JP3905129B2 - 滑らかな面を有するガラス微小球塗布物品及びその製造方法 - Google Patents
滑らかな面を有するガラス微小球塗布物品及びその製造方法 Download PDFInfo
- Publication number
- JP3905129B2 JP3905129B2 JP51748697A JP51748697A JP3905129B2 JP 3905129 B2 JP3905129 B2 JP 3905129B2 JP 51748697 A JP51748697 A JP 51748697A JP 51748697 A JP51748697 A JP 51748697A JP 3905129 B2 JP3905129 B2 JP 3905129B2
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- Prior art keywords
- layer
- irregularly shaped
- glass
- beads
- glass particles
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Images
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24355—Continuous and nonuniform or irregular surface on layer or component [e.g., roofing, etc.]
- Y10T428/24372—Particulate matter
- Y10T428/24421—Silicon containing
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24802—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
- Y10T428/24851—Intermediate layer is discontinuous or differential
- Y10T428/24868—Translucent outer layer
- Y10T428/24876—Intermediate layer contains particulate material [e.g., pigment, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/25—Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/25—Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
- Y10T428/252—Glass or ceramic [i.e., fired or glazed clay, cement, etc.] [porcelain, quartz, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/26—Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension
- Y10T428/268—Monolayer with structurally defined element
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Optics & Photonics (AREA)
- General Physics & Mathematics (AREA)
- Manufacturing & Machinery (AREA)
- Textile Engineering (AREA)
- Geochemistry & Mineralogy (AREA)
- Life Sciences & Earth Sciences (AREA)
- Laminated Bodies (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Optical Elements Other Than Lenses (AREA)
- Farming Of Fish And Shellfish (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US08/552,850 | 1995-11-03 | ||
| US08/552,850 US5620775A (en) | 1995-11-03 | 1995-11-03 | Low refractive index glass microsphere coated article having a smooth surface and a method for preparing same |
| PCT/US1996/017336 WO1997016754A1 (en) | 1995-11-03 | 1996-10-28 | Glass-microsphere coated article having a smooth surface and method for its preparation |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JPH11514943A JPH11514943A (ja) | 1999-12-21 |
| JPH11514943A5 JPH11514943A5 (enExample) | 2004-10-14 |
| JP3905129B2 true JP3905129B2 (ja) | 2007-04-18 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP51748697A Expired - Fee Related JP3905129B2 (ja) | 1995-11-03 | 1996-10-28 | 滑らかな面を有するガラス微小球塗布物品及びその製造方法 |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US5620775A (enExample) |
| EP (1) | EP0870209B1 (enExample) |
| JP (1) | JP3905129B2 (enExample) |
| KR (1) | KR100413736B1 (enExample) |
| DE (1) | DE69606436T2 (enExample) |
| ES (1) | ES2141544T3 (enExample) |
| WO (1) | WO1997016754A1 (enExample) |
Families Citing this family (125)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE69504370T2 (de) * | 1994-11-29 | 1999-05-12 | Minnesota Mining and Mfg. Co., St. Paul, Minn. | Transparenter dekorativer gegenstand mit einer geätzten erscheinung und einem prismatischen bild |
| US6344263B1 (en) * | 1998-03-30 | 2002-02-05 | 3M Innovative Properties Company | Light dispersing film and method of manufacture |
