JP2021512987A - 補強ゴム組成物を加硫する方法 - Google Patents
補強ゴム組成物を加硫する方法 Download PDFInfo
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- JP2021512987A JP2021512987A JP2020542853A JP2020542853A JP2021512987A JP 2021512987 A JP2021512987 A JP 2021512987A JP 2020542853 A JP2020542853 A JP 2020542853A JP 2020542853 A JP2020542853 A JP 2020542853A JP 2021512987 A JP2021512987 A JP 2021512987A
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- rubber
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- butylperoxy
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- 239000005060 rubber Substances 0.000 title claims abstract description 96
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- 238000000034 method Methods 0.000 title claims abstract description 29
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- 239000003963 antioxidant agent Substances 0.000 claims abstract description 57
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 claims abstract description 54
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- 230000003078 antioxidant effect Effects 0.000 claims abstract description 35
- 150000001875 compounds Chemical class 0.000 claims abstract description 25
- 238000002156 mixing Methods 0.000 claims abstract description 20
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- 150000002989 phenols Chemical class 0.000 claims abstract description 12
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical group O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 28
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- 238000009472 formulation Methods 0.000 claims description 19
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- 229910052717 sulfur Inorganic materials 0.000 claims description 16
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- HSLFISVKRDQEBY-UHFFFAOYSA-N 1,1-bis(tert-butylperoxy)cyclohexane Chemical compound CC(C)(C)OOC1(OOC(C)(C)C)CCCCC1 HSLFISVKRDQEBY-UHFFFAOYSA-N 0.000 claims description 5
- YKTNISGZEGZHIS-UHFFFAOYSA-N 2-$l^{1}-oxidanyloxy-2-methylpropane Chemical group CC(C)(C)O[O] YKTNISGZEGZHIS-UHFFFAOYSA-N 0.000 claims description 5
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- HXIQYSLFEXIOAV-UHFFFAOYSA-N 2-tert-butyl-4-(5-tert-butyl-4-hydroxy-2-methylphenyl)sulfanyl-5-methylphenol Chemical compound CC1=CC(O)=C(C(C)(C)C)C=C1SC1=CC(C(C)(C)C)=C(O)C=C1C HXIQYSLFEXIOAV-UHFFFAOYSA-N 0.000 claims description 4
- OXGOEZHUKDEEKS-UHFFFAOYSA-N 3-tert-butylperoxy-1,1,5-trimethylcyclohexane Chemical compound CC1CC(OOC(C)(C)C)CC(C)(C)C1 OXGOEZHUKDEEKS-UHFFFAOYSA-N 0.000 claims description 4
