2 (en) * | 2008-01-18 | 2012-03-27 | Exxonmobil Chemical Patents Inc. | Polymerization process and adhesives therefrom |
| WO2009114661A1 (en) | 2008-03-13 | 2009-09-17 | Dow Global Technologies Inc. | Long chain branched (lcb), block or interconnected copolymers of ethylene in combination with one other polymer |
| US8404773B2 (en) * | 2008-03-17 | 2013-03-26 | Dow Global Technologies Llc | Coating composition, method of producing the same, articles made therefrom, and method of making such articles |
| US8802797B2 (en) | 2008-06-20 | 2014-08-12 | Exxonmobil Chemical Patents Inc. | Vinyl-terminated macromonomer oligomerization |
| US8399725B2 (en) | 2008-06-20 | 2013-03-19 | Exxonmobil Chemical Patents Inc. | Functionalized high vinyl terminated propylene based oligomers |
| US8283428B2 (en) * | 2008-06-20 | 2012-10-09 | Exxonmobil Chemical Patents Inc. | Polymacromonomer and process for production thereof |
| US8283419B2 (en) | 2008-06-20 | 2012-10-09 | Exxonmobil Chemical Patents Inc. | Olefin functionalization by metathesis reaction |
| US8372930B2 (en) | 2008-06-20 | 2013-02-12 | Exxonmobil Chemical Patents Inc. | High vinyl terminated propylene based oligomers |
| US8497325B2 (en) | 2008-12-15 | 2013-07-30 | Exxonmobil Chemical Patents Inc. | Thermoplastic polyolefin blends and films therefrom |
| US8227547B2 (en) * | 2008-12-15 | 2012-07-24 | Exxonmobil Chemical Patents Inc. | Foamable thermoplastic reactor blends and foam article therefrom |
| US8106127B2 (en) * | 2008-12-15 | 2012-01-31 | Exxonmobil Chemical Patents Inc. | Heterogeneous in-reactor polymer blends |
| US8093335B2 (en) * | 2008-12-15 | 2012-01-10 | Exxonmobil Chemical Patents Inc. | Thermoplastic polyolefin in-reactor blends and molded articles therefrom |
| US8101685B2 (en) * | 2008-12-15 | 2012-01-24 | Exxonmobil Chemical Patents Inc. | Thermoplastic elastomer polyolefin in-reactor blends and molded articles therefrom |
| US8410217B2 (en) * | 2008-12-15 | 2013-04-02 | Exxonmobil Chemical Patents Inc. | Thermoplastic polyolefin blends |
| US8431651B2 (en) | 2009-07-14 | 2013-04-30 | Dow Global Technologies Llc | Vacuum thermoformed, extruded sheeting with improved reduced gloss |
| EP3489264B1 (en) | 2009-07-29 | 2021-08-25 | Dow Global Technologies LLC | Chain shuttling agents and their use for the preparation of block copolymers |
| US20110054117A1 (en) * | 2009-08-27 | 2011-03-03 | Hall Gregory K | Polyolefin Adhesive Compositions and Method of Making Thereof |
| US9458310B2 (en) | 2009-10-16 | 2016-10-04 | Exxonmobil Chemical Patents Inc. | Modified polyethylene film compositions |
| BR112012015024B1 (pt) * | 2009-12-18 | 2020-03-03 | Dow Global Technologies Llc | Núcleo de fibra óptica plástico, sistema automotivo, industrial, médico ou de consumidor e fibra óptica plástica |
| US8907034B2 (en) | 2010-09-30 | 2014-12-09 | Dow Global Technologies Llc | Comb architecture olefin block copolymers |
| JP2014505155A (ja) | 2011-02-15 | 2014-02-27 | エクソンモービル ケミカル パテンツ インコーポレイテッド | 熱可塑性ポリオレフィンブレンド |
| US8835563B2 (en) | 2011-03-25 | 2014-09-16 | Exxonmobil Chemical Patents Inc. | Block copolymers from silylated vinyl terminated macromers |
| US8669326B2 (en) | 2011-03-25 | 2014-03-11 | Exxonmobil Chemical Patents Inc. | Amine functionalized polyolefin and methods for preparation thereof |
