JP2018527702A - 黒鉛修飾リチウム金属電極 - Google Patents

黒鉛修飾リチウム金属電極 Download PDF

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Publication number
JP2018527702A
JP2018527702A JP2018504159A JP2018504159A JP2018527702A JP 2018527702 A JP2018527702 A JP 2018527702A JP 2018504159 A JP2018504159 A JP 2018504159A JP 2018504159 A JP2018504159 A JP 2018504159A JP 2018527702 A JP2018527702 A JP 2018527702A
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Prior art keywords
lithium metal
surface layer
lithium
graphite
metal electrode
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Pending
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JP2018504159A
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Japanese (ja)
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JP2018527702A5 (enExample
Inventor
ラリー ジェイ． クラウス，
ラリー ジェイ． クラウス，
ローウェル ディー． ジェンセン，
ローウェル ディー． ジェンセン，
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3M Innovative Properties Co
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3M Innovative Properties Co
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Publication of JP2018527702A publication Critical patent/JP2018527702A/ja
Publication of JP2018527702A5 publication Critical patent/JP2018527702A5/ja
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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/058—Construction or manufacture
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/42—Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
    • H01M10/4235—Safety or regulating additives or arrangements in electrodes, separators or electrolyte
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M12/00—Hybrid cells; Manufacture thereof
    • H01M12/08—Hybrid cells; Manufacture thereof composed of a half-cell of a fuel-cell type and a half-cell of the secondary-cell type
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/131—Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/136—Electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/139—Processes of manufacture
    • H01M4/1393—Processes of manufacture of electrodes based on carbonaceous material, e.g. graphite-intercalation compounds or CFx
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/362—Composites
    • H01M4/366—Composites as layered products
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
    • H01M4/381—Alkaline or alkaline earth metals elements
    • H01M4/382—Lithium
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/50—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
    • H01M4/505—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/52—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
    • H01M4/525—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/5825—Oxygenated metallic salts or polyanionic structures, e.g. borates, phosphates, silicates, olivines
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/583—Carbonaceous material, e.g. graphite-intercalation compounds or CFx
    • H01M4/587—Carbonaceous material, e.g. graphite-intercalation compounds or CFx for inserting or intercalating light metals
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50—Manufacturing or production processes characterised by the final manufactured product

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  • Chemical & Material Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Composite Materials (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Hybrid Cells (AREA)
  • Secondary Cells (AREA)
JP2018504159A 2015-07-27 2016-07-21 黒鉛修飾リチウム金属電極 Pending JP2018527702A (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201562197203P 2015-07-27 2015-07-27
US62/197,203 2015-07-27
PCT/US2016/043291 WO2017019436A1 (en) 2015-07-27 2016-07-21 Graphite modified lithium metal electrode

Publications (2)

Publication Number Publication Date
JP2018527702A true JP2018527702A (ja) 2018-09-20
JP2018527702A5 JP2018527702A5 (enExample) 2019-08-29

Family

ID=57885257

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2018504159A Pending JP2018527702A (ja) 2015-07-27 2016-07-21 黒鉛修飾リチウム金属電極

Country Status (6)

Country Link
US (1) US20180212270A1 (enExample)
EP (1) EP3329538A4 (enExample)
JP (1) JP2018527702A (enExample)
KR (1) KR20180026460A (enExample)
CN (1) CN107851835A (enExample)
WO (1) WO2017019436A1 (enExample)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11063248B2 (en) * 2018-05-24 2021-07-13 GM Global Technology Operations LLC Protective coating for lithium-containing electrode and methods of making the same
DE102018128451A1 (de) * 2018-11-13 2020-05-14 Bayerische Motoren Werke Aktiengesellschaft Kalorimetrisches Verfahren zur quantitativen Bestimmung von auf einer Anode einer Lithium-Ionen-Zelle abgeschiedenem metallischen Lithium
CN111430663A (zh) * 2019-11-28 2020-07-17 蜂巢能源科技有限公司 锂负极极片及其制备方法和锂电池
TWI722747B (zh) 2019-12-18 2021-03-21 財團法人工業技術研究院 電池
US20210351411A1 (en) * 2020-05-06 2021-11-11 Samsung Electronics Co., Ltd. Secondary battery and method of preparing the same
CN114388746B (zh) * 2020-10-21 2024-01-23 安徽盟维新能源科技有限公司 锂金属负极、锂金属电池及其制备方法与抑制锂枝晶方法