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- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 claims description 4
- UTGQNNCQYDRXCH-UHFFFAOYSA-N N,N'-diphenyl-1,4-phenylenediamine Chemical compound C=1C=C(NC=2C=CC=CC=2)C=CC=1NC1=CC=CC=C1 UTGQNNCQYDRXCH-UHFFFAOYSA-N 0.000 claims description 4
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- 238000000465 moulding Methods 0.000 claims description 4
- SSDSCDGVMJFTEQ-UHFFFAOYSA-N octadecyl 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 SSDSCDGVMJFTEQ-UHFFFAOYSA-N 0.000 claims description 4
- 229920001021 polysulfide Polymers 0.000 claims description 4
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- 239000004250 tert-Butylhydroquinone Substances 0.000 claims description 4
- 235000019281 tert-butylhydroquinone Nutrition 0.000 claims description 4
- OUBMGJOQLXMSNT-UHFFFAOYSA-N N-isopropyl-N'-phenyl-p-phenylenediamine Chemical compound C1=CC(NC(C)C)=CC=C1NC1=CC=CC=C1 OUBMGJOQLXMSNT-UHFFFAOYSA-N 0.000 claims description 3
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims description 3
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- 239000004927 clay Substances 0.000 claims description 3
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- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims description 3
- 239000000347 magnesium hydroxide Substances 0.000 claims description 3
- 229910001862 magnesium hydroxide Inorganic materials 0.000 claims description 3
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- DQXBYHZEEUGOBF-UHFFFAOYSA-N but-3-enoic acid;ethene Chemical compound C=C.OC(=O)CC=C DQXBYHZEEUGOBF-UHFFFAOYSA-N 0.000 claims description 2
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- GDOPTJXRTPNYNR-UHFFFAOYSA-N methyl-cyclopentane Natural products CC1CCCC1 GDOPTJXRTPNYNR-UHFFFAOYSA-N 0.000 claims description 2
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- IWDCLRJOBJJRNH-UHFFFAOYSA-N p-cresol Chemical compound CC1=CC=C(O)C=C1 IWDCLRJOBJJRNH-UHFFFAOYSA-N 0.000 claims 2
- WPMYUUITDBHVQZ-UHFFFAOYSA-M 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=CC(CCC([O-])=O)=CC(C(C)(C)C)=C1O WPMYUUITDBHVQZ-UHFFFAOYSA-M 0.000 claims 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 claims 1
- NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 claims 1
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- PVFZKRMYBKEXBN-UHFFFAOYSA-N piperidine;piperidine-1-carbodithioic acid Chemical compound C1CCNCC1.SC(=S)N1CCCCC1 PVFZKRMYBKEXBN-UHFFFAOYSA-N 0.000 description 1
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- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