| US8455597B2 (en) | 2011-03-25 | 2013-06-04 | Exxonmobil Chemical Patents Inc. | Catalysts and methods of use thereof to produce vinyl terminated polymers |
| EP2688954A4 (en) * | 2011-03-25 | 2014-10-01 | Exxonmobil Chem Patents Inc | OLEFIN TRIBLOCK POLYMERS WITH RING OPENING METATHESIS POLYMERIZATION |
| US8785562B2 (en) | 2011-03-25 | 2014-07-22 | Exxonmobil Chemical Patents Inc. | Amphiphilic block polymers prepared by alkene metathesis |
| US8399724B2 (en) | 2011-03-25 | 2013-03-19 | Exxonmobil Chemical Patents Inc. | Vinyl terminated higher olefin copolymers and methods to produce thereof |
| US8501894B2 (en) | 2011-03-25 | 2013-08-06 | Exxonmobil Chemical Patents Inc. | Hydrosilyation of vinyl macromers with metallocenes |
| US8940839B2 (en) | 2011-03-25 | 2015-01-27 | Exxonmobil Chemical Patents Inc. | Diblock copolymers prepared by cross metathesis |
| US8669330B2 (en) | 2011-03-25 | 2014-03-11 | Exxonmobil Chemical Patents Inc. | Olefin triblock polymers via ring-opening metathesis polymerization |
| US8623974B2 (en) | 2011-03-25 | 2014-01-07 | Exxonmobil Chemical Patents Inc. | Branched vinyl terminated polymers and methods for production thereof |
| US8426659B2 (en) | 2011-03-25 | 2013-04-23 | Exxonmobil Chemical Patents Inc. | Vinyl terminated higher olefin polymers and methods to produce thereof |
| US8841397B2 (en) | 2011-03-25 | 2014-09-23 | Exxonmobil Chemical Patents Inc. | Vinyl terminated higher olefin polymers and methods to produce thereof |
| US9340664B2 (en) | 2011-09-23 | 2016-05-17 | Exxonmobil Chemical Patents Inc. | Modified polyethylene compositions for blown film |
| US9321911B2 (en) | 2011-09-23 | 2016-04-26 | Exxonmobil Chemical Patents Inc. | Modified polyethylene compositions for cast film |
| US20160272798A1 (en) | 2011-09-23 | 2016-09-22 | Exxonmobil Chemical Patents Inc. | Modified Polyethylene Compositions with Enhanced Melt Strength |
| WO2013043796A2 (en) | 2011-09-23 | 2013-03-28 | Exxonmobil Chemical Patents Inc. | Modified polyethylene compositions |
| JP5600219B2 (ja) * | 2011-10-24 | 2014-10-01 | 三菱化学株式会社 | 熱可塑性エラストマー組成物及びその製造方法 |
| US8629217B2 (en) | 2011-11-22 | 2014-01-14 | Exxonmobil Chemical Patents Inc. | Modified polyethylene blown film compositions having excellent bubble stability |
| US8604148B2 (en) | 2011-11-29 | 2013-12-10 | Exxonmobil Chemical Patents Inc. | Functionalization of vinyl terminated polymers by ring opening cross metathesis |
| WO2013101933A1 (en) | 2011-12-29 | 2013-07-04 | Dow Global Technologies Llc | Ethylene-based polymer compositions with improved viscosities |
| US8796376B2 (en) | 2012-03-26 | 2014-08-05 | Exxonmobil Chemical Patents Inc. | Functionalized polymers and oligomers |
| US10822479B2 (en) | 2012-09-20 | 2020-11-03 | Exxonmobil Chemical Patents Inc. | Foamed polyethylene compositions |
| US10836853B2 (en) | 2012-09-20 | 2020-11-17 | Exxonmobil Chemical Patents Inc. | Crack-resistant polyethylene compositions |
| CN104812828B (zh) | 2012-12-05 | 2016-10-12 | 埃克森美孚化学专利公司 | 具有优异的膜泡稳定性的hdpe 改性聚乙烯吹塑膜组合物 |
| JP6439280B2 (ja) * | 2013-08-09 | 2018-12-19 | 三菱ケミカル株式会社 | 熱可塑性エラストマー組成物の製造方法 |
| US9321856B2 (en) | 2013-12-19 | 2016-04-26 | Exxonmobil Chemical Patents Inc. | Process to produce functionalized polymer |
| WO2015126797A1 (en) | 2014-02-24 | 2015-08-27 | Dow Global Technologies Llc | Thermoplastic polyolefin with reduced gloss for non-carpeted flooring |