| US6632506B1 (en) * | 1998-04-23 | 2003-10-14 | Consumer Care Products Inc. | High-visibility traction tape having embedded particle traction surface |
| US6514586B1 (en) * | 1998-08-28 | 2003-02-04 | Kun Lee Hwang | Hot stamping foil |
| US6247818B1 (en) | 1998-10-20 | 2001-06-19 | 3M Innovative Properties Company | Method for making retroreflective elements having enhanced retroreflectivity under dry and/or wet conditions |
| US6365262B1 (en) | 1998-10-20 | 2002-04-02 | 3M Innovative Properties Company | Pavement marking articles having enhanced retroreflectivity under dry or wet conditions and method for making same |
| ATE250511T1 (de) * | 1998-10-23 | 2003-10-15 | Harald Kaufmann | Siebdruck-reflexionstransfer und verfahren zu dessen herstellung |
| CA2316359A1 (en) * | 1998-10-26 | 2000-05-04 | Nashua Corporation | Heat-sealable adhesive label with spacer particles |
| EP0997750B1 (en) * | 1998-10-30 | 2005-05-04 | Avery Dennison Corporation | Retroreflective sheeting containing a validation image and methods of making the same |
| AU6067200A (en) | 1999-07-02 | 2001-01-22 | Ameritech Holdings Corporation | Systems and methods for producing and using fine particle materials |
| KR20010016784A (ko) * | 1999-08-03 | 2001-03-05 | 최병대 | 광택 및 반사 특성이 우수한 도금 미소 유리구슬, 그 제조방법 |
| WO2001016223A1 (en) * | 1999-09-02 | 2001-03-08 | Visibility Enhancement Technologies | Retroreflective inks and fabrics |
| US6764744B2 (en) * | 1999-10-12 | 2004-07-20 | Milliken & Company | Diffractive and retroreflective textile fabrics, methods of making same, and articles made therefrom |
| US6966660B1 (en) * | 1999-10-15 | 2005-11-22 | 3M Innovative Properties Company | Article exhibiting dry and wet retroreflectivity |
| FR2809666B1 (fr) * | 2000-05-31 | 2003-03-14 | Rollin Sa | Procede de fabrication d'un blanchet d'impression multicouches et blanchet ainsi obtenu |
| JP2004508580A (ja) * | 2000-09-01 | 2004-03-18 | スリーエム イノベイティブ プロパティズ カンパニー | ビニルフィルムに積層された光学コアを有するシート、再帰反射性物品、および方法 |
| US6348254B1 (en) * | 2001-01-12 | 2002-02-19 | Taiwan Paiho Limited | Reflective pad and its pattern formation process |
| JP3530979B2 (ja) * | 2001-02-26 | 2004-05-24 | 株式会社ギンガム | 接着装置、接着方法及びそれにより接着した部材 |
| CN1501892A (zh) * | 2001-03-20 | 2004-06-02 | PPG��ҵ����˾ | 形成压花和/或花纹玻璃的方法和设备及由其形成的玻璃制品 |
| US6631030B2 (en) * | 2001-03-30 | 2003-10-07 | 3M Innovative Properties Company | Projection screens and methods for making such projection screens |
| ITMO20010126A1 (it) * | 2001-06-21 | 2002-12-21 | Autoadesivi S R L | Tessuto o termoadesivo rinfrangente o retroriflettente |
| ITMO20010157A1 (it) * | 2001-07-27 | 2003-01-27 | Giorgio Corradi | Metodo per la fabbricazione di un laminato retroriflettente |
| AT5316U1 (de) * | 2001-08-08 | 2002-05-27 | Swarovski & Co | Einrichtung zum aufbringen von glaselementen auf eine unterlage |
| US20030039805A1 (en) * | 2001-08-20 | 2003-02-27 | 3M Innovative Properties Company | Removable retroreflective material |
| KR100412360B1 (ko) * | 2001-12-13 | 2003-12-31 | 엘지전자 주식회사 | 플라스틱 표면 개질 방법 |
| AU2003214999A1 (en) * | 2002-02-04 | 2003-09-02 | Avery Dennison Corporation | Topcoat compositions, coated substrates and method |
| KR20040082423A (ko) * | 2002-02-13 | 2004-09-24 | 코닌클리케 필립스 일렉트로닉스 엔.브이. | 폴리머 호일을 제조하는 방법 |
| US7036944B2 (en) | 2002-04-11 | 2006-05-02 | 3M Innovative Properties Company | Retrochromic articles |