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- VTHOKNTVYKTUPI-UHFFFAOYSA-N triethoxy-[3-(3-triethoxysilylpropyltetrasulfanyl)propyl]silane Chemical compound CCO[Si](OCC)(OCC)CCCSSSSCCC[Si](OCC)(OCC)OCC VTHOKNTVYKTUPI-UHFFFAOYSA-N 0.000 description 1
- BOXSVZNGTQTENJ-UHFFFAOYSA-L zinc dibutyldithiocarbamate Chemical compound [Zn+2].CCCCN(C([S-])=S)CCCC.CCCCN(C([S-])=S)CCCC BOXSVZNGTQTENJ-UHFFFAOYSA-L 0.000 description 1
- RKQOSDAEEGPRER-UHFFFAOYSA-L zinc diethyldithiocarbamate Chemical compound [Zn+2].CCN(CC)C([S-])=S.CCN(CC)C([S-])=S RKQOSDAEEGPRER-UHFFFAOYSA-L 0.000 description 1
- GOQCSVOOQKFAKT-UHFFFAOYSA-L zinc;n,n-bis(2-methylpropyl)carbamodithioate Chemical compound [Zn+2].CC(C)CN(C([S-])=S)CC(C)C.CC(C)CN(C([S-])=S)CC(C)C GOQCSVOOQKFAKT-UHFFFAOYSA-L 0.000 description 1
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- JGSUMMPGKPITGK-UHFFFAOYSA-L zinc;n,n-dipentylcarbamodithioate Chemical compound [Zn+2].CCCCCN(C([S-])=S)CCCCC.CCCCCN(C([S-])=S)CCCCC JGSUMMPGKPITGK-UHFFFAOYSA-L 0.000 description 1
- DUBNHZYBDBBJHD-UHFFFAOYSA-L ziram Chemical compound [Zn+2].CN(C)C([S-])=S.CN(C)C([S-])=S DUBNHZYBDBBJHD-UHFFFAOYSA-L 0.000 description 1
Classifications
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/12—Adsorbed ingredients, e.g. ingredients on carriers
-
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/20—Compounding polymers with additives, e.g. colouring
-
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/01—Use of inorganic substances as compounding ingredients characterized by their specific function
- C08K3/011—Crosslinking or vulcanising agents, e.g. accelerators
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/01—Use of inorganic substances as compounding ingredients characterized by their specific function
- C08K3/013—Fillers, pigments or reinforcing additives
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- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/04—Carbon
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- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/06—Sulfur
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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- C08K5/00—Use of organic ingredients
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- C08K5/0025—Crosslinking or vulcanising agents; including accelerators
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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Abstract
Description
(i)ゴムと、
(ii)少なくとも1つの無機充填剤と、
(iii)少なくとも1つの有機過酸化物と、
(iv)フェノール類、パラフェニリデンジアミン、および窒素酸化物から選択される少なくとも1つの酸化防止剤と