| KR101850233B1 (ko) | 2014-03-28 | 2018-04-18 | 미쓰이 가가쿠 가부시키가이샤 | 올레핀계 수지, 그의 제조 방법 및 프로필렌계 수지 조성물 |
| US10125247B2 (en) | 2014-05-29 | 2018-11-13 | Exxonmobil Chemical Patents Inc. | Polyethylene compositions |
| WO2015183577A1 (en) | 2014-05-29 | 2015-12-03 | Exxonmobil Chemical Patents Inc. | Cyclic-diene additives in polyethylene films and enhanced film orientation balance in production thereof |
| WO2015183578A1 (en) | 2014-05-29 | 2015-12-03 | Exxonmobil Chemical Patents Inc. | Polyethylene films and production of such films |
| KR101792171B1 (ko) | 2014-12-08 | 2017-10-31 | 주식회사 엘지화학 | 우수한 용융 강도를 갖는 올레핀계 중합체 및 이를 포함하는 필름 |
| ES2784518T3 (es) * | 2014-12-09 | 2020-09-28 | Mitsui Chemicals Inc | Composición de resina a base de propileno |
| US10246542B2 (en) | 2015-09-14 | 2019-04-02 | Exxonmobil Chemical Patents Inc. | Atactic polypropylene comb block polyolefins useful as modifiers in polyolefins and hydrocarbons |
| EP3601433B1 (en) | 2017-03-29 | 2023-05-03 | ExxonMobil Chemical Patents Inc. | Polyethylene compositions |
| BR112019024888A2 (pt) * | 2017-05-31 | 2020-06-16 | Dow Global Technologies Llc | Composições à base de etileno não polares com trialil fosfato para filmes encapsulantes |
| CN109748988B (zh) * | 2017-11-04 | 2021-12-03 | 天津大学 | 一种丙烯共聚物及其制备方法 |
| US11028196B2 (en) * | 2017-12-22 | 2021-06-08 | Exxonmobil Chemical Patents Inc. | Polyolefin compositions |
| CN111138575B (zh) * | 2018-11-05 | 2021-06-11 | 中国科学院化学研究所 | 有机硅烷化合物、聚烯烃树脂及其制备方法和应用 |
| KR102671695B1 (ko) * | 2018-11-29 | 2024-06-05 | 롯데케미칼 주식회사 | 우수한 용융 특성을 지닌 폴리프로필렌 수지 및 그 제조 방법 |
| US11377560B2 (en) | 2018-12-18 | 2022-07-05 | ExxonMobil Technology and Engineering Company | Modified asphalts and methods for producing the same |
| JP7370191B2 (ja) * | 2019-08-15 | 2023-10-27 | 三井化学株式会社 | オレフィン系樹脂、その製造方法および組成物 |
| WO2021035713A1 (en) * | 2019-08-30 | 2021-03-04 | Dow Global Technologies Llc | Photovoltaic encapsulant films comprising fumed alumina |
| US20220306792A1 (en) * | 2019-09-13 | 2022-09-29 | Cornell University | Graft copolymers for compatibilization of polyethylene and polypropylene |
| FR3105225B1 (fr) * | 2019-12-18 | 2021-12-03 | Michelin & Cie | Copolymère d’éthylène et d’un 1,3-diène |
| CN113861348B (zh) * | 2021-10-09 | 2022-07-26 | 天津大学 | 一种pmp共聚物及其制备方法 |
| JPWO2023101004A1 (https=) * | 2021-12-02 | 2023-06-08 | ||
| CN115850586A (zh) * | 2022-12-21 | 2023-03-28 | 浙江大学 | 一种梳状乙丙共聚物、交联梳状乙丙共聚物及其制备方法 |
Family Cites Families (117)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3350778A (en) | 1966-05-04 | 1967-11-07 | Joseph F Perry | Onion peeler |
| US3989768A (en) * | 1971-02-22 | 1976-11-02 | Cpc International Inc. | Chemically joined phase separated thermoplastic graft copolymers |
| BE793639A (fr) | 1972-01-03 | 1973-07-03 | Xerox Corp | Revelateur electrostatographique |
| JPS52141888A (en) | 1976-05-21 | 1977-11-26 | Nippon I P Rubber Kk | Ethyleneepropylene copolymers rubber |
| US4335225A (en) | 1978-06-20 | 1982-06-15 | E. I. Du Pont De Nemours And Company | Elastomeric polypropylene |
| DE3127133A1 (de) | 1981-07-09 | 1983-01-27 | Hoechst Ag, 6000 Frankfurt | Verfahren zur herstellung von polyolefinen und deren copolymerisaten |
| US4543399A (en) | 1982-03-24 | 1985-09-24 | Union Carbide Corporation | Fluidized bed reaction systems |
| US4588790A (en) | 1982-03-24 | 1986-05-13 | Union Carbide Corporation | Method for fluidized bed polymerization |
