JP3808672B2 - 回収ポリエチレンテレフタレート粉砕品からのテレフタル酸の工業的回収方法 - Google Patents

回収ポリエチレンテレフタレート粉砕品からのテレフタル酸の工業的回収方法 Download PDF

Info

Publication number
JP3808672B2
JP3808672B2 JP33590899A JP33590899A JP3808672B2 JP 3808672 B2 JP3808672 B2 JP 3808672B2 JP 33590899 A JP33590899 A JP 33590899A JP 33590899 A JP33590899 A JP 33590899A JP 3808672 B2 JP3808672 B2 JP 3808672B2
Authority
JP
Japan
Prior art keywords
ethylene glycol
terephthalic acid
terephthalate
solid
washing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
JP33590899A
Other languages
English (en)
Japanese (ja)
Other versions
JP2001151709A5 (cg-RX-API-DMAC10.html
JP2001151709A (ja
Inventor
仁一 矢崎
弘三郎 坂野
信之 船越
一穂 田中
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Tsukishima Kikai Co Ltd
Toyo Seikan Group Holdings Ltd
Original Assignee
Toyo Seikan Kaisha Ltd
Tsukishima Kikai Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toyo Seikan Kaisha Ltd, Tsukishima Kikai Co Ltd filed Critical Toyo Seikan Kaisha Ltd
Priority to JP33590899A priority Critical patent/JP3808672B2/ja
Priority to US09/721,057 priority patent/US6580005B1/en
Priority to KR1020000070408A priority patent/KR100630847B1/ko
Priority to DE10058773A priority patent/DE10058773A1/de
Publication of JP2001151709A publication Critical patent/JP2001151709A/ja
Priority to US10/424,042 priority patent/US7173150B2/en
Publication of JP2001151709A5 publication Critical patent/JP2001151709A5/ja
Application granted granted Critical
Publication of JP3808672B2 publication Critical patent/JP3808672B2/ja
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Images

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/42—Separation; Purification; Stabilisation; Use of additives
    • C07C51/43—Separation; Purification; Stabilisation; Use of additives by change of the physical state, e.g. crystallisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J11/00—Recovery or working-up of waste materials
    • C08J11/04—Recovery or working-up of waste materials of polymers
    • C08J11/10—Recovery or working-up of waste materials of polymers by chemically breaking down the molecular chains of polymers or breaking of crosslinks, e.g. devulcanisation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/09—Preparation of carboxylic acids or their salts, halides or anhydrides from carboxylic acid esters or lactones
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/41—Preparation of salts of carboxylic acids
    • C07C51/412—Preparation of salts of carboxylic acids by conversion of the acids, their salts, esters or anhydrides with the same carboxylic acid part
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/42—Separation; Purification; Stabilisation; Use of additives
    • C07C51/47—Separation; Purification; Stabilisation; Use of additives by solid-liquid treatment; by chemisorption
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J11/00—Recovery or working-up of waste materials
    • C08J11/04—Recovery or working-up of waste materials of polymers
    • C08J11/10—Recovery or working-up of waste materials of polymers by chemically breaking down the molecular chains of polymers or breaking of crosslinks, e.g. devulcanisation
    • C08J11/18—Recovery or working-up of waste materials of polymers by chemically breaking down the molecular chains of polymers or breaking of crosslinks, e.g. devulcanisation by treatment with organic material
    • C08J11/22—Recovery or working-up of waste materials of polymers by chemically breaking down the molecular chains of polymers or breaking of crosslinks, e.g. devulcanisation by treatment with organic material by treatment with organic oxygen-containing compounds
    • C08J11/24—Recovery or working-up of waste materials of polymers by chemically breaking down the molecular chains of polymers or breaking of crosslinks, e.g. devulcanisation by treatment with organic material by treatment with organic oxygen-containing compounds containing hydroxyl groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2367/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
    • C08J2367/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00—Technologies for solid waste management
    • Y02W30/50—Reuse, recycling or recovery technologies
    • Y02W30/62—Plastics recycling; Rubber recycling

