JP2017537918A5 - - Google Patents
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- Publication number
- JP2017537918A5 JP2017537918A5 JP2017529301A JP2017529301A JP2017537918A5 JP 2017537918 A5 JP2017537918 A5 JP 2017537918A5 JP 2017529301 A JP2017529301 A JP 2017529301A JP 2017529301 A JP2017529301 A JP 2017529301A JP 2017537918 A5 JP2017537918 A5 JP 2017537918A5
- Authority
- JP
- Japan
- Prior art keywords
- vaporizer
- stream
- products
- reaction fluid
- catalyst
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000006200 vaporizer Substances 0.000 claims description 53
- 238000000034 method Methods 0.000 claims description 37
- 239000003054 catalyst Substances 0.000 claims description 35
- 239000000047 product Substances 0.000 claims description 30
- 239000003446 ligand Substances 0.000 claims description 29
- 238000007037 hydroformylation reaction Methods 0.000 claims description 27
- 239000000376 reactant Substances 0.000 claims description 22
- 239000006227 byproduct Substances 0.000 claims description 21
- 238000006243 chemical reaction Methods 0.000 claims description 21
- 239000012530 fluid Substances 0.000 claims description 18
- 229910052739 hydrogen Inorganic materials 0.000 claims description 17
- 150000001336 alkenes Chemical class 0.000 claims description 16
- 239000007788 liquid Substances 0.000 claims description 16
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 14
- 230000007704 transition Effects 0.000 claims description 14
- 229910002091 carbon monoxide Inorganic materials 0.000 claims description 13
- 125000002485 formyl group Chemical class [H]C(*)=O 0.000 claims description 10
- 150000008301 phosphite esters Chemical class 0.000 claims description 7
- 229910052703 rhodium Inorganic materials 0.000 claims description 4
- 239000010948 rhodium Substances 0.000 claims description 4
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 claims description 4
- 230000003134 recirculating effect Effects 0.000 claims description 3
- 239000000126 substance Substances 0.000 claims 1
- 239000002699 waste material Substances 0.000 claims 1
- 239000007789 gas Substances 0.000 description 43
- 239000001257 hydrogen Substances 0.000 description 15
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 11
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 10
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 8
- 150000002431 hydrogen Chemical class 0.000 description 8
- 229910052757 nitrogen Inorganic materials 0.000 description 5
- 239000000463 material Substances 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- 150000001335 aliphatic alkanes Chemical class 0.000 description 2
- 239000012043 crude product Substances 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 238000004064 recycling Methods 0.000 description 2
- 229910052723 transition metal Inorganic materials 0.000 description 2
- -1 transition metal organophosphite Chemical class 0.000 description 2
- 238000009825 accumulation Methods 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 230000008034 disappearance Effects 0.000 description 1
- 238000011143 downstream manufacturing Methods 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 239000012263 liquid product Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201462087572P | 2014-12-04 | 2014-12-04 | |
| US62/087,572 | 2014-12-04 | ||