| US5324800A (en) | 1983-06-06 | 1994-06-28 | Exxon Chemical Patents Inc. | Process and catalyst for polyolefin density and molecular weight control |
| US4937299A (en) | 1983-06-06 | 1990-06-26 | Exxon Research & Engineering Company | Process and catalyst for producing reactor blend polyolefins |
| US4530914A (en) | 1983-06-06 | 1985-07-23 | Exxon Research & Engineering Co. | Process and catalyst for producing polyethylene having a broad molecular weight distribution |
| NO167039C (no) | 1985-01-31 | 1991-09-25 | Himont Inc | Fremgangsmaate for fremstilling av polypropylen med langkjedede forgreninger og anvendelse av dette |
| DE3508887A1 (de) | 1985-03-13 | 1986-09-25 | Hoechst Ag, 6230 Frankfurt | Verfahren zur herstellung von optisch aktiven polyolefinen |
| US4808561A (en) | 1985-06-21 | 1989-02-28 | Exxon Chemical Patents Inc. | Supported polymerization catalyst |
| US4665208A (en) | 1985-07-11 | 1987-05-12 | Exxon Chemical Patents Inc. | Process for the preparation of alumoxanes |
| US4701432A (en) | 1985-11-15 | 1987-10-20 | Exxon Chemical Patents Inc. | Supported polymerization catalyst |
| IL80888A (en) * | 1985-12-12 | 1991-12-12 | Exxon Chemical Patents Inc | Olefin polymerization catalysts,their preparation and use thereof |
| US4752597A (en) * | 1985-12-12 | 1988-06-21 | Exxon Chemical Patents Inc. | New polymerization catalyst |
| EP0279863B1 (en) | 1986-08-26 | 1992-10-14 | Mitsui Petrochemical Industries, Ltd. | Catalyst for polymerizing alpha-olefin and polymerization process |
| EP0812862B1 (en) | 1986-09-24 | 2002-11-13 | Mitsui Chemicals, Inc. | Process for polymerizing olefins |
| JPH0780933B2 (ja) | 1986-11-20 | 1995-08-30 | 三井石油化学工業株式会社 | オレフインの重合方法 |
| JP2618384B2 (ja) * | 1986-12-27 | 1997-06-11 | 三井石油化学工業株式会社 | オレフイン重合用固体触媒およびその製法 |
| US4921825A (en) | 1986-12-30 | 1990-05-01 | Mitsui Petrochemical Industries, Ltd. | Solid catalyst for olefin polymerization and processes for its production |
| PL276385A1 (en) | 1987-01-30 | 1989-07-24 | Exxon Chemical Patents Inc | Method for polymerization of olefines,diolefins and acetylene unsaturated compounds |
| US5198401A (en) | 1987-01-30 | 1993-03-30 | Exxon Chemical Patents Inc. | Ionic metallocene catalyst compositions |
| US5391629A (en) * | 1987-01-30 | 1995-02-21 | Exxon Chemical Patents Inc. | Block copolymers from ionic catalysts |
| IL85097A (en) | 1987-01-30 | 1992-02-16 | Exxon Chemical Patents Inc | Catalysts based on derivatives of a bis(cyclopentadienyl)group ivb metal compound,their preparation and their use in polymerization processes |
| JPH0742301B2 (ja) | 1987-02-14 | 1995-05-10 | 三井石油化学工業株式会社 | 微粒子状アルミノオキサン、その製法およびその用途 |
| US4769910A (en) | 1987-03-30 | 1988-09-13 | Northern Telecom Limited | Cutting tool for cylindrical articles |
| JP2538588B2 (ja) | 1987-04-03 | 1996-09-25 | 三井石油化学工業株式会社 | オレフイン重合用固体触媒の製法 |
| US5206199A (en) | 1987-04-20 | 1993-04-27 | Mitsui Petrochemical Industries, Ltd. | Catalyst for polymerizing an olefin and process for polymerizing an olefin |
| DE3742934A1 (de) | 1987-12-18 | 1989-06-29 | Hoechst Ag | Verfahren zur herstellung einer chiralen, stereorigiden metallocen-verbindung |
| US5120867A (en) | 1988-03-21 | 1992-06-09 | Welborn Jr Howard C | Silicon-bridged transition metal compounds |
| US5017714A (en) | 1988-03-21 | 1991-05-21 | Exxon Chemical Patents Inc. | Silicon-bridged transition metal compounds |
