JP2021530432A - メタセシス反応におけるn−キレート化ルテニウム錯体の使用 - Google Patents

メタセシス反応におけるn−キレート化ルテニウム錯体の使用 Download PDF

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JP2021530432A
JP2021530432A JP2020558468A JP2020558468A JP2021530432A JP 2021530432 A JP2021530432 A JP 2021530432A JP 2020558468 A JP2020558468 A JP 2020558468A JP 2020558468 A JP2020558468 A JP 2020558468A JP 2021530432 A JP2021530432 A JP 2021530432A
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alkyl
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alkoxy
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JP2021530432A5 (enExample
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ラファル ガヴィン
パトリク クライチィ
アンナ ガヴィン
クシシュトフ スコヴェルスキ
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アペイロン シンセシス エス アー
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2265—Carbenes or carbynes, i.e.(image)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2265—Carbenes or carbynes, i.e.(image)
    • B01J31/2269—Heterocyclic carbenes
    • B01J31/2273—Heterocyclic carbenes with only nitrogen as heteroatomic ring members, e.g. 1,3-diarylimidazoline-2-ylidenes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2265—Carbenes or carbynes, i.e.(image)
    • B01J31/2278—Complexes comprising two carbene ligands differing from each other, e.g. Grubbs second generation catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/30—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
    • C07C67/333—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/30—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
    • C07C67/333—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton
    • C07C67/343—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
    • C07C67/347—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by addition to unsaturated carbon-to-carbon bonds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
    • C07F15/0046—Ruthenium compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/50—Redistribution or isomerisation reactions of C-C, C=C or C-C triple bonds
    • B01J2231/54—Metathesis reactions, e.g. olefin metathesis
    • B01J2231/543—Metathesis reactions, e.g. olefin metathesis alkene metathesis
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/821—Ruthenium

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
JP2020558468A 2018-07-12 2019-07-10 メタセシス反応におけるn−キレート化ルテニウム錯体の使用 Pending JP2021530432A (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
PLPL426318 2018-07-12
PL426318A PL426318A1 (pl) 2018-07-12 2018-07-12 Zastosowanie N-chelatujących kompleksów rutenu w reakcji metatezy
PCT/IB2019/055864 WO2020012370A1 (en) 2018-07-12 2019-07-10 Use of n-chelating ruthenium complexes in the metathesis reaction

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JP2021530432A true JP2021530432A (ja) 2021-11-11
JP2021530432A5 JP2021530432A5 (enExample) 2021-12-23

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JP2020558468A Pending JP2021530432A (ja) 2018-07-12 2019-07-10 メタセシス反応におけるn−キレート化ルテニウム錯体の使用

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US (1) US12251688B2 (enExample)
EP (1) EP3820609B1 (enExample)
JP (1) JP2021530432A (enExample)
KR (1) KR20210030938A (enExample)
CA (1) CA3096337A1 (enExample)
PL (2) PL426318A1 (enExample)
WO (1) WO2020012370A1 (enExample)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR102536751B1 (ko) * 2020-04-07 2023-05-24 주식회사 엘지화학 촉매 조성물, 이를 포함하는 세척액 조성물 및 이를 이용한 중합장치의 세척방법
PL246181B1 (pl) * 2020-08-17 2024-12-16 Apeiron Synthesis Spolka Akcyjna Nowe kompleksy rutenu i ich zastosowanie w reakcji krzyżowej metatezy olefin

Citations (9)

* Cited by examiner, † Cited by third party
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JP2011521069A (ja) * 2008-05-22 2011-07-21 リミテッド・ライアビリティ・カンパニー・”ユナイテッド・リサーチ・アンド・デベロップメント・センター” ジシクロペンタジエンのメタセシス重合触媒、その製造方法および重合方法
RU2462308C1 (ru) * 2011-10-04 2012-09-27 Общество с ограниченной ответственностью "Объединенный центр исследований и разработок" Катализатор полимеризации дициклопентадиена и способ его получения
JP2013516392A (ja) * 2009-12-30 2013-05-13 ザンナン・サイテック・カンパニー・リミテッド Rompとrcm反応に対する高効率複分解触媒
WO2015126279A1 (ru) * 2014-02-18 2015-08-27 Открытое акционерное общество "Нефтяная компания "Роснефть" Способ получения микросфер полимерного проппанта из полимерной матрицы на основе метатезис_радикально сшитой смеси олигоциклопентадиенов
JP2015532639A (ja) * 2012-08-16 2015-11-12 アペイロン シンセシス エス エイApeiron Synthesiss.A. 新規金属錯体、特にそのルテニウム錯体、及びその使用方法
RU2577252C1 (ru) * 2015-02-26 2016-03-10 Открытое акционерное общество "Нефтяная компания "Роснефть" Способ получения катализатора метатезисной полимеризации дициклопентадиена
WO2017166578A1 (zh) * 2016-03-29 2017-10-05 上海东杰高分子材料有限公司 钌络合物催化剂
WO2017185324A1 (en) * 2016-04-29 2017-11-02 Xia, Ling Group 8 transition metal catalysts and method for making same and process for use of same in olefin disproportionation reactions
JP2021522207A (ja) * 2018-04-16 2021-08-30 アペイロン シンセシス エス アー 新規ルテニウム錯体及びオレフィンメタセシス反応におけるそれらの使用