| PCT/US2015/061332 WO2016089602A1 (en) | 2014-12-04 | 2015-11-18 | Hydroformylation process |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2020160278A Division JP2021008477A (ja) | 2014-12-04 | 2020-09-25 | ヒドロホルミル化プロセス |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2017537918A JP2017537918A (ja) | 2017-12-21 |
| JP2017537918A5 true JP2017537918A5 (enExample) | 2020-02-20 |
| JP7128622B2 JP7128622B2 (ja) | 2022-08-31 |
Family
ID=54705909
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2017529301A Active JP7128622B2 (ja) | 2014-12-04 | 2015-11-18 | ヒドロホルミル化プロセス |
| JP2020160278A Pending JP2021008477A (ja) | 2014-12-04 | 2020-09-25 | ヒドロホルミル化プロセス |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2020160278A Pending JP2021008477A (ja) | 2014-12-04 | 2020-09-25 | ヒドロホルミル化プロセス |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US10023516B2 (enExample) |
| EP (1) | EP3230248B1 (enExample) |
| JP (2) | JP7128622B2 (enExample) |
| KR (1) | KR102507703B1 (enExample) |
| CN (1) | CN107001218B (enExample) |
| BR (1) | BR112017011447B1 (enExample) |
| CA (1) | CA2969527C (enExample) |
| MX (1) | MX381950B (enExample) |
| MY (1) | MY184826A (enExample) |
| PL (1) | PL3230248T3 (enExample) |
| RU (1) | RU2699368C2 (enExample) |
| TW (1) | TWI586644B (enExample) |
| WO (1) | WO2016089602A1 (enExample) |
Families Citing this family (39)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| PL3374340T3 (pl) | 2015-11-10 | 2022-04-11 | Dow Technology Investments Llc | Sposób wytwarzania aldehydów |
| RU2751511C9 (ru) | 2016-02-11 | 2021-08-18 | Дау Текнолоджи Инвестментс Ллк | Способы превращения олефинов в спирты, простые эфиры или их комбинации |
| CN107469860B (zh) * | 2017-08-22 | 2020-05-19 | 中国海洋石油集团有限公司 | 一种提高铑/双亚膦酸酯催化剂稳定性的方法 |
| TWI793216B (zh) | 2017-12-07 | 2023-02-21 | 美商陶氏科技投資公司 | 氫甲醯化方法 |
| MY203235A (en) * | 2018-11-29 | 2024-06-19 | Dow Technology Investments Llc | Hydroformylation process |
| GB201907659D0 (en) | 2019-05-30 | 2019-07-17 | Johnson Matthey Davy Technologies Ltd | Process |
| WO2021247177A1 (en) | 2020-06-05 | 2021-12-09 | SCION Holdings LLC | Alcohols production |
| EP4161696A4 (en) * | 2020-06-05 | 2025-05-28 | Scion Holdings LLC | BRANCHED ALCOHOLS |
| WO2021247516A1 (en) | 2020-06-05 | 2021-12-09 | SCION Holdings LLC | Branched alcohols |
| US12221404B2 (en) | 2020-06-05 | 2025-02-11 | SCION Holdings LLC | Composition comprising branched aldehydes |
| ES2974422T3 (es) * | 2020-07-30 | 2024-06-27 | Evonik Oxeno Gmbh & Co Kg | Procedimiento para la preparación de aldehídos y separación del sistema catalítico mediante separación por membrana |
| GB202012930D0 (en) * | 2020-08-19 | 2020-09-30 | Johnson Matthey Davy Technologies Ltd | Process for hydroformylation with removal of dissolved hydrogen |
| CN116261565A (zh) | 2020-10-13 | 2023-06-13 | 美国陶氏有机硅公司 | 具有醛官能团的有机硅化合物的制备 |
| CN112403401B (zh) * | 2020-11-06 | 2022-06-21 | 中国海洋石油集团有限公司 | 一种烯烃氢甲酰化制醛中醛和催化剂分离的装置和方法 |
| WO2022132372A1 (en) * | 2020-12-14 | 2022-06-23 | Dow Technology Investments Llc | Processes to improve catalytic metal accountability in hydroformylation processes |
| US12145904B2 (en) | 2020-12-17 | 2024-11-19 | SCION Holdings LLC | Branched products |
| CN118019747A (zh) | 2021-10-06 | 2024-05-10 | 陶氏环球技术有限责任公司 | 丙基亚胺官能化有机硅化合物和伯氨基丙基官能化有机硅化合物的制备 |
| KR20240074844A (ko) | 2021-10-06 | 2024-05-28 | 다우 글로벌 테크놀로지스 엘엘씨 | 프로필이민-작용성 유기규소 화합물 및 1차 아미노프로필-작용성 유기규소 화합물의 제조 |