| US5149819A (en) | 1988-04-28 | 1992-09-22 | Ricoh Company, Ltd. | Squarylium compounds and optical information recording medium using the same |
| US4871705A (en) | 1988-06-16 | 1989-10-03 | Exxon Chemical Patents Inc. | Process for production of a high molecular weight ethylene a-olefin elastomer with a metallocene alumoxane catalyst |
| US4892851A (en) | 1988-07-15 | 1990-01-09 | Fina Technology, Inc. | Process and catalyst for producing syndiotactic polyolefins |
| FR2634212B1 (fr) | 1988-07-15 | 1991-04-19 | Bp Chimie Sa | Appareillage et procede de polymerisation d'olefines en phase gazeuse dans un reacteur a lit fluidise |
| US5155080A (en) | 1988-07-15 | 1992-10-13 | Fina Technology, Inc. | Process and catalyst for producing syndiotactic polyolefins |
| DE68919156T3 (de) | 1988-08-05 | 2002-08-14 | Fina Technology, Inc. | Verfahren zur Herstellung grosser symmetrischer Polymerteilchen. |
| US5091352A (en) | 1988-09-14 | 1992-02-25 | Mitsui Petrochemical Industries, Ltd. | Olefin polymerization catalyst component, olefin polymerization catalyst and process for the polymerization of olefins |
| US5382630A (en) | 1988-09-30 | 1995-01-17 | Exxon Chemical Patents Inc. | Linear ethylene interpolymer blends of interpolymers having narrow molecular weight and composition distribution |
| EP0366411A3 (en) | 1988-10-28 | 1991-04-24 | Exxon Chemical Patents Inc. | Graft polymers of ethylene-propylene-diene monomer polymers with propylene, means of preparation, and use of polypropylene compositions |
| US4999403A (en) * | 1988-10-28 | 1991-03-12 | Exxon Chemical Patents Inc. | Graft polymers of functionalized ethylene-alpha-olefin copolymer with polypropylene, methods of preparation, and use in polypropylene compositions |
| US4908463A (en) | 1988-12-05 | 1990-03-13 | Ethyl Corporation | Aluminoxane process |
| CA2008315C (en) | 1989-01-24 | 1995-03-21 | Toshiyuki Tsutsui | Olefin copolymers and processes for preparing same |
| US5047485A (en) | 1989-02-21 | 1991-09-10 | Himont Incorporated | Process for making a propylene polymer with free-end long chain branching and use thereof |
| US5103031A (en) | 1989-02-21 | 1992-04-07 | Ethyl Corporation | Falling film aluminoxane process |
| DE3907964A1 (de) | 1989-03-11 | 1990-09-13 | Hoechst Ag | Verfahren zur herstellung eines syndiotaktischen polyolefins |
| US4968827A (en) | 1989-06-06 | 1990-11-06 | Ethyl Corporation | Alkylaluminoxane process |
| US4924018A (en) | 1989-06-26 | 1990-05-08 | Ethyl Corporation | Alkylaluminoxane process |
| US5026798A (en) | 1989-09-13 | 1991-06-25 | Exxon Chemical Patents Inc. | Process for producing crystalline poly-α-olefins with a monocyclopentadienyl transition metal catalyst system |
| US5057475A (en) | 1989-09-13 | 1991-10-15 | Exxon Chemical Patents Inc. | Mono-Cp heteroatom containing group IVB transition metal complexes with MAO: supported catalyst for olefin polymerization |
| US5763549A (en) | 1989-10-10 | 1998-06-09 | Fina Technology, Inc. | Cationic metallocene catalysts based on organoaluminum anions |
| ATE120768T1 (de) | 1989-10-30 | 1995-04-15 | Fina Technology | Herstellung von metallocenkatalysatoren für olefinpolymerisation. |
| IL96810A0 (en) | 1990-01-02 | 1991-09-16 | Exxon Chemical Patents Inc | Supported ionic metallocene catalysts for olefin polymerization and methods for the preparation thereof |