を混合するステップを含む、方法に関する。
(a)上記の補強ゴム組成物、および
(b)硬化パッケージ
を含む混合物を調製するステップと、
前記混合物を成形し、加熱して加硫を引き起こすステップと
を含む、方法に関する。
天然ゴムを、トレッドゴム組成物の従来の成分であるカーボンブラック、プロセス油、オゾン劣化防止剤、および安定剤と予備配合した。詳細を表1に示す。
1,1−ジ(tert−ブチルペルオキシ)シクロヘキサン−Trigonox(登録商標)22−C50
1,1−ジ(tert−ブチルペルオキシ)−3,3,5−トリメチルシクロヘキサン−Trigonox(登録商標)29−E90
tert−ブチルペルオキシ−2−エチルヘキサノエート−Trigonox(登録商標)21S
tert−ブチル−ペルオキシ−3,5,5−トリメチルヘキサノエート−Trigonox(登録商標)42S
2,2−ジ(tert−ブチルペルオキシ)ブタン−Trigonox(登録商標)D
1,1−ビス(tert−ブチルペルオキシ)−2−イソプロピル−5−メチルシクロヘキサン
実施例1の手順に従って、表9のゴム組成物を調製した。
表10に示すように、異なる酸化防止剤を使用して実施例2を繰り返した。
表11に示すように、酸化防止剤の組合せを使用して、実施例3を繰り返した。
エマルションスチレン−ブタジエンゴム(e−SBR)を、120℃で3分間、成分を密閉式ミキサーで混合することにより、シリカおよび伸展油と予備配合した。詳細を表12に示す。
Claims (16)
- 補強ゴム組成物の調製方法であって、少なくとも120℃の温度で、少なくとも以下の化合物、
(i)ゴムと、
(ii)少なくとも1つ無機充填剤と、
(iii)少なくとも1つの有機過酸化物と、
(iv)フェノール類、パラフェニリデンジアミン、および窒素酸化物から選択される少なくとも1つの酸化防止剤と
を混合するステップを含む、方法。 - 補強ゴム組成物を加硫する方法であって、
(a)少なくとも120℃の温度で、少なくとも以下の化合物、
(i)ゴム、
(ii)少なくとも1つの無機充填剤、
(iii)少なくとも1つの有機過酸化物、ならびに
(iv)フェノール類、パラフェニリデンジアミン、および窒素酸化物から選択される少なくとも1つの酸化防止剤
を混合することにより得られた補強ゴム組成物、ならびに
(b)硬化パッケージ
を含む混合物を調製するステップと、
前記混合物を成形し、加熱して加硫を引き起こすステップと
を含む、方法。 - 前記ゴムが、エチレンプロピレンジエンターポリマーエラストマー(EPDM)、エチレン−プロピレンコポリマーエラストマー(EPM)、エチレン−ビニルアセテート(EVAおよびEVM)、天然ゴム(NR)、ブチルゴム(BR)、イソプレンゴム(IR)、ブロモブチルゴム(BIIR)、スチレン−ブタジエンゴム(e−SBRおよびs−SBRを含む)、ポリスルフィド(T)、ブチルゴム(IIR)、ニトリルゴム(NBR)、および水素化ニトリルゴム(HNBR)から選択される、請求項1または2に記載の方法。
- 前記少なくとも1つの無機充填剤が、シリカ、カーボンブラック、炭酸カルシウム、粘土、チョーク、タルク、水酸化アルミニウム、水酸化マグネシウム、およびそれらの組合せからなる群から選択され、好ましくは、シリカ、カーボンブラック、およびそれらの組合せから選択される、請求項1〜3のいずれか1項に記載の方法。
- 前記少なくとも1つの有機過酸化物が、ペルオキシケタールおよびペルオキシエステルからなる群から選択され、より好ましくはペルオキシケタールであり、最も好ましくは、1,1−ジ(tert−ブチルペルオキシ)シクロヘキサン、1−ジ(tert−ブチルペルオキシ)−3,3,5−トリメチルシクロヘキサン、2,2−ジ(tert−ブチルペルオキシ)ブタン、および1,1−ビス(tert−ブチルペルオキシ)−2−イソプロピル−5−メチルシクロヘキサンからなる群から選択される、請求項1〜4のいずれか1項に記載の方法。
- 前記少なくとも1つの有機過酸化物および任意の前記少なくとも1つの酸化防止剤が、5〜45重量%の固体無機担体上または10〜50重量%のゴム中のいずれかに分散される、10〜50重量%の有機過酸化物と0〜50重量%の酸化防止剤とを含む、固体配合物の形態で、前記ゴムおよび前記少なくとも1つの無機充填剤に添加される、請求項1〜5のいずれか1項に記載の方法。
- 前記少なくとも1つの有機過酸化物および前記少なくとも1つの酸化防止剤が、10〜50重量%の有機過酸化物と5〜45重量%の酸化防止剤と0〜50重量%の溶媒とを含む液体配合物の形態で、前記ゴムおよび前記少なくとも1つの無機充填剤に添加される、請求項1から6のいずれか一項に記載の方法。
- 少なくとも1つの酸化防止剤が、フェノール系酸化防止剤であり、好ましくはtert−ブチルヒドロキノン(TBHQ)、ブチル化ヒドロキシトルエン(BHT)、ポリ(ジシクロペンタジエン−co−p−クレゾール)、ペンタエリスリトールテトラキス(3−(3,5−ジ−tert−ブチル−4−ヒドロキシフェニル)プロピオネート)、オクタデシル−3−(3,5−ジ−tert−ブチル−4−ヒドロキシフェニル)−プロピオネート、ビス−(2−ヒドロキシ−3−tert−ブチル−5−メチルフェニル)メタン、4,4’−チオ−ビス(6−tert−ブチル−m−メチルフェノール)、および2,2’−チオビス(6−tert−ブチル−4−メチルフェノール)からなる群から選択される、請求項1〜7のいずれか1項に記載の方法。
- 少なくとも1つの酸化防止剤が、パラフェニリデンジアミンであり、好ましくはN−1,3−ジメチルブチル−N’−フェニル−p−フェニレンジアミン、N−イソプロピル−N’−フェニル−p−フェニレンジアミン、およびN,N’−ジフェニル−p−フェニレンジアミンからなる群から選択される、請求項1〜8のいずれか1項に記載の方法。