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH04248276A (ja) * 1991-01-25 1992-09-03 Matsushita Electric Ind Co Ltd リチウム二次電池
JPH0636759A (ja) * 1992-07-17 1994-02-10 Mitsubishi Cable Ind Ltd リチウム二次電池
US5387479A (en) * 1993-06-16 1995-02-07 Valence Technology, Inc. Electrodes for rechargeable lithium batteries
JPH11135116A (ja) * 1997-10-27 1999-05-21 Fuji Elelctrochem Co Ltd リチウム二次電池用負極及びその負極を用いたリチウム二次電池、並びにそのリチウム二次電池用負極の製造方法
JP2002516643A (ja) * 1994-09-29 2002-06-04 三菱化学株式会社 電解質電池と電解プロセスのための微粒子境界面
KR20130067920A (ko) * 2011-12-14 2013-06-25 한국전자통신연구원 탄소 분말을 리튬 표면에 코팅한 음극을 적용한 리튬 이차 전지

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5720780A (en) 1996-11-04 1998-02-24 Valence Technology, Inc. Film forming method for lithium ion rechargeable batteries
US6537701B1 (en) * 1998-09-03 2003-03-25 Polyplus Battery Company, Inc. Coated lithium electrodes
US6589299B2 (en) 2001-02-13 2003-07-08 3M Innovative Properties Company Method for making electrode
JP2003045415A (ja) * 2001-07-31 2003-02-14 Nec Corp 二次電池用負極
US7326497B2 (en) * 2001-12-21 2008-02-05 Samsung Sdi Co., Ltd. Graphite-containing composition, negative electrode for a lithium secondary battery, and lithium secondary battery
JP4150516B2 (ja) * 2001-12-21 2008-09-17 三星エスディアイ株式会社 リチウム二次電池の負極用の黒鉛含有組成物の製造方法並びにリチウム二次電池用の負極の製造方法及びリチウム二次電池の製造方法
US6939383B2 (en) 2002-05-03 2005-09-06 3M Innovative Properties Company Method for making electrode
US7348102B2 (en) * 2004-03-16 2008-03-25 Toyota Motor Corporation Corrosion protection using carbon coated electron collector for lithium-ion battery with molten salt electrolyte
JP5167914B2 (ja) 2008-04-09 2013-03-21 トヨタ自動車株式会社 固体リチウム二次電池の製造方法
US8178241B2 (en) * 2008-08-28 2012-05-15 3M Innovative Properties Company Electrode including current collector with nano-scale coating and method of making the same
CN103222090B (zh) * 2010-11-17 2016-06-08 3M创新有限公司 包括具有导电涂层的集电器的电化学导电制品及其制备方法
CN104025343A (zh) 2011-12-16 2014-09-03 3M创新有限公司 用于制造电极的方法

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH04248276A (ja) * 1991-01-25 1992-09-03 Matsushita Electric Ind Co Ltd リチウム二次電池
JPH0636759A (ja) * 1992-07-17 1994-02-10 Mitsubishi Cable Ind Ltd リチウム二次電池
US5387479A (en) * 1993-06-16 1995-02-07 Valence Technology, Inc. Electrodes for rechargeable lithium batteries
JP2002516643A (ja) * 1994-09-29 2002-06-04 三菱化学株式会社 電解質電池と電解プロセスのための微粒子境界面
JPH11135116A (ja) * 1997-10-27 1999-05-21 Fuji Elelctrochem Co Ltd リチウム二次電池用負極及びその負極を用いたリチウム二次電池、並びにそのリチウム二次電池用負極の製造方法
KR20130067920A (ko) * 2011-12-14 2013-06-25 한국전자통신연구원 탄소 분말을 리튬 표면에 코팅한 음극을 적용한 리튬 이차 전지

Also Published As

Publication number Publication date
KR20180026460A (ko) 2018-03-12
EP3329538A1 (en) 2018-06-06
EP3329538A4 (en) 2019-01-23
CN107851835A (zh) 2018-03-27
US20180212270A1 (en) 2018-07-26
WO2017019436A1 (en) 2017-02-02

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