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* Cited by examiner, † Cited by third party
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RU2402572C1 (ru) 2009-07-09 2010-10-27 Общество с ограниченной ответственностью "Объединенный центр исследований и разработок" Способ получения полидициклопентадиена и материалов на его основе
CN102596407B (zh) 2009-11-09 2014-09-03 埃克森美孚化学专利公司 复分解催化剂和其应用方法
RU2451692C2 (ru) * 2010-08-13 2012-05-27 Закрытое Акционерное Общество "Сибур Холдинг" Способ очистки полимеризационного оборудования от труднорастворимых отложений высокомолекулярного полимера (варианты)
RU2523321C1 (ru) * 2013-05-15 2014-07-20 Открытое акционерное общество "Нефтяная компания "Роснефть" Материал для проппанта и способ его получения
PL238806B1 (pl) * 2015-09-30 2021-10-04 Apeiron Synthesis Spolka Akcyjna Kompleks rutenu i sposób jego wytwarzania, związek pośredni stosowany w tym sposobie oraz zastosowanie kompleksu rutenu i związku pośredniego w metatezie olefin
PL241085B1 (pl) * 2016-11-10 2022-08-01 Apeiron Synthesis Spolka Akcyjna Zastosowanie kompleksów rutenu w reakcji metatezy olefin
US11291983B2 (en) * 2019-09-18 2022-04-05 Apeiron Synthesis S.A. Organoruthenium carbide complexes as precatalysts for olefin metathesis
PL246181B1 (pl) * 2020-08-17 2024-12-16 Apeiron Synthesis Spolka Akcyjna Nowe kompleksy rutenu i ich zastosowanie w reakcji krzyżowej metatezy olefin

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2011521069A (ja) * 2008-05-22 2011-07-21 リミテッド・ライアビリティ・カンパニー・”ユナイテッド・リサーチ・アンド・デベロップメント・センター” ジシクロペンタジエンのメタセシス重合触媒、その製造方法および重合方法
JP2013516392A (ja) * 2009-12-30 2013-05-13 ザンナン・サイテック・カンパニー・リミテッド Rompとrcm反応に対する高効率複分解触媒
RU2462308C1 (ru) * 2011-10-04 2012-09-27 Общество с ограниченной ответственностью "Объединенный центр исследований и разработок" Катализатор полимеризации дициклопентадиена и способ его получения
JP2015532639A (ja) * 2012-08-16 2015-11-12 アペイロン シンセシス エス エイApeiron Synthesiss.A. 新規金属錯体、特にそのルテニウム錯体、及びその使用方法
WO2015126279A1 (ru) * 2014-02-18 2015-08-27 Открытое акционерное общество "Нефтяная компания "Роснефть" Способ получения микросфер полимерного проппанта из полимерной матрицы на основе метатезис_радикально сшитой смеси олигоциклопентадиенов
RU2577252C1 (ru) * 2015-02-26 2016-03-10 Открытое акционерное общество "Нефтяная компания "Роснефть" Способ получения катализатора метатезисной полимеризации дициклопентадиена
WO2017166578A1 (zh) * 2016-03-29 2017-10-05 上海东杰高分子材料有限公司 钌络合物催化剂
WO2017185324A1 (en) * 2016-04-29 2017-11-02 Xia, Ling Group 8 transition metal catalysts and method for making same and process for use of same in olefin disproportionation reactions
JP2021522207A (ja) * 2018-04-16 2021-08-30 アペイロン シンセシス エス アー 新規ルテニウム錯体及びオレフィンメタセシス反応におけるそれらの使用

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PL426318A1 (pl) 2020-01-13
PL3820609T3 (pl) 2023-10-16
US12251688B2 (en) 2025-03-18
CA3096337A1 (en) 2020-01-16
EP3820609B1 (en) 2023-06-28
US20210237045A1 (en) 2021-08-05
EP3820609A1 (en) 2021-05-19
WO2020012370A1 (en) 2020-01-16
KR20210030938A (ko) 2021-03-18

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