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Sustainable Development (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
JP33590899A 1999-11-26 1999-11-26 回収ポリエチレンテレフタレート粉砕品からのテレフタル酸の工業的回収方法 Expired - Fee Related JP3808672B2 (ja)

Priority Applications (5)

Application Number Priority Date Filing Date Title
JP33590899A JP3808672B2 (ja) 1999-11-26 1999-11-26 回収ポリエチレンテレフタレート粉砕品からのテレフタル酸の工業的回収方法
US09/721,057 US6580005B1 (en) 1999-11-26 2000-11-22 Process for recovering terephthalic acid from pulverized product of spent polyethylene terephthalate and system for use in such process
KR1020000070408A KR100630847B1 (ko) 1999-11-26 2000-11-24 회수 폴리에틸렌테레프탈레이트 분쇄품에서 테레프탈산의회수 방법 및 장치
DE10058773A DE10058773A1 (de) 1999-11-26 2000-11-27 Verfahren zur Rückgewinnung von Terephthalsäure aus dem pulverisierten Produkt von verbrauchtem Polyethylenterephthalat und System für die Verwendung in diesem Verfahren
US10/424,042 US7173150B2 (en) 1999-11-26 2003-04-24 Process for recovering terephthalic acid from pulverized product of spent polyethylene terephthalate and system for use in such process

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP33590899A JP3808672B2 (ja) 1999-11-26 1999-11-26 回収ポリエチレンテレフタレート粉砕品からのテレフタル酸の工業的回収方法

Publications (3)

Publication Number Publication Date
JP2001151709A JP2001151709A (ja) 2001-06-05
JP2001151709A5 JP2001151709A5 (cg-RX-API-DMAC10.html) 2005-04-07
JP3808672B2 true JP3808672B2 (ja) 2006-08-16

Family

ID=18293724

Family Applications (1)

Application Number Title Priority Date Filing Date
JP33590899A Expired - Fee Related JP3808672B2 (ja) 1999-11-26 1999-11-26 回収ポリエチレンテレフタレート粉砕品からのテレフタル酸の工業的回収方法

Country Status (4)

Country Link
US (2) US6580005B1 (cg-RX-API-DMAC10.html)
JP (1) JP3808672B2 (cg-RX-API-DMAC10.html)
KR (1) KR100630847B1 (cg-RX-API-DMAC10.html)
DE (1) DE10058773A1 (cg-RX-API-DMAC10.html)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2021107691A1 (ko) * 2019-11-29 2021-06-03 롯데케미칼 주식회사 결정화를 이용하는 폐플라스틱의 화학적 재활용 방법
TWI820801B (zh) * 2021-07-19 2023-11-01 南韓商Lg化學股份有限公司 合成再生塑膠之單體組成物、其製備方法以及使用其所製之再生塑膠、模製物與塑化劑組成物
US12709670B1 (en) * 2025-09-18 2026-08-18 Mangalore Refinery & Petrochemicals Ltd. Process for treating textile waste