| GB2241244B (en) * | 1990-02-22 | 1994-07-06 | James C W Chien | Thermoplastic elastomers |
| WO1991015523A1 (en) | 1990-04-09 | 1991-10-17 | Mitsui Toatsu Chemicals, Incorporated | Propylene copolymer |
| WO1991017194A1 (en) | 1990-05-07 | 1991-11-14 | Exxon Chemical Patents Inc. | UNSATURATED α-OLEFIN COPOLYMERS AND METHOD FOR PREPARATION THEREOF |
| RU2118203C1 (ru) | 1990-06-22 | 1998-08-27 | Экксон Кэмикал Пейтентс Инк. | Каталитическая система для получения полиолефинов и композиция, используемая для полимеризации олефинов |
| US5272236A (en) * | 1991-10-15 | 1993-12-21 | The Dow Chemical Company | Elastic substantially linear olefin polymers |
| JP3115595B2 (ja) | 1990-07-24 | 2000-12-11 | 三井化学株式会社 | α―オレフィンの重合触媒及びそれを用いたポリ―α―オレフィンの製造方法 |
| US5243001A (en) | 1990-11-12 | 1993-09-07 | Hoechst Aktiengesellschaft | Process for the preparation of a high molecular weight olefin polymer |
| US5239022A (en) | 1990-11-12 | 1993-08-24 | Hoechst Aktiengesellschaft | Process for the preparation of a syndiotactic polyolefin |
| DE59107926D1 (de) | 1990-11-12 | 1996-07-18 | Hoechst Ag | Metallocene mit Liganden aus 2-substituierten Indenylderivaten, Verfahren zu ihrer Herstellung und ihre Verwendung als Katalysatoren |
| WO1992012162A1 (en) | 1990-12-27 | 1992-07-23 | Exxon Chemical Patents Inc. | An amido transition metal compound and a catalyst system for the production of isotactic polypropylene |
| US5189192A (en) | 1991-01-16 | 1993-02-23 | The Dow Chemical Company | Process for preparing addition polymerization catalysts via metal center oxidation |
| JP3076619B2 (ja) * | 1991-05-14 | 2000-08-14 | 三井化学株式会社 | ブロック共重合体の製造方法 |
| DE4120009A1 (de) | 1991-06-18 | 1992-12-24 | Basf Ag | Loesliche katalysatorsysteme zur herstellung von polyalk-1-enen mit hohen molmassen |
| US5721185A (en) | 1991-06-24 | 1998-02-24 | The Dow Chemical Company | Homogeneous olefin polymerization catalyst by abstraction with lewis acids |
| US5308815A (en) | 1991-07-26 | 1994-05-03 | Ethyl Corporation | Heterogeneous methylaluminoxane catalyst system |
| US5157137A (en) | 1991-07-26 | 1992-10-20 | Ethyl Corporation | Method of making gel free alkylaluminoxane solutions |
| US5235081A (en) | 1992-03-18 | 1993-08-10 | Ethyl Corporation | Method of removing gel forming materials from methylaluminoxanes |
| DE4130299A1 (de) | 1991-09-12 | 1993-03-18 | Basf Ag | Verfahren zur herstellung von polypropylen unter hochdruck |
| EP0537686B1 (de) | 1991-10-15 | 2005-01-12 | Basell Polyolefine GmbH | Verfahren zur Herstellung eines Olefinpolymers unter Verwendung von Metallocenen mit speziell substituierten Indenylliganden |
| CA2125480C (en) * | 1991-12-13 | 2003-06-24 | Patrick Brant | Ethylene/longer alpha-olefin copolymers |
| US5329032A (en) | 1992-03-18 | 1994-07-12 | Akzo Chemicals Inc. | Polymethylaluminoxane of enhanced solution stability |
| US5436304A (en) | 1992-03-19 | 1995-07-25 | Exxon Chemical Patents Inc. | Process for polymerizing monomers in fluidized beds |
| US5352749A (en) | 1992-03-19 | 1994-10-04 | Exxon Chemical Patents, Inc. | Process for polymerizing monomers in fluidized beds |
| US5310794A (en) * | 1992-03-31 | 1994-05-10 | Himont Incorporated | Theromoplastic blends containing graft copolymers of polyacrylates as impact modifiers |
| EP0641362B1 (en) | 1992-04-20 | 1998-11-11 | Exxon Chemical Patents Inc. | Ethylene/branched olefin copolymers |