| JP2024536162A (ja) | 2021-10-06 | 2024-10-04 | ダウ グローバル テクノロジーズ エルエルシー | イミン官能性有機ケイ素化合物及び一級アミノ官能性有機ケイ素化合物の調製 |
| WO2023086718A1 (en) | 2021-11-11 | 2023-05-19 | Dow Technology Investments Llc | Processes for recovering rhodium from hydroformylation processes |
| EP4437031A2 (en) | 2021-11-22 | 2024-10-02 | Dow Global Technologies LLC | Preparation of organosilicon compounds with carbinol functionality |
| CN118338965A (zh) | 2021-12-16 | 2024-07-12 | 陶氏技术投资有限责任公司 | 包含此类化合物的过渡金属络合物加氢甲酰化催化剂前体组合物和加氢甲酰化方法 |
| EP4448170B1 (en) | 2021-12-16 | 2025-08-20 | Dow Technology Investments LLC | Compounds, transition metal complex hydroformylation catalyst precuror compositions comprising such compounds, and hydroformylation processes |
| EP4496833A1 (en) | 2022-03-21 | 2025-01-29 | Dow Global Technologies LLC | Preparation of organosilicon compounds with carboxy functionality |
| EP4508106A1 (en) | 2022-04-13 | 2025-02-19 | Dow Global Technologies LLC | Silicone - vinylester functional compounds and methods for their preparation and use in personal care compositions |
| KR20250003565A (ko) | 2022-04-13 | 2025-01-07 | 다우 실리콘즈 코포레이션 | 조성물, 우레탄 프리폴리머, 및 관련 방법 및 용도 |
| US20250145647A1 (en) | 2022-04-13 | 2025-05-08 | Dow Silicones Corporation | Preparation of organosilicon compounds with vinylester functionality |
| CN118843652A (zh) | 2022-04-13 | 2024-10-25 | 陶氏环球技术有限责任公司 | 制备聚醚官能有机硅化合物 |
| CN114773172B (zh) * | 2022-06-20 | 2022-10-18 | 中海油天津化工研究设计院有限公司 | 一种烯烃氢甲酰化制醛工艺优化方法 |
| GB202213997D0 (en) | 2022-09-26 | 2022-11-09 | Johnson Matthey Davy Technologies Ltd | Parallel zone hydroformylation reaction |
| WO2024123510A1 (en) | 2022-12-06 | 2024-06-13 | Dow Technology Investments Llc | Process of controlling heavies in a recycle catalyst stream |
| GB202303617D0 (en) | 2023-03-13 | 2023-04-26 | Johnson Matthey Davy Technologies Ltd | Method and apparatus for producing aldehyde |
| WO2025029369A1 (en) | 2023-08-03 | 2025-02-06 | Dow Technology Investments Llc | Process for improving rhodium/phosphite- based homogenous hydroformylation catalyst activity |
| WO2025029349A1 (en) | 2023-08-03 | 2025-02-06 | Dow Technology Investments Llc | Hydroformylation process |
| WO2025038266A1 (en) | 2023-08-14 | 2025-02-20 | Dow Global Technologies Llc | Cobalt catalyzed hydroformylation of vinyl-functional polyorganosiloxanes |
| WO2025170897A1 (en) * | 2024-02-06 | 2025-08-14 | Eastman Chemical Company | Optimized gas-stripping hydroformylation process for oxo aldehydes |
| WO2025170887A1 (en) * | 2024-02-06 | 2025-08-14 | Eastman Chemical Company | Gas distribution in gas-stripping hydroformylation reactor for oxo aldehydes |
| WO2025170886A1 (en) * | 2024-02-06 | 2025-08-14 | Eastman Chemical Company | Purge for a gas-stripping hydroformylation reactor for oxo aldehydes |
| WO2025170891A1 (en) * | 2024-02-06 | 2025-08-14 | Eastman Chemical Company | Composition of matter for gas-stripping oxo aldehydes hydroformylation process |
Family Cites Families (50)
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|---|---|---|---|---|
| US3415906A (en) | 1964-05-29 | 1968-12-10 | Hooker Chemical Corp | Phosphite phospholane and phosphorinane compounds |
| US3527809A (en) | 1967-08-03 | 1970-09-08 | Union Carbide Corp | Hydroformylation process |
| US4148830A (en) | 1975-03-07 | 1979-04-10 | Union Carbide Corporation | Hydroformylation of olefins |