Families Citing this family (41)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3808672B2 (ja) * 1999-11-26 2006-08-16 東洋製罐株式会社 回収ポリエチレンテレフタレート粉砕品からのテレフタル酸の工業的回収方法
FR2809727B1 (fr) * 2000-05-31 2002-07-26 Galderma Res & Dev Nouveaux composes aminothiolesters, compositions pharmaceutiques et cosmetiques les contenant et utilisations
US7078440B2 (en) * 2000-11-27 2006-07-18 Teijin Limited Dimethyl terephthalate composition and process for producing the same
ATE458714T1 (de) * 2001-05-15 2010-03-15 Mitsubishi Chem Corp Verfahren zur herstellung einer verbindung
WO2005079140A2 (en) * 2003-02-27 2005-09-01 Petrecycle Ltd A method for the decontamination of polyethylene terephthalate
AU2003221034A1 (en) * 2003-04-04 2004-11-01 Teijin Fibers Limited Method of caustic reduction treatment for polyester fiber
JP4210221B2 (ja) * 2004-01-15 2009-01-14 乕 吉村 廃プラスチックの油化還元装置
DK1710226T3 (da) * 2004-01-27 2009-10-05 Univ Iberoamericana A C Kemisk fremgangsmåde til genanvendelse af polyethylenterephthalataffald (PET)
JP4285323B2 (ja) * 2004-05-19 2009-06-24 日立電線株式会社 高分子化合物の処理方法及びその装置
CN1314652C (zh) * 2005-01-14 2007-05-09 东华大学 粗对苯二甲酸的提纯方法
JP4937521B2 (ja) * 2005-03-31 2012-05-23 三井化学株式会社 ポリエステルより高純度モノマーを回収する方法及び高純度モノマー、ポリエステル
US7448515B2 (en) * 2005-04-14 2008-11-11 Ramirez-Delgado Roberto Alfred Automatic machine for dosing water and dental alginate
US7469801B2 (en) * 2005-04-14 2008-12-30 Ramirez-Delgado Roberto Alfred Automatic machine for dosing water and dental alginate
US8697906B2 (en) * 2006-03-01 2014-04-15 Grupo Petrotemex, S.A. De C.V. Methods and apparatus for producing a low-moisture carboxylic acid wet cake
US8173836B2 (en) * 2006-03-01 2012-05-08 Grupo Petrotemex, S.A. De C.V. Method and apparatus for drying carboxylic acid
KR101415346B1 (ko) * 2007-02-23 2014-07-04 데이진 화이바 가부시키가이샤 폴리에스테르 섬유 폐기물로부터 이종 소재를 분리 제거하는 방법
US8299135B2 (en) * 2009-07-02 2012-10-30 Bepex International, Llc Vapor phase assisted post-consumer polymer processing apparatus and method
KR101130453B1 (ko) 2009-09-11 2012-04-12 삼성석유화학(주) 폐 테레프탈산으로부터 테레프탈산을 회수하는 방법
US9458354B2 (en) 2010-10-06 2016-10-04 Resinate Technologies, Inc. Polyurethane dispersions and methods of making and using same
CA2838825A1 (en) 2011-06-10 2012-12-13 Kristopher M. Felice Clear coatings acrylic coatings