| US6978896B2 (en) * | 2002-04-11 | 2005-12-27 | 3M Innovative Properties Company | Method of making retrochromic beads and kit thereof |
| WO2004060654A1 (en) * | 2003-01-03 | 2004-07-22 | Epocol Ltd. | Improved roughened metal surfaces and methods of production thereof |
| EP1468619B1 (en) * | 2003-04-17 | 2006-10-18 | Industria Bergamasca Rifrangenti S.r.l. | Method for producing printed retroreflective high visibility products |
| BR122014029746B1 (pt) * | 2003-11-14 | 2019-09-17 | Wild River Consulting Group, Llc | Método de fabricação de um compósito polimérico metálico |
| US20110236699A1 (en) * | 2003-11-14 | 2011-09-29 | Tundra Composites, LLC | Work piece comprising metal polymer composite with metal insert |
| US20090324875A1 (en) * | 2003-11-14 | 2009-12-31 | Heikkila Kurt E | Enhanced property metal polymer composite |
| US9105382B2 (en) | 2003-11-14 | 2015-08-11 | Tundra Composites, LLC | Magnetic composite |
| US20090127801A1 (en) * | 2003-11-14 | 2009-05-21 | Wild River Consulting Group, Llc | Enhanced property metal polymer composite |
| US20050164619A1 (en) * | 2004-01-27 | 2005-07-28 | Soelch Richard R. | Thermoplastic sheet abrasives and methods of making the same |
| US20050227046A1 (en) * | 2004-04-09 | 2005-10-13 | Joe Lee | Glass shard-paved structure |
| US20050243420A1 (en) * | 2004-05-03 | 2005-11-03 | Harmony Fastening Systems, Inc. | Method of producing reflective design on a substrate and apparatus |
| US7504147B2 (en) * | 2004-07-22 | 2009-03-17 | Avery Dennison Corporation | Retroreflective sheeting with security and/or decorative image |
| KR100580655B1 (ko) * | 2004-11-06 | 2006-05-16 | 삼성전자주식회사 | 단방향 투명 광학계의 제조 방법 |
| KR101303508B1 (ko) * | 2004-12-28 | 2013-09-03 | 쓰리엠 이노베이티브 프로퍼티즈 컴파니 | 불소- 또는 규소-함유 프리즘을 갖는 프리즘 역반사 물품 |
| JP4885839B2 (ja) * | 2005-02-21 | 2012-02-29 | 富士フイルム株式会社 | 拡散フィルムの設計方法及び製造方法並びにそれにより得られる拡散フィルム |
| US20060237117A1 (en) * | 2005-04-21 | 2006-10-26 | Lee In-Hwan | Method of producing a retro-reflective product with a transparent protective film for whole surface |
| US7198377B2 (en) * | 2005-04-21 | 2007-04-03 | Lee In-Hwan | Method of producing a retro-reflective heat transfer film with a transparent protective sheet for whole surface |
| GB0515088D0 (en) * | 2005-07-22 | 2005-08-31 | Imerys Minerals Ltd | Particulate glass compositions and methods of production |
| KR100583251B1 (ko) * | 2005-08-29 | 2006-05-26 | 주식회사 성일토탈프린팅 | 원형 유리비드를 이용하여 입체감이 있는 에칭효과를가지도록 한 유리판 및 그 무늬 성형방법 |
| GB0517951D0 (en) * | 2005-09-05 | 2005-10-12 | Viz Reflectives Ltd | Retro-reflective coatings and articles |
| KR100716143B1 (ko) * | 2005-09-05 | 2007-05-10 | 도레이새한 주식회사 | 광확산 필름 |
| JP4752725B2 (ja) * | 2005-11-17 | 2011-08-17 | 株式会社ニコン | ガラス基板およびその製造方法 |
| WO2007094764A2 (en) * | 2006-02-09 | 2007-08-23 | Wild River Consulting Group, Llc | Metal polymer composite with enhanced viscoelastic and thermal properties |
| US9248470B2 (en) | 2006-07-31 | 2016-02-02 | Safe Reflections, Inc. | Colorized retroreflective material and method |
| WO2008016716A2 (en) * | 2006-08-01 | 2008-02-07 | Tao-Ming Tom King | A process of making retro-reflective material |
| US20100108247A1 (en) * | 2006-08-01 | 2010-05-06 | Tao-Ming Tom King | Method and Apparatus for a Retro-reflective Material |
| ITBO20060669A1 (it) * | 2006-09-29 | 2008-03-30 | Momaboma S R L | Materiale composito, in particolare per l'abbigliamento, la moda e l'arredo |