| DE2646792C2 (de) | 1975-10-23 | 1985-05-09 | Mitsubishi Petrochemical Co., Ltd., Tokio/Tokyo | Verfahren zur Herstellung einer α-(arylsubstituierten)-Propionsäure und/oder eines Esters derselben |
| US4247486A (en) | 1977-03-11 | 1981-01-27 | Union Carbide Corporation | Cyclic hydroformylation process |
| US4518809A (en) | 1981-06-11 | 1985-05-21 | Monsanto Company | Preparation of pentyl nonanols |
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| GB8334359D0 (en) | 1983-12-23 | 1984-02-01 | Davy Mckee Ltd | Process |
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| US5110990A (en) | 1984-03-30 | 1992-05-05 | Union Carbide Chemicals & Plastics Technology Corporation | Process for recovery of phosphorus ligand from vaporized aldehyde |
| US4567302A (en) | 1984-07-20 | 1986-01-28 | Angus Chemical | Polymeric quaternary ammonium salts possessing antimicrobial activity and methods for preparation and use thereof |
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| US4668651A (en) | 1985-09-05 | 1987-05-26 | Union Carbide Corporation | Transition metal complex catalyzed processes |
| US4774361A (en) * | 1986-05-20 | 1988-09-27 | Union Carbide Corporation | Transition metal complex catalyzed reactions |
| US4835299A (en) | 1987-03-31 | 1989-05-30 | Union Carbide Corporation | Process for purifying tertiary organophosphites |
| US5113022A (en) | 1988-08-05 | 1992-05-12 | Union Carbide Chemicals & Plastics Technology Corporation | Ionic phosphites used in homogeneous transition metal catalyzed processes |
| US5001274A (en) | 1989-06-23 | 1991-03-19 | Union Carbide Chemicals And Plastics Company Inc. | Hydroformylation process |
| US5277532A (en) | 1989-07-31 | 1994-01-11 | Cefin S.P.A. | Mechanical acceleration device in can welding machines |
| DE4026406A1 (de) | 1990-08-21 | 1992-02-27 | Basf Ag | Rhodiumhydroformylierungskatalysatoren mit bis-phosphit-liganden |
| US5179055A (en) | 1990-09-24 | 1993-01-12 | New York University | Cationic rhodium bis(dioxaphosphorus heterocycle) complexes and their use in the branched product regioselective hydroformylation of olefins |
| US5102505A (en) | 1990-11-09 | 1992-04-07 | Union Carbide Chemicals & Plastics Technology Corporation | Mixed aldehyde product separation by distillation |
| TW213465B (enExample) | 1991-06-11 | 1993-09-21 | Mitsubishi Chemicals Co Ltd | |
| US5360938A (en) | 1991-08-21 | 1994-11-01 | Union Carbide Chemicals & Plastics Technology Corporation | Asymmetric syntheses |
| DE4204808A1 (de) | 1992-02-18 | 1993-08-19 | Basf Ag | Verfahren zur herstellung von (omega)-formylalkancarbonsaeureestern |
| US5312996A (en) | 1992-06-29 | 1994-05-17 | Union Carbide Chemicals & Plastics Technology Corporation | Hydroformylation process for producing 1,6-hexanedials |
| US5364950A (en) | 1992-09-29 | 1994-11-15 | Union Carbide Chimicals & Plastics Technology Corporation | Process for stabilizing phosphite ligands in hydroformylation reaction mixtures |
| FR2700535B1 (fr) | 1993-01-19 | 1995-04-14 | Hoechst France | Procédé continu de fabrication industrielle du diméthoxyéthanal. |
| US5426238A (en) | 1993-06-10 | 1995-06-20 | Mitsubishi Kasei Corporation | Method for producing an aldehyde |
| BE1008017A3 (nl) | 1994-01-06 | 1995-12-12 | Dsm Nv | Werkwijze voor de bereiding van 5-formylvaleriaanzure ester. |