US9732026B2 (en) 2012-12-14 2017-08-15 Resinate Technologies, Inc. Reaction products containing hydroxyalkylterephthalates and methods of making and using same
JP2018510225A (ja) 2015-01-30 2018-04-12 レジネート マテリアルズ グループ、インコーポレイテッド Pet及びpttのリサイクル流の統合処理方法
PL411679A1 (pl) 2015-03-20 2016-09-26 Rs Pet Spółka Z Ograniczoną Odpowiedzialnością Instalacja do ciągłej przeróbki odpadów politereftalanu etylenu PET
TWI602860B (zh) * 2016-02-05 2017-10-21 遠東新世紀股份有限公司 由聚酯製備環己烷二甲酸的方法
ITUB20160843A1 (it) * 2016-02-18 2017-08-18 Recyclinnova S R L S Processo di conversione di rifiuti in Polietilene Tereftalato (PET) in prodotti chimici di valore
RU2616299C1 (ru) * 2016-05-19 2017-04-14 Общество с ограниченной ответственностью "ХИМТЕХ-ИНЖИНИРИНГ" Способ щелочного гидролиза отходов ПЭТФ с получением терефталевой кислоты
CN108658758B (zh) * 2018-07-18 2021-05-11 南京道港贸易有限公司 对苯二甲酰氯的制备方法、对苯二甲酰氯和应用、对苯二胺的制备方法和对苯二胺
DE102018122210B4 (de) * 2018-09-12 2023-06-29 Rittec Umwelttechnik Gmbh Verfahren und Verwendung einer Vorrichtung zur Wiederaufarbeitung von Polyalkylenterephthalat enthaltenden Abfällen
TWI694064B (zh) 2018-09-26 2020-05-21 遠東新世紀股份有限公司 對苯二甲酸的製造方法及其系統
TWI708761B (zh) * 2019-09-26 2020-11-01 遠東新世紀股份有限公司 製造對苯二甲酸的方法
CN110862520A (zh) * 2019-10-24 2020-03-06 江苏聚杰微纤科技集团股份有限公司 一种利用碱减量废水中的对苯二甲酸制备pet的方法
DE102019135578A1 (de) * 2019-12-20 2021-06-24 Rittec Umwelttechnik Gmbh Verfahren, Vorrichtung und Verwendung zur Wiederaufarbeitung
CN116033967A (zh) 2020-08-10 2023-04-28 奥里格聚合物股份有限公司 用于来自废聚酯的化学再循环的回收乙二醇的纯化的方法
KR102676709B1 (ko) * 2021-01-14 2024-06-18 코오롱인더스트리 주식회사 폴리에스테르의 탈색 방법 및 이를 포함하는 폴리에스테르의 해중합 방법
CN112898630B (zh) * 2021-01-26 2022-06-17 佛山科学技术学院 一种聚酯类塑料的机械化学绿色降解方法
DE102021105970A1 (de) 2021-03-11 2022-09-15 Rittec Umwelttechnik Gmbh Verfahren zur Gewinnung aromatischer Dicarbonsäuren aus ihren Metallsalzen
KR20230162609A (ko) * 2021-03-26 2023-11-28 츠키시마 기카이 가부시키가이샤 결정화 장치, 결정화 시스템, 및 결정화 방법
KR102381508B1 (ko) * 2021-09-28 2022-04-01 김 영 범 고유점도가 0.75㎗/g 이상인 고중합도의 폴리에틸렌테레프탈레이트를 이용한 테레프탈산의 제조방법
JP2025536667A (ja) * 2022-11-16 2025-11-07 デポリー エスアー テレフタル酸の精製方法
EP4766768A1 (en) * 2023-06-26 2026-07-01 Use Waste Prosta Spolka Akcyjna A PROCESS FOR RECYCLING ARTICLES CONTAINING POLY (ETHYLENE TEREPHTHALATE), IN PARTICULAR POLYESTER CLOTHING WASTE
DE102023134489A1 (de) 2023-12-08 2025-06-12 Rittec 8.0 Umwelttechnik GmbH Verfahren zur Gewinnung aromatischer Dicarbonsäuren