| US7645355B2 (en) * | 2006-11-17 | 2010-01-12 | 3M Innovative Properties Company | Method of making a microsphere transfer adhesive |
| US20090035520A1 (en) * | 2007-08-03 | 2009-02-05 | Brian Frederick Sagar | Retro-reflective materials and components thereof |
| US20090117162A1 (en) * | 2007-11-01 | 2009-05-07 | Victor Bruce H | Topical Cosmetic Compositions |
| US20110193335A1 (en) * | 2007-12-21 | 2011-08-11 | Budd Kenton D | Retroreflective security articles |
| CN101946192B (zh) * | 2007-12-21 | 2012-09-05 | 3M创新有限公司 | 回射制品以及包括球芯和两个同心光学干涉层的回射元件 |
| JP2011509421A (ja) * | 2007-12-21 | 2011-03-24 | スリーエム イノベイティブ プロパティズ カンパニー | 衣類、繊維及びフィラメント形態の再帰反射物品 |
| CA2712124C (en) | 2008-01-18 | 2016-08-16 | Wild River Consulting Group, Llc | Melt molding polymer composite and method of making and using the same |
| KR100854625B1 (ko) * | 2008-06-02 | 2008-08-27 | (주)디나옵틱스 | 유리 액세서리와 그 제조 장치 및 방법 |
| AT10381U1 (de) * | 2008-06-19 | 2009-02-15 | Swarovski & Co | Längliches dekoratives element |
| WO2010002725A2 (en) * | 2008-07-03 | 2010-01-07 | 3M Innovative Properties Company | Fixed abrasive particles and articles made therefrom |
| AT507129B1 (de) * | 2008-07-23 | 2010-08-15 | Swarovski & Co | Verfahren zur herstellung einer schmucksteinanordnung |
| US8840956B2 (en) * | 2008-10-31 | 2014-09-23 | Potters Industries, Llc | Retroreflective coating and method for applying a retroreflective coating on a structure |
| EP2211207A1 (en) * | 2009-01-23 | 2010-07-28 | Reflec PLC | Retro-reflective materials and components thereof |
| US20100266862A1 (en) * | 2009-04-17 | 2010-10-21 | 3M Innovative Properties Company | Metal particle transfer article, metal modified substrate, and method of making and using the same |
| US20100272962A1 (en) * | 2009-04-22 | 2010-10-28 | Potters Industries Inc. | Reflective substrate surface system, reflective assembly, and methods of improving the visibility of a substrate surface |
| US9249283B2 (en) | 2009-04-29 | 2016-02-02 | Tundra Composites, LLC | Reduced density glass bubble polymer composite |
| DE102010001511B4 (de) | 2010-02-02 | 2012-07-12 | Harald Kaufmann | Verfahren zum Herstellen eines Textilprodukts |
| US8647013B2 (en) * | 2010-02-09 | 2014-02-11 | Potters Industries, Llc | Reflective substrate surface system, reflective assembly, and methods of improving the visibility of a substrate surface |
| TW201209774A (en) * | 2010-08-17 | 2012-03-01 | Hannspree Inc | Manufacturing method of display frame with artificial diamond |
| WO2012054283A1 (en) | 2010-10-18 | 2012-04-26 | 3M Innovative Properties Company | Functional particle transfer liner |
| WO2012082536A2 (en) * | 2010-12-17 | 2012-06-21 | 3M Innovative Properties Company | Transfer article having multi-sized particles and methods |
| DE102011077700A1 (de) | 2011-06-17 | 2012-12-20 | Tesa Se | Trennbeschichtung mit einem niedrigen Reibungskoeffizienten |
| JP6355185B2 (ja) * | 2011-09-27 | 2018-07-11 | エスケイシー ハイテク アンド マーケティング カンパニー リミテッド | 高輝度光学シートを製造する方法 |
| US20150010723A1 (en) | 2012-02-22 | 2015-01-08 | 3M Innovative Properties Company | Microsphere articles and transfer articles |
| CN104302719B (zh) | 2012-02-28 | 2017-10-10 | 3M创新有限公司 | 具有包含聚有机硅氧烷和亲水性组分的防粘涂层的片材制品 |
| TWM436561U (en) * | 2012-04-27 | 2012-09-01 | Chaei Hsin Entpr Co Ltd | Reflection film structure for preformed structural component |
