KR102507703B1 - 하이드로포르밀화 공정 - Google Patents

하이드로포르밀화 공정 Download PDF

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KR102507703B1
KR102507703B1 KR1020177016356A KR20177016356A KR102507703B1 KR 102507703 B1 KR102507703 B1 KR 102507703B1 KR 1020177016356 A KR1020177016356 A KR 1020177016356A KR 20177016356 A KR20177016356 A KR 20177016356A KR 102507703 B1 KR102507703 B1 KR 102507703B1
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vaporizer
stream
catalyst
kpa
rhodium
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KR20170093152A (ko
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마이클 에이. 브래머
조지 알. 필립스
토마스 씨. 아이젠슈미드
얼빈 비. 콕스
로버트 해터리
미카엘 존 베인브리지
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다우 테크놀로지 인베스트먼츠 엘엘씨.
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    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/185Phosphites ((RO)3P), their isomeric phosphonates (R(RO)2P=O) and RO-substitution derivatives thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22Organic complexes
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/78Separation; Purification; Stabilisation; Use of additives
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C47/00Compounds having —CHO groups
    • C07C47/02Saturated compounds having —CHO groups bound to acyclic carbon atoms or to hydrogen
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00002Chemical plants
    • B01J2219/00027Process aspects
    • B01J2219/00033Continuous processes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32Addition reactions to C=C or C-C triple bonds
    • B01J2231/321Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82Metals of the platinum group
    • B01J2531/822Rhodium

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
KR1020177016356A 2014-12-04 2015-11-18 하이드로포르밀화 공정 Active KR102507703B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201462087572P 2014-12-04 2014-12-04
US62/087,572 2014-12-04
PCT/US2015/061332 WO2016089602A1 (en) 2014-12-04 2015-11-18 Hydroformylation process

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KR20170093152A KR20170093152A (ko) 2017-08-14
KR102507703B1 true KR102507703B1 (ko) 2023-03-09

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US (1) US10023516B2 (enExample)
EP (1) EP3230248B1 (enExample)
JP (2) JP7128622B2 (enExample)
KR (1) KR102507703B1 (enExample)
CN (1) CN107001218B (enExample)
BR (1) BR112017011447B1 (enExample)
CA (1) CA2969527C (enExample)
MX (1) MX381950B (enExample)
MY (1) MY184826A (enExample)
PL (1) PL3230248T3 (enExample)
RU (1) RU2699368C2 (enExample)
TW (1) TWI586644B (enExample)
WO (1) WO2016089602A1 (enExample)

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CN112403401B (zh) * 2020-11-06 2022-06-21 中国海洋石油集团有限公司 一种烯烃氢甲酰化制醛中醛和催化剂分离的装置和方法
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JP2024536286A (ja) 2021-10-06 2024-10-04 ダウ グローバル テクノロジーズ エルエルシー プロピルイミン官能性有機ケイ素化合物及び一級アミノプロピル官能性有機ケイ素化合物の調製
KR20240074835A (ko) 2021-10-06 2024-05-28 다우 글로벌 테크놀로지스 엘엘씨 아미노-작용성 유기규소 화합물의 제조
CN118019747A (zh) 2021-10-06 2024-05-10 陶氏环球技术有限责任公司 丙基亚胺官能化有机硅化合物和伯氨基丙基官能化有机硅化合物的制备
JP2024543330A (ja) 2021-11-11 2024-11-21 ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー ヒドロホルミル化プロセスからロジウムを回収するためのプロセス
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JP2024545133A (ja) 2021-12-16 2024-12-05 ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー 化合物、そのような化合物を含む遷移金属錯体ヒドロホルミル化触媒前駆体組成物、及びヒドロホルミル化プロセス
JP2025509182A (ja) 2022-03-21 2025-04-11 ダウ グローバル テクノロジーズ エルエルシー カルボキシ官能性を有する有機ケイ素化合物の調製
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KR20250021433A (ko) 2022-04-13 2025-02-13 다우 글로벌 테크놀로지스 엘엘씨 비닐에스테르 관능성을 갖는 유기규소 화합물의 제조
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CA2969527C (en) 2023-08-22
JP2021008477A (ja) 2021-01-28
WO2016089602A1 (en) 2016-06-09
US10023516B2 (en) 2018-07-17
CN107001218B (zh) 2021-02-26
TW201620863A (zh) 2016-06-16
US20170355656A1 (en) 2017-12-14
RU2017121307A3 (enExample) 2019-02-01
BR112017011447A2 (pt) 2018-02-27
MX2017006792A (es) 2017-09-08
CA2969527A1 (en) 2016-06-09
EP3230248A1 (en) 2017-10-18
JP7128622B2 (ja) 2022-08-31
JP2017537918A (ja) 2017-12-21
EP3230248B1 (en) 2019-12-25
RU2699368C2 (ru) 2019-09-05
KR20170093152A (ko) 2017-08-14
TWI586644B (zh) 2017-06-11
MY184826A (en) 2021-04-24
CN107001218A (zh) 2017-08-01
RU2017121307A (ru) 2018-12-19
MX381950B (es) 2025-03-13
PL3230248T3 (pl) 2020-05-18
BR112017011447B1 (pt) 2020-12-15

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