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3544622A (en) * 1965-03-10 1970-12-01 Du Pont Alkaline saponification of polyethylene terephthalate at high temperatures using controlled amount of sodium hydroxide
US4542239A (en) * 1981-11-18 1985-09-17 Board Of Control Of Michigan Technological University Process for recovering terephthalic acid from waste polyethylene terephthalate
DE3639958A1 (de) * 1986-01-10 1987-07-16 Amberger Kaolinwerke Gmbh Mehrstufige anordnung zur gegenstromwaschung, sowie zugehoerige verfahrensmassnahmen
US5502247A (en) * 1994-11-17 1996-03-26 Amoco Corporation Process for recovery of aromatic acid or ester and polyol from waste polyester resins
US6075163A (en) * 1995-12-30 2000-06-13 Sunkyong Industries Co., Ltd. Process for manufacturing terephthalic acid
JP3350696B2 (ja) * 1996-04-23 2002-11-25 財団法人生産開発科学研究所 ポリエチレンテレフタレ−トよりテレフタル酸とエチレングリコールとを回収する方法
JP3808672B2 (ja) * 1999-11-26 2006-08-16 東洋製罐株式会社 回収ポリエチレンテレフタレート粉砕品からのテレフタル酸の工業的回収方法

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2021107691A1 (ko) * 2019-11-29 2021-06-03 롯데케미칼 주식회사 결정화를 이용하는 폐플라스틱의 화학적 재활용 방법
TWI820801B (zh) * 2021-07-19 2023-11-01 南韓商Lg化學股份有限公司 合成再生塑膠之單體組成物、其製備方法以及使用其所製之再生塑膠、模製物與塑化劑組成物
US12679926B2 (en) 2021-07-19 2026-07-14 Lg Chem, Ltd. Monomer composition for synthesizing recycled plastic, preparation method thereof, and recycled plastic, molded product, plasticizer composition using the same
US12709670B1 (en) * 2025-09-18 2026-08-18 Mangalore Refinery & Petrochemicals Ltd. Process for treating textile waste

Also Published As

Publication number Publication date
US6580005B1 (en) 2003-06-17
US20030225299A1 (en) 2003-12-04
US7173150B2 (en) 2007-02-06
KR20010051935A (ko) 2001-06-25
KR100630847B1 (ko) 2006-10-09
JP2001151709A (ja) 2001-06-05
DE10058773A1 (de) 2001-08-16

Similar Documents

Publication Publication Date Title
JP2001151709A (ja) 回収ポリエチレンテレフタレート粉砕品からのテレフタル酸の工業的回収方法
JP2001151709A5 (cg-RX-API-DMAC10.html)
JP3069917B2 (ja) テレフタル酸の製造方法
JP3140469B2 (ja) テレフタル酸の製造方法
TWI225804B (en) Process for recovering crystals from a slurry
JP3342011B2 (ja) 精製テレフタル酸を回収するための改良方法
KR100278525B1 (ko) 폴리알킬렌 테레프탈레이트로부터 알칼리 금속 또는 알칼리토류 금속의 테레프탈레이트 및 알킬렌 글리콜을 회수하는 방법
JP3917811B2 (ja) 回収ポリエチレンテレフタレート粉砕品からのテレフタル酸の工業的回収方法
CN114929377B (zh) 用于聚合物解聚的设备和方法
JP3889219B2 (ja) 回収ポリエチレンテレフタレート粉砕品からのテレフタル酸の工業的回収方法及び装置
CN1204107C (zh) 回收纯化的对苯二甲酸(pta)的方法
JP3850149B2 (ja) 芳香族ジカルボン酸の回収方法
JP3032907B2 (ja) テレフタル酸の製造方法
JP3942817B2 (ja) 回収ポリエチレンテレフタレート粉砕品からのテレフタル酸の回収方法
JP3942818B2 (ja) 回収ポリエチレンテレフタレート粉砕品からのテレフタル酸の工業的回収方法
CN1113846C (zh) 生产对苯二甲酸的方法
CN120132736A (zh) 一种生产高纯电子级碳酸乙烯酯的系统和方法
JPH0360762B2 (cg-RX-API-DMAC10.html)
JP3972500B2 (ja) 回収ポリエステルボトルより高純度のテレフタル酸を回収する方法
JP4918264B2 (ja) ビスフェノールaの回収方法および回収設備
PL211594B1 (pl) Sposób i układ instalacji do odzyskiwania kwasu tereftalowego oraz glikolu etylenowego z odpadów polietylenotereftalanu
CN116020379B (zh) 用于制备草酸银的装置和草酸银的制备方法
CN118546059A (zh) 一种pet聚酯连续化学法回收工艺
JP2002155011A5 (cg-RX-API-DMAC10.html)

Legal Events

Date Code Title Description
A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20040528

A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20040528

A977 Report on retrieval

Free format text: JAPANESE INTERMEDIATE CODE: A971007

Effective date: 20050128

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20050729

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20050922

TRDD Decision of grant or rejection written
A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

Effective date: 20060512

A61 First payment of annual fees (during grant procedure)

Free format text: JAPANESE INTERMEDIATE CODE: A61

Effective date: 20060518

R150 Certificate of patent or registration of utility model

Free format text: JAPANESE INTERMEDIATE CODE: R150

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20090526

Year of fee payment: 3

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20100526

Year of fee payment: 4

LAPS Cancellation because of no payment of annual fees