| EP0578838A1 (en) | 1992-04-29 | 1994-01-19 | Hoechst Aktiengesellschaft | Olefin polymerization catalyst, process for its preparation, and its use |
| US5350723A (en) | 1992-05-15 | 1994-09-27 | The Dow Chemical Company | Process for preparation of monocyclopentadienyl metal complex compounds and method of use |
| US5240894A (en) | 1992-05-18 | 1993-08-31 | Exxon Chemical Patents Inc. | Method for making and using a supported metallocene catalyst system |
| US5434115A (en) | 1992-05-22 | 1995-07-18 | Tosoh Corporation | Process for producing olefin polymer |
| EP0572034A2 (en) * | 1992-05-29 | 1993-12-01 | Idemitsu Kosan Company Limited | Ethylenic copolymer and ethylenic copolymer composition |
| EP0574597B2 (en) | 1992-06-13 | 2002-06-26 | Basell Polyolefine GmbH | Process for the preparation of bridged, chiral metallocene catalysts of the bisindenyl type |
| US5710222A (en) | 1992-06-22 | 1998-01-20 | Fina Technology, Inc. | Method for controlling the melting points and molecular weights of syndiotactic polyolefins using metallocene catalyst systems |
| JPH07509752A (ja) | 1992-08-05 | 1995-10-26 | エクソン・ケミカル・パテンツ・インク | オレフィン重合用の担持されたイオン遷移金属触媒 |
| US5248801A (en) | 1992-08-27 | 1993-09-28 | Ethyl Corporation | Preparation of methylaluminoxanes |
| RU95110681A (ru) | 1992-09-29 | 1997-01-10 | Эксон Кемикэл Пейтентс Инк. (US) | Разветвленные длинноцепочечные полимеры и способ получения разветвленных длинноцепочечных полимеров |
| EP0662979B1 (en) | 1992-10-02 | 1997-07-16 | The Dow Chemical Company | Supported homogeneous catalyst complexes for olefin polymerization |
| EP0667359B1 (en) | 1992-10-28 | 2004-03-31 | Idemitsu Kosan Company Limited | Olefin copolymers and process for producing the same |
| US5939346A (en) | 1992-11-02 | 1999-08-17 | Akzo Nobel N.V. | Catalyst system comprising an aryloxyaluminoxane containing an electron withdrawing group |
| US5635573A (en) | 1992-12-01 | 1997-06-03 | Exxon Chemical Patents Inc. | Method for preparing alpha-olefin/cycloolefin copolymers |
| CA2110654C (en) | 1992-12-17 | 2006-03-21 | Albert Rossi | Dilute process for the polymerization of ethylene/alpha-olefin copolymer using metallocene catalyst systems |
| IL107927A0 (en) | 1992-12-17 | 1994-04-12 | Exxon Chemical Patents Inc | Oil soluble ethylene/1-butene copolymers and lubricating oils containing the same |
| DE69430910T2 (de) * | 1993-02-22 | 2002-12-12 | Idemitsu Kosan Co. Ltd., Tokio/Tokyo | Ethylencopolymer, dieses enthaltende thermoplastische harzzusammensetzung und verfahren zu seiner herstellung |
| JP3077940B2 (ja) | 1993-04-26 | 2000-08-21 | エクソン・ケミカル・パテンツ・インク | 流動層重合法のための安定な操作条件を決定する方法 |
| EP0696300B1 (en) * | 1993-04-28 | 1998-12-23 | The Dow Chemical Company | Fabricated articles made from ethylene polymer blends |
| KR100314971B1 (ko) | 1993-05-25 | 2002-07-03 | 엑손모빌 케미칼 패턴츠 인코포레이티드 | 올레핀중합을위한지지된메탈로센촉매시스템,그의제조방법및용도 |
| US5414027A (en) | 1993-07-15 | 1995-05-09 | Himont Incorporated | High melt strength, propylene polymer, process for making it, and use thereof |
| JPH081575B2 (ja) * | 1993-07-26 | 1996-01-10 | 工業技術院長 | 機器構成用多機能モジュール |
| KR0126658B1 (ko) * | 1993-10-05 | 1997-12-29 | 구자홍 | 비표준 텔레비젼 신호처리를 위한 샘플률 변환장치 |
| JP3363904B2 (ja) * | 1993-10-26 | 2003-01-08 | 出光興産株式会社 | 分岐状エチレン系マクロモノマー及びそれを用いた重合体 |
| US5594080A (en) | 1994-03-24 | 1997-01-14 | Leland Stanford, Jr. University | Thermoplastic elastomeric olefin polymers, method of production and catalysts therefor |