| US5756855A (en) | 1994-08-19 | 1998-05-26 | Union Carbide Chemicals & Plastics Technology Corporation | Stabilization of phosphite ligands in hydroformylation process |
| US5648553A (en) | 1994-12-09 | 1997-07-15 | Mitsubishi Chemical Corporation | Method for producing aldehydes |
| DE19530698A1 (de) | 1995-08-21 | 1997-02-27 | Basf Ag | Verfahren zur Aufarbeitung eines flüssigen Hydroformylierungsaustrags |
| US5731472A (en) | 1995-12-06 | 1998-03-24 | Union Carbide Chemicals & Plastics Technology Corporation | Metal-ligand complex catalyzed processes |
| US5744650A (en) | 1995-12-06 | 1998-04-28 | Union Carbide Chemicals & Plastics Technology Corporation | Metal-Ligand complex catalyzed processes |
| JP3812095B2 (ja) | 1997-10-28 | 2006-08-23 | 三菱化学株式会社 | アルデヒド類の製造方法及びこれに用いるビスホスファイト |
| DE19913352A1 (de) | 1999-03-24 | 2000-09-28 | Basf Ag | Katalysator, umfassend einen Komplex eines Metalls der VIII. Nebengruppe auf Basis eines Phospinamiditliganden |
| DE10048301A1 (de) | 2000-09-29 | 2002-04-11 | Oxeno Olefinchemie Gmbh | Stabilisierung von Rhodiumkatalysatoren für die Hydroformylierung von Olefinen |
| WO2003091262A1 (en) | 2002-04-24 | 2003-11-06 | Symyx Technologies, Inc. | Bridged bi-aromatic ligands, complexes, catalysts and processes for polymerizing and poymers therefrom |
| CA2575122C (en) | 2004-08-02 | 2013-06-25 | Union Carbide Chemicals & Plastics Technology Corporation | Stabilization of a hydroformylation process |
| MY146608A (en) | 2007-03-20 | 2012-09-14 | Dow Technology Investments Llc | Hydroformylation process with improved control over product isomers |
| KR101060375B1 (ko) | 2007-05-29 | 2011-08-29 | 주식회사 엘지화학 | 하이드로포르밀화 방법 및 장치 |
| CN102143933B (zh) * | 2008-07-03 | 2014-09-17 | 陶氏技术投资有限公司 | 控制再循环催化剂料流中重物质的方法 |
| KR101310552B1 (ko) | 2010-04-20 | 2013-09-23 | 주식회사 엘지화학 | 올레핀의 하이드로포르밀화에 의한 알데히드 제조 방법 |
| EP2491062B1 (en) | 2010-05-17 | 2013-12-11 | Dow Global Technologies LLC | Process for selectively polymerizing ethylene and catalyst therefor |
| CN102826972B (zh) | 2011-06-17 | 2015-05-13 | 中国石油化工股份有限公司 | 一种烯烃氢甲酰化反应制备醛的方法 |
| US9422383B2 (en) | 2011-12-20 | 2016-08-23 | Dow Global Technologies Llc | Ethylene/alpha-olefin/nonconjugated polyene interpolymers and processes to form the same |
| DE102012223572A1 (de) | 2012-12-18 | 2014-06-18 | Evonik Industries Ag | Steuerung der Viskosität von Reaktionslösungen in Hydroformylierungverfahren |
-
2015
- 2015-11-08 MY MYPI2017000834A patent/MY184826A/en unknown
- 2015-11-18 CN CN201580064234.5A patent/CN107001218B/zh active Active
- 2015-11-18 US US15/522,137 patent/US10023516B2/en active Active
- 2015-11-18 PL PL15801645T patent/PL3230248T3/pl unknown
- 2015-11-18 RU RU2017121307A patent/RU2699368C2/ru active
- 2015-11-18 KR KR1020177016356A patent/KR102507703B1/ko active Active
- 2015-11-18 CA CA2969527A patent/CA2969527C/en active Active
- 2015-11-18 JP JP2017529301A patent/JP7128622B2/ja active Active
- 2015-11-18 WO PCT/US2015/061332 patent/WO2016089602A1/en not_active Ceased
- 2015-11-18 EP EP15801645.1A patent/EP3230248B1/en active Active
- 2015-11-18 MX MX2017006792A patent/MX381950B/es unknown
- 2015-11-18 BR BR112017011447-0A patent/BR112017011447B1/pt active IP Right Grant
- 2015-11-25 TW TW104139257A patent/TWI586644B/zh active
-
2020
- 2020-09-25 JP JP2020160278A patent/JP2021008477A/ja active Pending
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