| ITRM20120282A1 (it) * | 2012-06-18 | 2013-12-19 | Battista Davide Di | Metodo per l¿applicazione di elementi decorativi su superfici curve. |
| BE1020819A3 (fr) | 2012-07-05 | 2014-05-06 | Ct Rech Metallurgiques Asbl | Revetement a haute teneur en microbilles. |
| CN104853931A (zh) * | 2012-10-04 | 2015-08-19 | 3M创新有限公司 | 可热成形的微球制品 |
| EP2716471B1 (en) | 2012-10-05 | 2016-05-11 | Reflectra USA Inc. | A method of producing a reflection transfer for transferring a motif onto a substrate |
| CN103792603B (zh) * | 2012-10-26 | 2016-07-06 | 3M创新有限公司 | 回归反射材料及制品 |
| CN103792604B (zh) * | 2012-10-26 | 2016-12-21 | 3M创新有限公司 | 回归反射制品和附饰物 |
| CN103869535B (zh) | 2012-12-14 | 2016-09-07 | 乐金显示有限公司 | 显示装置及制造用于显示装置的反射片的方法 |
| KR102102904B1 (ko) * | 2012-12-14 | 2020-05-29 | 엘지디스플레이 주식회사 | 표시 장치 및 반사 시트의 제조 방법 |
| CN105359009A (zh) * | 2013-06-24 | 2016-02-24 | 3M创新有限公司 | 具有多层密封膜的回射制品 |
| USD733560S1 (en) * | 2013-06-25 | 2015-07-07 | Lincoln Global, Inc. | Packing bead ring for a wire coil |
| KR102263937B1 (ko) * | 2013-06-26 | 2021-06-11 | 쓰리엠 이노베이티브 프로퍼티즈 컴파니 | 내오염성 미소구체 물품 |
| JP6461115B2 (ja) | 2013-10-04 | 2019-01-30 | スリーエム イノベイティブ プロパティズ カンパニー | 装飾用マイクロスフェア物品 |
| EP3105047B1 (en) * | 2014-02-13 | 2020-12-09 | 3M Innovative Properties Company | Flexible microsphere articles having high temperature stability |
| EP3105048B1 (en) * | 2014-02-13 | 2021-06-16 | 3M Innovative Properties Company | Dual cure stain resistant microsphere articles |
| JP5612790B1 (ja) * | 2014-03-28 | 2014-10-22 | ユニチカスパークライト株式会社 | 再帰性反射性材料 |
| WO2015153701A1 (en) * | 2014-04-02 | 2015-10-08 | 3M Innovative Properties Company | Abrasion resistant microsphere articles |
| EP3140683B1 (en) * | 2014-05-09 | 2025-10-29 | 3M Innovative Properties Company | Retroreflective articles |
| CN106459352B (zh) | 2014-06-16 | 2020-01-14 | 3M创新有限公司 | 具有耐洗性珠粘结层的回射制品 |
| DE102014110611A1 (de) * | 2014-07-28 | 2016-01-28 | Interstuhl Büromöbel GmbH & Co. KG | Textiles Flächengebilde |
| US10300490B2 (en) * | 2014-07-29 | 2019-05-28 | Patent Applied Technology | Rotary mill |
| US10844160B2 (en) | 2015-02-13 | 2020-11-24 | 3M Innovative Properties Company | Flexible microsphere articles having high temperature stability |
| DE112016003676T5 (de) | 2015-08-12 | 2018-05-30 | 3M Innovative Properties Company | Chemikalienbeständige Mikrokügelchen-Artikel |
| EP3390070B1 (en) | 2015-12-18 | 2022-04-06 | 3M Innovative Properties Company | Decorative article featuring a microscopic periodic pattern and methods of making the same |
| US11413846B2 (en) | 2016-03-30 | 2022-08-16 | 3M Innovative Properties Company | Article featuring a predetermined pattern of randomly distributed microspheres and methods of making the same |
| CN107471795B (zh) * | 2016-06-07 | 2019-08-23 | 上海劲嘉建材科技有限公司 | 复合饰面板及其制备方法 |
| US20190136446A1 (en) * | 2016-06-28 | 2019-05-09 | Safe Reflections, Inc. | Textured reflective synthetic leather |
| EP3529645B1 (en) | 2016-10-18 | 2023-03-29 | 3M Innovative Properties Company | Thermoformable beaded articles with removable stabilizing layer and methods thereof |
| US10353273B2 (en) * | 2016-11-14 | 2019-07-16 | Magic Memories Innovation Limited | Backdrop for chroma key photography with partially transparent beading |
| IL251430B (en) | 2017-03-28 | 2018-10-31 | Erez Thermoplastic Products Agriculture Coop Association Ltd | Retroreflective fabrics |