| WO1996000245A1 (en) | 1994-06-24 | 1996-01-04 | Exxon Chemical Patents Inc. | Polymerization catalyst systems, their production and use |
| ES2143636T3 (es) | 1994-06-24 | 2000-05-16 | Exxon Chemical Patents Inc | Sistemas de catalizadores de polimerizacion, su produccion y uso. |
| US5643847A (en) | 1994-08-03 | 1997-07-01 | Exxon Chemical Patents Inc. | Supported ionic catalyst composition |
| EP0775164B1 (en) | 1994-08-03 | 2001-11-07 | ExxonMobil Chemical Patents Inc. | Supported ionic catalyst composition |
| EP0805826B1 (en) | 1995-01-24 | 2003-04-23 | E.I. Du Pont De Nemours And Company | Olefin polymers |
| US5539056A (en) | 1995-01-31 | 1996-07-23 | Exxon Chemical Patents Inc. | Thermoplastic elastomers |
| CA2223258A1 (en) | 1995-07-06 | 1997-01-23 | Exxon Chemical Patents, Inc. | Method for producing prepolymerized, supported metallocene catalyst systems |
| US6084030A (en) * | 1995-08-04 | 2000-07-04 | Dsm Copolymer, Inc. | Branched polymers with polyolefin arms |
| EP1408078B1 (en) * | 1995-09-11 | 2009-08-05 | Mitsui Chemicals, Inc. | Resin composition comprising a linear ethylene/alpha-olefin-copolymer and a long-chain branched ethylene/alpha-olefin-copolymer and films of the same |
| EP0855413B1 (en) | 1997-01-23 | 2002-01-02 | JSR Corporation | Ethylene copolymer rubber composition |
| US6184327B1 (en) | 1997-12-10 | 2001-02-06 | Exxon Chemical Patents, Inc. | Elastomeric propylene polymers |
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- 1998-02-06 BR BR9807672-8A patent/BR9807672A/pt active Search and Examination
- 1998-02-06 US US09/019,609 patent/US6147180A/en not_active Expired - Lifetime
- 1998-02-06 KR KR1019997007137A patent/KR100564500B1/ko not_active Expired - Fee Related
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- 1998-02-06 DE DE69808243T patent/DE69808243T2/de not_active Expired - Lifetime
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- 1998-02-06 JP JP53506398A patent/JP2001511215A/ja active Pending
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Also Published As
| Publication number | Publication date |
|---|---|
| DE69809192D1 (de) | 2002-12-12 |
| BR9808578A (pt) | 2000-05-30 |
| US6660809B1 (en) | 2003-12-09 |
| KR100564500B1 (ko) | 2006-03-29 |
| US6147180A (en) | 2000-11-14 |
| JP2001511215A (ja) | 2001-08-07 |
| CN1246871A (zh) | 2000-03-08 |
| EP0958314B1 (en) | 2002-11-06 |
| DE69808243T2 (de) | 2003-05-08 |
| CN1113915C (zh) | 2003-07-09 |
| KR20000070780A (ko) | 2000-11-25 |
| KR100564499B1 (ko) | 2006-03-29 |
| US20030078350A1 (en) | 2003-04-24 |
| ES2187005T3 (es) | 2003-05-16 |
| EP0958314A1 (en) | 1999-11-24 |
| CN1259147A (zh) | 2000-07-05 |
| US20040048984A1 (en) | 2004-03-11 |
| CA2277063C (en) | 2007-03-20 |
| ES2181173T3 (es) | 2003-02-16 |
| CA2277063A1 (en) | 1998-08-13 |
| US6774191B2 (en) | 2004-08-10 |
| DE69808243D1 (de) | 2002-10-31 |
| DE69809192T2 (de) | 2003-07-24 |
| US6750307B2 (en) | 2004-06-15 |
| JP2001527589A (ja) | 2001-12-25 |
| WO1998034971A1 (en) | 1998-08-13 |
| WO1998034970A1 (en) | 1998-08-13 |
| KR20000070872A (ko) | 2000-11-25 |
| CA2277111A1 (en) | 1998-08-13 |
| EP0958313A1 (en) | 1999-11-24 |
| CN1130406C (zh) | 2003-12-10 |
| EP0958313B1 (en) | 2002-09-25 |
| BR9807672A (pt) | 2000-02-15 |
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