- 少なくとも1つの酸化防止剤が、窒素酸化物であり、好ましくは2,2,6,6−テトラメチル−1−ピペリジニルオキシフリーラジカル(TEMPO)、2,2,6,6−テトラメチル−4−ヒドロキシ−1−ピペリジニルオキシフリーラジカル(OH−TEMPO)、4−カルボキシ−2,2,6,6−テトラメチル−1−ピペリジニルオキシフリーラジカル(4−カルボキシ−)、2,2,6,6−テトラメチル−4−アミノ−1−ピペリジニルオキシフリーラジカル(4−アミノ−TEMPO)、および2,2,6,6−テトラメチル−4−オキソピペリジノオキシフリーラジカル(4−オキソ−TEMPO)からなる群から選択される、請求項1〜9のいずれか1項に記載の方法。
- 前記硬化パッケージが、元素状硫黄および1以上の硫黄硬化促進剤および/または硫黄供与体を含む、請求項1〜10のいずれか1項に記載の方法。
- 5〜45重量%の少なくとも1つの固体無機担体上に分散される、10〜50重量%の少なくとも1つの有機過酸化物と、5〜50重量%のフェノール類、パラフェニリデンジアミン、および窒素酸化物から選択される少なくとも1つの酸化防止剤とを含む、固体配合物。
- 10〜50重量%のゴム中に分散される、10〜50重量%の少なくとも1つの有機過酸化物と、0〜50重量%の少なくとも1つの無機担体と、5〜50重量%のフェノール類、パラフェニリデンジアミン、および窒素酸化物から選択される少なくとも1つの酸化防止剤とを含む、固体配合物。
- 10〜50重量%の少なくとも1つの有機過酸化物と、フェノール類、パラフェニリデンジアミン、および窒素酸化物から選択される5〜50重量%の少なくとも1つの酸化防止剤と、0〜50重量%の溶媒とを含む、液体配合物。
- 20〜90重量%のカーボンブラック上に分散される、10〜80重量%の1,1−ジ(tert−ブチルペルオキシ)シクロヘキサン、1−ジ(tert−ブチルペルオキシ)−3,3,5−トリメチルシクロヘキサン、2,2−ジ(tert−ブチルペルオキシ)ブタン、および1,1−ビス(tert−ブチルペルオキシ)−2−イソプロピル−5−メチルシクロヘキサンからなる群から選択される少なくとも1つの有機過酸化物を含む、固体配合物。
- 前記少なくとも1つの有機過酸化物が、ペルオキシケタールおよびペルオキシエステルからなる群から選択され、より好ましくはペルオキシケタールであり、最も好ましくは、1,1−ジ(tert−ブチルペルオキシ)シクロヘキサン、1−ジ(tert−ブチルペルオキシ)−3,3,5−トリメチルシクロヘキサン、2,2−ジ(tert−ブチルペルオキシ)ブタン、および1,1−ビス(tert−ブチルペルオキシ)−2−イソプロピル−5−メチルシクロヘキサンからなる群から選択される、請求項12〜14のいずれか1項に記載の配合物。
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Citations (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS4817456B1 (ja) * | 1968-03-11 | 1973-05-29 | ||
US4631304A (en) * | 1983-07-29 | 1986-12-23 | Phillips Petroleum Company | Novel carbon black and process for preparing same |
JPH04311746A (ja) * | 1991-04-09 | 1992-11-04 | Mitsubishi Cable Ind Ltd | 電力ケーブル用剥離性半導電性組成物 |
US5245084A (en) * | 1988-06-14 | 1993-09-14 | Luperox Gmbh | Mixture suited for crosslinking polymers and process for crosslinking polymers with extension of scorch time |
JP2003519270A (ja) * | 1999-12-30 | 2003-06-17 | ソシエテ ド テクノロジー ミシュラン | 熱誘発性ラジカル開始剤によって活性化されるカップリング剤(白色充填剤/ジエンエラストマー)を含むタイヤ用ゴム組成物 |
JP2007137927A (ja) * | 2005-11-15 | 2007-06-07 | Nok Corp | 有機過酸化物マスターバッチ |
JP2011148895A (ja) * | 2010-01-21 | 2011-08-04 | Yokohama Rubber Co Ltd:The | 変性粉砕加硫ゴムの製造法 |
WO2012023607A1 (ja) * | 2010-08-20 | 2012-02-23 | 横浜ゴム株式会社 | ゴム組成物および空気入りタイヤ |
JP2014159505A (ja) * | 2013-02-19 | 2014-09-04 | Nippon Valqua Ind Ltd | シール材用ゴム組成物及びこれを用いたシール材 |
JP2014534991A (ja) * | 2011-10-24 | 2014-12-25 | アルケマ フランス | 電気ケーブル絶縁層製造用マスターバッチ |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4332918A (en) * | 1980-06-30 | 1982-06-01 | Bridgestone Tire Co., Ltd. | Nitrile rubber composition having high modulus |
CN1071937A (zh) | 1991-10-29 | 1993-05-12 | 阿克佐公司 | 轮胎和胶带组合物 |
US6943220B2 (en) * | 2001-03-26 | 2005-09-13 | Mitsui Chemicals, Inc. | Rubber compositions and their uses |