| US11297885B2 (en) | 2017-05-21 | 2022-04-12 | Nike, Inc. | Reflective articles of wear |
| US10555565B2 (en) | 2017-05-31 | 2020-02-11 | Nike, Inc. | Reflective articles of wear |
| JP6933006B2 (ja) * | 2017-06-09 | 2021-09-08 | 横浜ゴム株式会社 | 空気入りタイヤ |
| US12220786B2 (en) * | 2019-01-21 | 2025-02-11 | TVITEC System Glass SL | Method for producing a glass substrate with an embossed surface finish and glass substrate obtained using said method |
| CN109738980A (zh) * | 2019-03-01 | 2019-05-10 | 黄山兴伟反光材料有限公司 | 一种混珠型工程级反光膜及其制备方法 |
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Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2326634A (en) * | 1941-12-26 | 1943-08-10 | Minnesota Mining & Mfg | Reflex light reflector |
| NL133265C (enExample) * | 1959-11-02 | |||
| US3764455A (en) * | 1970-04-01 | 1973-10-09 | Goodyear Tire & Rubber | Reflective surface and method of production |
| US3758192A (en) * | 1970-08-20 | 1973-09-11 | Minnesota Mining & Mfg | Reflex-reflective structures including fabric and transfer foils |
| US3700305A (en) * | 1970-12-14 | 1972-10-24 | Minnesota Mining & Mfg | Retroreflective microspheres having a dielectric mirror on a portion of their surface and retroreflective constructions containing such microspheres |
| IT1045806B (it) * | 1973-01-22 | 1980-06-10 | Eigenmann Ludwig | Perfezionamento ai materiali per segnaletica stradle orizzontale ed ai metodi per la loro produzione e relativi materiali perfezionati ad alta aderenza resistenza all usura evisibilita |
| US4102562A (en) * | 1976-06-14 | 1978-07-25 | Minnesota Mining And Manufacturing Company | Retroreflective transfer sheet material |
| US4328274A (en) * | 1979-08-10 | 1982-05-04 | Minnesota Mining And Manufacturing Company | Transparent friction surface sheet material |
| US4961770A (en) * | 1987-05-22 | 1990-10-09 | Gte Products Corporation | Process for producing spherical glass particles |
| JP2546853B2 (ja) * | 1987-09-03 | 1996-10-23 | オーツタイヤ株式会社 | 装飾性ビーズコートシートおよびその製造方法 |
| US5344705A (en) * | 1993-05-05 | 1994-09-06 | Minnesota Mining And Manufacturing Company | Retroreflective transfer sheet material |
| CA2147710A1 (en) * | 1994-05-20 | 1995-11-21 | Gregory F. Jacobs | Retroreflective pavement marking |
| US5417515A (en) * | 1994-05-20 | 1995-05-23 | Minnesota Mining And Manufacturing Company | Retroreflective article with dual reflector |
-
1995
- 1995-11-03 US US08/552,850 patent/US5620775A/en not_active Expired - Lifetime
-
1996
- 1996-10-28 WO PCT/US1996/017336 patent/WO1997016754A1/en not_active Ceased
- 1996-10-28 JP JP51748697A patent/JP3905129B2/ja not_active Expired - Fee Related
- 1996-10-28 KR KR10-1998-0703276A patent/KR100413736B1/ko not_active Expired - Fee Related
- 1996-10-28 DE DE69606436T patent/DE69606436T2/de not_active Expired - Lifetime
- 1996-10-28 ES ES96937796T patent/ES2141544T3/es not_active Expired - Lifetime
- 1996-10-28 EP EP96937796A patent/EP0870209B1/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| US5620775A (en) | 1997-04-15 |
| DE69606436T2 (de) | 2000-09-14 |
| KR100413736B1 (ko) | 2004-02-18 |
| JPH11514943A (ja) | 1999-12-21 |
| EP0870209A1 (en) | 1998-10-14 |
| DE69606436D1 (de) | 2000-03-02 |
| KR19990067297A (ko) | 1999-08-16 |
| ES2141544T3 (es) | 2000-03-16 |
| EP0870209B1 (en) | 2000-01-26 |
| WO1997016754A1 (en) | 1997-05-09 |
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