CN102218879B (zh) * | 2010-04-18 | 2013-06-26 | 黎明 | 一种废旧聚丙烯改性发泡板材及其制造方法 |
KR102511659B1 (ko) * | 2014-12-09 | 2023-03-20 | 알케마 인코포레이티드 | 액체 등급 및 용융성 고체 등급의 스코치 보호 과산화물 |
WO2016160781A1 (en) * | 2015-03-30 | 2016-10-06 | Kraton Polymers U.S. Llc | Diene rubber composition configured to be vulcanized at lower temperature; and manufacturing process of rubber article |
AR104219A1 (es) | 2015-04-23 | 2017-07-05 | Akzo Nobel Chemicals Int Bv | Composición de caucho entrecruzable, neumático que la comprende y proceso para entrecruzar una composición de caucho |
US20180134864A1 (en) * | 2015-04-23 | 2018-05-17 | Akzo Nobel Chemicals International B.V. | Crosslinkable rubber composition |
CN106674632B (zh) * | 2016-12-22 | 2018-10-12 | 江苏通用科技股份有限公司 | 胎面胶及其制备方法 |
-
2019
- 2019-02-01 TW TW108104088A patent/TW201936749A/zh unknown
- 2019-02-06 EP EP19702296.5A patent/EP3749709A1/en active Pending
- 2019-02-06 JP JP2020542853A patent/JP2021512987A/ja active Pending
- 2019-02-06 WO PCT/EP2019/052842 patent/WO2019154825A1/en unknown
- 2019-02-06 US US16/968,302 patent/US11505677B2/en active Active
- 2019-02-06 KR KR1020207024801A patent/KR20200120919A/ko not_active Application Discontinuation
- 2019-02-06 CN CN201980010290.9A patent/CN111655773B/zh active Active
-
2022
- 2022-10-17 US US18/046,998 patent/US20230084880A1/en active Pending
-
2023
- 2023-10-25 JP JP2023182893A patent/JP2024020234A/ja active Pending
Patent Citations (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS4817456B1 (ja) * | 1968-03-11 | 1973-05-29 | ||
US4631304A (en) * | 1983-07-29 | 1986-12-23 | Phillips Petroleum Company | Novel carbon black and process for preparing same |
US5245084A (en) * | 1988-06-14 | 1993-09-14 | Luperox Gmbh | Mixture suited for crosslinking polymers and process for crosslinking polymers with extension of scorch time |
JPH04311746A (ja) * | 1991-04-09 | 1992-11-04 | Mitsubishi Cable Ind Ltd | 電力ケーブル用剥離性半導電性組成物 |
JP2003519270A (ja) * | 1999-12-30 | 2003-06-17 | ソシエテ ド テクノロジー ミシュラン | 熱誘発性ラジカル開始剤によって活性化されるカップリング剤(白色充填剤/ジエンエラストマー)を含むタイヤ用ゴム組成物 |
JP2007137927A (ja) * | 2005-11-15 | 2007-06-07 | Nok Corp | 有機過酸化物マスターバッチ |
JP2011148895A (ja) * | 2010-01-21 | 2011-08-04 | Yokohama Rubber Co Ltd:The | 変性粉砕加硫ゴムの製造法 |
WO2012023607A1 (ja) * | 2010-08-20 | 2012-02-23 | 横浜ゴム株式会社 | ゴム組成物および空気入りタイヤ |
JP2014534991A (ja) * | 2011-10-24 | 2014-12-25 | アルケマ フランス | 電気ケーブル絶縁層製造用マスターバッチ |
JP2014159505A (ja) * | 2013-02-19 | 2014-09-04 | Nippon Valqua Ind Ltd | シール材用ゴム組成物及びこれを用いたシール材 |
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